JPS604566A - Clear paint and flexible plastic - Google Patents
Clear paint and flexible plasticInfo
- Publication number
- JPS604566A JPS604566A JP11400783A JP11400783A JPS604566A JP S604566 A JPS604566 A JP S604566A JP 11400783 A JP11400783 A JP 11400783A JP 11400783 A JP11400783 A JP 11400783A JP S604566 A JPS604566 A JP S604566A
- Authority
- JP
- Japan
- Prior art keywords
- water
- transparent
- paint
- polyvinyl alcohol
- food
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は塗布したとき、全体が透明でかつ着色されてい
る透明塗料に関するものである。詳しくは、安全性の高
い透明塗料に関づるものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a transparent coating that is completely transparent and colored when applied. Specifically, it relates to highly safe transparent paints.
塗料には種々の種類があり、そのうちの１つに塗イｌｉ
シたとき物体が着色されながらかつ塗イロされた面全
体が透明となるいわゆる透明塗料がある。There are various types of paint, one of which is
There are so-called transparent paints that, when applied, color the object while making the entire painted surface transparent.
この透明塗料を透明なガラス又はプラスチック等に塗布
するとガラス等が着色されながらなおかつガラスの向う
側がづ゛き透るものである。従来、透明塗料としでは、
種々の高分子化合物から成る溶剤を使用したものが使用
されているが、このような溶剤を使用した塗料は、それ
自身有害であり、子供が使用したりＪるには危険であり
、またその用途も毒性の為制限されるものであった。ま
た従来の溶剤タイプの透明塗料を着色した後、洗い落Ｊ
には、再び溶剤を使用しなくてはならず、この洗い落し
作業もまた有害なものであった。When this transparent paint is applied to transparent glass, plastic, etc., the glass, etc. is colored, yet the other side of the glass is completely transparent. Conventionally, as transparent paint,
Paints using solvents made of various polymer compounds are used, but paints using such solvents are themselves harmful and dangerous for children to use or use. Its uses were also limited due to its toxicity. In addition, after coloring conventional solvent-based transparent paint, it can be washed off.
The solvent had to be used again, and this cleaning process was also harmful.
本発明者ｔよ、かかる従来の透明塗料の欠点を解消した
安全性の高い透明塗料を開発Ｊるため種々検討を重ねた
。その結宋、色素として食用色素を用いである種の溶媒
を組み合せて用いると安全性の極めＣ高くしかも水溶性
の透明塗料が得られることを見い出し本発明を完成した
。The inventor of the present invention has conducted various studies in order to develop a highly safe transparent paint that eliminates the drawbacks of conventional transparent paints. As a result, Sung discovered that by using food coloring in combination with a certain type of solvent, a highly safe and water-soluble transparent paint could be obtained, and the present invention was completed.
づなわち、本発明の目的は安全性が高く、且つ水溶性の
透明塗料を提供づることにありかかる目的はポリビニル
アルコール、食用色素、グリ廿すン及び水を含有するこ
とを特徴と覆る透明塗料ににり達成される。In other words, the object of the present invention is to provide a highly safe and water-soluble transparent paint, which is characterized by containing polyvinyl alcohol, food coloring, glycerin, and water. Accomplished by applying paint.
以下に、本発明の詳細な説明覆るに、本発明はポリビニ
ルアルコール、食用色素、グリセリン及び水を必須成分
とづるものである。ポリビニルアルコールとしては酢酸
ビニルを重合しｃ得られるポリＦｊｌ酸ビニルをケン化
して得られる水Ｍｌを持つビニル樹脂であり、水酸基の
みのもの（完全クン化物）、大部分水酸基（−−一部酢
酸阜が残っているものく部分ケン化物）があるが、これ
らともに使用づることができる。ポリビニルアルコール
のケシ化度は約７０〜１００の種々の５のが知られ−Ｃ
いるが、本発明ではこれらの範囲のものならば、いずれ
も使用することができる。Below is a detailed description of the present invention.The present invention includes polyvinyl alcohol, food coloring, glycerin, and water as essential components. Polyvinyl alcohol is a vinyl resin with water Ml obtained by polymerizing vinyl acetate and saponifying the resulting polyvinyl acetate. There are some partially saponified products that still have some residue, but both of these can be used. The degree of pycnicity of polyvinyl alcohol is known to vary from about 70 to 100, ranging from -C
However, in the present invention, any material within these ranges can be used.
