JPS60219095A - Transfer material for thermal recording - Google Patents
Transfer material for thermal recordingInfo
- Publication number
- JPS60219095A JPS60219095A JP59076039A JP7603984A JPS60219095A JP S60219095 A JPS60219095 A JP S60219095A JP 59076039 A JP59076039 A JP 59076039A JP 7603984 A JP7603984 A JP 7603984A JP S60219095 A JPS60219095 A JP S60219095A
- Authority
- JP
- Japan
- Prior art keywords
- transfer material
- base
- lubricating substance
- resin composition
- composition layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 11
- 230000001050 lubricating effect Effects 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 9
- 239000011342 resin composition Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 238000004040 coloring Methods 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims description 13
- 239000011353 cycloaliphatic epoxy resin Substances 0.000 claims description 6
- -1 polyethylene terephthalate Polymers 0.000 abstract description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 4
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 4
- 239000003822 epoxy resin Substances 0.000 abstract description 3
- 229920000647 polyepoxide Polymers 0.000 abstract description 3
- 239000011737 fluorine Substances 0.000 abstract description 2
- 229910052731 fluorine Inorganic materials 0.000 abstract description 2
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 10
- 239000000975 dye Substances 0.000 description 7
- 229920002545 silicone oil Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000010408 film Substances 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 238000000859 sublimation Methods 0.000 description 4
- 230000008022 sublimation Effects 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920006254 polymer film Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- AAWDTJWBMQRPCW-UHFFFAOYSA-N 3-chloroocta-1,3-diene Chemical compound CCCCC=C(Cl)C=C AAWDTJWBMQRPCW-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/405—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by layers cured by radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
- B41M5/443—Silicon-containing polymers, e.g. silicones, siloxanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、熱転写による記録に用いられる感熱記録用転
写体に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a heat-sensitive recording transfer member used for recording by thermal transfer.
従来例の構成とその問題点
感熱記録用転写体（以下、転写体と略す）の概略断面図
を図に示す。１は転写体の基体、２はその上に形成され
た色材層、３は樹脂層である。Structure of a conventional example and its problems A schematic cross-sectional view of a transfer body for thermal recording (hereinafter abbreviated as transfer body) is shown in the figure. 1 is a base of the transfer body, 2 is a coloring material layer formed thereon, and 3 is a resin layer.
ポリエチレンテレフタレート（以下、ＰＥＴと略す）等
の高分子フィルムを基体１に用いた場合、サーマルヘッ
ドの熱パルスによる基体の熱溶融あるいは走行時に発生
する静電気により基体がサーマルヘッド液付着するいわ
ゆるスティック現象が発生する。その結果、基体かサー
マルヘッド上を安定に走行しない。When a polymer film such as polyethylene terephthalate (hereinafter abbreviated as PET) is used for the substrate 1, the so-called stick phenomenon occurs in which the thermal head liquid adheres to the substrate due to thermal melting of the substrate due to the heat pulse of the thermal head or static electricity generated during running. Occur. As a result, the substrate does not run stably on the thermal head.
そのため、基体の下面に耐熱性保護膜を設けること（特
開昭５６−７４６７号公報）、滑性の高い無機顔料と熱
硬化性または高軟化点の樹脂材料とからなるスティック
防止層を設ける（特開昭５６−１５５７９４号公報）、
常温で固体ないし半固体の界面活性剤まだは有機塩類を
含有する園脂層を設ける（特開昭５７−１２９７８９号
公報）の提案がなされている。Therefore, it is necessary to provide a heat-resistant protective film on the lower surface of the substrate (Japanese Unexamined Patent Publication No. 56-7467), or to provide a stick prevention layer consisting of a highly slippery inorganic pigment and a thermosetting or high softening point resin material ( JP-A-56-155794),
It has been proposed to provide a resin layer containing a surfactant that is solid or semi-solid at room temperature or an organic salt (Japanese Patent Application Laid-Open No. 129789/1989).
しかし１．Ｊ：記のように種々の餠脂層が提案されてい
るが、熱溶融性インキよりも４〜５倍の熱エネルギーが
必要とされる昇華性染料方式にも適用できる最適な樹脂
層が見出されていない。But 1. J: Various resin layers have been proposed as described below, but we have not yet found the optimal resin layer that can be applied to the sublimation dye method, which requires 4 to 5 times more thermal energy than hot-melt ink. Not served.
