JPS60166336A - ハロゲン含有樹脂用液状安定剤 - Google Patents
ハロゲン含有樹脂用液状安定剤Info
- Publication number
- JPS60166336A JPS60166336A JP2259384A JP2259384A JPS60166336A JP S60166336 A JPS60166336 A JP S60166336A JP 2259384 A JP2259384 A JP 2259384A JP 2259384 A JP2259384 A JP 2259384A JP S60166336 A JPS60166336 A JP S60166336A
- Authority
- JP
- Japan
- Prior art keywords
- dioctyltin
- stabilizer
- mercaptocarboxylic acid
- acid ester
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003381 stabilizer Substances 0.000 title claims abstract description 39
- 239000007788 liquid Substances 0.000 title claims abstract description 18
- 229920005989 resin Polymers 0.000 title claims abstract description 18
- 239000011347 resin Substances 0.000 title claims abstract description 18
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 17
- 150000002367 halogens Chemical class 0.000 title claims abstract description 17
- -1 octyltin mercaptocarboxylic acid ester Chemical class 0.000 claims abstract description 39
- 239000007983 Tris buffer Substances 0.000 claims abstract description 20
- ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical compound CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 claims abstract description 17
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 claims abstract description 12
- GZCKAZBPQRJEOX-UHFFFAOYSA-L SC(=O)[O-].C(CCCCCCC)[Sn+2]CCCCCCCC.SC(=O)[O-] Chemical compound SC(=O)[O-].C(CCCCCCC)[Sn+2]CCCCCCCC.SC(=O)[O-] GZCKAZBPQRJEOX-UHFFFAOYSA-L 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000000203 mixture Substances 0.000 abstract description 9
- 238000002845 discoloration Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 15
- 238000004040 coloring Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 239000004014 plasticizer Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 102100035591 POU domain, class 2, transcription factor 2 Human genes 0.000 description 4
- 101710084411 POU domain, class 2, transcription factor 2 Proteins 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- KEUUHXDTZRYITO-UHFFFAOYSA-L 2,2-dioctyl-1,3,2-oxathiastannolan-5-one Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)CS1 KEUUHXDTZRYITO-UHFFFAOYSA-L 0.000 description 3
- NAUUNCGQQSDWHM-UHFFFAOYSA-K 2-(6-methylheptylsulfanyl)acetate octyltin(3+) Chemical compound CCCCCCCC[Sn+3].CC(C)CCCCCSCC([O-])=O.CC(C)CCCCCSCC([O-])=O.CC(C)CCCCCSCC([O-])=O NAUUNCGQQSDWHM-UHFFFAOYSA-K 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical class OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- LZQSKUQISWIZQS-UHFFFAOYSA-N 2-dodecylsulfanylacetic acid Chemical compound CCCCCCCCCCCCSCC(O)=O LZQSKUQISWIZQS-UHFFFAOYSA-N 0.000 description 2
- RZBBHEJLECUBJT-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS RZBBHEJLECUBJT-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- XDNRDJYSJCAHFY-UHFFFAOYSA-K CCCCCCCC[Sn](OC(=O)C(C)SCC(CC)CCCC)(OC(=O)C(C)SCC(CC)CCCC)OC(=O)C(C)SCC(CC)CCCC Chemical compound CCCCCCCC[Sn](OC(=O)C(C)SCC(CC)CCCC)(OC(=O)C(C)SCC(CC)CCCC)OC(=O)C(C)SCC(CC)CCCC XDNRDJYSJCAHFY-UHFFFAOYSA-K 0.000 description 2
- 239000004593 Epoxy Chemical class 0.000 description 2
- 229920006385 Geon Polymers 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- VXGIVDFKZKMKQO-UHFFFAOYSA-L dioctyltin isooctylthioglycolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCCCCCC)(CCCCCCCC)SCC(=O)OCC(CC)CCCC VXGIVDFKZKMKQO-UHFFFAOYSA-L 0.000 description 2
