JPS6049115B2 - Transfer material - Google Patents
Transfer materialInfo
- Publication number
- JPS6049115B2 JPS6049115B2 JP14641877A JP14641877A JPS6049115B2 JP S6049115 B2 JPS6049115 B2 JP S6049115B2 JP 14641877 A JP14641877 A JP 14641877A JP 14641877 A JP14641877 A JP 14641877A JP S6049115 B2 JPS6049115 B2 JP S6049115B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- transferable
- base sheet
- pattern layer
- transfer material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Description
【発明の詳細な説明】
本発明は、転写材に関するものてあり、その目的とす
るところは、部分、的に異る金属光沢を有し、該金属光
沢の異る部分に完全に見当合せのされた着色が行われて
いる転写材を提供するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a transfer material, and an object of the present invention is to provide a transfer material having different metallic luster in different parts, and to completely register the different parts of the metallic luster. The present invention provides a transfer material that has been colored in a certain manner.
従来、部分的に異る金属光沢を有する転写材としては
、マット加工、ヘアーライン加工等の凹凸加工を部分的
に施した基体シートに剥離層、金属蒸着層、接着層を順
次設けた転写材等が知られている。Conventionally, transfer materials with partially different metallic luster include transfer materials in which a release layer, a metal vapor deposition layer, and an adhesive layer are sequentially provided on a base sheet that has been partially subjected to uneven processing such as matte processing or hairline processing. It has been known.
又、部分的に表面凹凸および表面光沢を異にする転写材
としては、基体シートに艶消し層、れ■、Ｊ−ＬＬに＝
ｉｍｋ亡Ａマ おケう七Ｅヨ゛１、ｉ；、’Ａｐ壬几′
↓、ｊ、一本＝ｑゴ＋＋Δケよｓ 知られている。 し
かしながら、これらの転写材では、いずれも部分的に異
る金属光沢、或いは部分的に異る表面光沢を被転写体表
面に転写することは可能であるが、該金属光沢或いは表
面光沢の異る部分と完全に見当合せのされた着色模様を
被転写体表面に転写することは不可能であつた。In addition, as a transfer material with partially different surface unevenness and surface gloss, there is a matte layer on the base sheet, and J-LL =
imk dead Ama okay 7Eyo 1, i;, 'Ap 壬几'
↓, j, one piece = q go + + Δkeyos is known. However, with these transfer materials, it is possible to transfer partially different metallic luster or partially different surface gloss to the surface of the transferred object; It was not possible to transfer a colored pattern that was completely in register to the surface of the receiver.
つまり、前記の層構成の転写材で本発明の目的を達成す
る為には、基体シート上に非転写性艶消し層、剥離層、
図柄層、金属蒸着層、接着層を順次積層した転写材を使
用し、非転写性艶消し層と図柄層とを完全に見当合せし
て印刷する、所謂「毛抜き合せ印刷」、必要があるが、
これは印刷技術的に非常に困難なものであつた。したが
つて、転写材の意匠は限定されたものであつた。 本発
明は、係る従来法の欠点を除去した新規な転写材である
。In other words, in order to achieve the purpose of the present invention with a transfer material having the above-described layer structure, a non-transferable matte layer, a release layer, a release layer,
It is necessary to use a transfer material in which a pattern layer, a metal vapor deposition layer, and an adhesive layer are sequentially laminated, and to print with the non-transferable matte layer and pattern layer perfectly registered, which is called "tweezing combination printing." ,
This was extremely difficult in terms of printing technology. Therefore, the designs of transfer materials were limited. The present invention is a novel transfer material that eliminates the drawbacks of the conventional method.
即ち、本発明の転写材は、艶消し加工を施した基体シ
ート上に該基体シートと接着性を有し熱移・行性又は溶
剤ブリード性の着色剤を含む非転写性図柄層を設け、該
非転写性図柄層上に基体シート及ひ非転写性図柄層と剥
離性を有し加熱時又は剥離層印刷時に前記着色剤により
着色可能な剥離層を設け、その上に金属蒸着層を設け、
更にその上・に接着層を設けた構成、或いは光沢を有す
る基体シート上に該基体シートと接着性を有し熱移行性
又は溶剤ブリード性の着色剤と艶消剤とを含む非転写性
図柄層を設け、該非転写性図柄層上に基体シート及ひ非
転写性図柄層と剥離性を有し加熱時′又は剥離層印刷時
に前記着色剤により着色可能な剥離層を設け、その上に
金属蒸着層を設け、更にその上に接着層を設けた構成よ
りなる転写材である。That is, the transfer material of the present invention provides a non-transferable pattern layer on a matte-treated base sheet, which has adhesive properties with the base sheet and contains a heat-transferable or solvent-bleeding colorant, On the non-transferable pattern layer, a release layer is provided which has releasability from the base sheet and the non-transferable pattern layer and can be colored with the colorant during heating or release layer printing, and a metal vapor deposited layer is provided thereon,
Further, an adhesive layer is provided thereon, or a non-transferable pattern containing a glossy base sheet and a heat-transferable or solvent-bleedable coloring agent and a matting agent that are adhesive to the base sheet. A layer is provided on the non-transferable pattern layer, and a release layer is provided on the non-transferable pattern layer, which has peelability from the base sheet and the non-transferable pattern layer and can be colored with the coloring agent when heated or when printing the release layer, This transfer material has a structure in which a vapor-deposited layer is provided and an adhesive layer is further provided on top of the vapor-deposited layer.
