JPS60104190A - Water-incorporated fuel oil and its manufacture - Google Patents

Abstract

PURPOSE:To obtain the titled oil of good dispersion stability and high combustion efficiency with little environmental pollution, by incorporating heavy fuel oil with water and aqueous solution containing nonylphenyl polyethylene glycol ether and PVA. CONSTITUTION:The objective fuel oil can be obtained by incorporating (A) 7- 10t of heavy fuel oil with (B) 1-5t of water and (C) 20-80l of an aqueous solution containing (i) 0.01wt% of nonylphenyl polyethylene glycol ether [pref. of formula I (n is 1,500-2,500)] and (ii) 4wt% of PVA [pref. of formula II (n is 500-2,500)].

Description

[Detailed description of the invention]

The present invention relates to a hydrated fuel oil, and more particularly to a hydrated fuel oil having good dispersion compatibility and a method for producing the same. Currently, our country imports more than 90% of its petroleum-based fuels from foreign countries, consuming valuable foreign currency, but its petroleum resources are limited, and the price is rising year by year, and the appetite for supply is decreasing. It is a well-known fact that there is a need to burn oil more efficiently and reduce air pollution and other pollution, as it is showing signs of decreasing. In order to meet this need, many researchers around the world are currently making various efforts to develop the principle that ``adding water to oil increases the combustion effect.'' Attempts have been made to create emulsion fuel by applying this method and adding water from dead bodies to oil. However, most of them have low economic value or are unstable, and the current situation is that we cannot find anything worthy of achieving the original purpose. The inventors are based on a statement made by Soviet scientists 20 years ago: ``When a water particle is surrounded by oil, and the oil on the outside is unburned or incompletely combusted, the water particle loses heat. It is vaporized by conduction, and this vaporized water vapor rapidly increases its volume (approximately 5800 times) and diffuses the oil on the outside.
Focusing on the theory of fine scratches, oil particles are evenly surrounded around water particles, and the combination of water and oil continues semi-permanently, resulting in complete combustion, which is better than raw heavy oil. This research has made it possible to obtain a fuel with high efficiency and low carbon monoxide emissions. It is generally known that in the chemical chain reaction process of hydrogen (H2), an appropriate amount of H2O is advantageous for the rapid reaction of H2, but at the same time, in the chemical chain reaction process of CO, an appropriate amount of H2O is advantageous for the rapid reaction of CO. It is also known that it is beneficial for In the reaction process, fuel oil such as
There is a process of generating CO and IJ20 in fuel oil.
It is known that the addition of fuel oil has an effect on the rapid reaction between II2 and CO, and is also effective on the rapid combustion of the fuel oil itself. In fact, CO that does not contain H2O requires a lot of 0□ during combustion, but the amount of 02 that is required for combustion of CO'/i that contains H2O is considerably smaller. There is relatively less excess oxygen in the combustion process than with hydrous fuel oil. Under the same conditions, a hydrous fuel pF mixture takes less time to burn than a non-hydrous fuel mixture, and for the same combustion time and the same fuel mixture, a hydrous fuel burns better and more completely. . Therefore, a suitable hydrous fuel oil for burning in a boiler will be more abundant and burn more completely than a non-hydrous fuel 1'-1 oil. That is, all fuel oils in a boiler must have an appropriate moisture content in the fuel mixture to achieve better and more complete combustion under certain combustion conditions. There are various attempts to achieve this goal, but the first one mentioned above
10 <Conventional emulsion fuels form emulsions using the power of surfactants and emulsifiers, but most of them do not have a complete bond and do not reach the required shelf life or have low economic efficiency. Met. The present invention completely combines water and heavy oil to create hydrated heavy oil, which is useful for energy saving and prevention of environmental pollution.The water and oil can be stored for a long time without separating, can be stored and transported, and has good combustion efficiency. The present invention provides a new hydrated fuel oil that emits JJ1 gas without environmental pollution and a method for producing the same. The hydrated fuel oil according to the present invention is obtained by dispersion bonding heavy fuel oil and water in the presence of polyvinyl alcohol and nonylphenyl polyethylene dalicol ether, and if desired, the hydrated fuel oil further contains a small amount of alkali metal chlorine. It may contain additives selected from the group consisting of acid salts, diesel oil or heavy fuel oil. The hydrated fuel oil of the present invention can be made into an antifreeze form by replacing part of the water with ethylene glycol or ethylene glycol and saturated saline. The heavy fuel oil used in the present invention is B=C heavy oil. The amount of water added is 1 to 5 tons per 7 to 10 tons of heavy fuel oil. The polyvinyl alcohol used is represented by the formula: %Formula %] where n is from 500 to 2,500, preferably about 1,700. Represented by nonylphenyl polyethylene glycolny,
Preferably, n is about 2000. Nonylphenyl polyethylene glycol ether (hereinafter referred to as NPEG) and polyvinyl alcohol (hereinafter referred to as PvA) as emulsifying and dispersing agents are NPEGEo, 01%.