食用色素としては、食用赤色３ ＋：５（−１リス［］
シン）、食用赤色１０２号くニューコクシン〉、食用赤
色１０５号（ロースベンガル）、食用黄色４号（タート
ラジン）、食用黄色５号（リーンレットイＩ ［：ｌ
−Ｆ ＣＦ ） 、食用肖邑１号（ブリリアンｌ−フル
ー Ｆ ＣＦ ） 、食用青色２号（インジゴカルミン
）等種々の合成色素：あるいはカロチノイド系、フラボ
ノイド系、ノラビン系、キノン系、ノＡ−ピリン系、ツ
ク１−ン系、カタシアニジン系等の天然色素が使用でさ
る。またグリはリンも通常の市販のグリセリンがそのま
ま使用覆ることができる。As food coloring, food red 3 +:5 (-1 squirrel[]
Food Red No. 102 New Coccin), Food Red No. 105 (Roast Bengal), Food Yellow No. 4 (Tartrazine), Food Yellow No. 5 (Lean Lettoi I [:l
Various synthetic pigments such as Edible Blue No. 1 (F CF), Edible Blue No. 2 (Indigo Carmine), or carotenoid, flavonoid, norabine, quinone, and NoA-pyrine types. Natural pigments such as , tsuk-1-type, catacyanidin-type, etc. can be used. In addition, glycerin and phosphorus can be covered with ordinary commercially available glycerin as is.
以上の成分の量比はポリビニルアルコールが３０〜８０
中量部、好ましくは４０〜６０千吊部、食用色素が０．
５・〜３重半部、りｒましくは０．８・〜・１．５重量
部、グリセリンが０．５〜１０小帛部、りＹましくは１
へ・３重量部、水が過員、好ましくは１００−６００重
量部、特に好ましくは２００〜５００重半部が適当であ
る。このうらグリセリンが０．５Φｍ部よりも少ないと
色素が析出する傾向があり、 ｏｒましくない。また１
０小吊部よりも多くなると生別全体がやわらかくなり好
ましくない。−に）小の成分以下にも公知の種々の添１
ｊ１１剤、例えば酸化防止剤あるいは食用色素以外の顔
１′８１等を若干添加してもよいことは当然のことであ
る。The quantitative ratio of the above components is 30 to 80 for polyvinyl alcohol.
Medium parts, preferably 40 to 60 thousand parts, food coloring 0.
5 to 3 parts by weight, preferably 0.8 to 1.5 parts by weight, 0.5 to 10 parts by weight of glycerin, preferably 1 part by weight
3 parts by weight, preferably 100 to 600 parts by weight, particularly preferably 200 to 500 parts by weight. If this amount of glycerin is less than 0.5 Φm, the dye tends to precipitate, which is not desirable. Also 1
If the number is more than 0, the whole part will become soft, which is not preferable. - to) various known additives below the small ingredients 1
It is of course possible to add a small amount of j11 agents, such as antioxidants or ingredients other than food coloring.
上述の成分よりなる本発明の透明塗料を製造りるには各
成分を混合後７０〜９０℃で約４０−６Ｏ時間撹拌混合
すると色素が析出づることがなく、ポリビニルアルコー
ルが食用色素により染色され、塗料が製造できる。この
撹欅混合時間が不充分であると、乾燥後不透明な塗料と
なりからである。To produce the transparent paint of the present invention consisting of the above-mentioned components, stirring and mixing at 70-90°C for approximately 40-60 hours after mixing each component will prevent the pigment from precipitating and the polyvinyl alcohol will be dyed with the food pigment. , paint can be manufactured. If the mixing time is insufficient, the paint will become opaque after drying.