本発明に使用できる艶消し加工した基体シートとしては
、ポリエステル、ポリプロピレン、ポリアミド等のフィ
ルム或いはこれらと紙の複合体の表面にサンドプラス、
ブラッシング処理等を施したもの、キャスティングマッ
ト加工等を施したフィルム、或いは艶消し層をコーティ
ングにより施したフィルム等を挙げることができる。The matte-treated base sheet that can be used in the present invention includes Sandplus,
Examples include films that have been subjected to brushing treatment, etc., films that have been subjected to casting matte treatment, and films that have been coated with a matte layer.
又、光沢性を有する基体シートとしては、紙、フィルム
或いはこれの複合体を使用することができる。Further, as the glossy base sheet, paper, film, or a composite thereof can be used.
非転写性図柄層に使用する樹脂バインダーとしては耐熱
性を有し、基体シートと十分な接着性を有する樹脂を選
択して使用するのが好ましい。As the resin binder used in the non-transferable pattern layer, it is preferable to select and use a resin that has heat resistance and sufficient adhesion to the base sheet.
これらの樹脂としては酢酸セルロース、酢酸酩酸セルロ
ース、プロピオン酸セルロース、エチルセルロース等の
繊維素樹脂、硬化性ウレタン樹脂、エポキシ樹脂等が使
用できる。非転写性図柄層に混入することのできる艶消
剤としては０．５μ〜３ｐ程度の粒子径をもつシリカ、
カオリン、炭酸マグネシウム等の体質顔料を使用できる
。As these resins, cellulose resins such as cellulose acetate, cellulose acetate, cellulose propionate, and ethyl cellulose, curable urethane resins, and epoxy resins can be used. Examples of matting agents that can be mixed into the non-transferable pattern layer include silica with a particle size of about 0.5μ to 3p;
Extender pigments such as kaolin and magnesium carbonate can be used.
非転写性図柄層に含まれる熱移行性又は溶剤ブリード性
の着色剤としては、分散染料、硫化染料、油溶性染料等
を挙げることができる。Examples of the heat-transferable or solvent-bleedable colorant contained in the non-transferable pattern layer include disperse dyes, sulfur dyes, and oil-soluble dyes.
これらの着色剤は、転写材を被転写体に重ね合せ加熱す
る時に非転写性図柄層から剥離層へ移行するか、もしく
は、基体シート上に非転写性図柄層を設．け、更に剥離
層を印刷する時に剥離層となるインキ中に含まれている
溶剤によりブリードする。したがつて非転写性図柄層の
印刷された部分の剥離層のみを着色するものてある。剥
離層に使用する非転写性図柄層及ひ基体シー．トと剥離
性を有する樹脂としては、アクリル系樹脂、含ハロゲン
系樹脂、ジエン系樹脂等の樹脂及びこれらの樹脂との共
重合物を使用することができる。These colorants are transferred from the non-transferable pattern layer to the release layer when the transfer material is placed on the transfer target and heated, or when a non-transferable pattern layer is provided on the base sheet. Furthermore, when the release layer is printed, it bleeds due to the solvent contained in the ink that becomes the release layer. Therefore, there is a method in which only the peeling layer of the printed portion of the non-transferable pattern layer is colored. Non-transferable pattern layer and base sheet used for release layer. As the resin that has removability, it is possible to use resins such as acrylic resins, halogen-containing resins, diene resins, and copolymers with these resins.
