JPS60174689A - Transfer material for thermal recording - Google Patents

Transfer material for thermal recording

Info

Publication number
JPS60174689A
JPS60174689A JP59030541A JP3054184A JPS60174689A JP S60174689 A JPS60174689 A JP S60174689A JP 59030541 A JP59030541 A JP 59030541A JP 3054184 A JP3054184 A JP 3054184A JP S60174689 A JPS60174689 A JP S60174689A
Authority
JP
Japan
Prior art keywords
white carbon
layer
base
polymer composition
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP59030541A
Other languages
Japanese (ja)
Other versions
JPH0530197B2 (en
Inventor
Akihiro Imai
章博 今井
Tokihiko Shimizu
清水 時彦
Nobuyoshi Taguchi
田口 信義
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP59030541A priority Critical patent/JPS60174689A/en
Priority to CA000464122A priority patent/CA1228728A/en
Priority to EP84306649A priority patent/EP0138483B1/en
Priority to DE8484306649T priority patent/DE3482459D1/en
Publication of JPS60174689A publication Critical patent/JPS60174689A/en
Priority to US06/910,832 priority patent/US4684561A/en
Publication of JPH0530197B2 publication Critical patent/JPH0530197B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/405Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by layers cured by radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/44Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
    • B41M5/443Silicon-containing polymers, e.g. silicones, siloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/423Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/426Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/44Intermediate, backcoat, or covering layers characterised by the macromolecular compounds

Abstract

PURPOSE:To prevent drop-out from occurring, by a method wherein a high molecular weight composition layer comprising white carbon particles and having a surface roughened by the presence of the particles is provided on the lower side of a base. CONSTITUTION:A coloring material layer 5 is provided on the upper side of the base 4, and the high molecular weight composition layer 6 is provided on the lower side. The composition comprises white carbon 7 at the inside part and the surface of the layer 6, and white carbon comprises hydrated silicon dioxide or calcium silicate as a main constituent. A thermosetting resin or a hardenable resin can be used as a binder in the composition, and a thermosetting resin is particularly excellent in adhesion to the base and heat resistance. The coloring material layer may have one of various constructions. The transfer material free of drop-out can be obtained by providing the high molecular weight composition layer comprising white carbon on a film base consisting of a polyester, a polyimide or the like.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は熱転写による記録に用いられる感熱記録用転写
体に関する。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a heat-sensitive recording transfer member used for recording by thermal transfer.

従来例の構成とその問題点 感熱記録用転写体(以下、転写体と略す)の概略断面図
を第1図に示す。1は転写体の基体、2はその上に形成
された色材層である。転写体の基体1にポリエチレンテ
レフタレート(以下、PETと略す)あるいはポリイミ
ド等の高分子フィルムを用いた場合、サーマルヘッドか
らの熱パルスによる基体の熱溶融あるいは走行時の静電
気によりサーマルヘッド上を安定に走行できない。その
ため基体の下面に帯電防止および滑性を有する高分子組
成物層3を形成することが提案された。しかし、サーマ
ルヘッドの発熱体付近には数μmの微小な凹凸があるた
め、プラテンとサーマルヘッドの抑圧の不均一な所で特
に高分子組成物あるいは添加剤が削られてきて発熱体上
にたまり、画像のプリント抜け(ドロップアウト)が生
じるという問題を発生した。
1 shows a schematic cross-sectional view of a transfer body for thermal recording (hereinafter abbreviated as transfer body) of a conventional example and its problems. 1 is a base of the transfer body, and 2 is a coloring material layer formed thereon. When a polymer film such as polyethylene terephthalate (hereinafter abbreviated as PET) or polyimide is used for the substrate 1 of the transfer body, the substrate is thermally melted by heat pulses from the thermal head, or static electricity during movement stabilizes the surface of the thermal head. I can't drive. Therefore, it has been proposed to form an antistatic and slippery polymer composition layer 3 on the lower surface of the substrate. However, since there are minute irregularities of several micrometers near the heating element of the thermal head, the polymer composition or additives in particular are scraped away at the uneven pressure between the platen and the thermal head, and accumulate on the heating element. , a problem occurred in which images would be missing in print (dropouts).

発明の目的 本発明は、上記のような従来の欠点を解消し、画像にド
ロップアウトのない転写体を提供することを目的とする
OBJECTS OF THE INVENTION It is an object of the present invention to eliminate the above-mentioned conventional drawbacks and to provide a transfer member that does not cause image dropouts.

