JP3077951B2 - Manufacturing method of hot-dip zinc alloy plating coating - Google Patents
Manufacturing method of hot-dip zinc alloy plating coatingInfo
- Publication number
- JP3077951B2 JP3077951B2 JP04113070A JP11307092A JP3077951B2 JP 3077951 B2 JP3077951 B2 JP 3077951B2 JP 04113070 A JP04113070 A JP 04113070A JP 11307092 A JP11307092 A JP 11307092A JP 3077951 B2 JP3077951 B2 JP 3077951B2
- Authority
- JP
- Japan
- Prior art keywords
- plating
- hot
- alloy plating
- zinc
- manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Coating With Molten Metal (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、鉄鋼材料表面に溶融亜
鉛合金めっき被覆物を形成するに際し、良好な外観と均
一なめっき厚さを有する溶融亜鉛合金めっき被覆物を製
造する方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a hot-dip galvanized alloy coating having a good appearance and a uniform plating thickness when forming a hot-dip galvanized alloy coating on a steel material surface.
【０００２】[0002]
【従来の技術およびその問題点】近年、亜鉛めっきに比
較して高耐食性であることから、亜鉛アルミニウム合金
めっきが注目され、建材、吊架線、架線金物等、屋外の
用途に広く使われることとなり、海洋、海岸地域、温泉
地帯を初めとする厳しい腐食環境において、またメイン
テナンスフリーが要求される場合の鋼材の防錆方法とし
て位置付けられている。2. Description of the Related Art In recent years, zinc-aluminum alloy plating has attracted attention because of its higher corrosion resistance than zinc plating, and has been widely used in outdoor applications such as building materials, suspension wires, and overhead wire hardware. It is positioned as a rust prevention method for steel materials in severe corrosive environments such as oceans, coastal areas and hot spring areas, and when maintenance-free is required.
【０００３】亜鉛アルミニウム合金めっきの方法として
は、鋼材を脱脂あるいは焼鈍し、酸洗あるいは還元を行
うことによって、表面の清浄化を行った後、フラックス
処理を実施した上で、あるいは還元雰囲気のまま、溶融
めっき浴に浸漬あるいは通過せしめる方法が一般的であ
る。溶融めっき浴への浸漬法は次の二つに大別できる。
すなわち、（１）直接浸漬法：溶融亜鉛アルミニウム合
金浴に直接浸漬する方法、（２）間接浸漬法：一旦亜鉛
めっき（溶融めっき法、電気めっき法のいずれも可）あ
るいは金属めっきを施し、その後に溶融亜鉛アルミ合金
浴に浸漬する方法、である。[0003] As a method of zinc-aluminum alloy plating, a steel material is degreased or annealed, pickled or reduced to clean the surface, and then subjected to a flux treatment or to a reduction atmosphere. Generally, a method of immersing or passing through a hot-dip plating bath is used. The immersion method in the hot-dip plating bath can be roughly classified into the following two methods.
That is, (1) direct immersion method: a method of directly immersing in a molten zinc aluminum alloy bath, (2) indirect immersion method: once zinc plating (both hot-dip plating and electroplating are possible) or metal plating, and thereafter Immersion in a molten zinc aluminum alloy bath.
【０００４】これら亜鉛アルミニウム合金めっき被覆物
における外観の良好さ、及びめっき厚さの均一性は実用
上極めて重要である。しかるに、従来、亜鉛アルミニウ
ム合金めっき、特にＡｌ−Ｃｕ−Ｚｎ合金めっきにおい
て、めっき皮膜の一部に微細な膨れが生じ、めっき厚さ
の不均一化、外観不良がしばしば生じ、問題となってい
た。[0004] Good appearance and uniformity of plating thickness of these zinc-aluminum alloy plating coatings are extremely important in practical use. However, conventionally, in zinc-aluminum alloy plating, particularly in Al-Cu-Zn alloy plating, fine swelling occurs in a part of the plating film, and unevenness of plating thickness and poor appearance often occur, which has been a problem. .
【０００５】本発明は、めっき皮膜に膨れを生じず、め
っき厚さが均一で、外観不良の起こらない実用性の高い
亜鉛アルミニウム合金めっき被覆物を製造し得る方法を
提供することを目的とする。An object of the present invention is to provide a method for producing a highly practical zinc-aluminum alloy plating coating which does not cause swelling of a plating film, has a uniform plating thickness, and does not cause appearance defects. .
【０００６】[0006]
【問題点を解決するための手段】本発明は、鉄鋼材料
を、アルミニウム０．１０〜１０重量％及び銅１．５〜
１０重量％を含み、残部が不可避不純物を別として亜鉛
からなる浴中に浸漬してその表面に亜鉛アルミニウム合
金めっきを施すに際し、めっき後の冷却速度を１００℃
／sec以下に保つことにより、前記課題を達成したもの
である。SUMMARY OF THE INVENTION The present invention relates to a steel material containing 0.10 to 10% by weight of aluminum and 1.5 to 1.5% of copper.
10% by weight, the remainder being immersed in a bath made of zinc except for unavoidable impurities, and applying a zinc-aluminum alloy plating on the surface thereof.
/ Sec or less achieves the above object.