and an aqueous solution containing PVA4 (hereinafter referred to as 4% P solution)
It is preferable to prepare and use heavy fuel oil 7 to 1.
20-80 g of 4-chi P liquid is used per 0 t. Potassium chlorate is usually used as the alkali metal chlorate, and it acts as a combustion improver to prevent the generation of soot and sediment.
007 is used and is preferably added in advance as a 4% by weight aqueous solution. When adding diesel oil or A heavy oil, use heavy fuel
[1 to 251 tg is used per 7 to 10 t of oil, and if the heavy window 4F oil is C heavy oil, it is used for adding water. It helps the initial stage of fire when there is a lot of oil, and is necessary when used in large internal combustion engines such as ships. . A blending example of the hydrated fuel oil of the present invention is as follows. A) 9 to 11 tons of B heavy oil, for example 1 to 5 tons of water to 10 tons
t, e.g. 2t, and 4% P solution 3o-4ot, e.g. 40
t. B) C heavy oil 9 to liter, for example 10 tons to 2.5 liters of water
~3.5t, e.g. 3t24% P liquid 25-35t, e.g. 30 and 4kg of 4% KCtO3 aqueous solution. c) 6.5 to 7.5 t of C heavy oil, e.g. 7 t to 2 t of water
．． 5-3.5t, for example 3L14 P liquid 25-35t,
For example, 30t, 4% KCl-03 aqueous solution 2J31tg and diesel oil 10-131cg, for example 13/cg. D) 7.5 to 8.5 t of C heavy oil, for example 1 ton of water to 7 t
．． 8-2.2t, e.g. 2t, 4% P liquid 25-35t1
For example, 30 tons, 2.81 tg of 4-chi KCtO3 aqueous solution and 10 to 12 kg of heavy oil, for example 111 tg. E) C heavy oil 9.5-10.5t, for example 10t, 71 (3.5-4.5L, for example 4t14chi P liquid 25-
35t, e.g. 4kg of 3'0m4 KCt03 aqueous solution and 18-221cg of diesel oil or A heavy oil, e.g. 201tg. In the above formulation example, in the case of Bi oil, A) B [f
In the case of 10 tons of I oil, 2 parts water, 4% P liquid, 4°m C heavy oil. B) 3 tons of water, 30 tons of 4% P liquid for C heavy oil lot, 4
%KC6O3 aqueous solution 4 kg and A heavy oil or diesel oil 201 tg. To prevent the hydrated fuel oil of the present invention from freezing in winter,
In the above formulation, 2 to 15 portions of the added water can be replaced with ethylene glycol. In this case, the amount of water replaced with ethylene glycol can be changed depending on the temperature as follows. Temperature Replacement amount 0 to -10°C 2 to 5% -10 to -20°C 5 to 10 ratio -20°C or less 10 to 15 ratio The amount of ethylene glycol was further reduced to 8, and the amount of ethylene glycol was reduced to 8. By adding ~400 cc of saturated saline, a stable product that is not affected by weather and temperature can be obtained. The hydrated fuel oil of the present invention is produced as follows. Polyvinyl alcohol was dissolved in heated water in a jacketed container equipped with a stirrer, and nonylphenyl polyethylene glycol ether was added thereto to obtain a 4-functional polyvinyl alcohol solution containing 0.01% of nonylnoenyl polyethylene glycol. Prepare. A predetermined amount of this M solution was added to water in a separate container heated to 40-50℃ with stirring, and this was heated to 40-50℃ in another container with a stirrer.
