JPS6026652A - Hot dip galvanized sheet for press - Google Patents

Hot dip galvanized sheet for press

Info

Publication number
JPS6026652A
JPS6026652A JP58133600A JP13360083A JPS6026652A JP S6026652 A JPS6026652 A JP S6026652A JP 58133600 A JP58133600 A JP 58133600A JP 13360083 A JP13360083 A JP 13360083A JP S6026652 A JPS6026652 A JP S6026652A
Authority
JP
Japan
Prior art keywords
layer
galvanized sheet
sheet
dip galvanized
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58133600A
Other languages
Japanese (ja)
Inventor
Takeshi Sekiya
関屋 武之
Tetsuo Miki
三木 徹夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP58133600A priority Critical patent/JPS6026652A/en
Publication of JPS6026652A publication Critical patent/JPS6026652A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Abstract

PURPOSE:To prevent surely the formation of dent marks on dies during the press working of a galvanized sheet by specifying the amount of Fe in a layer ranging from the surface of an alloy layer along the boundary between each zinc layer of the galvanized sheet and the iron base to a position just below the zinc layer. CONSTITUTION:The amount of Fe in a layer ranging from the surface of an alloy layer along the boundary between each zing layer of a galvanized sheet and the iron base to a position just below the zinc layer is regulated to 1-6% within the range of about 40-70% of the thickness of the zinc layer. A galvanized sheet having said Fe content can be easily manufactured by adding 0.07-0.16% Al to a Zn bath for hot dipping, heating a sheet to a relatively high temp. such as about 500-540 deg.C, and introducing the sheet into the bath.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、プレス加工用溶融亜鉛メッキ鋼板に関するも
のである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a hot-dip galvanized steel sheet for press working.

〔従来技術〕[Prior art]

溶融亜鉛メッキ鋼板のプレス加工(成形)に際しては、
金型に亜鉛が付着するのを防止するため、潤滑性の高い
プレス油を用いてプレス加工を施すものである。
When press working (forming) hot-dip galvanized steel sheets,
In order to prevent zinc from adhering to the mold, press processing is performed using press oil with high lubricating properties.

〔従来技術の欠点〕[Disadvantages of conventional technology]

溶融亜鉛メッキ鋼板のメッキ層はメッキ原板の地鉄(素
地)とメッキ層の境界に約3μm以下の厚みのFe−Z
n合金層(Fe量約30%)が形成され、残り表面部は
大部分はほとんど亜鉛金属単味であり、従って軟く固着
性の大きいものであって。
The plating layer of the hot-dip galvanized steel sheet has a Fe-Z layer with a thickness of approximately 3 μm or less at the boundary between the base iron (base material) of the plated original plate and the plating layer.
An n-alloy layer (Fe content of about 30%) is formed, and the rest of the surface is mostly made of zinc metal, and is therefore soft and highly adhesive.

プレス加工時に振売が入り易く、流部の亜鉛が金型に付
着(固着)して抑流となり1品質を著しく低下させる等
の欠点をともなうものである。
It is accompanied by drawbacks such as the tendency for sagging to occur during press working, and the zinc in the flow part to adhere (fix) to the mold, resulting in flow restriction and a significant deterioration in quality.

〔発明の構成〕[Structure of the invention]

本発明は、このような欠点を有利に解決するためなされ
たものであり、その特徴とするところは。
The present invention has been made to advantageously solve these drawbacks, and its features are as follows.

亜鉛メッキ鋼板のメッキ層と原板鉄素地境界の合金層表
面からメッキ層表面直下までのFe量を1〜6φ含有せ
しめた。プレス加工用溶融亜鉛メッキ鋼板に関するもの
である。
The amount of Fe contained from the surface of the alloy layer at the boundary between the plating layer of the galvanized steel sheet and the iron substrate of the original sheet to just below the surface of the plating layer was 1 to 6φ. This invention relates to hot-dip galvanized steel sheets for press working.

即ちメッキ層表面直下としては、メッキ層厚み方向40
〜70%厚までの範囲つまり、メッキ層表面直下までを
1〜6φのFe量を含有さぜればよく、70φ以上にな
るとメッキ層表面に一部合金層が生成し、亜鉛メッキ鋼
板特有の光沢がなくなり、又犠牲電極効果による防錆効
果が低下し裸耐食性が劣り、好ましくない。
That is, immediately below the surface of the plating layer, 40 in the thickness direction of the plating layer
~70% thickness, that is, just below the surface of the plating layer, it is sufficient to contain an amount of Fe of 1 to 6 φ.If the thickness exceeds 70 φ, a part of the alloy layer will be formed on the surface of the plating layer, which is unique to galvanized steel sheets. It is undesirable because it loses its luster, and the rust prevention effect due to the sacrificial electrode effect decreases, resulting in poor bare corrosion resistance.

又約40%未満のメッキ層の下層部で合金化してもほと
んど効果はない。
Also, alloying in the lower layer of less than about 40% of the plating layer has little effect.

