JPS60133058A - Composite resin composition - Google Patents
Composite resin compositionInfo
- Publication number
- JPS60133058A JPS60133058A JP24101983A JP24101983A JPS60133058A JP S60133058 A JPS60133058 A JP S60133058A JP 24101983 A JP24101983 A JP 24101983A JP 24101983 A JP24101983 A JP 24101983A JP S60133058 A JPS60133058 A JP S60133058A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- glass
- softening point
- decomposition temperature
- manufactured
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000000805 composite resin Substances 0.000 title claims description 9
- 239000011521 glass Substances 0.000 claims abstract description 33
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 12
- 239000000057 synthetic resin Substances 0.000 claims abstract description 12
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims description 6
- 229920005989 resin Polymers 0.000 abstract description 20
- 239000011347 resin Substances 0.000 abstract description 20
- 238000000465 moulding Methods 0.000 abstract description 11
- 239000006104 solid solution Substances 0.000 abstract description 6
- 238000004898 kneading Methods 0.000 abstract description 5
- 238000010348 incorporation Methods 0.000 abstract 2
- -1 polyethylene Polymers 0.000 description 7
- 239000008188 pellet Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920006393 polyether sulfone Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 239000004695 Polyether sulfone Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000005385 borate glass Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000005355 lead glass Substances 0.000 description 2
- 239000005365 phosphate glass Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920006389 polyphenyl polymer Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920001342 Bakelite® Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- AQLMHYSWFMLWBS-UHFFFAOYSA-N arsenite(1-) Chemical compound O[As](O)[O-] AQLMHYSWFMLWBS-UHFFFAOYSA-N 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000005387 chalcogenide glass Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- ZPPSOOVFTBGHBI-UHFFFAOYSA-N lead(2+);oxido(oxo)borane Chemical compound [Pb+2].[O-]B=O.[O-]B=O ZPPSOOVFTBGHBI-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、複合樹脂組成物に関し、詳しくは成形収縮率
が極めて小さく、衝撃強度、誘電率、難燃性等の優れた
複合樹脂組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a composite resin composition, and more particularly to a composite resin composition that has extremely low mold shrinkage and is excellent in impact strength, dielectric constant, flame retardance, etc.
従来より合成樹脂に無機充填材を配合した組成物は、物
性が改善されることが知られており、各種用途に巾広く
利用されている。しかしながら、従来配合されている充
填材は、樹脂中に分散系として存在しているため外的応
力の集中点となり、機械的性質を低下させ、かつ成形収
縮率が大きいなどの問題があった。BACKGROUND ART Compositions made by blending inorganic fillers with synthetic resins have been known to have improved physical properties and are widely used in various applications. However, fillers that have been conventionally blended exist as a dispersed system in the resin, which causes problems such as a concentration point of external stress, deterioration of mechanical properties, and a high molding shrinkage rate.
そこで、５本発明者らは機械的性質に優れ、成形収縮率
が小さく、かつ誘電率などに優れた樹脂組成物を開発す
べく研究した結果、特定のガラスを配合することにより
、合成樹脂とガラスが固溶丼化状態となる組成物が得ら
れ、これが」ニ記目的、特に機械的性質に優れているこ
とを見い出し、本発明を完成した。Therefore, the present inventors conducted research to develop a resin composition with excellent mechanical properties, low mold shrinkage, and excellent dielectric constant, etc., and found that by blending a specific glass, it The present invention was completed based on the discovery that a composition in which the glass is in a solid solution bowl state is obtained, and that this composition has excellent mechanical properties, in particular, for the above objects.
すなわち、本発明は合成樹脂に該合成樹脂の分解温度以
下の温度で塑性軟化する低軟化点ガラスを配合してなる
複合樹脂組成物である。That is, the present invention is a composite resin composition formed by blending a synthetic resin with a low softening point glass that plastically softens at a temperature below the decomposition temperature of the synthetic resin.