- SBOSGIJGEHWBKV-UHFFFAOYSA-L dioctyltin(2+);dichloride Chemical compound CCCCCCCC[Sn](Cl)(Cl)CCCCCCCC SBOSGIJGEHWBKV-UHFFFAOYSA-L 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- MADOXCFISYCULS-UHFFFAOYSA-N octyl 2-sulfanylacetate Chemical compound CCCCCCCCOC(=O)CS MADOXCFISYCULS-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- WLDRJVJOEKXTIE-UHFFFAOYSA-L 2,2-dioctyl-1,3,2-oxathiastanninan-6-one Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)CCS1 WLDRJVJOEKXTIE-UHFFFAOYSA-L 0.000 description 1
- IICRHVJNHYVVKT-UHFFFAOYSA-N 2-(2-ethylhexylsulfanyl)propanoic acid Chemical compound CCCCC(CC)CSC(C)C(O)=O IICRHVJNHYVVKT-UHFFFAOYSA-N 0.000 description 1
- YXNWKYMLMYBZSA-UHFFFAOYSA-N 2-dodecylsulfanylpropanoic acid Chemical compound CCCCCCCCCCCCSC(C)C(O)=O YXNWKYMLMYBZSA-UHFFFAOYSA-N 0.000 description 1
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 description 1
- YNGUXAKJEVGKCF-UHFFFAOYSA-N 2-octadecylsulfanylacetic acid Chemical compound CCCCCCCCCCCCCCCCCCSCC(O)=O YNGUXAKJEVGKCF-UHFFFAOYSA-N 0.000 description 1
- KZYNPINQSVKGQR-UHFFFAOYSA-N 2-octadecylsulfanylpropanoic acid Chemical compound CCCCCCCCCCCCCCCCCCSC(C)C(O)=O KZYNPINQSVKGQR-UHFFFAOYSA-N 0.000 description 1
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 1
- ORDRGXFSRBRQQG-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)C(C)S ORDRGXFSRBRQQG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- CAWFGLZVKAGWCV-UHFFFAOYSA-L CCCCCCCC[Sn](CCCCCCCC)(OC(=O)C(C)SCC(CC)CCCC)OC(=O)C(C)SCC(CC)CCCC Chemical compound CCCCCCCC[Sn](CCCCCCCC)(OC(=O)C(C)SCC(CC)CCCC)OC(=O)C(C)SCC(CC)CCCC CAWFGLZVKAGWCV-UHFFFAOYSA-L 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- IVRFYNSETZKRSJ-UHFFFAOYSA-N ClC=C.N#CC=CC=CC1=CC=CC=C1 Chemical compound ClC=C.N#CC=CC=CC1=CC=CC=C1 IVRFYNSETZKRSJ-UHFFFAOYSA-N 0.000 description 1
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- NSUQAMKMHFAQHJ-UHFFFAOYSA-K [bis[2-(6-methylheptylsulfanyl)propanoyloxy]-octylstannyl] 2-(6-methylheptylsulfanyl)propanoate Chemical compound C(CCCCC(C)C)SC(C(=O)[O-])C.C(CCCCC(C)C)SC(C(=O)[O-])C.C(CCCCC(C)C)SC(C(=O)[O-])C.C(CCCCCCC)[Sn+3] NSUQAMKMHFAQHJ-UHFFFAOYSA-K 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- BBEAQIROQSPTKN-UHFFFAOYSA-N antipyrene Natural products C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- ZJPJECQPVMSILT-UHFFFAOYSA-N chloroethene 3-(2-phenylethenyl)furan-2,5-dione Chemical compound ClC=C.O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 ZJPJECQPVMSILT-UHFFFAOYSA-N 0.000 description 1
- IEJNAGSUKYCWCR-UHFFFAOYSA-N chloroethene;1,1-dichloroethene;ethenyl acetate Chemical compound ClC=C.ClC(Cl)=C.CC(=O)OC=C IEJNAGSUKYCWCR-UHFFFAOYSA-N 0.000 description 1
- VSJDEWYENWWMAV-UHFFFAOYSA-N chloroethene;2-methylprop-2-enoic acid Chemical compound ClC=C.CC(=C)C(O)=O VSJDEWYENWWMAV-UHFFFAOYSA-N 0.000 description 1
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 1
- SQNNHEYXAJPPKH-UHFFFAOYSA-N chloroethene;prop-2-enoic acid Chemical compound ClC=C.OC(=O)C=C SQNNHEYXAJPPKH-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006704 dehydrohalogenation reaction Methods 0.000 description 1
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical compound C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 1
- UMKDEMLFCZGWIZ-UHFFFAOYSA-L dioctyltin(2+) 2-(6-methylheptylsulfanyl)propanoate Chemical compound CC(C)CCCCCSC(C)C([O-])=O.CC(C)CCCCCSC(C)C([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC UMKDEMLFCZGWIZ-UHFFFAOYSA-L 0.000 description 1
- VGOZWKNEUDQLQY-UHFFFAOYSA-L dioctyltin(2+) 2-octadecylsulfanylacetate Chemical compound C(CCCCCCCCCCCCCCCCC)SCC(=O)[O-].C(CCCCCCCCCCCCCCCCC)SCC(=O)[O-].C(CCCCCCC)[Sn+2]CCCCCCCC VGOZWKNEUDQLQY-UHFFFAOYSA-L 0.000 description 1