該剥離層は、転写材を被転写体に重ね合せ加熱する時に
非転写性図柄層中に含まれる熱移行・性着色剤により、
非転写性図柄層に対応した部分が着色されるが、又は剥
離層の印刷時に剥離層インキ成分中に含まれる溶剤によ
り非転写性図柄層中に含まれる溶剤ブリード性着色剤が
非転写性図柄層に対応した部分をブリードして着色する
。尚、前記加熱は転写時の熱を利用するか、或いは転写
前の適宜の手段による。金属蒸着層は、アルミニウム等
の金属を真空蒸着法等の方法により設けることができる
。The peeling layer is formed by the heat-transferable coloring agent contained in the non-transferable pattern layer when the transfer material is superimposed on the object to be transferred and heated.
The area corresponding to the non-transferable pattern layer is colored, or when the release layer is printed, the solvent bleed colorant contained in the non-transferable pattern layer is removed by the solvent contained in the ink component of the release layer. Bleed and color the parts corresponding to the layers. The heating may be performed using heat during transfer, or by appropriate means before transfer. The metal vapor deposition layer can be formed using a metal such as aluminum by a method such as a vacuum vapor deposition method.
接着層に使用する樹脂としては、被転写体に十分な接着
性を有する樹脂を適宜選択して使用することができる。As the resin used for the adhesive layer, a resin having sufficient adhesion to the transfer target can be appropriately selected and used.
例えば、アクリル系樹脂、酢酸ビニル塩化ビニル共重合
体等がある。ノ 尚、接着層と金属蒸着層との接着性が
とぼしい際には、これら両層と接着力を有する樹脂をア
ンカーコート層として設けることができる。Examples include acrylic resins, vinyl acetate vinyl chloride copolymers, and the like. In addition, when the adhesiveness between the adhesive layer and the metal vapor deposition layer is poor, a resin having adhesive strength with both these layers can be provided as an anchor coat layer.
以上、説明した如く、本発明の転写材は、艶消し加工を
施した基体シート上に該基体シートと接・着性を有し熱
移行性又は溶剤ブリード性の着色剤を含む非転写性図柄
層を設けるか、又は光沢を有する基体シート上に該基体
シートと接着性を有し熱移行性又は溶剤ブリード性の着
色剤と艶消剤とを含む非転写性図柄層を設け、更に該非
転写性図”柄層上に基体シート及び非転写性図柄層と剥
離性を有し前記着色剤により着色可能な剥離層を設け、
加熱時に非転写性図柄層中に含まれる熱移行性着色剤が
剥離層へ移行又は剥離層印刷時に非転写性図柄層中に含
まれる溶剤ブリード性着色剤が剥離層へブリードする層
構成としているので、金属光沢の異る部分と完全に見当
の合つた着色模様とがどの様な模様であつても表現可能
であり、意匠効果のすぐれた転写模様が被転写体に転写
できるものである。As explained above, the transfer material of the present invention has a non-transferable pattern on a matte-treated base sheet that has adhesion to the base sheet and contains a heat-transferable or solvent-bleedable colorant. or provide a non-transferable pattern layer on a glossy base sheet, which has adhesive properties with the base sheet and includes a heat-transferable or solvent-bleedable coloring agent and a matting agent, and further provides the non-transferable pattern layer on the base sheet having gloss. A peeling layer that is releasable from the base sheet and the non-transferable pattern layer and can be colored with the colorant is provided on the pattern layer,
The layer structure is such that the heat-transferable colorant contained in the non-transferable pattern layer migrates to the release layer when heated, or the solvent-bleedable colorant contained in the non-transferable pattern layer bleeds to the release layer when the release layer is printed. Therefore, it is possible to express any pattern with a colored pattern in which parts with different metallic luster are completely in register, and a transferred pattern with excellent design effect can be transferred onto the transferred object.
実施例１
ポリエステルキヤステングマツトフイルム（２１μ厚）
に下記組成（イ）のインキを用て非転写性図柄層を設け
、次に組成（口）のインキを全面にグラビア印刷して剥
離層を設けた後、アルミニウム蒸着を行い金属蒸着層を
設け、更に下記組成（ハ）のインキをグラビア印刷し接
着層を全面に設けた転写材を得た。Example 1 Polyester cast matte film (21μ thickness)
A non-transferable pattern layer is formed using an ink with the following composition (A), and then an ink with the composition (A) is gravure printed on the entire surface to form a release layer, and then aluminum vapor deposition is performed to form a metal vapor deposition layer. Further, an ink having the following composition (c) was gravure printed to obtain a transfer material provided with an adhesive layer over the entire surface.