本発明に用いる合成樹脂としては特に制限はなく、熱可
塑性樹脂および熱硬化性樹脂のいずれでも良い。熱可塑
性樹脂としては、例えばポリエチレン、ポリプロピレン
、アクリロニトリル−ブタジェン−スチレン樹脂（ＡＢ
Ｓ樹脂）、アクリロニトリル−スチレン樹脂（ＡＳ 樹
脂）、ナイロン−６やナイロン−６，６などのポリアミ
ド樹脂、ポリスチレン、ポリエーテル、ポリエチレンテ
レフタレートやポリブチレンテレフタレートなどのポリ
エステル、ポリカーボネート、ポリ塩化ビニル。The synthetic resin used in the present invention is not particularly limited, and may be either a thermoplastic resin or a thermosetting resin. Examples of thermoplastic resins include polyethylene, polypropylene, acrylonitrile-butadiene-styrene resin (AB
S resin), acrylonitrile-styrene resin (AS resin), polyamide resins such as nylon-6 and nylon-6,6, polystyrene, polyether, polyesters such as polyethylene terephthalate and polybutylene terephthalate, polycarbonate, and polyvinyl chloride.
ポリエーテルサルホン、ポリメチルメタアクリレ−卜、
ポリオキシメチレン、ポリサルフオン、ポリフェニルオ
キサイド、合成ゴム等を挙げることができる。また、熱
硬化性樹脂としては例えばメラミン樹脂、ユリア樹脂、
フェノール樹脂、ケイ素ｍｔｆ、エポキシ樹脂、アルキ
ド樹脂、不飽和ポリエステル樹脂、ウレタン樹脂、ポリ
イミド樹脂等を挙げることができる。polyether sulfone, polymethyl methacrylate,
Examples include polyoxymethylene, polysulfone, polyphenyl oxide, and synthetic rubber. In addition, examples of thermosetting resins include melamine resin, urea resin,
Examples include phenol resin, silicon mtf, epoxy resin, alkyd resin, unsaturated polyester resin, urethane resin, and polyimide resin.
次に、」下記樹脂の分解温度以下の温度で塑性軟化する
低軟化点ガラスとしては、種々のものがあるが、とりわ
け軟化点４００°Ｃ以下のガラスが好捷しい。このよう
なガラスとしてはケイ酸塩ガラス、リン酸塩ガラス、ホ
ウ酸塩ガラス、鉛ガラス。Next, although there are various kinds of low softening point glasses that plastically soften at temperatures below the decomposition temperature of the resin described below, glasses with a softening point of 400° C. or below are particularly preferred. Such glasses include silicate glasses, phosphate glasses, borate glasses, and lead glasses.
バリウムガラス、ゲルマン酸塩ガラス、アルミン酸塩ガ
ラス、バナジン酸塩ガラス、亜砒酸塩ガラス、タングス
テン酸塩ガラス、モリブデン酸塩ガラス、硫酸塩ガラス
、ノ・ロゲン化物ガラス、カルコゲナイドガラス、水利
ガラス、水溶性ガラス等を単独であるいは組み合わせた
ものが挙げられる。Barium glass, germanate glass, aluminate glass, vanadate glass, arsenite glass, tungstate glass, molybdate glass, sulfate glass, norogenide glass, chalcogenide glass, water conservancy glass, water-soluble Examples include glass and the like alone or in combination.
本発明において合成樹脂と低軟化点ガラスの配合量は目
的とする樹脂組成物の物性、使用する成分の種類により
異なり一義的に決定されない。通常は合成樹脂の配合量
は５〜９０重量％、好ましくは１０〜８０重量％、ガラ
ス配合量１０〜９５重量％、好ましくは２０〜９０重量
％である。合成樹脂量が５重量％未満であると、固溶化
するための樹脂が不足し、固溶化が不充分であり、９０
重量％を超えると、目的とする物性が得られず実用的で
ない。In the present invention, the blending amounts of the synthetic resin and low softening point glass vary depending on the physical properties of the intended resin composition and the types of components used, and are not uniquely determined. Usually, the synthetic resin content is 5 to 90% by weight, preferably 10 to 80% by weight, and the glass content is 10 to 95% by weight, preferably 20 to 90% by weight. If the amount of synthetic resin is less than 5% by weight, there will be insufficient resin for solid solution formation, and solid solution formation will be insufficient.
If it exceeds % by weight, the desired physical properties cannot be obtained and it is not practical.
本発明の樹脂組成物は上記樹脂およびガラスを混練する
ことにより得られるが、固溶化状態として得られること
に特色がある。混練は通常行なわシ
れている方法、例えばバンバリーミキザー、軸押出機、
ニ軸押出機等の混線機を用いて行なわれる。The resin composition of the present invention can be obtained by kneading the above-mentioned resin and glass, and is characterized by being obtained in a solid solution state. Kneading is usually carried out using conventional methods such as Banbury mixer, screw extruder,
This is carried out using a mixer such as a twin-screw extruder.