発明の目的
本発明は、上記のような従来の欠点を解消し、昇華性染
料方式にも適用でき、スティックがなく安定に走行する
転写体を提供することを目的とする。OBJECTS OF THE INVENTION An object of the present invention is to eliminate the above-mentioned conventional drawbacks, to provide a transfer member that can be applied to a sublimation dye method and that runs stably without stickiness.
発明の構成
本発明による感熱記録用転写体は、基体の下面に潤滑性
物質を含有する環状脂肪族エポキシ樹脂の紫外線硬化樹
脂組成物層が設けられたことを特徴とする。Structure of the Invention The heat-sensitive recording transfer body according to the present invention is characterized in that an ultraviolet curable resin composition layer of a cycloaliphatic epoxy resin containing a lubricating substance is provided on the lower surface of the substrate.
環状脂肪族エポキシ樹脂は、高分子フィルム基体との接
着性、薄膜形成性、潤滑性物質との親和性、耐熱性に優
れている。そのため、潤滑性物質と組み合わせることに
より走行性の安定な転写体を得ることができる。Cycloaliphatic epoxy resins have excellent adhesion to polymer film substrates, thin film forming properties, affinity with lubricating substances, and heat resistance. Therefore, by combining it with a lubricating substance, a transfer member with stable running properties can be obtained.
実施例の説明 以下、本発明の実施例について説明する。Description of examples Examples of the present invention will be described below.
本発明において用いるエポキシ樹脂は、環状脂肪族エポ
キシ樹脂である。例えば、ビニルンクロヘキセンジオキ
シド、３，４−エポキシ−６−メチルシクロヘキシルメ
チル−３，４−エポキシ−Ｆ−メチルシクロヘキサンカ
ルボキンレイ）、３．４−エポキシシクロヘキシルメチ
ル−３，４−エポキシ／りロヘキサン力ルボキ／レイト
等がある。The epoxy resin used in the present invention is a cycloaliphatic epoxy resin. For example, vinylchlorohexene dioxide, 3,4-epoxy-6-methylcyclohexylmethyl-3,4-epoxy-F-methylcyclohexanecarboxylene), 3,4-epoxycyclohexylmethyl-3,4-epoxy/lylohexane There are kiruboki/late etc.
重合開始剤としては、芳香族ジブゾニウム塩、あるいは
芳香族ヨードニウム塩、あるいは芳香族スルホニウム塩
がある。環状脂肪族エポキシ樹脂と重合開始剤と潤滑性
物質の混合物に紫外線を照射することにより表面滑性の
優れた耐熱１生のある硬い硬化樹脂組成物層が得られる
。Examples of the polymerization initiator include aromatic dibuzonium salts, aromatic iodonium salts, and aromatic sulfonium salts. By irradiating a mixture of a cycloaliphatic epoxy resin, a polymerization initiator, and a lubricating substance with ultraviolet rays, a hard cured resin composition layer with excellent surface smoothness and heat resistance can be obtained.
１だ、環状脂肪族エポキシ槌脂を主成分として史にビス
フェノールＡ型等の他のエポキシ１町脂を混入して用い
ることもできる。However, it is also possible to use cycloaliphatic epoxy resin as the main component and to mix other epoxy resins such as bisphenol A type.
潤滑性物質は滑剤あるいは界面活性剤であり、特に滑剤
と界面活性剤を併用した時にヘッドに対して優れた非接
着性を示した。The lubricating substance is a lubricant or a surfactant, and particularly when a lubricant and a surfactant were used in combination, it exhibited excellent non-adhesion to the head.
