JPS60161382A - Manufacture of glazed cement product - Google Patents

Manufacture of glazed cement product

Info

Publication number
JPS60161382A
JPS60161382A JP1379784A JP1379784A JPS60161382A JP S60161382 A JPS60161382 A JP S60161382A JP 1379784 A JP1379784 A JP 1379784A JP 1379784 A JP1379784 A JP 1379784A JP S60161382 A JPS60161382 A JP S60161382A
Authority
JP
Japan
Prior art keywords
cement
glazed
hardened
cement product
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1379784A
Other languages
Japanese (ja)
Other versions
JPS646150B2 (en
Inventor
飯島 英雄
茂 飯田
英明 早川
谷地 秀則
哲也 小出
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inax Corp
Original Assignee
Inax Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inax Corp filed Critical Inax Corp
Priority to JP1379784A priority Critical patent/JPS60161382A/en
Publication of JPS60161382A publication Critical patent/JPS60161382A/en
Publication of JPS646150B2 publication Critical patent/JPS646150B2/ja
Granted legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は、溶削技術を利用した施釉セメント製品の製造
方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of manufacturing a glazed cement product using a cutting technique.

施釉セメント製品は、表面が美麗であり、且表面強度や
耐久性にすぐれているといった特徴をもち、従来は、セ
メントに水及び骨材、さらに必要により各種添加剤や補
強用のIll維を加えた原料組成物を混練し、それを加
圧成形、押出し成形、流し込み等の成形法により成形し
、得られた成形体に施釉して焼成したのち、再水相処理
することによって製造している。この方法は、セメント
製品全体を焼成するため多量のエネルギーを必要とする
ばかりか、焼成の際、濡洩コントロールが難しいという
問題があった。また、使用する窯の大きさの制限により
ブレキャストコンクリー]〜板等の大型セメント製品の
施釉ができないという問題もあった。
Glazed cement products have a beautiful surface and have excellent surface strength and durability. Conventionally, glazed cement products are made by adding water and aggregate to cement, and if necessary, various additives and reinforcing fibers. It is manufactured by kneading the raw material composition, molding it by a molding method such as pressure molding, extrusion molding, or pouring, and then glazing and firing the resulting molded product, and then re-treating it with a water phase. . This method not only requires a large amount of energy to fire the entire cement product, but also has the problem that it is difficult to control leakage during firing. Furthermore, there was also the problem that large cement products such as cast concrete sheets and boards could not be glazed due to the size limitations of the kilns used.

一方、ガス溶射、プラズマ溶射を利用して、フリッ1へ
状釉薬成分をセメント硬化体に溶着させる技術は昔から
研究されてはいるが、未だ実用に供されていない。それ
は、窯の中で焼成して得られた施釉セメント製品と比べ
て、釉面が平滑でなく且発泡、ハジキ等の問題があった
ことによる。
On the other hand, although the technique of welding the flake-like glaze component to the hardened cement body using gas spraying or plasma spraying has been studied for a long time, it has not yet been put to practical use. This is because, compared to glazed cement products obtained by firing in a kiln, the glazed surface was not smooth and there were problems such as foaming and repellency.

本発明は、従来の施釉セメント製品の製造方法の欠点を
是正したものであり、その要旨とするところは、セメン
トに水及び必要により骨材、各種添加剤や補強用の繊維
を加えた原料組成物を混練し、成形して1qられたセメ
ント硬化体を、予め仮焼してから、その表面にカス溶射
、プラズマ溶用技術を用いて、フリット状釉薬成分を溶
着させてなる施釉セメント製品の製造方法にある。
The present invention rectifies the shortcomings of the conventional manufacturing method of glazed cement products, and its gist is that the raw material composition is made by adding water and, if necessary, aggregate, various additives, and reinforcing fibers to cement. A glazed cement product is produced by kneading, molding, and calcining 1q of hardened cement, and then welding a frit-like glaze component to its surface using scum spraying or plasma melting technology. It's in the manufacturing method.

以下、本発明を第1図にもとづいて説明する。The present invention will be explained below based on FIG.