発明の構成 本発明は、基体の下面にホワイトカーボンの粒子を含み
、この粒子によって表面が粗面化された高分子組成物の
層を設けた転写体である。
Structure of the Invention The present invention is a transfer body in which a layer of a polymer composition containing white carbon particles and whose surface is roughened by the particles is provided on the lower surface of a substrate.

ホワイトカーボンは、その単粒子がほとんど0.1μm
以下という超微粒子であるため、高分子組成物中に添加
された場合、高分子組成物の表面が超微細に粗面化され
る。その結果、サーマルヘッド上を走行してもその粗面
がヘッド上の鋭い凹凸を吸収する作用があるためか発熱
体上にまったく堆積物が発生しない。そのため、ドロッ
プアウトが生じない。また、粒径が小さいため、サーマ
ルヘッドとの摩擦抵抗もあまシ大きくならない。
White carbon has a single particle size of almost 0.1 μm.
Since they are ultrafine particles, when added to a polymer composition, the surface of the polymer composition is ultrafinely roughened. As a result, even when the thermal head is run on, no deposits are generated on the heating element, probably because the rough surface has the effect of absorbing sharp irregularities on the head. Therefore, no dropout occurs. Furthermore, since the particle size is small, the frictional resistance with the thermal head does not increase too much.

実施例の説明 以下、本発明の実施例について説明する。Description of examples Examples of the present invention will be described below.

本発明の実施例として転写体の概略断面図を第2図に示
す。基体4の上面に色材層6があり、下面に高分子組成
物層6がある。高分子組成物は内部および表面にホワイ
トカーボン7を含有シテいる。ホワイトカーボンは主成
分が含水二酸化ケイ素あるいはケイ酸カルシウムである
。例えば、塩野義製薬株式会社の1カープレツクス」、
日本シリカニ業株式会社の1ニツプシール」、水澤化学
工業株式会社の「ジルトン」等の名称で市販されている
。ホワイトカーボンは高分子組成物の結着剤に対し0.
1〜200重量%の範囲で用いることができる。特に添
加比率が6〜100重量%の範囲で安定した特性を示す
。ホワイトカーボンは、超音波、三本ロール、ホモジナ
イザー等により結着剤等中によく分散される。また、含
水二酸化ケイ素は高温熱処理することによって表面シラ
ノール基を減少させて用いることもできる。
FIG. 2 shows a schematic cross-sectional view of a transfer body as an embodiment of the present invention. A coloring material layer 6 is provided on the upper surface of the substrate 4, and a polymer composition layer 6 is provided on the lower surface. The polymer composition contains white carbon 7 inside and on the surface. The main component of white carbon is hydrated silicon dioxide or calcium silicate. For example, 1 Carplex by Shionogi & Co., Ltd.
It is commercially available under the names of ``1 Nip Seal'' manufactured by Nippon Silikani Gyo Co., Ltd. and ``Jilton'' manufactured by Mizusawa Chemical Industry Co., Ltd. White carbon is 0.0% relative to the binder of the polymer composition.
It can be used in a range of 1 to 200% by weight. In particular, stable characteristics are exhibited when the addition ratio is in the range of 6 to 100% by weight. White carbon is well dispersed in a binder etc. by ultrasonic waves, a triple roll, a homogenizer, etc. Further, hydrated silicon dioxide can be used after the surface silanol groups are reduced by subjecting it to high temperature heat treatment.

高分子組成物の結着剤は、その材質を特に限定するもの
でなく、熱可塑性樹脂、熱、光、電子線等による各種硬
化性樹脂を用いることができる。
The material of the binder of the polymer composition is not particularly limited, and various resins such as thermoplastic resins and resins that can be cured by heat, light, electron beams, etc. can be used.

特に硬化性樹脂は基体との接着性および耐熱性が良好で
優れている。例えば、シリコーン系、アクリレート系、
エポキシ系、不飽和アルデヒド系樹脂等がある。中でも
アクリレート系樹脂の硬化物が優れた特性を示す。また
、光、電子線による硬化性樹脂が短時間で容易に硬化す
るため、長尺の618 : 転写体を作製しやすく良好な特性を示す。例えば、ウレ
タンアクリレート、エポキシアクリレート。
In particular, curable resins have excellent adhesion to substrates and heat resistance. For example, silicone-based, acrylate-based,
There are epoxy resins, unsaturated aldehyde resins, etc. Among these, cured products of acrylate resins exhibit excellent properties. Further, since the resin curable by light or electron beam is easily cured in a short time, it is easy to produce a long 618: transfer body and exhibits good characteristics. For example, urethane acrylate, epoxy acrylate.