例えば、二硫化モリブデン、タルク、クラファイト、ぶ
つ化黒鉛等の無機固体滑剤、ステアリルステアレート、
セチルパルミテ〜ト、ペンクエリスリトールテトラステ
アレート、ステアリルアルコール、ワックス等の有機固
体滑剤、アルキルベンゼン、ポリブテン、アルキルナフ
タレン、アルキルジフェニルエタン、リン酸エステル、
ポリアルキレングリコール、各種シリコーンオイル等の
各種合成油、さらに各種飽和炭化水素、動植物油。For example, inorganic solid lubricants such as molybdenum disulfide, talc, graphite, graphite butt, stearyl stearate,
Organic solid lubricants such as cetyl palmite, penquerythritol tetrastearate, stearyl alcohol, wax, alkylbenzenes, polybutenes, alkylnaphthalenes, alkyldiphenylethanes, phosphoric esters,
Various synthetic oils such as polyalkylene glycol and various silicone oils, as well as various saturated hydrocarbons, animal and vegetable oils.
鉱物油等の液体滑剤がある。There are liquid lubricants such as mineral oil.
界面活性剤としては、すべての界面活性剤を用いること
ができる。特に、帯電防止性、潤滑性のいずれか、ある
いは両特性を有していることが望ましい。特に常温で液
体のシリコーン系、あるいは７ノン系界面活性剤が優れ
た特性を示す。As surfactant all surfactants can be used. In particular, it is desirable to have antistatic properties, lubricity properties, or both properties. In particular, silicone-based or 7-non-based surfactants that are liquid at room temperature exhibit excellent properties.
例えば、ポリエーテル変性シリコーンオイル。For example, polyether modified silicone oil.
カルボキシル変性シリコーンオイル、エポキシ変性シリ
コーンオイル、アルキルアラルキルポリエルチル変性シ
リコーンオイル、エポキ／・ポリエーテル変性シリコー
ンオイル等の各種変性７リコーンオイル、ポリオキシア
ルキレングリコールとシリコーンとの共重合体、バーフ
ルオロアルキル化合物等がある。Various modified silicone oils such as carboxyl-modified silicone oil, epoxy-modified silicone oil, alkyl aralkyl polyerthyl-modified silicone oil, epoxy/polyether-modified silicone oil, copolymers of polyoxyalkylene glycol and silicone, barfluoroalkyl compounds etc.
硬化樹脂組成物層の膜厚は特に限定されるものでない。The thickness of the cured resin composition layer is not particularly limited.
一般に製造面から０．１μか１以上の膜厚を有する樹脂
組成物層が得やすく均一な特性を示す。Generally, from a production standpoint, a resin composition layer having a thickness of 0.1 μm or more is easily obtained and exhibits uniform characteristics.
色材層は特に限定されるものでなくワックス方式、昇華
染料方式等で用いられている各種色相層構成を用いるこ
とができる。色材は顔料、染料のほかにカラーフォルマ
ーも含む。昇華性染料としては、３００°Ｃ以下で昇華
あるいは蒸発を始める染料を用いることができ、例えば
、塩基性染料。The color material layer is not particularly limited, and various hue layer configurations used in wax methods, sublimation dye methods, etc. can be used. Color materials include pigments, dyes, and color formers. As the sublimable dye, a dye that starts to sublimate or evaporate at 300°C or lower can be used, such as a basic dye.
分散染料等がある。There are disperse dyes, etc.
本発明の基体は高分子フィルムであれば特に限定される
ものでなく、例えば、ポリエチレンテレフタレート、ポ
リエチレンナフタレート、ポリカーボネート等のエステ
ル系高分子、ナイロン等のアミド系高分子、アセチルセ
ルロース、セロハン等のセルロース誘導体、ポリフッ化
ビニリデン。The substrate of the present invention is not particularly limited as long as it is a polymer film, and examples thereof include ester polymers such as polyethylene terephthalate, polyethylene naphthalate, and polycarbonate, amide polymers such as nylon, acetyl cellulose, and cellophane. Cellulose derivative, polyvinylidene fluoride.
４７ノ化エチレン−６７ノ化プロピレン共重合体テフロ
ン等のフッソ系高分子、ポリオキ／ノチレン、ポリアセ
タール等のエルチル系高分子、ポリスチレン、ポリエチ
レン、ポリプロピレン、メチルペノテンポリマー等のオ
レフィン系高分子、ポリイミド、ポリアミドイミド、ポ
リエーテルイミド等のイミド系高分子等を用いることが
できる。Fluorine-based polymers such as 47-no-ethylene-67-no-propylene copolymer Teflon, erthyl-based polymers such as polyoxy/notylene and polyacetal, olefin polymers such as polystyrene, polyethylene, polypropylene, and methylpenotene polymers, polyimide , polyamideimide, polyetherimide, and other imide-based polymers can be used.