- Add to the specified heavy oil and stir and mix for about 20 minutes to obtain the product. If necessary, add 4% KCto3 bath liquid or diesel oil and mix. It is preferable that the ``addition of water containing the 4% P liquid'' to heavy fuel oil, IJl, be carried out by atomization. The hydrated fuel oil of the present invention has properties as shown in the following table. Table Actual Losses 11-17% 2-5% at most Burner Temperature Approx. 1,120'C Approx. Something like American Poetry A4158551,
At most 22 units of water and anion ethoxylate
Methods using emulsifiers consisting of dalkylphenol (ethoxyalkylphenol) have been published, but these come at the cost of efficiency and the mixture is cloudy and separates due to bond rupture. As far as is known so far, it has not been possible to obtain the property that water particles and oil particles combine completely and do not separate, whether they are stored in tanks or transported on the road. Furthermore, no combustion engine has been perfected that does not suffer losses in efficiency and performance due to incomplete combustion due to intermittent combustion. On the contrary, the hydrated fuel oil of the present invention is shown in the Examples.
: Sea urchin is extremely stable and can withstand long-term storage.Water and oil do not separate when transported (whether on the road or in pipes), and when compared to combustion, it burns completely. Therefore, there is no generation of soot or tar, which causes energy loss, and on the contrary, it is possible to burn and remove even the substances deposited on the furnace wall that should naturally be used as energy. In addition, the amount of carbon monoxide in the υV output gas is not only reduced due to partial substitution of heavy oil with water, but also the amount of SO3 nitrogen oxides, unburnt coal mine hydrogen, etc. in the exhaust gas is reduced, which is advantageous for energy saving. In addition to providing sex, it is also useful for environmental conservation. It also has the advantage of not causing deposits or corrosion on the burner or furnace walls. That is, compared to conventional heavy oil, the hydrated heavy oil of the present invention has the effect of achieving high utilization of energy through complete combustion, extending the life of combustion equipment, and essentially making it possible to lower energy costs. The additive JJO agent used in the present invention is a liquid receiver and is extremely inexpensive, and is produced in large quantities in Japan.
In addition to being exported at a low price, the new hydrated fuel oil produced by this method does not require any limitations on the combustion equipment in which it is used and is suitable for all fields requiring thermal energy. It can be used in the same way as conventional heavy oil. In addition, the bond between water and oil particles is uniform and stable and does not separate, regardless of whether it is in the container or during storage. The method for producing hydrated fuel oil of the present invention and its miscellaneous additives are expected to achieve complete combustion, which cannot be expected with conventional non-hydrated heavy oil alone, and associated thermal efficiency close to 100%, and are environmentally friendly. It has the effect of emitting preferable clean exhaust gas, extending the life of combustion equipment, and saving at least 20% or more of fuel consumption. The present invention is based on the principle known 70 years ago that adding water to oil improves the combustion effect, and the theory of slight scratches to bring out the movement of water in the most effective way. This has been realized and resolved, and its implementation will have a huge economic effect socially and nationally. In an example, 10 tons of water was put into a pot of a multi-layered stirrer that could be indirectly heated by passing steam between the inner and outer walls, and heated to 90 to 100 degrees Celsius with stirring blades of 80℃. ~1
PVA (
Polyvinyl alcohol (polymerization degree 1700) powder 400
Gradually add y and dissolve it completely, add 4 y of nonylphenyl polyethylene glycol ether to make 0.01 of nonylphenyl polyethylene glycol.
Make a 4-chiP solution containing %. Next, put 10 tons of heavy oil B into a large container equipped with a heating steam pipe (serpentine pipe), warm it to 40-50℃, and then transfer it to another container for 4 hours.
3 tons of 4ZP for 2 tons of water warmed to 0-50℃
Pour in the liquid and mix thoroughly. Add the water plus the 41P liquid gradually, preferably in the form of a spray, and add 500 to 120 Or;'p.