（イ）
（重量部） 硝酸
セルロース ２０セリトンイエロ
ーＳＦ７８６３（ＢＡＳＦ） １０エチルアルコー
ル ２０酢酸エチル
３０トルエン
２０（ロ）（ ■ （三菱 ）
（ハ）
（重量部）「 惜
共二Ａ二この転写材を用いてスチロール成型物に２３０
′Ｃて２中間加熱加圧しフィルムを除去したところ、図
柄部分か艶状金光沢を有し、他の部分が艶消し状銀光沢
を有する転写絵付ができた。(A) (Parts by weight) Cellulose nitrate 20 Seriton Yellow SF7863 (BASF) 10 Ethyl alcohol 20 Ethyl acetate
30 toluene
20 (B) (■ (Mitsubishi) (C) (Weight part)
Use this transfer material to print styrene molded products at 230
When the film was removed by heating and pressing for two intermediate periods, a transferred painting was obtained in which the design part had a glossy golden luster and the other parts had a matte silver luster.
実施例２
表面光沢のセロハン（６０幡）に下記組成（ニ）のイン
キを用いて艶消し状非転写性図柄層を設け、次に実施例
１と同様のインキを全面にグラビア印刷し剥離層を設け
た後、アルミニウム蒸着を行い金属蒸着層を設け、更に
実施例１と同様のインキをクラヒア印刷し装着層を全面
に設け転写材を得た。Example 2 A matte non-transferable pattern layer was provided on cellophane (60 square meters) with a glossy surface using an ink with the following composition (d), and then the same ink as in Example 1 was gravure printed on the entire surface to form a release layer. After that, aluminum was vapor-deposited to form a metal vapor-deposited layer, and then the same ink as in Example 1 was printed using Crachia to form a mounting layer on the entire surface to obtain a transfer material.
（二）
（重量部）（Ｊｊ（←
））乞 （！；（（−・−・・）
この転写材を実施例１と同様にスチロール成型物に転写
したところ、図柄部分が艶消し状青色金属光沢を有し、
他の部分が艶状銀光沢を有する転写絵付ができた。(2) (Parts by weight) (Jj(←
)) (!;((-・-・・) When this transfer material was transferred to a styrene molded product in the same manner as in Example 1, the design part had a matte blue metallic luster.
A transfer painting was created in which other parts had a glossy silver luster.
実施例３
実施例１の熱移行性着色剤の代りに溶剤ブリード性着色
剤として、ビクトリアブルーＦ４Ｒ（ＢＡＳＦ）を使用
して実施例１に従つて転写材を作成し、転写絵付を行つ
た所、図柄部分が艶状青色金属光沢を有し、他の部分が
艶消し状銀光沢を有する転写絵付ができた。Example 3 A transfer material was prepared according to Example 1 using Victoria Blue F4R (BASF) as a solvent bleed colorant instead of the heat transferable colorant of Example 1, and transfer painting was performed. A transfer painting was created in which the design part had a glossy blue metallic luster and the other parts had a matte silver luster.
実施例４
実施例２の着色剤の代りに溶剤ブリード性着色剤として
スーダンブルー■（ＢＡＳＦ）を使用して転写材を実施
例２に従つて作成し、転写絵付をしたところ、実施例２
と同様の転写絵付ができた。Example 4 A transfer material was prepared according to Example 2 using Sudan Blue ■ (BASF) as a solvent-bleedable colorant in place of the colorant in Example 2, and transfer painting was applied.
A transfer painting similar to that was created.
第１図及び第３図は本発明による転写材の断面図を示す
。
第２図及び第４図は、本発明による転写材の転写工程で
の断面図を示す。図中、１は艶消し状基体シート、１″
は、光沢を有する基体シート、２は、非転写性図柄層、
２″は、艶消し状非転写性図柄層、３は、剥離層、４は
、金属蒸着層、５は、接着層、６は、アンカーコート層
、７は被転写体。1 and 3 show cross-sectional views of a transfer material according to the present invention. FIGS. 2 and 4 show cross-sectional views of the transfer material according to the present invention during the transfer process. In the figure, 1 is a matte base sheet, 1″
2 is a glossy base sheet; 2 is a non-transferable pattern layer;
2'' is a matte non-transferable pattern layer, 3 is a release layer, 4 is a metal vapor deposition layer, 5 is an adhesive layer, 6 is an anchor coat layer, and 7 is a transfer target.
