JPS60121296A - Metallic strip for roll power supply surface treatment - Google Patents

Metallic strip for roll power supply surface treatment

Info

Publication number
JPS60121296A
JPS60121296A JP22920083A JP22920083A JPS60121296A JP S60121296 A JPS60121296 A JP S60121296A JP 22920083 A JP22920083 A JP 22920083A JP 22920083 A JP22920083 A JP 22920083A JP S60121296 A JPS60121296 A JP S60121296A
Authority
JP
Japan
Prior art keywords
power supply
roll
roll power
surface treatment
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP22920083A
Other languages
Japanese (ja)
Other versions
JPH0530918B2 (en
Inventor
Kazuo Chiba
千葉 和郎
Koji Mitamura
三田村 康二
Hisashi Shimizu
久 清水
Isao Takeuchi
竹内 庸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MA Aluminum Corp
Original Assignee
Mitsubishi Aluminum Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Aluminum Co Ltd filed Critical Mitsubishi Aluminum Co Ltd
Priority to JP22920083A priority Critical patent/JPS60121296A/en
Publication of JPS60121296A publication Critical patent/JPS60121296A/en
Publication of JPH0530918B2 publication Critical patent/JPH0530918B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE:To provide the titled metallic strip with a small loss of voltage in a roll power supply surface treatment and enabling the supply of a high current at a stable voltage by regulating appropriately the roughness of the surface on the roll power supply side. CONSTITUTION:The generation of a voltage drop in a roll power supply surface treatment can be prevented, and the roll power supply surface treatment can be efficiently carried out with a supply of a high current at a stable voltage by regulating the mean roughness at the center line of the surface on the roll power supply side of a metallic strip for the roll power supply surface treatment to <=about 0.3mum. In addition, the cost of the treatment can be reduced by preventing the generation of arc spots to reduce the damage of the metallic strip or the power supply roll. The mean roughness at the center line of the surface on the roll power supply side is preferably regulated to >=0.05mum from the standpoint of the polishing cost and the life of the strip, and the mean roughness at the center line on the surface opposite to the roll power supply side is desirably regulated to about 0.25-0.45mum to prevent the defects such as decalescence or the roll marks remaining after polishing.

Description

【発明の詳細な説明】 〔並業上の利用分野〕 本発明は、例えば建材、PS板用等の連続アルマイト(
電路着色)処理、コンデンサー用等の電解エツチング処
理、又は連続メノギ処理といったロール給電表111」
処理に用いられるロール給電表面処理用金属ストリップ
に係り、特に金属ストリングのロール給電側表面の中心
線平均粗さを約0.3 tll+nl以下にしておくこ
とによって、ロール給電表面処理に際して電圧損失が少
なく、すなわち女疋な電圧で大電流を供給して処理でき
るよりになり、そしてロール給電表面処理が効果的に行
なわれるようになり、しかも処理に際して金属ストリッ
プあるいは給電ロールが損傷することがなく、処理が低
コストに行なえるものとなるロール給電表面処理用金属
ストリップに係るものである。
[Detailed Description of the Invention] [Field of Application in the Ordinary Industry] The present invention is directed to continuous anodized aluminum (for example, for building materials, PS boards, etc.)
Roll power supply table 111, such as electric circuit coloring) treatment, electrolytic etching treatment for capacitors, or continuous agate treatment.
Regarding the metal strip for roll feeding surface treatment used in the treatment, in particular, by keeping the center line average roughness of the roll feeding side surface of the metal string to about 0.3 tll+nl or less, voltage loss can be reduced during roll feeding surface treatment. In other words, it is now possible to process by supplying a large current at a low voltage, and the roll feeding surface treatment can be performed effectively, and the metal strip or the feeding roll is not damaged during processing. This invention relates to a metal strip for roll feeding surface treatment which can be carried out at low cost.