, rn for about 20 minutes to obtain about 12 tons of new hydrostatic fuel oil. This hydrated fuel oil requires less oxygen to burn than unhydrated heavy oil, and as shown in the first measurement at the Minamikyushu Pollution Research Institute (Table 2), the CO2 value of its exhaust gas is lower. The amount of remaining 02 is small. In addition, the evaporometer of this type was larger than that of unhydrated heavy oil, and the exhaust gas temperature was lower, indicating that the thermal efficiency of the boiler (combustion engine) was lower. Furthermore, according to the test conducted by the Fukuoka Prefectural Industrial Research Institute in Table (1), even though 20 parts of water is added, the calorific value is 10,470 cat for unhydrated heavy oil, whereas the calorific value of heavy oil with 20 parts of water is 10,470 cat. The fact that the fuel oil is 1019 oeat is a great way to save energy. Table 1 (Fukuoka Prefecture Fukuoka Industrial Testing Station commissioned test results) B heavy oil
Hydrogenated fuel oil calories (cat) of the present invention 1 0470 1 01 90 Table 2
Comparison of exhaust gas (Test commissioned by Minami Kyushu Pollution Analysis Center, test results) Hydrogenated fuel 4F oil A heavy oil JJ1 output amount (humid)), N% 210 300
〃 (dry), y'iH1so 280 exhaust gas temperature,
℃ 157 211 Exhaust gas composition, CO21-2,68,4 o23.9 11.4 C〇 - Table 3 Comparison of exhaust gas (results of tests commissioned by Power Engineering Research Institute) A
Heavy oil Hydrated fuel oil gas of the present invention CO2 10% 13% Temperature 230°C 210°C Boiler efficiency 87% 90.5 Table 4 Evaporation test by Bo and Ira combustion (results of test commissioned by Power Engineering Research Institute) Evaporated water amount A heavy oil 11.28I- (1985/'i8 to 5/23
) Triple heavy oil 11.25t (1986/1-6/4) Hydrogenated fuel oil of the present invention 11.95t (1986/24-F
y29) (Test using the same boiler under the same conditions) Example 2 Actual/Ii! 1 Using the same equipment and method as in Example 1, 1 ton of heavy oil C, 3 ton of water, and 4ZP liquid (containing 0.01% nonylphenyl polyethylene glycol ether).
25t, 4 kg of 4% KClO3 aqueous solution, 201
cg of A heavy oil was added to obtain about 13 tons of new hydrated heavy oil. The combustion effect of this hydrated C heavy oil was also excellent, similar to that of the hydrated fuel oil obtained in Example 1. Example 3 Of the 2 tons of water used in the formulation of Example 1, 4
Even if a portion of the hydrated fuel oil 1d, which was prepared by replacing 0L with ethylene glycol and following the same steps, was placed in a container with a freezing capacity of -15°C and left overnight, no freezing phenomenon was observed. There wasn't. Example 4 Also, in Example 3, the ethylene glycol to be replaced with water was reduced to 17/2, and 480 cc of saturated saline was added instead and mixed with stirring.The product obtained did not freeze in the freezing test of the same method, and was evaluated as an example. Good results were obtained that were no different from the products obtained with 1. As for the samples taken from each of the above-mentioned Examples, no separation of components was observed in sample 1. Procedurality 0 official document (spontaneous) November 15, 1981 Commissioner of the Japan Patent Office Wakasugi Wanu Hitting 1 Display of the incident −・ 1.2′〆・)′ 〆′ /
・Patent application 2 filed on November 10, 1988 Name of the invention Hydrated fuel oil and its relation to the case of the person making the amendment 3 Patent applicant Takaharu Shigemitsu, 1-14-50, Shinsui, Kumamoto City, Kumamoto Prefecture 4 Agent 2-4 Goban-cho, Chiyoda-ku, Tokyo 5 Date of amendment order t Column for detailed explanation of the invention in IJ specification '7 Contents of amendment Part of the matters stated in the specification of the present application will be amended as follows. (1) On page 11, line 11 of the specification, the phrase "nonylphenyl polyethylene glycol" is amended to read "r-nonylphenyl polyethylene glycol". (2) The word “reduction” on page 13, line 12 of the same book was replaced with “