ポリエステルアクリレート、シリコンアクリレート等の
オリゴアクリレート、不飽和シクロアセタール化合物の
光あるいは電子線硬化物、あるいは芳香族ジアゾニウム
塩触媒によるエポキシ樹脂の光硬化物等が優れている。
Oligoacrylates such as polyester acrylate and silicone acrylate, photo- or electron beam-cured products of unsaturated cycloacetal compounds, and photo-cured products of epoxy resins using aromatic diazonium salt catalysts are excellent.

樹脂には、ブトキシエチルアクリレート、ペンタエリス
リトールトリアクリレート等の種々の反応性希釈剤を添
加して用いることができる。高分子組成物の膜厚は特に
限定されるものでない。一般に製造面から0.1μm以
上の膜厚を有する高分子組成物が得やすく均一な特性を
示す。
Various reactive diluents such as butoxyethyl acrylate and pentaerythritol triacrylate can be added to the resin. The film thickness of the polymer composition is not particularly limited. Generally, from a production standpoint, a polymer composition having a film thickness of 0.1 μm or more is easily obtained and exhibits uniform characteristics.

色材層は、特に限定されるものでなく、ワックス方式、
昇華染料方式等で用いられている各種色材層構成を用い
ることができる。色材は、顔料。
The color material layer is not particularly limited, and may be a wax method,
Various color material layer configurations used in sublimation dye systems and the like can be used. Coloring materials are pigments.

染料のほかにカラーフォーマ−も含む。昇華性染料とし
ては、300℃以下で昇華あるいは蒸発を始める染料を
用いることができ、例えば、塩基性染料1分散染料等が
ある。
In addition to dyes, it also includes color formers. As the sublimable dye, a dye that starts to sublimate or evaporate at 300° C. or lower can be used, such as basic dye 1 disperse dye.

6ベーン 高分子組成物中には、滑剤、界面活性剤等の添加剤を加
えて用いることができ、例えば、シリコン系、フッ素系
の添加剤が特に優れた効果を示す。
Additives such as lubricants and surfactants can be added to the six-vane polymer composition, and silicone-based and fluorine-based additives, for example, exhibit particularly excellent effects.

本発明の基体は、高分子フィルムであれば特に限定する
ものでなく、例えば、ポリエチレンテレフタレート、ポ
リエチレンナフタレート、ポリカーボネート等のエステ
ル系高分子、ナイロン等のアミド系高分子、アセチルセ
ルロース、七ロノ・ン等のセルロース誘導体、ポリフッ
化ビニリデン。
The substrate of the present invention is not particularly limited as long as it is a polymer film, and examples include ester polymers such as polyethylene terephthalate, polyethylene naphthalate, and polycarbonate, amide polymers such as nylon, acetyl cellulose, Cellulose derivatives, such as polyvinylidene fluoride.

4フッ化エチレン−6フツ化プロピレン共重合体。Tetrafluoroethylene-hexafluoropropylene copolymer.

テフロン等のフッ素系高分子、ポリオキシメチレン、ポ
リアセタール等のエーテル系高分子、ポリスチレン、ポ
リエチレン、ポリプロピレン、メチルペンテンポリマー
等のオレフィン系高分子、ホリイミド、ポリアミドイミ
ド、ポリエーテルイミド等のイミド系高分子等を用いる
ことができる。
Fluorine polymers such as Teflon, ether polymers such as polyoxymethylene and polyacetal, olefin polymers such as polystyrene, polyethylene, polypropylene and methylpentene polymers, imide polymers such as polyimide, polyamideimide and polyetherimide etc. can be used.

特に、基体がポリエステル系高分子は薄く、ある程度の
耐熱性を有しており、安価であるので有用である。
In particular, polyester-based polymers are useful because they are thin, have a certain degree of heat resistance, and are inexpensive.

また、基体がポリエステル系高分子より耐熱性7、・ 
、 のあるイミド系、アミド系等の高分子は転写体を繰り返
し使用する場合、高速で使用する場合に耐熱的に優れて
いるので有用である。
In addition, the base material is more heat resistant than polyester polymers.
Imide-based, amide-based, and other polymers with , are useful when the transfer material is used repeatedly or when used at high speeds because they have excellent heat resistance.

以下、さらに具体的に説明する。This will be explained in more detail below.

実施例1 基体に厚さ9μmのPETフィルムを用いる。Example 1 A PET film with a thickness of 9 μm is used as the base.