〔従来技術と問題点〕[Conventional technology and problems]

ロール給電表面処理、例えば連@電解処理は、その概略
を図面に示すような連続電解処理装置によって行なわれ
ている。
Roll feeding surface treatment, for example continuous @electrolytic treatment, is carried out using a continuous electrolytic treatment apparatus as schematically shown in the drawings.

tなわち、金属ストリップ(アルミニウムコイル)1は
、電解槽の入側前方に適宜の位置を採って設けられたガ
イドローラ2から′電解槽の入側上部に設けられた給電
ロール3に巻き付けられて電所槽内における浸漬ロール
に導かれた後、所要の電解処理が与えられるものであり
、そしてこのような金属ストリップに対する給電をなす
為におさえロール/1を硬質コムのような絶縁性の硬賀
利−C構成し、このような月質のお妊えロール4の下方
に電気伝導性の艮い材質、例えば金属層で構成された給
′亀ロール3を設け、きしに図示はしていないがこのお
さえロール11に抑圧機構を配設し、給電ロール:うか
あ・さえロール4に対して圧着するよう構成されている
That is, a metal strip (aluminum coil) 1 is wound from a guide roller 2 provided at an appropriate position in front of the entrance side of the electrolytic cell to a power supply roll 3 provided at the upper part of the entrance side of the electrolytic cell. After being guided through immersion rolls in a power station bath, the required electrolytic treatment is applied and the holding roll/1 is covered with an insulating material such as a hard comb to provide electrical power to such metal strips. A feeding roll 3 made of an electrically conductive material such as a metal layer is provided below the lunar pregnancy roll 4. Although not included, a suppressing mechanism is disposed on this presser roll 11, and the presser roll 11 is configured to be press-bonded to the power supply roll: presser roll 4.

同、5は、給電ロール;3とお延えロール4との間の削
1.111’ 111Qに設けられた冷却液スプレーノ
ズルであり、この(M却lイタスプレーノズル5より冷
却液が給電ロール、3の圧着てれる部分に吐出供給され
、そし−C/″1′¥却液スプレーノズル5に対向して
おさえロール・1とイ6′屯ロール;3との間の後面側
には冷却液スフレーノズル6が設けられており、この冷
却7P1.スプレーノズル6によって給電を受けた金属
ストリップ1を適当に冷却Jさせるようになっている。
5 is a cooling liquid spray nozzle installed in the cut 1.111' 111Q between the power supply roll 3 and the rolling roll 4, and the cooling liquid is sprayed from the spray nozzle 5 onto the power supply roll. , 3 is discharged and supplied to the crimped part, and the cooling liquid is supplied to the rear side between the pressure roll 1 and the 6'roll; A liquid souffle nozzle 6 is provided, and this cooling 7P1 spray nozzle 6 is used to suitably cool the metal strip 1 which is supplied with electricity.

目1■記のようンよ例えば連@電解処理装置における電
解処理に際して、給醒部において大きな電圧降下が起き
る場合かあり、すなわち犬@な電圧降−トが起きてアー
クスポット等のトラブルが発生ずる場合カムある。すな
わち、局部的に抵抗の小さな部分に酸流が集中し、発熱
、アークが飛ひ、金属ストリップ並びに給電ロールが損
傷する場合がある。
As mentioned in item 1, for example, during electrolytic treatment in a continuous electrolytic treatment device, a large voltage drop may occur in the supply section, which can cause problems such as arc spots. There is a cam when it occurs. In other words, the acid stream may locally concentrate on a portion of low resistance, causing heat generation, arcing, and damage to the metal strip and power supply roll.

そして、アークスポットに至らずとも金属ストリップの
連続処理の場合、例えば4 +J O(J〜5000ア
ンペアといった数千アンペアという大電流が用いられる
ので、電圧降下に応じて発熱が極めて大きく、冷却液ス
プレー等冷却機構にも犬がかりな設備勿璧するようにな
り、それだけ装置の大型化、コスト高となり、し刀)も
この電力は電解に全く寄与しない無駄なものであり、そ
れだけランニング処理コストも高いものとなる。
In the case of continuous processing of metal strips even if an arc spot does not occur, a large current of several thousand amperes, for example 4 The cooling mechanism also requires a lot of equipment, which increases the size and cost of the equipment.Also, this electric power is wasted and does not contribute to electrolysis at all, and the running processing costs are correspondingly high. Become something.