I am corrected by saying, ``Minor.'' (3) In the same book, page 15, lines 1 and 2, [nonylphenyl polyethylene glycol J] was corrected to "nonylphenyl polyethylene glycol ether." There are no changes to the content other than the matters stated in the column subject to amendment. 1'r-Ito Pdne City 1-1 Me (Spontaneous) March 21, 1980[] Special, t'1 Agency Director Wakasugi Wainu 1 ° 1- Display of 1988 Patent Application No. 209960 No. 2 Name of 11 Hydrated fuel oil and its manufacturing method 3 Supplement 11: Relationship with the person who does it and the II nature Patent applicant l'f Himoto Prefecture Nohmoto Yamashinsui l 14-50 Ko Mitsutaka R
j 4 Agent Higashi 4;
Supplement 11 of Instruction 11 Appendix 1; 1-6 Qi +E subject matter M11 NS Claims and Detailed Description of the Invention columns. 7. Contents of Supplement 1F (A) The entire text of the specification is amended as shown in the attached sheet. There is no change in the content except l'4 written in the column of subject of Ni + [-.Details Book 1, Name of the invention Process for manufacturing hydrated fuel oil Claims (1) Tega Buzeno'l f+17 to 1()''
To water 1, 5i L polyvinylfluor 1-1%
Hydrogenated fuel 111 oil containing 20 to 80 liters of an aqueous solution consisting of. (2) The polyvinyl resin: 1%) @1 The hydrated fuel oil described in item 1. (3) Add about 2 to 15% of the above water to the same soil. ,2,l:I! 17 Range 114' week or the hydrated fuel oil according to paragraph 2. (4) The hydrated fuel oil according to claim 3, wherein the water content of the soil is reduced to a maximum of 1/2 ω and replaced with 40 to 400 cc of saturated saline per liter of product. (5) A predetermined amount of polyvinyl alcohol was dissolved in water to prepare a 4% aqueous solution of polyvinyl alcohol, and additives selected from the group consisting of easel oil and heavy oil were added in advance. In addition to heavy fuel oil, a method for producing hydrated fuel oil (which includes uniformly avoiding dispersion bonds). 3. Detailed description of the invention 41' Burning fuel with high combustion efficiency and low environmental pollution11
It is concerned with the production method of hydrated fuel oil Jj J, which has the characteristics. Rule 1: Most of the petroleum-based fuels contain 9% or more.
It is imported from Sotoda and consumes the heavy Soto C1, but -f
1. Oil resources 4. Since it is limited to L and J, and its price is I//1, and the supply is showing a decreasing trend, it burns the oil more efficiently and makes it a popular pollutant. It is a well-known fact that pollution needs to be reduced. In order to satisfy this need, many ill researchers have been making various efforts in various countries around the world to date.
1F) A Several types of devices to increase combustion efficiency and improvements to fuel oil supply methods have been known for 70 years.
Attempts have been made to create margin fuel by adding an optimal amount of water to oil by applying the principle that adding water to oil produces a combustion effect. Most of them are worth II (squid,
In addition, there are many situations where t<t b is unstable, and the current situation is that C cannot find a sign that requires M or i to achieve the original target. The apologists argue that oil surrounds a particle of water, as described by a Soviet scientist in 2010, and in a state where the outer oil is unburned or incompletely combusted, δ゛1 child of water

[,1.
J, the moment when the Buddha mind effect of heat +1. 'l vaporized, this mind It. ShilJ Hyogo Hada! The number of beats increased dramatically (approximately 51
1 (l01) - due to the energy of diffusion of the outer oil particles, an atomization phenomenon occurs in which they become even finer, resulting in more complete combustion. According to the fine jM theory, '?S [1, the oil particles are uniformly surrounded around the water r, but since the combination of water and i+l+ continues semi-permanently and complete combustion occurs, the raw material It is more efficient than simple, and in addition, the carbon monoxide output gas is reduced by 11 (
b (J) C. In the chemical chain reaction process of water It is known that H20 is useful for the rapid reaction of 1-12, but if20t, tco is suitable for J3 in the chemical chain reaction process of +131c CO.