このフィルムの下面に以下の組成を有する塗布液をワイ
ヤーバーで塗布し、60℃の熱風で溶媒を蒸発させた後
、1KWの高圧水銀灯を照射して硬化させた。
A coating liquid having the following composition was applied to the lower surface of this film using a wire bar, the solvent was evaporated with hot air at 60° C., and then a 1 KW high-pressure mercury lamp was irradiated to cure it.

(以下余白) 塗布液組成 9t・ ・ 次に下記の分子構造で表わされる染料2重量部、ポリカ
ーボネート4重量部、塩化メチレン100重量部を混合
したインキを上記P IE Tフィルムの上面にワイヤ
ーバーで塗布した後、60’Cの熱風で乾燥させ転写体
を作製した。
(Leaving space below) Coating liquid composition: 9 tons. Next, ink containing 2 parts by weight of a dye represented by the molecular structure shown below, 4 parts by weight of polycarbonate, and 100 parts by weight of methylene chloride was applied to the top surface of the PIE T film using a wire bar. After coating, it was dried with hot air at 60'C to prepare a transfer body.

この転写体について、以下の薄膜型サーマルヘッド記録
条件でムー6版の活性クレーコート紙上に記録させた。
This transfer body was recorded on Mu 6 version activated clay coated paper under the following thin film type thermal head recording conditions.

主および副走査の線密度= 4ドツト/rlI11記録
電力 : 0.7W/ドツト ヘツドの加熱時間 :Bms 1ラインの記録時間 : 33.3mg記録面積 :ム
ー6版 活性クレーコート紙10枚に対してプリントし10・、
 ・ た結果、画像に白線を発生させるドロップアウト個数は
零であった。
Linear density of main and sub-scanning = 4 dots/rlI11 Recording power: 0.7 W/dot Head heating time: Bms Recording time for 1 line: 33.3 mg Recording area: Printed on 10 sheets of Mu6 version activated clay coated paper 10・、
- As a result, the number of dropouts that caused white lines in the image was zero.

実施例2 基体に厚さ約12μmのポリイミド(商品名。Example 2 The base is made of polyimide (trade name) with a thickness of approximately 12 μm.

KAPTON、東し株式会社)フィルムを用いる。KAPTON, Toshi Co., Ltd.) film is used.

このフィルムの下面に実施例1の塗布液組成の中のホワ
イトカーボンをニップシールVN3に変えて塗布し、そ
の後実施例1と同様の手順を経て転写体を作製し活性ク
レーコート紙10枚にプリントした。この結果もドロッ
プアウト個数は零であった。
White carbon in the coating solution composition of Example 1 was changed to Nip Seal VN3 and applied to the lower surface of this film, and then a transfer body was prepared through the same procedure as in Example 1 and printed on 10 sheets of activated clay coated paper. . This result also showed that the number of dropouts was zero.

以上の結果は、また、ワックスタイプインキの転写体お
よび厚膜型サーマルヘッドの場合にも同様に良好な特性
を示した。なお、転写体の構成として基体の上面、下面
に下塗層を設けてその上に色材層、高分子組成物層を形
成させてもよい。また、本発明は、紙1合成紙等の紙状
基体に塗布してもドロップアウトが発生しなかった。
The above results also showed similar good characteristics in the case of wax type ink transfer bodies and thick film type thermal heads. In addition, as a structure of the transfer body, an undercoat layer may be provided on the upper and lower surfaces of the substrate, and a coloring material layer and a polymer composition layer may be formed thereon. Further, the present invention did not cause dropout even when applied to a paper-like substrate such as Paper 1 synthetic paper.

発明の効果 以上のように本発明は、ポリエステル、ポリイ11 パ
 ・ ミド等の各種フィルム基体にホワイトカーボンを含む高
分子組成物の層を形成させることにより、ドロップアウ
トの発生しない転写体を得ることができる。そのため無
処理基体の1までは使えない高エネルギー記録(あるい
は高速記録)にも利用できる。
Effects of the Invention As described above, the present invention provides a transfer material that does not cause dropouts by forming a layer of a polymeric composition containing white carbon on various film substrates such as polyester and polyamide. I can do it. Therefore, it can be used for high-energy recording (or high-speed recording) that cannot be used with untreated substrates.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来例の転写体の概略断面図、第2図は本発明
の一実施例における転写体の概略断面図である。 1.4・・・・・・基体、2,6・・・・・・色材層、
3,6・・・・・・高分子組成物、7・・・・・・ホワ
イトカーボン。 代理人の氏名 弁理士 中 尾 敏 男 ほか1名第1
図 第2図
FIG. 1 is a schematic sectional view of a conventional transfer body, and FIG. 2 is a schematic sectional view of a transfer body in an embodiment of the present invention. 1.4...Base, 2,6...Coloring material layer,
3, 6... Polymer composition, 7... White carbon. Name of agent: Patent attorney Toshio Nakao and 1 other person No. 1
Figure 2