〔発明の開示〕[Disclosure of the invention]

厚与が約02〜Q、5nlInの金属ストリップのロー
ル給′醒囲の中ノし・肪平均粗さくI(a)が約0.3
071m以下であるよう構成しておくことにより、表面
処理に際して電圧降下の発生が防止される。
The average roughness I(a) of the roll-fed metal strip with a thickness of about 02 to Q and 5nlIn is about 0.3.
By configuring it so that it is 0.71 m or less, a voltage drop can be prevented from occurring during surface treatment.

すなわち、本発明者は、電圧降下発生の原因について独
々の研究の結果、金属ストリップのロール給電側面の表
面粗さの程度によって電圧降下の程度(アークスポット
の発生度)が変ることを突き止め、ずなわち甲Iシ・肪
平均粗a (JIS B12O3に規定きれたHa)が
0.31μnl以上の場合には電圧降Fが大きく、アー
クスポット発生率は急凍に著しく大きくなることを見い
出した。
That is, as a result of independent research into the cause of voltage drop, the inventor found that the degree of voltage drop (degree of occurrence of arc spots) changes depending on the degree of surface roughness of the roll feeding side of the metal strip, It was found that when the average roughness a (Ha specified in JIS B12O3) is 0.31μnl or more, the voltage drop F is large and the arc spot occurrence rate becomes significantly large due to rapid freezing. .

同、中心線平均粗さが小でい程電圧降下が小さく望捷し
いものではめったが、すなわちエイ・ルギーロスの少な
い安ボ操業のものであったが、 Raを小さくするに妥
するコストは小さくすればする程急激にJ%l シ、か
つロール寿命も短かくなるため、すなわち研磨コスト及
びロール寿命の面より)(aは005μm以上であるこ
とか望捷しい。
In the same way, the smaller the average roughness of the center line, the smaller the voltage drop, which was rarely desirable, that is, the cheap operation with less energy loss, but the cost that is reasonable for reducing Ra is small. The more the polishing is done, the more rapidly the J%l decreases, and the roll life also becomes shorter (in other words, from the standpoint of polishing cost and roll life) (it is desirable that a is 0.005 μm or more).

尚、より一層望nしい範囲は、Haが010〜025μ
■1のものである。
In addition, a more desirable range is Ha of 010 to 025μ.
■It is from 1.

又、例えは印刷版用アルミニウムストリップ(PS扱)
は、11J処理で表面をブラシ研磨(又は砂目立て)す
るのであるが、この際給電側面と反対側の而(製品面)
の中心線平均粗3が0.25 tr 11+より小さい
場合にはテカリと称する欠陥が起き−やすく、又0.4
5μmより大きな場合には研磨後に圧姑目が残ることが
判明し、従って金属スト1)ラグが印刷版用の場合には
給電91!1面と反対側の而(製品面)の中心線平均粗
さRa f O,25〜0.45 trm、望1しくは
O;30〜0./1.0μmに仕上げておくことが重要
であることも判った。
Also, for example, aluminum strip for printing plates (PS treatment)
The surface is brush-polished (or grained) using 11J treatment, but at this time, the side opposite to the power supply side (product side)
If the center line average roughness 3 is smaller than 0.25 tr 11+, a defect called shine is likely to occur;
It has been found that if the metal strip is larger than 5 μm, the indentation remains after polishing. Roughness Ra f O, 25-0.45 trm, preferably O; 30-0. It was also found that it is important to finish the thickness to /1.0 μm.

同、このように金属ストリップ両面における次面粗さが
異なるものを得るには、表面粗さが互いに異なるローラ
を用いれば良い。
Similarly, in order to obtain a metal strip with different surface roughnesses on both sides, rollers with different surface roughnesses may be used.