特にガラスの軟化点より＋１０°Ｃ以上の温度で、樹脂
の分解温度以下で行なうことが好ましい。混練時間につ
いては特に制限はないが、バンバリーミキサ−を用いた
場合は、通常１５〜２０分間程度である。また、混線に
際して予め予備混合しておくことが好ましい。In particular, it is preferable to carry out the reaction at a temperature of +10° C. or more above the softening point of the glass and below the decomposition temperature of the resin. There is no particular restriction on the kneading time, but when a Banbury mixer is used, the kneading time is usually about 15 to 20 minutes. Further, it is preferable to pre-mix the components beforehand.
次いで、このようにして得られた複合樹脂組成物をペレ
ット化し、さらにこのペレットを射出成形、押出成形等
の成形手段により適宜形状に成形して各種成形品を製造
することができる。ここで成形温度はガラスの軟化点よ
り４−１０°Ｃ以上でありに樹脂の分解温度以下の温度
で行なうことが好ましい。成形温度および上記の混線温
度をともにガラスの軟化点より＋１０°Ｃ以上であり、
樹脂分解温度以下の温度とすることにより樹脂中のガラ
スを融解させ、樹脂を分解することなく、冷時下に分散
系的ではなく固溶〆化状態で強力な結合が得られるので
ある。Next, the composite resin composition thus obtained is pelletized, and the pellets are further molded into an appropriate shape by a molding means such as injection molding or extrusion molding to produce various molded products. Here, the molding temperature is preferably 4-10°C or higher than the softening point of the glass and lower than the decomposition temperature of the resin. Both the molding temperature and the above crosstalk temperature are +10°C or higher than the softening point of the glass,
By setting the temperature below the resin decomposition temperature, the glass in the resin is melted, and a strong bond can be obtained in a solid solution state rather than a dispersion state under cold conditions without decomposing the resin.
したがって、本発明の複合樹脂組成物によれば、機械的
性質、とりわけ衝撃強度にすぐれた成形品を得ることが
できる。しかも、本発明の複合樹脂組成物は成形時にお
ける成形収縮率がきわめて小さく、かつ成形性にすぐれ
ており、成形外観も良好である。さらに、本発明の複合
樹脂組成物は難燃性に優れ、燃焼の際に有毒ガス等の発
生が少ない。また、成形品は誘電率に優れている。Therefore, according to the composite resin composition of the present invention, a molded article having excellent mechanical properties, particularly impact strength, can be obtained. Moreover, the composite resin composition of the present invention has extremely low molding shrinkage during molding, has excellent moldability, and has a good molded appearance. Furthermore, the composite resin composition of the present invention has excellent flame retardancy and generates little toxic gas when burned. Furthermore, the molded product has excellent dielectric constant.
したがって、本発明の樹脂組成物は精密工業部材、建材
、オフィス機器ハウジング、音響部品。Therefore, the resin composition of the present invention can be used as precision industrial parts, building materials, office equipment housings, and acoustic parts.
自動車部品などの素材として有効に利用し得る。It can be effectively used as a material for automobile parts, etc.
次に、本発明を実施例により詳しく説明する。Next, the present invention will be explained in detail with reference to examples.
実施例１〜１８および比較例１〜７
第２表に示す成分を所定桁配合し、５ＱＴｎＴｎφ−軸
押出機（ナカタニ機械■製）にて第１表に示す温度で混
練押出しし、ペレットを作製した。ペレットを１０オン
ス射出成形機（東芝機械■製）を用い第１表に示す温度
で１５０ｍ＋ｎＸ ｌ ５ Ｑ＋＋ｏ＋＋Ｘ３．２ｍｍ
のプレートを作製し、評価を行なった。配合割合および
評価結果を第２表に示す。なお、評価は下記の方法によ
り行なった。Examples 1 to 18 and Comparative Examples 1 to 7 The components shown in Table 2 were blended in a predetermined order, and the mixture was kneaded and extruded using a 5QTnTnφ-shaft extruder (manufactured by Nakatani Kikai ■) at the temperature shown in Table 1 to produce pellets. did. Using a 10 oz injection molding machine (manufactured by Toshiba Machine ■), the pellets were molded into 150m+n
A plate was prepared and evaluated. The blending ratios and evaluation results are shown in Table 2. In addition, the evaluation was performed by the following method.