【０００７】本発明者らは、通常の溶融めっきで一般的
に用いられている水冷、空冷による冷却方法をＡｌ−Ｃ
ｕ−Ｚｎ合金めっきに適用した場合、めっき皮膜におけ
る微細な膨れが生じ、めっき厚さの不均一が生じること
につき、種々検討を重ねたところ、従来の冷却方法に従
う場合、めっき後の冷却過程で空気あるいは水の分解に
よって生じた水蒸気又は水素がめっき皮膜が凝固する際
にめっき皮膜中に浸入、吸蔵することによって皮膜を押
し上げ、膨れを招くことを見出した。The present inventors have proposed a water-cooling method and an air-cooling method which are generally used in ordinary hot-dip galvanizing.
When applied to u-Zn alloy plating, fine swelling of the plating film occurs, and unevenness of the plating thickness occurs, and various studies have been made. When the conventional cooling method is followed, the cooling process after plating It has been found that when the plating film solidifies, water vapor or hydrogen generated by decomposition of air or water penetrates and occludes the plating film, thereby pushing up the film and causing blistering.
【０００８】従って、めっき皮膜の膨れを防止し、めっ
き厚さの均一性を保には、めっき後の冷却過程で空気あ
るいは水の分解を抑え、水蒸気又は水素のめっき皮膜中
への浸入あるいは吸蔵を抑制すればよい。そのため、本
発明ではめっき後の冷却速度を１００℃／sec以下、好
ましくは１０℃／sec〜８０℃／secに保持するようにす
る。Accordingly, in order to prevent the plating film from swelling and to keep the plating thickness uniform, the decomposition of air or water is suppressed in the cooling process after plating, and the penetration or occlusion of water vapor or hydrogen into the plating film. May be suppressed. Therefore, in the present invention, the cooling rate after plating is kept at 100 ° C./sec or less, preferably 10 ° C./sec to 80 ° C./sec.
【０００９】具体的には、めっき後の鋼材表面温度、水
または空気の温度、その浸入速度、保持時間等を調整し
て冷却速度を上記所定速度に保持する。Specifically, the cooling rate is maintained at the above-mentioned predetermined rate by adjusting the surface temperature of the steel material after plating, the temperature of water or air, the infiltration speed, the holding time, and the like.
【００１０】[0010]
【実施例】６．２％Ａｌ−７．４％Ｃｕ−Ｚｎ合金めっ
き浴を用い、一般構造用圧延鋼材（ＳＳ ４１）をこの
浴中に浸漬後、冷却速度を変えて前記鋼材表面にめっき
皮膜を形成した。その結果を表１に示す。EXAMPLE Using a 6.2% Al-7.4% Cu-Zn alloy plating bath, a rolled steel material for general structural use (SS41) was immersed in this bath, and the cooling rate was changed to plate the steel material surface. A film was formed. Table 1 shows the results.
【００１１】[0011]
【表１】 [Table 1]
【００１２】[0012]
【発明の効果】以上のような本発明によれば、Ａｌ−Ｃ
ｕ−Ｚｎ合金めっき皮膜の膨れが回避でき、従ってめっ
き厚さが均一で外観も美麗で平滑なめっき皮膜を得るこ
とができ、実用性の高いめっき被覆物が得られる。According to the present invention as described above, Al-C
The swelling of the u-Zn alloy plating film can be avoided, so that a plating film having a uniform plating thickness, a beautiful appearance and a smooth appearance can be obtained, and a highly practical plating coating can be obtained.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭61−195960（ＪＰ，Ａ) (58)調査した分野(Int.Cl.7，ＤＢ名) C23C 2/00 - 2/40 ────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-61-195960 (JP, A) (58) Field surveyed (Int. Cl. 7 , DB name) C23C 2/00-2/40
Claims (1)
０重量％及び銅１．５〜１０重量％を含み、残部が不可
避不純物を別として亜鉛からなる浴中に浸漬してその表
面に亜鉛アルミニウム合金めっきを施すに際し、めっき
後の冷却速度を１００℃／sec以下に保つことを特徴と
する溶融亜鉛合金めっき被覆物の製造方法。The steel material is made of aluminum 0.10 to 1
0% by weight and 1.5 to 10% by weight of copper, the remainder being immersed in a bath made of zinc except for unavoidable impurities, and applying a zinc-aluminum alloy plating on the surface thereof. / Sec or less, a method for producing a hot dip galvanized alloy coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04113070A JP3077951B2 (en) | 1992-04-06 | 1992-04-06 | Manufacturing method of hot-dip zinc alloy plating coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04113070A JP3077951B2 (en) | 1992-04-06 | 1992-04-06 | Manufacturing method of hot-dip zinc alloy plating coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05287484A JPH05287484A (en) | 1993-11-02 |
| JP3077951B2 true JP3077951B2 (en) | 2000-08-21 |
Family
ID=14602738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP04113070A Expired - Fee Related JP3077951B2 (en) | 1992-04-06 | 1992-04-06 | Manufacturing method of hot-dip zinc alloy plating coating |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3077951B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113846282A (en) * | 2021-09-24 | 2021-12-28 | 广东省科学院新材料研究所 | Medical stainless steel with Zn-Cu alloy coating, preparation method and application |
-
1992
- 1992-04-06 JP JP04113070A patent/JP3077951B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05287484A (en) | 1993-11-02 |
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