次に合金層としては前記のごとく、Fe量を1〜5%に
するものであるが、1襲以下では、効果がなく、約5%
以上になると、耐食性が劣化するととがちり、又製造上
メッキ層表面部近傍まで合金化が進むことがあシ、外観
上好捷しくない。このような亜鉛メッキ鋼板の製造法と
しては1例えば。
Next, as mentioned above, the alloy layer is made to have an Fe content of 1 to 5%, but if it is less than 1 attack, it is ineffective, and the Fe content is about 5%.
If the corrosion resistance deteriorates, the corrosion resistance may deteriorate, and alloying may progress to the vicinity of the surface of the plating layer during manufacturing, which is unsatisfactory in terms of appearance. For example, there is one method for manufacturing such a galvanized steel sheet.

熱漬メンキ浴のZn浴中にAεを0.07〜0.16%
添加し、俗人へ導入するメッキ原板の温度を500〜5
40℃と高めにすることにより容易に製造することがで
きる。又メッキ後合金化炉へ導き加熱する方法もとり得
ることができる。
Add 0.07 to 0.16% Aε in the Zn bath of the hot pickled menki bath.
The temperature of the plated original plate to be added and introduced to the public is 500~5.
It can be easily produced by increasing the temperature to 40°C. It is also possible to introduce the material into an alloying furnace and heat it after plating.

このような本発明は1両面溶融亜鉛メッキ鋼板。The present invention is a single-sided hot-dip galvanized steel sheet.

片面溶融亜鉛メッキ鋼板1片面溶融亜鉛メッキ。One side hot-dip galvanized steel sheet One side hot-dip galvanized.

他面合金化亜鉛メッキ鋼板等に適用できるものである。On the other hand, it can be applied to alloyed galvanized steel sheets, etc.

即ち、プレス加工時、金型でのカジリ等によりメッキ金
属が機械的に剥離するが1通常(従来)のメッキ鋼板に
おいては、カジリによって、剥離した亜鉛が柔く粘着性
があり、剥離亜鉛どうしが互に凝集して大きな粒子とな
って金型に付着し。
In other words, during press working, the plated metal peels off mechanically due to galling in the die, etc.1 However, in normal (conventional) plated steel sheets, due to galling, the peeled zinc becomes soft and sticky, and the peeled zinc does not stick to each other. The particles aggregate with each other to form large particles that adhere to the mold.

これがプレスの抑流となる。This acts as a restraint on the press.

〔作用〕[Effect]

しかして本発明によれば、前記のごとく構成しており、
純亜鉛層が薄く、メッキ層が硬くなっており、カジリに
より剥離しにりく、又剥離しても亜鉛片は1粒着性が低
く、大きな粒子にはならず。
However, according to the present invention, configured as described above,
The pure zinc layer is thin and the plating layer is hard, making it difficult to peel off due to galling, and even when peeled off, the zinc flakes have low adhesion and do not become large particles.

金型にも固着しないものと認められ、結果として抑流の
発生を確実に防止できるものである。
It is recognized that it does not stick to the mold, and as a result, it is possible to reliably prevent the occurrence of flow restriction.

〔発明の効果〕〔Effect of the invention〕

プレス加工時に金型へ亜鉛メッキ金属の付着がほとんど
なくなり、溶融亜鉛メッキ鋼板の品質。
There is almost no adhesion of galvanized metal to the mold during stamping, which improves the quality of hot-dip galvanized steel sheets.

奥面を向上することができる。又金型へ付着したメッキ
金属を除去する作業を省略でき、プレス加工の生産性を
向上することができる。
You can improve your inner side. Further, the work of removing plated metal adhering to the mold can be omitted, and the productivity of press working can be improved.

更にハンドリング中にメッキ表面に振売が入りにくくな
り、この点からも品質を向上させることができる等の優
れた効果が得られる。
Furthermore, it is difficult for the plated surface to be blown during handling, and from this point of view as well, excellent effects such as improved quality can be obtained.

〔実施例〕〔Example〕

次に本発明の実施例を比較例とともに挙げる。 Next, examples of the present invention will be listed together with comparative examples.

注1:メツキは、熱漬亜鉛(通常の成分)メッキを施し
、合金化炉で加熱した。
Note 1: The metal plate was hot-dipped zinc (normal component) plated and heated in an alloying furnace.

注2:合金層厚は、メッキ層とメッキ原板境界に生成し
た合金N (2,5μm)の上部に生成せしめた合金層
厚。
Note 2: The alloy layer thickness is the thickness of the alloy layer formed on top of the alloy N (2.5 μm) formed at the boundary between the plating layer and the plated original plate.

注3ニブレス条件、ブランク1.00φ、ポンチ50φ
−5R(コーナー) −5,R(肩)。
Note 3 Nibbles conditions, blank 1.00φ, punch 50φ
-5R (corner) -5,R (shoulder).