特に、ポリエステル系高分子は薄く、ある程度の耐熱性
もあり、安価であるので有用である。In particular, polyester polymers are useful because they are thin, have a certain degree of heat resistance, and are inexpensive.
又、基体がポリエステル系高分子より耐熱性のあるイミ
ド系、アミド系等の高分子は転写体を繰り返し使用する
場合、高速で使用する場合に耐熱的に優れているので有
用である。In addition, imide-based, amide-based, and other polymers whose substrates are more heat resistant than polyester polymers are useful because they have excellent heat resistance when the transfer body is used repeatedly or at high speeds.
以下、さらに具体的に説明する。This will be explained in more detail below.
実施例１
基体に厚さ１２μｍのＰＥＴフィルムを用いたこのフィ
ルムの下面に以下の組成を有する塗布液をワイヤーバー
で塗布し、６０’Ｃの熱風で溶媒を蒸発させた後、１Ｋ
Ｗの高圧水銀灯を照射して硬次に下記の分子構造で表わ
される昇華性浄料２重量部、ポリカーボネート４重量部
、塩化メチレン１００重量部を混合したインキを上記Ｐ
ＥＴフィルムの上面にワイヤーバーで塗布した後６０°
Ｃの熱風、で乾燥させ転写体を作製した。Example 1 A PET film with a thickness of 12 μm was used as the substrate. A coating liquid having the following composition was applied to the bottom surface of this film using a wire bar, and after evaporating the solvent with hot air at 60'C, a 1K
After hardening by irradiating with a W high-pressure mercury lamp, the above P ink was mixed with 2 parts by weight of a sublimable purifier represented by the following molecular structure, 4 parts by weight of polycarbonate, and 100 parts by weight of methylene chloride.
60° after applying with a wire bar to the top surface of ET film
A transfer body was prepared by drying with hot air (C).
この転写体を用い、以下の薄膜型サーマルヘッド記録条
件で活性クレーコート紙に記録した。Using this transfer body, recording was performed on activated clay coated paper under the following thin film type thermal head recording conditions.
主および副走査の線密度：４ドツト／ｗｎ記録電力 ：
０．７Ｗ／ドツト
ヘツドの加熱時間 ：２−５ｍ５
１ラインの記録時間 ：３３．３ｍｓ
記録面積 ：Ａ−５版
この結果、転写体の樹脂組成物層は、２〜８ｍｓのすべ
ての範囲においてサーマルヘッドに対してまったく溶融
接着現象を示さず安定に走行した。Main and sub-scanning linear density: 4 dots/wn Recording power:
0.7W/Dot head heating time: 2-5m5 Recording time for 1 line: 33.3ms Recording area: A-5 version As a result, the resin composition layer of the transfer body was heated to the thermal head in the entire range of 2 to 8ms. It ran stably without showing any melt adhesion phenomenon.
以上の結果は、又、ワックスタイプインキの転写体、及
び厚膜型サーマルヘッドの場合にも同様であった。なお
、転写体の構成として基体の上面。The above results were also the same in the case of a wax type ink transfer body and a thick film type thermal head. Note that the structure of the transfer body is the top surface of the base.
下面に下塗層を設けてその上に色材層、高分子組成物層
を形成させてもよい。又、本発明は、紙。An undercoat layer may be provided on the lower surface, and a coloring material layer and a polymer composition layer may be formed thereon. Further, the present invention relates to paper.
合成紙等の紙状基体に塗布してもスティックを発生せず
安定に走行した。Even when applied to paper-like substrates such as synthetic paper, it ran stably without causing stickiness.
発明の効果
以上のように本発明の転写体は、昇華性染料方式のよう
に高い熱エネルギーが印加される場合でもスティックが
なく安定に走行するため、画像プリンター用としてその
工業的利用価値が犬である。Effects of the Invention As described above, the transfer body of the present invention has no stick and runs stably even when high heat energy is applied as in the sublimation dye method, so its industrial utility value as an image printer is high. It is.