Claims (1)

【特許請求の範囲】 0)基体の上面に色材層を設け、前記基体の下面にホワ
イトカーボンの粒子を含み、この粒子によって表面が粗
面化された高分子組成物の層を設けた感熱記録用転写体
。 (2)高分子組成物の結着剤が光硬化性樹脂の硬化物で
ある特許請求の範囲第1項記載の感熱記録用転写体。 (3)高分子組成物の結着剤がオリゴアクリレートの硬
化物である特許請求の範囲第1項記載の感熱記録用転写
体。
[Scope of Claims] 0) A heat-sensitive device comprising a coloring material layer provided on the upper surface of a substrate, and a layer of a polymer composition containing white carbon particles and having a surface roughened by the particles provided on the lower surface of the substrate. Recording transfer material. (2) The transfer body for thermal recording according to claim 1, wherein the binder of the polymer composition is a cured product of a photocurable resin. (3) The transfer body for thermal recording according to claim 1, wherein the binder of the polymer composition is a cured product of oligoacrylate.
JP59030541A 1983-09-28 1984-02-20 Transfer material for thermal recording Granted JPS60174689A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP59030541A JPS60174689A (en) 1984-02-20 1984-02-20 Transfer material for thermal recording
CA000464122A CA1228728A (en) 1983-09-28 1984-09-27 Color sheets for thermal transfer printing
EP84306649A EP0138483B1 (en) 1983-09-28 1984-09-28 Color sheets for thermal transfer printing
DE8484306649T DE3482459D1 (en) 1983-09-28 1984-09-28 COLOR LAYERS FOR HEAT TRANSFER PRINTING.
US06/910,832 US4684561A (en) 1983-09-28 1986-09-23 Color sheets for thermal transfer printing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59030541A JPS60174689A (en) 1984-02-20 1984-02-20 Transfer material for thermal recording

Publications (2)

Publication Number Publication Date
JPS60174689A true JPS60174689A (en) 1985-09-07
JPH0530197B2 JPH0530197B2 (en) 1993-05-07

Family

ID=12306652

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59030541A Granted JPS60174689A (en) 1983-09-28 1984-02-20 Transfer material for thermal recording

Country Status (1)

Country Link
JP (1) JPS60174689A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61143195A (en) * 1984-12-17 1986-06-30 Dainippon Printing Co Ltd Thermal transfer sheet
JPS61175089A (en) * 1985-01-31 1986-08-06 Dainippon Printing Co Ltd Thermal transfer sheet
JPS62173955U (en) * 1986-04-25 1987-11-05
JPS62286788A (en) * 1986-06-05 1987-12-12 Hitachi Maxell Ltd Thermal transfer recording material
JPS62286789A (en) * 1986-06-05 1987-12-12 Hitachi Maxell Ltd Thermal transfer recording material
JPS62290581A (en) * 1986-06-09 1987-12-17 Mitsubishi Paper Mills Ltd Heat transfer recording material
JPS6389841A (en) * 1986-09-22 1988-04-20 イーストマン コダック カンパニー Protective layer for heat treatable element
JPS6363467U (en) * 1986-10-16 1988-04-26
JPS6398484A (en) * 1986-10-15 1988-04-28 Toray Ind Inc Transfer material for thermal recording
JPS63222892A (en) * 1987-03-12 1988-09-16 Mitsubishi Paper Mills Ltd Thermal transfer material
JPS6487295A (en) * 1987-06-16 1989-03-31 Eastman Kodak Co Solid grain lubricant for sliding layer of dye dative element used for heat transfer of dye
JPH05127333A (en) * 1990-12-26 1993-05-25 Oriental Photo Ind Co Ltd Heat developable photosensitive material
US6476842B1 (en) * 1995-09-05 2002-11-05 Olive Tree Technology, Inc. Transfer printing