はじめにセメント硬化体1の製法について記述すると、
本発明に用いるセメントはポルトランドセメン(−、ア
ルミナセメントなど通常使用されているセメントから任
意に選ぶことができる。ま1=、骨材として川砂、ケイ
砂、シェルペン、シャ[ツ1−等通常しメント用母祠と
して用いられるものを必要に応じ−C使用することがで
き、補強材としてガラスミ!維9石綿、スチール繊紺等
を加えてもよく、さらに所望に応じ各種添加剤、例えば
減水剤、硬化促進剤等を用いることもできる。以上の原
料組成物に水を加えて混練し、これを流し込みや加圧成
形又は押出し成形等の成形方法によって所望の形状に成
形し、且つ硬化させることによりセメント硬化体1を作
成する。
First, we will describe the manufacturing method of hardened cement body 1.
The cement used in the present invention can be arbitrarily selected from commonly used cements such as portland cement (-) and alumina cement. -C can be used as needed for the mother shrine used for menting, glass fibers, asbestos, steel fibers, etc. may be added as reinforcing materials, and various additives such as water reducing agents can be added as desired. , a curing accelerator, etc. can also be used.Water is added to the above raw material composition, kneaded, molded into a desired shape by a molding method such as pouring, pressure molding, extrusion molding, etc., and hardened. A hardened cement body 1 is created.

次に、このセメント硬化体を炉2の中で500℃以上好
ましくは600℃以上の温度で仮焼して、表面に付着し
ている吸着水や、次工程の溶射の際分解して発生してく
るセメント中に含まれる構造水や、各種添加剤の分解に
より発生ずるガスを予め取りのぞいておく。
Next, this hardened cement body is calcined in a furnace 2 at a temperature of 500°C or higher, preferably 600°C or higher, to eliminate adsorbed water adhering to the surface and decomposition during thermal spraying in the next process. The structural water contained in the cement and the gas generated by the decomposition of various additives are removed in advance.

続いて、通常のガス溶銅またはプラズマ溶9A3を用い
てフリット状釉薬成分をセメント硬化体表面に溶着させ
ることにより施釉セメント製品を衝ることができる。
Subsequently, a frit-like glaze component is welded to the surface of the hardened cement body using ordinary gas molten copper or plasma molten 9A3, thereby making it possible to obtain a glazed cement product.

ここで使用するフリット状釉薬成分は、たとえばカラス
粉末に亜鉛華、ジルコンなどの慣用の助剤及び無機顔料
を加えたものを使用すればよい。
The frit-like glaze component used here may be, for example, a mixture of crow powder and a commonly used auxiliary agent such as zinc white or zircon and an inorganic pigment.

フリット状釉薬成分の粒度は、40〜160μの間で調
整されることが望ましい。フリット状釉薬成分は、特に
限定するものではないが、できるだけ低温で軟化し、且
ぬれ性が高いといった特徴をもつものが好ましい。
The particle size of the frit-like glaze component is desirably adjusted to between 40 and 160 microns. The frit-like glaze component is not particularly limited, but it is preferably one that has the characteristics of being softened at as low a temperature as possible and having high wettability.

従来の釉薬溶射技術では、溶射の際セメン1〜硬化体の
セメント水和物(たとえばCa(OH)2゜ケーイ酸カ
ルシウム水和物)の結合水が脱水して水蒸気が発生した
り、添加剤中の有機成分の分解によるカスが発生して釉
薬の溶着を阻害するという欠点があったが、本発明はあ
らかじめセメント硬化体を仮焼することにより、溶射時
にはセメント硬化体中の蒸発成分が存在しないため、溶
融した釉薬の密着が阻害されることなく、釉面が平滑で
しかも、発泡、ハジキ等の欠点がないすぐれた釉面をも
つセメント硬化体が(qられる。
In conventional glaze spraying technology, during thermal spraying, the bound water of cement 1 to hardened cement hydrate (e.g. Ca(OH)2゜calcium silicate hydrate) is dehydrated and water vapor is generated, and additives are However, in the present invention, by pre-calcining the hardened cement, the evaporated components in the hardened cement are not present at the time of thermal spraying. As a result, the adhesion of the molten glaze is not inhibited, and a hardened cement body with a smooth glazed surface and an excellent glazed surface free from defects such as foaming and repellency is produced.

まIc、仮焼温度によっては、ヒメン(へ硬化体の強度
が劣化することも考えられるが、この時には、本出願人
がかつて特願昭52−87196で出願したように、後
で再水和処理を施せば強度が回復するため、強度上問題
は全くない。
However, depending on the calcination temperature, the strength of the hardened product may deteriorate, but in this case, as the applicant once filed in Japanese Patent Application No. 52-87196, rehydration may be necessary. There is no problem with the strength, as the strength will be restored after treatment.