Claims (1)
接着性を有しかつ熱移行性又は溶剤ブリード性の着色剤
を含む非転写性図柄層を設け、該非転写性図柄層上に基
体シート及び非転写性図柄層と剥離性を有し加熱時又は
剥離層印刷時に前記着色剤による着色可能な剥離層を設
け、その上に金属蒸着層を設け、更にその上に接着層を
設けてなることを特徴とする転写材。 ２ 光沢を有する基体シート上に該基体シートと接着性
を有し熱移行性又は溶剤ブリード性の着色剤と艶消し剤
とを含む非転写性図柄層を設け、該非転写性図柄層上に
基体シート及び非転写性図柄層と剥離性を有し、加熱時
又は剥離層印刷時に前記着色剤により着色可能な剥離層
を設け、その上に金属蒸着層を設け、更にその上に接着
層を設けてなることを特徴とする転写材。[Scope of Claims] 1. A non-transferable pattern layer having adhesive properties with the base sheet and containing a heat-transferable or solvent-bleeding colorant is provided on a matte-treated base sheet, On the pattern layer, a release layer is provided which has peelability from the base sheet and the non-transferable pattern layer and can be colored with the colorant during heating or release layer printing, and a metal vapor deposition layer is provided on top of the release layer, A transfer material characterized by being provided with an adhesive layer. 2. A non-transferable pattern layer having adhesive properties with the base sheet and containing a heat-transferable or solvent-bleedable coloring agent and a matting agent is provided on a glossy base sheet, and a non-transferable pattern layer is provided on the non-transferable pattern layer. A release layer is provided that has releasability from the sheet and the non-transferable pattern layer and can be colored with the colorant during heating or release layer printing, a metal vapor deposition layer is provided on top of the release layer, and an adhesive layer is further provided on top of the release layer. A transfer material that is characterized by the ability to
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14641877A JPS6049115B2 (en) | 1977-12-05 | 1977-12-05 | Transfer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14641877A JPS6049115B2 (en) | 1977-12-05 | 1977-12-05 | Transfer material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5479706A JPS5479706A (en) | 1979-06-26 |
| JPS6049115B2 true JPS6049115B2 (en) | 1985-10-31 |
Family
ID=15407230
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14641877A Expired JPS6049115B2 (en) | 1977-12-05 | 1977-12-05 | Transfer material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6049115B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0228062Y2 (en) * | 1980-07-09 | 1990-07-27 | ||
| JPS59178661U (en) * | 1983-05-13 | 1984-11-29 | 大日本印刷株式会社 | hologram products |
| JPH0661999B2 (en) * | 1984-11-15 | 1994-08-17 | 味の素株式会社 | Transfer printing film for retort |
| JPH0790679B2 (en) * | 1986-12-25 | 1995-10-04 | 日本写真印刷株式会社 | Transfer material capable of expressing glossy surface and uneven surface and manufacturing method thereof |
| JPS63260484A (en) * | 1987-04-17 | 1988-10-27 | Nissha Printing Co Ltd | Partial dull-finished transfer material |
| JPH02151478A (en) * | 1988-12-05 | 1990-06-11 | Ube Ind Ltd | Preparation of material or molded product having pattern |
| JPH0444396Y2 (en) * | 1990-03-29 | 1992-10-20 |
-
1977
- 1977-12-05 JP JP14641877A patent/JPS6049115B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5479706A (en) | 1979-06-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6277229B1 (en) | Image transfer sheets and a method of manufacturing the same | |
| US7854965B2 (en) | Method of forming images or decorations on a support body | |
| US4012552A (en) | Decorative metal film heat transfer decalcomania | |
| JPS6049115B2 (en) | Transfer material | |
| JPS6040399B2 (en) | Manufacturing method of partially vapor deposited transfer sheet | |
| JPS58114987A (en) | Transfer sheet | |
| JPH04142988A (en) | Thermal transfer cover film | |
| JPH0210000Y2 (en) | ||
| JP2000351265A (en) | Aluminum transfer vapor-deposited recording sheet and tacked recording sheet using it | |
| JP3114977B2 (en) | Thermal transfer sheet | |
| JPS6151074B2 (en) | ||
| KR20020080690A (en) | Heat transcription film by partial vacuum evaporation having a multicolor effect and the method of making it | |
| KR100479711B1 (en) | Heat transcription film transcribing gold or silver foil by partial adhesion having a transparent effect and the method of making it | |
| JPH0483700A (en) | Transfer foil | |
| JPS6160200B2 (en) | ||
| JPS597598B2 (en) | Transfer method | |
| JPS631108B2 (en) | ||
| JP2545929B2 (en) | Method for manufacturing polyester decorative board | |
| JPH0780362B2 (en) | Metal luster thermal transfer recording medium | |
| JPS63230389A (en) | Electrothermo-transfer recording medium provided with metallic luster printing | |
| JP2826735B2 (en) | Transfer foil | |
| JP3210069B2 (en) | Transfer sheet and transfer method | |
| JPS6280100A (en) | Muffle painting method to base body with vitreous or ceramicsurface | |
| JPH09123693A (en) | Transfer material and transfer matter | |
| JPH0259347A (en) | Transfer material for mat fabrication and its manufacture |