It is also known that it is published by fJ due to its quick response. In the reaction process of υ1111 fuel 11i1 oil-b, there is always a process of generating 112 CO, and adding an appropriate amount of 11,0 to the fuel lIl oil has an effect on the rapid reaction of 142 and CO. It is also known to be effective in quickly burning fuel oil whites. Also, CO that does not contain H2O requires a large amount of 02 during combustion, but CO that contains l-120 requires a much smaller amount of 02 during combustion. In the combustion process of hydrous fuel F1 oil, C excess oxygen is relatively small. On the same article A71, the hydrous fuel first mixture has a shorter combustion time than the [1 water-containing fuel mixture], and the combustion is the same. When the fuel mixture is the same as the time, the water-containing fuel is more completely combusted. ! i 1: Compared to tl oil, more J,
It is more complete combustion. In other words, the boiler's fuel oil (reveal C fuel oil has a constant combustion line fl F +3 and J, well J, and in order to completely reduce the combustion effect -11)
Appropriate water content in the mixture! There are various attempts to achieve this purpose, but as mentioned above, 1) This "-Full Dione" combustion gas: 1 is a W surface active agent.
゛] The power of the emulsion is to form a J-mulsion, but there is no complete 41 bond (1111 bond), the required bond (1111 bond) is not reached, or the economic effect is low. Most of the things are gas IC1゜Uninvented!In order to make a water-added material that is useful for preventing environmental pollution, two types of heavy oil are completely combined and water is added. A new hydrated fuel oil that can be stored for a long time, withstands storage and transportation, has good fuel efficiency, and emits gas without environmental pollution; and its production; The hydrated fuel oil according to the present invention includes -C, which is obtained by dispersion-bonding a high-quality fuel oil, water, etc. in the presence of polyvinyl alcohol, and optionally pre-hydrogenated fuel oil. The 5d hydrogenated fuel oil further contains an additive selected from the group consisting of raw gay-bill oil or heavy fuel oil.The amount of water added according to the present invention is
31 Oil contains a part of water]-Brene glycol or G;U]
: It is possible to change the liquid to saturated saline to prevent freezing. The heavy fuel oil used in the present invention is 1-3, C heavy oil. 1-1 ml of water added per 11 ml of fuel oil 7-10
,．． There are 51. Polyvinyl alcohol used
j j−'C: (C112・CIl (011') −). (Represented by PVΔ, and preferably 11 is about 1700. Polyvinyl alcohol (hereinafter expressed as PVΔ) is 1
) It is preferable to prepare an aqueous solution containing 4% VΔ (hereinafter referred to as 4% P liquid) and use it.
After 01, 20 to 80 sentences of 4% P waves are used. 1"E L oil or (when adding Δheavy oil, ΦNegative combustion 1
31 oil 7-10t then 1-2! When the heavy fuel oil is C heavy oil or when a large amount of water is added, it helps the hatching fish fire, and it is necessary when using it for artificial internal combustion such as ships.The water addition of the present invention An example of fuel I::1 oil arrangement is as follows. △) B heavy oil 9-1111 example; tl; [101, KIJ
2 water 1 ”・E) t N e.g. 21, 11%+]
Liquid 3 O-ho 1, M epo 40 sentences. +3) Ci[i oil 9-. 111. , Example IJ,'
10t 3J L/Water 25-3.51:, for example 3
1, l1% [] liquid 2; J~: rijI firing, Bi2e (
Ma3()ri,. C) C heavy oil [i,! i・~, 7.51 For example, 71 is phantom water 2.5"-3,5t, ltl;tlf 3 1-
, 'I % P solution 2. 'i-□351. Example LJ: 301, and (f j' E t' JLi
10-13++ g of oil, e.g. 13 hag. 1)) C heavy oil 7. : Now 8.4i't,, For example, 71 to 1.8-2.2t of water, 1 row GJ'2t, 1% P liquid 25-35a, for example 30a, and heavy oil 1o-121
(and, for example, 111 (g. tE) C heavy oil! 1.5 = 10.5 t, for example +o
lJJt, 3.5-4.5'l of water, e.g. 4L14%P
25 to 35 parts of liquid, for example 30 parts, and 18 to 22 parts of Divil oil or heavy oil, such as 201 parts (!? In the case of +7 C113 heavy oil in the above formulation 1 row, Δ')
D heavy oil iot to 2 liters of water and 40 fL of 4% P solution. 1 cup of C heavy oil, 13') C2 [i oil 10F to 3 tablespoons water 4% P liquid 301
, Δ heavy use 1 or D LJ and 9 can be returned to mountain 20. To prevent winter freezing of the hydrated fuel oil of the present invention, 2 to 15% of the water added to the formulation can be replaced with earthen glycol. In this case, the ω of the water to be replaced by Boulengericol is further reduced to 1/2 filtrate to 400 for every 11 ton of hydrated heavy oil added.