なお、仮焼による、水蒸気、〕jスの排出作用は前述の
如く炉中で行なった方が確実に行えるが、かならずしも
それに限定Jることなく、釉薬溶射を行う前にトーチな
どで表面を十分に加熱して、蒸気等を排出させCもよい
。特に、この場合には、既に施工された建築物への補修
ができるといった長所がある。
Note that the evacuation of water vapor and soot during calcination can be more reliably performed by performing it in a furnace as described above, but this is not necessarily the case. C may also be used by heating to a temperature of In particular, this case has the advantage that repairs can be made to buildings that have already been constructed.

(実施例) セメント 100重量部 セメント硬化体 骨材 100 ll の原料組成物 (シャモット) 石綿 5 II 水 35 上記原料組成物を混練、成形し、さらに水和硬化させて
セメント硬化体とした。
(Example) Cement 100 parts by weight Hardened cement Aggregate 100 ll Raw material composition (Chamotte) Asbestos 5 II Water 35 The above raw material composition was kneaded and molded, and further hydrated and hardened to obtain a hardened cement.

次に、このセメンl−硬化体を800℃の炉中で2時間
仮焼した。
Next, this cement L-hardened body was calcined in a furnace at 800°C for 2 hours.

仮焼したセメン1〜Wl!化体の表面に、下記フリット
を溶銅した。
Calcined cement 1~Wl! The following frit was molten copper on the surface of the composite.

フリット 日向産業(株)製M25 粒度60〜100μに調整 溶射カンは、メテコ製5Pガンを使用 仮焼によるセメント硬化体の強度低下を回復させるため 60℃×100%Rl−I X 48時間の条件で蒸気
養生した。
Frit: M25 manufactured by Hyuga Sangyo Co., Ltd. Particle size adjusted to 60 to 100 μ The spray gun is a 5P gun manufactured by Metco. Conditions of 60°C x 100% Rl-I x 48 hours to recover the strength loss of hardened cement due to calcination. It was steam cured.

その結果、表面が平滑で、発泡、ハジキのない均一な釉
面をもつセメント硬化体が得られIこ。
As a result, a hardened cement product with a smooth surface and a uniform glazed surface without foaming or repelling was obtained.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例を示す図である。 1・・・セメント硬化体 2・・・炉 3・・・カス溶射またはプラズマ溶射 特許出願人 伊奈製陶株式会社 第1図 0二二二二コヘ7 ↓ 手続打■ヱE書(方式) %式% 1、事件の表示 昭和59年特許願第13797号 2、発明の名称 施釉ごメント製品の製造方法 3、補正をする者 事件との関係 特許出願人 住所 〒479 愛知県常滑市II江本町3丁目6番地
ff105693−5−2700 4、補正命令の日付 昭和59年4月4日(発送日:59.4..24)5、
補正の対象 1) 明細書全文 6、補止の内容 1) 明細書の浄書(内容に変更なし)手続ネ1tj正
書(自発) 昭和59年6月1 日 特許庁長官 若杉 和犬 殿 2、発明の名称 施釉セメント製品の製造方法 3、補正をする者 事件との関係 特許出願人 住所 〒479 愛知県常滑市鯉江木町3丁目6番地3
05693−5−2700 4、補正命令゛の日付 自発による補正 6、補正の内容 1)明細書第3頁第20行目から第4頁第1行目に記載
の「500℃以上好ましくは60.0℃以上の温度」を
、「200℃以上、好ましくは300℃以上950℃以
下の温度」と訂正する。 2)明細書箱4頁4行目F水や、」の後に以下の文言を
挿入する。 「セメント自体から発生する各種ガスや、」3)明細書
第4頁9行目[・・・・・・できる。」の後に以下の文
言を挿入する。 [ガス溶射又はプラズマ溶射3とは、ガス又はプラズマ
を用いて、溶融した釉薬成分をセメント硬化体に吹きつ
(プで該表面に溶着させたり、特開昭52−10341
3号公報に記載の如く、あらかじめセメント硬化体の表
面に塗布された釉薬成分を該ガス又はプラズマを用いて
溶融させて溶tt−yる技術を指す。」
FIG. 1 is a diagram showing an embodiment of the present invention. 1...Cement hardened body 2...Furnace 3...Cast spraying or plasma spraying patent applicant Ina Seito Co., Ltd. Figure 1 02222 Cohe 7 ↓ Procedures ■ヱE book (method) % Formula % 1. Indication of the case Patent Application No. 13797 of 1982 2. Name of the invention Method for manufacturing glazed products 3. Person making the amendment Relationship to the case Patent applicant address 479 II Ehonmachi, Tokoname City, Aichi Prefecture 3-6 ff105693-5-2700 4. Date of amendment order: April 4, 1982 (shipment date: 59.4..24) 5.
Subject of amendment 1) Full text of the specification 6, Contents of amendment 1) Engraving of the specification (no change in content) Procedures 1 tj original copy (spontaneous) June 1, 1980 Commissioner of the Patent Office Mr. Wanu Wakasugi 2, Name of the invention Method for manufacturing glazed cement products 3, Relationship with the case of the person making the amendment Patent applicant address 3-6-3 Koiegicho, Tokoname City, Aichi Prefecture 479
05693-5-2700 4. Date of amendment order Voluntary amendment 6. Contents of amendment 1) From page 3, line 20 of the specification to page 4, line 1 of ``500°C or higher, preferably 60°C. "Temperature of 0°C or higher" is corrected to "Temperature of 200°C or higher, preferably 300°C or higher and 950°C or lower." 2) Insert the following words after "F Water," on page 4, line 4 of the statement box. "Various gases generated from the cement itself," 3) Page 4, line 9 of the specification [...can be done. Insert the following words after ``. [Gas spraying or plasma spraying 3 refers to blowing a molten glaze component onto a hardened cement body using gas or plasma (or welding it to the surface with a sprayer, or
As described in Publication No. 3, it refers to a technique in which a glaze component previously applied to the surface of a hardened cement body is melted using the gas or plasma. ”