この撹拌混合後、さらに塗料を乾燥して水分を除去する
と、樹脂が固化し、軟質のプラスチック状になる。この
固化した軟質プラスチック状物は水に溶解させるとその
まま本発明の透明塗お１となる。After stirring and mixing, the paint is further dried to remove moisture, and the resin solidifies into a soft plastic-like material. When this solidified soft plastic material is dissolved in water, it becomes the transparent coating 1 of the present invention.
軟質プラスチック状物はフィルム状にもづることができ
る。The soft plastic material can also be made into a film.
本発明透明塗料は以上のポリビニルアルコール、食用色
素、グリセリン及び水を含有づることを特徴とターるも
のである。その為極めて安全性が高く、７供でも安心し
て使用することができ又、安全性が高いので用途に制限
を受【プない。そして、この透明塗料を例えば窓ガラス
の内側に塗布すると、光は寞外から案内に入り、なおか
つガラスが着色され、あたかもステンドグラスのように
なるっまた、本発明透明塗料は水溶性Ｃあるため一旦塗
布した後も水で洗うことにＪ：り前単に除去することが
できる。なお・、耐水性を持たせるためには本ＩＦ。The transparent paint of the present invention is characterized by containing the above polyvinyl alcohol, food coloring, glycerin and water. Therefore, it is extremely safe and can be used with peace of mind even by children up to 7 years old, and there are no restrictions on its uses. When this transparent paint is applied to the inside of a window glass, for example, light enters the window from outside and the glass is colored, making it look like stained glass. Once applied, it can be easily removed before washing with water. In addition, in order to have water resistance, this IF.
明透明塗判を塗布した後に耐水性樹脂を含有づるスプレ
ーにＪ：り表面をさらにコーティングづれはよい。また
ポリビニルアルコール等の水溶性樹脂を使用した従来の
塗料は乾燥後色素が析出づるという欠点があったが、本
発明の透明塗料には析出するということはない。また前
述のように本発明透明塗料は液体の状態でなく固化した
軟質プラスチック状の形態Ｃも提供Ｊることかができ使
用１１．５この軟質プラスチックでを水で溶解づれば、
そのまま透明塗オ′３１となるため運搬にビンを入れる
必要がない。このため運搬が極めて簡単となる効果もあ
る。またフィルム状にした軟質プラスチックは、水溶性
の包装フィルムとしても使用できる。After applying the clear and transparent coating, the surface is further coated with a spray containing a water-resistant resin to prevent slippage. Further, conventional paints using water-soluble resins such as polyvinyl alcohol had the disadvantage that pigments precipitated after drying, but the transparent paint of the present invention does not cause such precipitation. In addition, as mentioned above, the transparent paint of the present invention can also be provided in the form C of a solidified soft plastic rather than in a liquid state.Use 11.5 If this soft plastic is dissolved in water,
Since it becomes a transparent coating as it is, there is no need to put a bottle in it for transportation. This also has the effect of making transportation extremely easy. Furthermore, the soft plastic made into a film can also be used as a water-soluble packaging film.
以下に実施例により本発明をさらに詳細に説明するが、
本発明はその要旨を越えない限り以下の実施例により限
定されることはない。The present invention will be explained in more detail with reference to Examples below.
The present invention is not limited by the following examples unless it exceeds the gist thereof.
実施例
ポリビニルアルコール５０ｇ、食用赤色３号１ｇ１グリ
ヒリン２ｇ、水３５０（＋を混合し８０℃で４８時間撹
拌混合したどころ透明な赤色塗料が１！１られた。この
透明赤色塗料を窓ガラスに塗布したところガラスは赤色
に着色されたが、カラスの向う側はイのまま見える透明
赤色となった。また１１χ拌混合を４８時間続り、次に
乾燥して水分を除去したところ赤色塗料は固化し軟質の
プラスブーツク形状になった。このプ、ラスデックを水
に溶解したところ、再び、赤色の透明塗料となりこの赤
色透明塗料す窓ガラスに前）ホ同様に塗布できた。塗布
した赤色塗料は一週間後水にぬらした雑１１〕で簡単に
除去づることができた。Example: 50 g of polyvinyl alcohol, 1 g of Food Red No. 3, 2 g of Glychrin, and 350 g of water were mixed and stirred at 80°C for 48 hours, resulting in a transparent red paint of 1:1.This transparent red paint was applied to a window glass. As a result, the glass was colored red, but the color on the other side of the glass was a transparent red that could be seen as is.The red paint solidified after 48 hours of 11x mixing and then drying to remove moisture. It took on the shape of a soft plush boot stick.When I dissolved this plastic in water, it turned into a red transparent paint again, and this red transparent paint could be applied to window glass in the same manner as before. After one week, the applied red paint could be easily removed with water-soaked dirt 11].