By adding cc of saturated saline, it is possible to create a stable product that is not affected by weather conditions. The hydrated fuel oil of the present invention is produced as follows. Dissolve polyvinyl alcohol in warm water in a container to prepare a 4% polyvinyl alcohol solution. Add a predetermined amount of this solution to water in a separate container heated to 40°C and 50°C (J container C40=
At 5Q°C, add a predetermined amount of the product to a predetermined amount of the product and stir for about 20 minutes. Ill. Add i-pil oil as needed and mix. Said 4 to heavy fuel 1 oil
%]) The addition of water to which oil has been added is preferably carried out by atomization. The hydrolyzed fuel J'l oil of the present invention is shown in the following table: J, Unatake 7'1
Let's do it. (Hereinafter [・margins] Conventional mixtures of water and oil, such as fuel oil mixed with alcohol and water, U.S. 1: j i+'tNL+,
J of 4158551, ・), Kei ``22% water shade - (-14 of (!L11(IXI/1aL(![Ia
A method using an emulsifying agent consisting of lky11111e410I (11111e410I) (11-4 dialkyl phenol) has been published, but these involve sacrifices in efficiency and the mixture is cloudy and bonds are broken and separated. As far as is known so far, water particles and oil particles are completely combined,
If it is stored in a tank or transported on the road (whether on a platform or on a platform, 5)
! 1 f sex! Until now, no combustion method has been completed without causing a loss in efficiency and performance due to incomplete combustion. On the contrary, the hydrated fuel oil of the present invention is
, sea urchin, ) is extremely stable and can withstand long-term survival, does not cause separation of water and oil when transported (whether on the road or in pipes), and is resistant to combustion. Because it has a complete combustion power of 2, there is no soot or tar, which causes energy loss, and on the contrary, it naturally deposits on the furnace wall - [Nel 1! - It burns until 3 times! c The small to be removed is i
jl fil. In addition, 1) the carbon monoxide level of the output gas is not only lowered due to partial substitution of heavy oil in water, but also due to the partial substitution of heavy oil with SO2 in the exhaust gas
Non-flammable hydrocarbons, etc. 4;
Not only does it bring about 111 benefits, but it also helps protect the environment.
Tsub no guru 1, also IJi material and corrosion burnout and furnace ha! There is also a right-handed person who does not have any problems. That is, compared to conventional medium oil, the hydrated heavy oil of the present invention not only utilizes one energy through complete combustion, but also has the effect of extending the life of the combustion equipment, making it possible to reduce energy costs in terms of wood quality. The amount of additives used in the present invention is very small (
The price is low, and we produce it in our farm at A3°C.
Not only is it exported to 1Ili (lIIl), but also the powerful hydrocarbons produced by this method.
-31 oil does not require any limitations on the fuel loading used, and can be used in any field requiring thermal nineel-1 in the same way as conventional heavy fuel oil. However, whether during transportation or storage, the bond between water and oil particles is uniform and stable, and they do not separate. The lj method for producing hydrated fuel oil of the present invention as well as the additives used therewith are expected to achieve complete combustion, which cannot be achieved with conventional non-hydrated small oils alone, and associated thermal efficiency close to 100%. Moreover, it publishes a clean JJI gas that is preferable for environmental conservation, and has the effect of increasing the number of lives of combustion KIS i (i), and can save more than 20% of the fuel cost. The principle that the combustion effect increases when water is added to oil, which has been known for many years, and the most effective way to bring out the knowledge of water! The theory of fine formation is actually applied at the lowest cost and in a 119-minute method. This will be implemented and solved, and it will have a great economic effect on the social and national level. A stirrer that can indirectly heat C by passing steam between the outer walls (1) Pour 10 D of water into a pot, and heat it to 90 - 1 (l'C) while turning the stirring blades to 80 - 1001'C. , l+ , I
ll speed 1. ! Summer 'Q rotated lII: is I51 ■△(
Polymerized 1700% polyvinylfluor)'t! J
) Gradually add 400 g of unused U and 4% P until completely dissolved.