〔実施例〕〔Example〕

例えば図111]に示すような金属ストリップに対する
給電装置を用いた連続電解処理装置における処理におい
て、全綱ストリップのロール給電側の表面粗さく J’
IS BO601に規定でれたRa)を0.0 :37
1111.0.04ノ+lrl、0.05μnl、0.
07μIn、o、osμrLoj1/1m、0.17μ
nl、0.1971111.0.25μm s o、2
sμm 1 0.30z+Inといった程度に、かつ反
対側の面における表面粗さく中心線平均粗さHa)を0
.25 ”n* 0.30 pm s O,35tlm
 s 0.40 μm 0.45 Il”1といった程
j及にそれぞれ仕上げた99チAl純度の0.3txt
ouuwコイルを用意し、このコイルに対して硫酸電解
液中で;〕(川用JA給電して連続アルマイト処理をイ
ー4’ yz ″) /ン二。
For example, in the treatment in a continuous electrolytic treatment apparatus using a power supply device for metal strip as shown in FIG.
Ra) specified in IS BO601 is 0.0:37
1111.0.04ノ+lrl, 0.05μnl, 0.
07μIn, o, osμrLoj1/1m, 0.17μ
nl, 0.1971111.0.25 μm s o, 2
sμm 1 0.30z+In, and the surface roughness on the opposite side is 0.
.. 25 ”n* 0.30 pm s O, 35 tlm
s 0.40 μm 0.45 Il”1 0.3txt of 99% Al purity finished respectively
Prepare an ouuw coil, and place this coil in a sulfuric acid electrolyte.

この連■ヅじアルマ’l l−処理に除して、給電ロー
ル側の表1イu粗さと成用降]:並びにアークスポット
の発生率を7Jテずと表1の辿りである。
After this series of alumina treatments, Table 1 shows the roughness and growth rate of the power supply roll and the rate of occurrence of arc spots as shown in Table 1.

〔比戟例] 前記実用例においで述べた給電ロール側の表面粗さく中
!シ緋平均粗さHa)が、例えは0.31μm、0.3
71+m、0.44 /fillといった99%AI純
度で0.3t x 1(JOOWのアルミニウムコイル
音用いて、硫酸電解液中で51JOOA給電して連続ア
ルマイト処理した。
[Comparison example] The surface roughness of the power supply roll side mentioned in the above practical example is medium! The average roughness Ha) is, for example, 0.31 μm, 0.3
71+m, 0.44/fill, 99% AI purity, 0.3t x 1 (JOOW aluminum coil sound), 51JOOA power supply in sulfuric acid electrolyte, continuous alumite treatment.

この)!l:統アルマづト処理に際して、給電ロール側
の表面粗さと電圧時−F並びにアークスポット発生率と
の関係を表2にボす。
this)! Table 2 shows the relationship between the surface roughness of the power supply roll and the voltage -F and arc spot generation rate during the standard aluminate treatment.

表2 〔効果〕 給電ロール側における金属ストリップ&llI+の中ノ
し・線平均粗さが約0.30μill以下であるよつ構
成し−Cおくことにより、給電ロール部での電圧降下は
小さく、従ってエネルギーロスの少ないランニング処理
コストの低摩なものとなる。
Table 2 [Effects] By configuring the metal strip &llI+ on the power supply roll side so that the center cut/line average roughness is approximately 0.30 μill or less, the voltage drop at the power supply roll portion is small, and therefore This results in low friction and low running processing costs with little energy loss.

又、アークスポットが起きにくいものであるから、金属
ストリップを損傷しにりく、金属ストリップの表面処理
の歩留りも高く、従ってそれだけ処理コストも安いもの
となる。
Further, since arc spots are less likely to occur, the metal strip is less likely to be damaged, the yield of surface treatment of the metal strip is high, and the treatment cost is accordingly lower.

又、従来アークスポットが起きる程の大きな電圧降下が
起きなかったにしても、従来では電圧降下の程度が比較
的大きなものであり、冷却機構に特別な工夫を施さなけ
ればならず、それたけ装置の大型化及びコストQ’にも
たらすものであるのに対し、金属ストリップにおける給
電ロール側表面の中心脚平均粗さHaを0.30/Im
以「に構成するの今で電圧降下は小さなものとなり、従
ってこれに起因する発熱量も少なく、装置に特別な冷却
機構を構成する必要はなく、処理装置としても小型で低
コストなものでできるようになる。
Furthermore, even if the voltage drop was not large enough to cause an arc spot in the past, the degree of voltage drop was relatively large in the past, and special measures had to be taken to the cooling mechanism, which made the equipment However, the center leg average roughness Ha of the power supply roll side surface of the metal strip is 0.30/Im.
With the following configuration, the voltage drop is now small, the amount of heat generated by this is also small, there is no need to configure a special cooling mechanism in the equipment, and the processing equipment can be small and low cost. It becomes like this.