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56155794A (en) * 1980-05-06 1981-12-02 Fuji Kagaku Kogyo Kk Thermo-sensitive transfer material
JPS58101095A (en) * 1981-12-12 1983-06-16 Fuji Kagakushi Kogyo Co Ltd Heat transfer recording medium
JPS58171992A (en) * 1982-04-01 1983-10-08 Dainippon Printing Co Ltd Heat sensitive transfer sheet
JPS58187396A (en) * 1982-04-27 1983-11-01 Dainippon Printing Co Ltd Heat-sensitive transfer sheet

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56155794A (en) * 1980-05-06 1981-12-02 Fuji Kagaku Kogyo Kk Thermo-sensitive transfer material
JPS58101095A (en) * 1981-12-12 1983-06-16 Fuji Kagakushi Kogyo Co Ltd Heat transfer recording medium
JPS58171992A (en) * 1982-04-01 1983-10-08 Dainippon Printing Co Ltd Heat sensitive transfer sheet
JPS58187396A (en) * 1982-04-27 1983-11-01 Dainippon Printing Co Ltd Heat-sensitive transfer sheet

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0473391B2 (en) * 1984-12-17 1992-11-20 Dainippon Printing Co Ltd
JPS61143195A (en) * 1984-12-17 1986-06-30 Dainippon Printing Co Ltd Thermal transfer sheet
JPS61175089A (en) * 1985-01-31 1986-08-06 Dainippon Printing Co Ltd Thermal transfer sheet
JPS62173955U (en) * 1986-04-25 1987-11-05
JPS62286788A (en) * 1986-06-05 1987-12-12 Hitachi Maxell Ltd Thermal transfer recording material
JPS62286789A (en) * 1986-06-05 1987-12-12 Hitachi Maxell Ltd Thermal transfer recording material
JPS62290581A (en) * 1986-06-09 1987-12-17 Mitsubishi Paper Mills Ltd Heat transfer recording material
JPH0519917B2 (en) * 1986-06-09 1993-03-18 Mitsubishi Paper Mills Ltd
JPS6389841A (en) * 1986-09-22 1988-04-20 イーストマン コダック カンパニー Protective layer for heat treatable element
JPS6398484A (en) * 1986-10-15 1988-04-28 Toray Ind Inc Transfer material for thermal recording
JPS6363467U (en) * 1986-10-16 1988-04-26
JPS63222892A (en) * 1987-03-12 1988-09-16 Mitsubishi Paper Mills Ltd Thermal transfer material
JPS6487295A (en) * 1987-06-16 1989-03-31 Eastman Kodak Co Solid grain lubricant for sliding layer of dye dative element used for heat transfer of dye
JPH05127333A (en) * 1990-12-26 1993-05-25 Oriental Photo Ind Co Ltd Heat developable photosensitive material
US6476842B1 (en) * 1995-09-05 2002-11-05 Olive Tree Technology, Inc. Transfer printing

Also Published As

Publication number Publication date
JPH0530197B2 (en) 1993-05-07

Similar Documents

Publication Publication Date Title
US5252531A (en) Thermal transfer image-receiving sheet
JPS60174689A (en) Transfer material for thermal recording
JPS62169694A (en) High-molecular weight polycarbonate receiving layer used in heat dyestuff transfer
JPH02111586A (en) Resin-coated paper supporter of acceptor for thermal dye transfer
JPS60219094A (en) Transfer material for thermal recording
US5409758A (en) Thermal image transfer recording medium
US5710096A (en) Thermal transfer image-receiving sheet
US4757047A (en) Sublimation-type thermal transfer image receiving paper
US5943084A (en) Thermal transfer image-receiving sheet
JPH0582318B2 (en)
JPS6082385A (en) Thermal transfer recording body
JPH0263893A (en) Heat transfer printing receiver sheet
JPS60219096A (en) Transfer material for thermal recording
JPH0548198B2 (en)
JPH028086A (en) Sliding layer for dye dative element used for dye thermal transfer containing polysiloxane modified by amino group and other polysiloxane
JPS6071292A (en) Transfer material for thermal recording
JP2940928B2 (en) Sublimation type heat transfer sheet
JPS6094388A (en) Thermal transfer recording medium
JP2538196B2 (en) Transferr for thermal recording
JP3191435B2 (en) Polyester film for thermal transfer material
JPS62151393A (en) Image-receiving sheet for thermal transfer
JP2575340B2 (en) Laminated resin sheet
JPS61154997A (en) Thermal transfer material
JPS60219095A (en) Transfer material for thermal recording
JPH01291985A (en) Thermal transfer accepting sheet for preparation of transparent copy