図は感熱記録用転写体の概略断面図である。
１・・・・・・基体、２・・・・・・色材層、３・・樹
脂層。The figure is a schematic cross-sectional view of a transfer body for thermal recording. 1...Base body, 2...Coloring material layer, 3...Resin layer.
Claims (2)
に潤滑性物質を含有する環状脂肪族エポキシ樹脂を主成
分とする紫外線硬化樹脂組成物層力殺けられた感熱記録
用転写体。(1) A coloring material layer is provided on the upper surface of the substrate, and an ultraviolet curable resin composition mainly composed of a cycloaliphatic epoxy resin containing a lubricating substance is provided on the lower surface of the substrate. body.
体界面活性剤である特許請求の範囲第１項記載の感熱記
録用転写体。(2) The transfer body for thermal recording according to claim 1, wherein the lubricating substance is a silicone-based or nonon-based liquid surfactant.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59076039A JPS60219095A (en) | 1984-04-16 | 1984-04-16 | Transfer material for thermal recording |
| CA000464122A CA1228728A (en) | 1983-09-28 | 1984-09-27 | Color sheets for thermal transfer printing |
| EP84306649A EP0138483B1 (en) | 1983-09-28 | 1984-09-28 | Color sheets for thermal transfer printing |
| DE8484306649T DE3482459D1 (en) | 1983-09-28 | 1984-09-28 | COLOR LAYERS FOR HEAT TRANSFER PRINTING. |
| US06/910,832 US4684561A (en) | 1983-09-28 | 1986-09-23 | Color sheets for thermal transfer printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59076039A JPS60219095A (en) | 1984-04-16 | 1984-04-16 | Transfer material for thermal recording |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60219095A true JPS60219095A (en) | 1985-11-01 |
| JPH0526676B2 JPH0526676B2 (en) | 1993-04-16 |
Family
ID=13593660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59076039A Granted JPS60219095A (en) | 1983-09-28 | 1984-04-16 | Transfer material for thermal recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60219095A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987005564A1 (en) * | 1986-03-18 | 1987-09-24 | Dai Nippon Insatsu Kabushiki Kaisha | Thermal transfer recording ribbon |
| JPS62227786A (en) * | 1986-03-31 | 1987-10-06 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56155794A (en) * | 1980-05-06 | 1981-12-02 | Fuji Kagaku Kogyo Kk | Thermo-sensitive transfer material |
| JPS57129789A (en) * | 1981-02-05 | 1982-08-11 | Fuji Kagakushi Kogyo Co Ltd | Heat sensitive transferring material |
| JPS58101095A (en) * | 1981-12-12 | 1983-06-16 | Fuji Kagakushi Kogyo Co Ltd | Heat transfer recording medium |
| JPS58171992A (en) * | 1982-04-01 | 1983-10-08 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS58187396A (en) * | 1982-04-27 | 1983-11-01 | Dainippon Printing Co Ltd | Heat-sensitive transfer sheet |
-
1984
- 1984-04-16 JP JP59076039A patent/JPS60219095A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56155794A (en) * | 1980-05-06 | 1981-12-02 | Fuji Kagaku Kogyo Kk | Thermo-sensitive transfer material |
| JPS57129789A (en) * | 1981-02-05 | 1982-08-11 | Fuji Kagakushi Kogyo Co Ltd | Heat sensitive transferring material |
| JPS58101095A (en) * | 1981-12-12 | 1983-06-16 | Fuji Kagakushi Kogyo Co Ltd | Heat transfer recording medium |
| JPS58171992A (en) * | 1982-04-01 | 1983-10-08 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS58187396A (en) * | 1982-04-27 | 1983-11-01 | Dainippon Printing Co Ltd | Heat-sensitive transfer sheet |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987005564A1 (en) * | 1986-03-18 | 1987-09-24 | Dai Nippon Insatsu Kabushiki Kaisha | Thermal transfer recording ribbon |
| JPS62227786A (en) * | 1986-03-31 | 1987-10-06 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0526676B2 (en) | 1993-04-16 |
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