代理人 弁理士 足立 勉 ばか１名Agent: Patent Attorney Tsutomu Adachi 1 idiot
Claims (1)
水を含有づることを特徴とＪる透明Φ料。 ２ ポリビニルアルコールが３０〜８０ｍｆｆ１部、食
用色素が０．５〜３重■部、グリセリンが０゜５〜１０
重量部、水が１００〜６００ ＥＴ’ｉ ｊｆｉ部含右
されている特許請求の範囲第１項記載の透明塗料。 ３ ポリビニルアルコール、食用色素及びグリセリンを
含有することを特徴とづる着色軟質プラスチック。[Claims] 1. A transparent Φ material containing polyvinyl alcohol, food coloring, glycerin, and water. 2 1 part of polyvinyl alcohol 30-80 mff, 0.5-3 parts of food coloring, 0°5-10 parts of glycerin
The transparent paint according to claim 1, containing 100 to 600 parts by weight of water. 3. A colored soft plastic characterized by containing polyvinyl alcohol, food coloring and glycerin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11400783A JPS604566A (en) | 1983-06-23 | 1983-06-23 | Clear paint and flexible plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11400783A JPS604566A (en) | 1983-06-23 | 1983-06-23 | Clear paint and flexible plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS604566A true JPS604566A (en) | 1985-01-11 |
| JPH0339115B2 JPH0339115B2 (en) | 1991-06-12 |
Family
ID=14626717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11400783A Granted JPS604566A (en) | 1983-06-23 | 1983-06-23 | Clear paint and flexible plastic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS604566A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4215439A1 (en) * | 1992-05-11 | 1993-12-09 | Springer Eva Marie | Water based non-toxic paints for finger painting - contg. polyvinyl alcohol, glycerine, mineral thickener, non-toxic pigment and preservative |
| JPH07316488A (en) * | 1994-05-25 | 1995-12-05 | Health Kk | Composition used for painting skin or container |
| US7833471B2 (en) | 2004-08-23 | 2010-11-16 | Koyo Thermo Systems Co., Ltd. | Carburizing apparatus and carburizing method |
| WO2010064917A3 (en) * | 2008-12-05 | 2011-05-05 | Patent 06-001 B.V. | Coating for lily bulbs |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5725366A (en) * | 1980-07-22 | 1982-02-10 | Teikoku Chem Ind Corp Ltd | Composition for water-soluble surface protective film |
-
1983
- 1983-06-23 JP JP11400783A patent/JPS604566A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5725366A (en) * | 1980-07-22 | 1982-02-10 | Teikoku Chem Ind Corp Ltd | Composition for water-soluble surface protective film |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4215439A1 (en) * | 1992-05-11 | 1993-12-09 | Springer Eva Marie | Water based non-toxic paints for finger painting - contg. polyvinyl alcohol, glycerine, mineral thickener, non-toxic pigment and preservative |
| DE4215439C2 (en) * | 1992-05-11 | 2001-02-15 | Earlychildhood Com Llc Salinas | Finger paint and process for making it |
| JPH07316488A (en) * | 1994-05-25 | 1995-12-05 | Health Kk | Composition used for painting skin or container |
| US7833471B2 (en) | 2004-08-23 | 2010-11-16 | Koyo Thermo Systems Co., Ltd. | Carburizing apparatus and carburizing method |
| WO2010064917A3 (en) * | 2008-12-05 | 2011-05-05 | Patent 06-001 B.V. | Coating for lily bulbs |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0339115B2 (en) | 1991-06-12 |
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