評価方法
１ 成形収縮率
プレート成形から、２４時間経過後のプレートの冊およ
びＴＤ 方向の寸法を測定し、金型寸法から収縮率を計
算した。Evaluation method 1 Molding shrinkage rate After 24 hours had elapsed from plate molding, the dimensions of the plate in the book and TD directions were measured, and the shrinkage rate was calculated from the mold dimensions.
２ アイゾツト衝撃試験
ＡＳＴＭＤ −２５６に準拠
３ 誘電率
ＡＳＴＭ Ｄ −１５０に準拠
４ 難燃性
ＵＬ−９４の燃焼試験法に準拠、難燃度の高さは以下の
順序である。2 Izot impact test in accordance with ASTM D-256 3 Dielectric constant in accordance with ASTM D-150 4 Flame retardancy In accordance with the UL-94 combustion test method, the height of flame retardancy is in the following order.
Ｖ −０＞Ｖ −１＞Ｖ −２＞ＨＢ
５ 成形性
■メルトフローインデックス（Ｍ、Ｆ、１．）ＪＩＳＫ
−７２１０に準拠。V -0>V -1>V -2>HB 5 Formability ■Melt flow index (M, F, 1.) JISK
-Compliant with 7210.
■成形外観
成形収縮率の測定に使用したプレートの外観を目視によ
り判定した。■ Molding appearance The appearance of the plate used for measuring the molding shrinkage rate was visually judged.
実施例１９〜２４
リン酸塩、系ガラス（水溶性ガラス二大平化学工業■製
、軟化温度２８０°Ｃ）を５０％水溶液とし、これに第
２表に示す合成樹脂を所定量配合し、ヘンシェルミキサ
ーで温度１５０℃で３０分間混練した。次いで、ベント
付き５０關φ−軸押出機（ナカタニ機械■製）にて第１
表に示す温度で混線押出しし、ペレットを作製した。得
られたペレットを１０オンス射出成形機にて第１表に示
す温度で、１５０祁Ｘ １５０＋ｏ＋Ｘ ３．２關のプ
レー１・を作製した。このプレートについて実施例１と
同様に評価を行なった。評価結果を第２表に示す。Examples 19-24 A 50% aqueous solution of phosphate and glass (manufactured by Water Soluble Glass Ni-Ohira Kagaku Kogyo ■, softening temperature 280°C) was mixed with a predetermined amount of the synthetic resin shown in Table 2, and Henschel The mixture was kneaded using a mixer at a temperature of 150° C. for 30 minutes. Next, a 50 mm φ-shaft extruder with a vent (manufactured by Nakatani Kikai ■) was used to extrude the first
Pellets were produced by cross-wire extrusion at the temperature shown in the table. The obtained pellets were used in a 10-ounce injection molding machine at the temperature shown in Table 1 to produce a play 1 of 150 x 150 + o + x 3.2. This plate was evaluated in the same manner as in Example 1. The evaluation results are shown in Table 2.
本庄： 熱硬化性樹脂（フェノール樹脂）の場合はガラ
スと常温にて予備混合した後、射出成形機により成形を
行なった。Honjo: In the case of thermosetting resin (phenol resin), it was premixed with glass at room temperature and then molded using an injection molding machine.