ダイ53φ−5R1しゎ押えカ400Kg。Die 53φ-5R1 presser force 400Kg.

成型長さ28on。Molded length 28 on.

このように本発明によればプレス加工後の金型\のメッ
キ金属の付着は、はとんどなく、優れた1果をもたらし
た。
As described above, according to the present invention, the adhesion of plated metal on the mold after press working was almost nonexistent, resulting in excellent results.

Claims (1)

【特許請求の範囲】[Claims] 亜鉛メッキ鋼板のメッキ層と原板鉄素地境界の合金層表
面からメッキ層表面直下までのFe量を1〜6%含有せ
しめたプレス加工用溶融亜鉛メッキ鋼板。
A hot-dip galvanized steel sheet for press working, containing 1 to 6% Fe from the surface of the alloy layer at the boundary between the plating layer and the iron substrate of the galvanized steel sheet to just below the surface of the plating layer.
JP58133600A 1983-07-23 1983-07-23 Hot dip galvanized sheet for press Pending JPS6026652A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58133600A JPS6026652A (en) 1983-07-23 1983-07-23 Hot dip galvanized sheet for press

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58133600A JPS6026652A (en) 1983-07-23 1983-07-23 Hot dip galvanized sheet for press

Publications (1)

Publication Number Publication Date
JPS6026652A true JPS6026652A (en) 1985-02-09

Family

ID=15108590

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58133600A Pending JPS6026652A (en) 1983-07-23 1983-07-23 Hot dip galvanized sheet for press

Country Status (1)

Country Link
JP (1) JPS6026652A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2671809A1 (en) * 1991-01-23 1992-07-24 Delot Process Sa CONTINUOUS GALVANIZATION PROCESS AT HIGH TEMPERATURE.
EP0882810A2 (en) * 1993-06-30 1998-12-09 Nkk Corporation Method for manufacturing an alloying-treated iron-zinc alloy dip-plated steel sheet excellent in press-formability

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2671809A1 (en) * 1991-01-23 1992-07-24 Delot Process Sa CONTINUOUS GALVANIZATION PROCESS AT HIGH TEMPERATURE.
EP0882810A2 (en) * 1993-06-30 1998-12-09 Nkk Corporation Method for manufacturing an alloying-treated iron-zinc alloy dip-plated steel sheet excellent in press-formability
EP0882810A3 (en) * 1993-06-30 2000-01-26 Nkk Corporation Method for manufacturing an alloying-treated iron-zinc alloy dip-plated steel sheet excellent in press-formability

Similar Documents

Publication Publication Date Title
US3962501A (en) Method for coating of corrosion-resistant molten alloy
KR890001829B1 (en) Hot dip zinc plated basin
CN113249672B (en) Alloyed galvanized sheet and preparation method and application thereof
KR20190077199A (en) Galvinized steel sheet having excellent adhesion at low temperature and excellent workability and method for manufacturing the same
JPS6026652A (en) Hot dip galvanized sheet for press
JP3931859B2 (en) Galvanized steel for hot forming and hot forming method
JP7321370B2 (en) ALUMINUM ALLOY PLATED STEEL SHEET EXCELLENT IN WORKABILITY AND CORROSION RESISTANCE AND METHOD FOR MANUFACTURING SAME
US701298A (en) Process of depositing metals on metallic surfaces and the product thereof.
JPH0355542B2 (en)
JP3485410B2 (en) Manufacturing method of hot-dip aluminized steel sheet with excellent heat blackening resistance
JP2001020050A (en) HOT DIP Zn-Al-Mg PLATED STEEL EXCELLENT IN CORROSION RESISTANCE IN NONCOATED PART AND COATED EDGE PART AND ITS PRODUCTION
JP2803566B2 (en) Alloyed galvanized steel sheet with excellent film destruction resistance
JP3133235B2 (en) Steel plate for fuel tank with excellent workability
JP3637702B2 (en) Method for producing hot-dip galvanized steel sheet with excellent workability
JPS58120772A (en) Manufacture of steel plate coated with alloyed zinc by galvanizing and provided with superior workability
JPH04360A (en) Galvannealed steel sheet excellent in workability
JP2825675B2 (en) Manufacturing method of galvannealed steel sheet with excellent workability
JPH03158449A (en) Production of alloying hot dip galvanized steel sheet
JPH0544006A (en) Production of alloyed hot dip galvanized steel sheet having excellent workability and corrosion resistance
JPH04235266A (en) Manufacture of alloying galvannealed steel sheet excellent in workability and corrosion resistance
JP3456459B2 (en) Surface-treated steel sheet with excellent drawability and ironability after drawing
JP2792809B2 (en) Hot-dip galvanized steel sheet
JPH0343347B2 (en)
JP3077951B2 (en) Manufacturing method of hot-dip zinc alloy plating coating
JPH0681170A (en) Checkered steel sheet excellent in workability and corrosion resistance