- TVMDUMQNXXNGMG-UHFFFAOYSA-N dodecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCOC(=O)CS TVMDUMQNXXNGMG-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- INTLMJZQCBRQAT-UHFFFAOYSA-K trichloro(octyl)stannane Chemical compound CCCCCCCC[Sn](Cl)(Cl)Cl INTLMJZQCBRQAT-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2259384A JPS60166336A (ja) | 1984-02-09 | 1984-02-09 | ハロゲン含有樹脂用液状安定剤 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2259384A JPS60166336A (ja) | 1984-02-09 | 1984-02-09 | ハロゲン含有樹脂用液状安定剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60166336A true JPS60166336A (ja) | 1985-08-29 |
| JPH0524936B2 JPH0524936B2 (enrdf_load_stackoverflow) | 1993-04-09 |
Family
ID=12087137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2259384A Granted JPS60166336A (ja) | 1984-02-09 | 1984-02-09 | ハロゲン含有樹脂用液状安定剤 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60166336A (enrdf_load_stackoverflow) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS517581A (ja) * | 1974-07-08 | 1976-01-21 | Shigeto Fukuzawa | Setsusakutsutsukiribaito |
| JPS519138A (ja) * | 1974-07-12 | 1976-01-24 | Sankyo Organic Chemicals Co | Enkabinirujushoanteizai |
| JPS57205434A (en) * | 1981-06-12 | 1982-12-16 | Adeka Argus Chem Co Ltd | Halogen-containing resin composition |
| JPS5852353A (ja) * | 1981-09-21 | 1983-03-28 | Adeka Argus Chem Co Ltd | ハロゲン含有樹脂組成物 |
| JPS6013849A (ja) * | 1983-07-01 | 1985-01-24 | Katsuta Kako Kk | 含ハロゲン樹脂用安定剤組成物 |
-
1984
- 1984-02-09 JP JP2259384A patent/JPS60166336A/ja active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS517581A (ja) * | 1974-07-08 | 1976-01-21 | Shigeto Fukuzawa | Setsusakutsutsukiribaito |
| JPS519138A (ja) * | 1974-07-12 | 1976-01-24 | Sankyo Organic Chemicals Co | Enkabinirujushoanteizai |
| JPS57205434A (en) * | 1981-06-12 | 1982-12-16 | Adeka Argus Chem Co Ltd | Halogen-containing resin composition |
| JPS5852353A (ja) * | 1981-09-21 | 1983-03-28 | Adeka Argus Chem Co Ltd | ハロゲン含有樹脂組成物 |
| JPS6013849A (ja) * | 1983-07-01 | 1985-01-24 | Katsuta Kako Kk | 含ハロゲン樹脂用安定剤組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0524936B2 (enrdf_load_stackoverflow) | 1993-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2042158C (en) | Polymer stabilizer and polymer composition stabilized therewith | |
| CN101864186B (zh) | 稳定化的聚合物组合物 | |
| US5225108A (en) | Polymer stabilizer and polymer composition stabililzed therewith | |
| JPH0559237A (ja) | 帯電防止能を有する熱安定化された含ハロゲン樹脂組成物 | |
| EP3030610B1 (en) | Heat stabilizer for halogen-containing polymers | |
| JP3712308B2 (ja) | 食品包装フィルム用ポリ塩化ビニル系樹脂組成物 | |
| US4021407A (en) | Synergistic organotin borate stabilizer compositions and resins containing same | |
| EP0070092B1 (en) | Stabilising materials for halogen-containing polymers, polymer compositions containing the same and shaped articles formed therefrom | |
| JPS60166336A (ja) | ハロゲン含有樹脂用液状安定剤 | |
| JPH0135014B2 (enrdf_load_stackoverflow) | ||
| US4711921A (en) | Stabilization of vinyl chloride polymers | |
| JPS638446A (ja) | 安定化ポリマ−組成物 | |
| US3985828A (en) | Flame-retarded acrylic multipolymer-vinyl chloride polymer compositions | |
| JPH0219855B2 (enrdf_load_stackoverflow) | ||
| JPH0236146B2 (ja) | Ensokaenkabinirujushisoseibutsu | |
| JP2001031819A (ja) | 塩素含有樹脂組成物 | |
| JPH021180B2 (enrdf_load_stackoverflow) | ||
| US3216968A (en) | Flame resistant compositions comprising organic polymers mixed with quaternary ammonium hexafluorophosphate compounds | |
| JPS6352671B2 (enrdf_load_stackoverflow) | ||
| JPS6231737B2 (enrdf_load_stackoverflow) | ||
| JPS5852353A (ja) | ハロゲン含有樹脂組成物 | |
| JPS5998150A (ja) | ハロゲン含有樹脂組成物 | |
| CA1045146A (en) | Non-toxic organotin stabilizers for vinyl chloride polymers | |
| JPH07157617A (ja) | 農業用塩化ビニル系樹脂組成物 | |
| JPH0337578B2 (enrdf_load_stackoverflow) |