＊１ ・ＰＥＳ ：ポリエーテルサルフオン（インペリ
アル番ケミカル・インダストリーズ・
リミテッド製、 「ＶＩＣＴＲＥｘ３００Ｐ」）ＰＰ：
ポリゾロピレン（出光石油化学■製、ｒＪ−２０００Ｇ
Ｊ ）
ＡＢＳ ：アクリロニトリルーブタジエンースチレン樹
脂（宇部ザイフン■製、
ｒ’ＥＸ −１５１，１’）
ＰＰＳ ：ポリフェニルサルファイド（信越化学工業■
製、「ライドンＲ−４Ｊ）
フェノール ：フェノール樹脂（住友ベークライト■製
、ｒＰＭ−９３００ＪＪ）
／リコンゴノ・：信越化学工業■製、ｒ−ＫＥ−９７１
ｕ−１）ＰＥＴ ：ポリエチレンテレフタレート（日本
ユニベット■製、ｒＲＴ−５８０Ｊ）
ＰＥ：ポリエチレン（出光石油化学■製、ｒｌｌＯＪＪ
）
ｐｖｃ ：ポリビニルクロライド（信越化学工業■製、
ｒ’ＴＫ−１０００」）
＊２ ・Ａ：、ホウ酸鉛ガラス（東芝硝子■製）Ｂニホ
ウ酸鉛ガラス（東芝硝子■製）
Ｃ： 〃 （〃 ）
Ｄ：鉛ガラス（日本フエロウ■製）
Ｅ：水溶性ガラス（リン酸塩系ガラス）（太平化学工業
■製）
Ｆニホウケイ酸塩ガラス（日本フエロウ■製）
Ｇニホウケイ酸塩ガラス（日本フエロウ■製）*1 ・PES: Polyether sulfon (manufactured by Imperial Chemical Industries Limited, "VICTREx300P") PP:
Polyzolopyrene (manufactured by Idemitsu Petrochemical ■, rJ-2000G
J) ABS: Acrylonitrile-butadiene-styrene resin (manufactured by Ube Zaifun ■, r'EX-151,1') PPS: Polyphenyl sulfide (Shin-Etsu Chemical ■)
manufactured by Rydon R-4J) Phenol: Phenol resin (manufactured by Sumitomo Bakelite ■, rPM-9300JJ) / Recongono: manufactured by Shin-Etsu Chemical ■, r-KE-971
u-1) PET: Polyethylene terephthalate (manufactured by Nippon Unibet ■, rRT-580J) PE: Polyethylene (manufactured by Idemitsu Petrochemical ■, rllOJJ
) pvc: polyvinyl chloride (manufactured by Shin-Etsu Chemical,
r'TK-1000'') *2 ・A: Lead borate glass (manufactured by Toshiba Glass ■) B Lead diborate glass (manufactured by Toshiba Glass ■) C: 〃 (〃 ) D: Lead glass (manufactured by Nippon Fellow ■) E: Water-soluble glass (phosphate glass) (manufactured by Taihei Kagaku Kogyo ■) F Niborosilicate glass (manufactured by Nippon Fellow ■) G Niborosilicate glass (manufactured by Nippon Fellow ■)
Claims (1)
塑性軟化する低軟化点ガラスを配合してなる複合樹脂組
成物。tll A composite resin composition formed by blending a synthetic resin with a low softening point glass that plastically softens at a temperature below the decomposition temperature of the synthetic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24101983A JPS60133058A (en) | 1983-12-22 | 1983-12-22 | Composite resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24101983A JPS60133058A (en) | 1983-12-22 | 1983-12-22 | Composite resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS60133058A true JPS60133058A (en) | 1985-07-16 |
Family
ID=17068122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24101983A Pending JPS60133058A (en) | 1983-12-22 | 1983-12-22 | Composite resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60133058A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63305168A (en) * | 1987-06-05 | 1988-12-13 | Matsushita Electric Works Ltd | Resin composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5230853A (en) * | 1975-09-03 | 1977-03-08 | Takashi Ishikawa | Flame-retardant synthetic resin |
| JPS5514810A (en) * | 1978-07-14 | 1980-02-01 | Toshiba Corp | Metal anticorrosive |
| JPS5595642A (en) * | 1979-01-09 | 1980-07-21 | Int Standard Electric Corp | Glass composition for water hardenable ionn polymer cement |
| JPS5667363A (en) * | 1979-11-05 | 1981-06-06 | Furukawa Electric Co Ltd:The | Highly inorganic substance-filled flame retardant resin composition |
| JPS57162754A (en) * | 1981-03-31 | 1982-10-06 | Mitsubishi Petrochem Co Ltd | Synthetic resin material having excellent light transmittance and heat retaining property |
-
1983
- 1983-12-22 JP JP24101983A patent/JPS60133058A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5230853A (en) * | 1975-09-03 | 1977-03-08 | Takashi Ishikawa | Flame-retardant synthetic resin |
| JPS5514810A (en) * | 1978-07-14 | 1980-02-01 | Toshiba Corp | Metal anticorrosive |
| JPS5595642A (en) * | 1979-01-09 | 1980-07-21 | Int Standard Electric Corp | Glass composition for water hardenable ionn polymer cement |
| JPS5667363A (en) * | 1979-11-05 | 1981-06-06 | Furukawa Electric Co Ltd:The | Highly inorganic substance-filled flame retardant resin composition |
| JPS57162754A (en) * | 1981-03-31 | 1982-10-06 | Mitsubishi Petrochem Co Ltd | Synthetic resin material having excellent light transmittance and heat retaining property |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63305168A (en) * | 1987-06-05 | 1988-12-13 | Matsushita Electric Works Ltd | Resin composition |
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