Add oil. Next, the steam pipe for heating <'J! i
A 13-fold tube of 10 tons was placed in a sacrificial container equipped with a tube), and 40...! i 0 ℃ From C, another γ
Add 3.
lt, 30 minutes of 4% 1) Add the liquid and mix thoroughly. Add water plus 4% 1] 8k gradually and spray at a speed of 500 to 1200 r, p, m. 2 (stir for 1 minute and add fresh water 1 ! 3 + oil approx. 1
I got 21. This hydrated fuel oil has a fuel power of K1. ．． : However, more oxygen is required for combustion than unhydrated heavy oil, as shown by Minamikyushu Pollution Research Institute's if RI + negative (Table 2).
, the exhaust gas (/02 value is high, and the remaining 02m is small. Also, non-hydrated CF-i + IIJ, Rimo 1 hi〉! 1's black light 1
The large size and low IJI gas temperature indicated that the thermal efficiency of the boiler (combustion section) was low. Table (1)
According to a test conducted at the Fukuoka 94 ■ Ju Experimental Station, 20% of water was added to C, but it did not cause any damage;
While triple fuel oil has 0.01470 Caρ, the fact that there is 20% hydrated fuel, ioH+Ocanr, can be seen as a great saving effect. (1, blank) Table 2 Comparison of II + Gas (Minami Kyushu Pollution Analysis Center ■ Table 331) Comparison of 1 Gas (Ri!l!J' 8 Power Extraction Commissioned Test Results? Table 4 J for Boiler Combustion , evaporation amount test (river N') power technique ω1 forest trust test results) (same column ('t J, test on the same boiler) Example 2 Same equipment as in Example 1 "l and bv1"c, C heavy oil 10t
To this, add 3 parts of water, add 4% P liquid 25α, 201τ3 of A heavy oil, and add about 131 of new hydrated heavy oil C to If7. /j,
The combustion effect of this hydrated C fuel oil was also similar to that of Example 1 (-1S), and excellent J results could be obtained. Of these, 40
Replace 1 with 1F Renglilin 1-L C and proceed as follows: 1) Add the culm to 1 ¥ (The prepared hydrated fuel oil is (-) Place a portion of it in a container in a refrigerator with a freezing capacity of 15℃. - IJS left overnight - No Naoe IS phenomenon was observed in -C.Example 4 Also, in Example 3, the amount of ethylene glycol used to replace water was reduced to 1/2, and 480 cc of saturated saline was added instead. Add and stir to mix.Ui!7/This product passed the same freezing test as L1.
3 (Freezing is avoided! Product and 1 in example 1)
I was impressed with the good results, with 11 mag and no change. -Currently, no separation of the C component is observed in the leftover samples taken from each of the eggplants listed in F.

Claims (1)

[Claims] 01 For 7 to 10 tons of heavy fuel oil, 1 to 5 tons of water and nonylphenyl polyethylene glycol ether Q, 01
Aqueous solution consisting of % and 4 parts of polyvinyl alcohol 20
~80t of hydrated fuel oil. (2) the polyvinyl alcohol is represented by the formula %, where 11 is from 500 to 2,500, and is represented by nonylphenyl polyethylene glycol ether;
The hydrated fuel oil according to claim 1, wherein (1) is 1,500 to 2,500. (3) The hydrated fuel oil according to claim 1 or 2, further comprising 40 to 200 f of alkali metal chlorate per 7 to 2 lots of heavy fuel oil. (4) Hydrogenated Vat oil according to claim 1, 2 or 3, wherein about 2 to 15% of said water is replaced with the same amount of ethylene glycol. (5) The hydrated fuel oil according to claim 4, wherein the amount of ethylene glycol is reduced by a maximum of 1% and the product 1 is replaced with 40 to 400 cc of saturated saline. (6) Dissolve a predetermined amount of polyvinyl alcohol in water,
, fLK/=ruphenyl polyethylene glycol ether to prepare a polyvinyl alcohol 4 aqueous solution containing 0.01% nonylphenyl polyethylene glycol ether, and add a predetermined amount of this solution to a predetermined amount of water,
A hydrated fuel oil characterized in that it is added to pre-warmed heavy fuel oil and uniformly dispersed and mixed with an additive selected from the group consisting of an alkali metal chlorate aqueous solution, diesel oil or A heavy oil, if desired. manufacturing method.