Claims (1)

【特許請求の範囲】[Claims] セメントに水及び必要により骨材、Ill帷、各種添加
剤等を加えた原料組成物を混線、成形、水和硬化させC
なるセメント硬化体を、予め仮焼し、次にガス溶射また
はプラズマ溶削により釉薬成分をセメント硬化体表面上
に溶着させてなる施釉セメント製品の製造方法。
C
A method for producing a glazed cement product, which comprises preliminarily calcining a hardened cement product, and then welding a glaze component onto the surface of the hardened cement product by gas spraying or plasma cutting.
JP1379784A 1984-01-27 1984-01-27 Manufacture of glazed cement product Granted JPS60161382A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1379784A JPS60161382A (en) 1984-01-27 1984-01-27 Manufacture of glazed cement product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1379784A JPS60161382A (en) 1984-01-27 1984-01-27 Manufacture of glazed cement product

Publications (2)

Publication Number Publication Date
JPS60161382A true JPS60161382A (en) 1985-08-23
JPS646150B2 JPS646150B2 (en) 1989-02-02

Family

ID=11843240

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1379784A Granted JPS60161382A (en) 1984-01-27 1984-01-27 Manufacture of glazed cement product

Country Status (1)

Country Link
JP (1) JPS60161382A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59199592A (en) * 1983-04-27 1984-11-12 積水化学工業株式会社 Manufacture of cement formed body
JPS6395179A (en) * 1986-10-03 1988-04-26 株式会社イナックス Method of glazing cement product
JPS63100085A (en) * 1986-10-16 1988-05-02 株式会社イナックス Elongated glazed prestressed concrete material and manufacture
JPH01100075A (en) * 1987-10-13 1989-04-18 Nippon Steel Corp Baking of glaze on concrete substrate

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58151387A (en) * 1982-03-03 1983-09-08 工業技術院長 Manufacture of glazed cement formed body

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58151387A (en) * 1982-03-03 1983-09-08 工業技術院長 Manufacture of glazed cement formed body

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59199592A (en) * 1983-04-27 1984-11-12 積水化学工業株式会社 Manufacture of cement formed body
JPH0339032B2 (en) * 1983-04-27 1991-06-12 Sekisui Chemical Co Ltd
JPS6395179A (en) * 1986-10-03 1988-04-26 株式会社イナックス Method of glazing cement product
JPS63100085A (en) * 1986-10-16 1988-05-02 株式会社イナックス Elongated glazed prestressed concrete material and manufacture
JPH01100075A (en) * 1987-10-13 1989-04-18 Nippon Steel Corp Baking of glaze on concrete substrate

Also Published As

Publication number Publication date
JPS646150B2 (en) 1989-02-02

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