又、大電流を供給しても安定な成用で連続処理でき、金
属ストリップ及び給電ロールを損傷することがなく、処
理装置自体の耐久性に富み、しかも効果的な連続処理が
可能である。
Furthermore, continuous processing can be performed with stable performance even when a large current is supplied, the metal strip and the power supply roll are not damaged, the processing apparatus itself is highly durable, and moreover, effective continuous processing is possible.

又、金属ストリップの製品側向の中IC1平均粗さf(
aを025〜045μmに仕上げていることより、PS
板として用いる場合においてテカリと称する欠点もなく
、かつ研PM後において圧延目が残ることもなく、極め
て好ましいものとなる。
In addition, the average roughness f(
By finishing a to 025 to 045 μm, PS
When used as a plate, there is no drawback called shine, and no rolling marks remain after polishing and PM, making it extremely preferable.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は、連続電解処理装置の概略説明図である。 1・・金属ストリップ。 ( The drawing is a schematic explanatory diagram of a continuous electrolytic treatment apparatus. 1. Metal strip. (

Claims (1)

【特許請求の範囲】 ■ロールi(合′屯六面処理用金属ス) l)ツブのロ
ール給電側表向の中心線平均粗式が約0.31JμIn
以下であるよう構成したことを特徴とするロール給電表
面処理用金属ストリップ。 ■特許請求の範囲第1項記載のロール給電表面処理用金
橋ストl)ツブVこおいて、ロール給電側表面の中心線
平均粗さが約00bμIl1以上であるもの。 ■ロール給電表向処理用金属ストリップのロール給電側
光1I]jの中心線平均粗豆を約t)、3(lz+nl
以Fに、ロール給電側と反対側表面の中心脚平均粗さを
約025〜045μIl+に構成したことを特徴とする
ロール給m:衣向処理用金属ストリップ。
[Claims] ■Roll i (metal for six-sided processing) l) The center line average roughness of the roll power feeding side surface of the tube is approximately 0.31JμIn
A metal strip for roll feeding surface treatment, characterized in that it is configured as follows. (1) Kanahashi steel for roll power feeding surface treatment according to claim 1; l) Tube V in which the centerline average roughness of the roll power feeding side surface is about 00bμIl1 or more. ■Roll power supply side light of roll power supply side of metal strip for surface treatment
Hereinafter, a roll-fed metal strip for cloth processing is characterized in that the center leg average roughness of the surface opposite to the roll power-fed side is about 025 to 045 μIl+.
JP22920083A 1983-12-06 1983-12-06 Metallic strip for roll power supply surface treatment Granted JPS60121296A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22920083A JPS60121296A (en) 1983-12-06 1983-12-06 Metallic strip for roll power supply surface treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22920083A JPS60121296A (en) 1983-12-06 1983-12-06 Metallic strip for roll power supply surface treatment

Publications (2)

Publication Number Publication Date
JPS60121296A true JPS60121296A (en) 1985-06-28
JPH0530918B2 JPH0530918B2 (en) 1993-05-11

Family

ID=16888379

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22920083A Granted JPS60121296A (en) 1983-12-06 1983-12-06 Metallic strip for roll power supply surface treatment

Country Status (1)

Country Link
JP (1) JPS60121296A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005240056A (en) * 2004-02-24 2005-09-08 Nichicon Corp Feed roller of foil feed type etching device for electrolytic capacitor

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5818997A (en) * 1981-07-27 1983-02-03 株式会社東芝 Method of producing hybrid integrated circuit substrate

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5818997A (en) * 1981-07-27 1983-02-03 株式会社東芝 Method of producing hybrid integrated circuit substrate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005240056A (en) * 2004-02-24 2005-09-08 Nichicon Corp Feed roller of foil feed type etching device for electrolytic capacitor
JP4520178B2 (en) * 2004-02-24 2010-08-04 ニチコン株式会社 Feed roller for foil-fed etching equipment for electrolytic capacitors

Also Published As

Publication number Publication date
JPH0530918B2 (en) 1993-05-11

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