JPS5973973A - Heat sensitive recording head - Google Patents

Heat sensitive recording head

Info

Publication number
JPS5973973A
JPS5973973A JP18560882A JP18560882A JPS5973973A JP S5973973 A JPS5973973 A JP S5973973A JP 18560882 A JP18560882 A JP 18560882A JP 18560882 A JP18560882 A JP 18560882A JP S5973973 A JPS5973973 A JP S5973973A
Authority
JP
Japan
Prior art keywords
recording head
heat
heat generating
silicon wafer
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18560882A
Other languages
Japanese (ja)
Inventor
Keiji Nunomura
布村 恵史
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Nippon Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp, Nippon Electric Co Ltd filed Critical NEC Corp
Priority to JP18560882A priority Critical patent/JPS5973973A/en
Publication of JPS5973973A publication Critical patent/JPS5973973A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/315Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
    • B41J2/32Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
    • B41J2/335Structure of thermal heads

Landscapes

  • Electronic Switches (AREA)

Abstract

PURPOSE:To reduce the heat capacity of a heat generating part to a large extent to enable high speed recording, by a method wherein a bridge part is formed to a silicon wafer by anisotropic etching and heat generating resistance is formed on said bridge part. CONSTITUTION:A silicon wafer 6 is covered with an etching mask 9 and anisotropic etching is applied to the hole provided to said mask 9 to form a bridge part l' of the silicon wafer 6 while leaving an etch stop layer 7. An electric insulating layer 8, heat generating resistance 3, a lead wire 4 and a surface protective layer 5 are provided on the bridge part l' of the silicon wafer 6.

Description

【発明の詳細な説明】 本発明は感熱記録ヘッドに関し、特に感熱印字装置に使
用される感熱記録ヘッドに関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a thermal recording head, and particularly to a thermal recording head used in a thermal printing device.

感熱記録方式は低騒音の一次発色型記録であシ、装置機
構が簡略、メンテナンスフリーで且つ、装置及び記録紙
も比較的低コストである為に、プリンタやファクシミリ
等の主要な記録印字方式となっている。この感熱記録方
式による印字は複数個の微細な発熱抵抗体からなる感熱
記録ヘッドを用い、画素情報に応じて発熱抵抗体を選択
通電発熱させて感熱記録紙上に発色記録させるものであ
るが、熱現象を利用している為に他の記録方式に比較し
て、−画素形成当りの記録エネルギーが犬であり、また
記録速度も遅い欠点を有している。近年、感熱記録方式
において紅感熱記録紙特性の向上や感熱記録ヘッドの改
善が図られ電力効率や印字速度の改善が行なわれている
が、まだ十分とは云えない。
The thermal recording method is a low-noise, primary color recording method, and the device mechanism is simple and maintenance-free, and the device and recording paper are relatively low-cost, so it has become the main recording and printing method used in printers, facsimile machines, etc. It has become. Printing using this thermal recording method uses a thermal recording head consisting of multiple fine heating resistors, and selectively energizes the heating resistors according to pixel information to generate heat to record colors on thermal recording paper. Since this method utilizes a phenomenon, it has the drawbacks that the recording energy per pixel formation is low and the recording speed is slow compared to other recording methods. In recent years, efforts have been made to improve the characteristics of red thermal recording paper and the thermal recording head in thermal recording systems, and to improve power efficiency and printing speed, but this is still not sufficient.

まず、従来の薄膜型感熱記録ヘッドは第1図に示すよう
に発熱部の構造を備えているが、これはガラスグレーズ
2されたアルミナ基板1上にパターン化された発熱抵抗
体3、及びリード電極4が形成され、表面保護膜5で覆
われた構造である。
First, a conventional thin film type thermal recording head has a structure of a heat generating part as shown in FIG. It has a structure in which an electrode 4 is formed and covered with a surface protective film 5.

一般的にはガラスグレーズ2と発熱抵抗体3の間に反応
防止、あるいはエッチストップ層としてTa2051換
等が挿入されたり、表面保画層は酸化防止用として5i
02、耐摩耗層としてTa205等の2層構成の採用等
よシ構成層数の多い構造が使用されている。
Generally, Ta2051 or the like is inserted between the glass glaze 2 and the heating resistor 3 as a reaction prevention or etch stop layer, and a surface image retention layer is 5I for oxidation prevention.
02, a structure with a large number of layers is used, such as a two-layer structure made of Ta205 or the like, as the wear-resistant layer.

このような感熱記録ヘッドは′電力効率や印字1時性が
基板の熱特性に依存しているためアルミ基板が用いられ
ている。しかしアルミナ基板は熱伝導性が良い為に直接
アルミナ基板上に発熱抵抗体を形成した場合基板への熱
の散失が多く発熱体表面の温度を晶くすることが困難で
ある。そこで熱伝導性の小さいグレーズガラスをアルミ
ナ基板上に設けることにより発熱抵抗体で発生するジー
ー比熱の蓄熱効果を利用して電力効率の向上が図られて
いる。しかしガラスグレーズの蓄熱層の採用は発熱抵抗
体素子の冷却の時定数も長くなるために高速印字粂件で
は尾引き、にじみ等の印字品質上の問題をもたらす為に
1胱力効率と印字品質の両者を勘案して1ψ用条件に合
わせて最適グレーズ厚さを決定する必要がある。通常は
30〜100ミクロン程度の厚さが採用されており、電
力効率は主走査方向8ドツト/ミリメートル、副走査方
向7.7ライン/ミリメートルの感熱記録ヘッドにおい
ては、約0.8〜1.0ミリ・ジュール/ドツトの印字
エネルギーであシ、印字速度は最高5ミリ秒/ライン程
度が、発熱抵抗体等の構成拐料の開発の寄与もあり、現
在達成され、はぼ限界に近付いている。
In such a thermal recording head, an aluminum substrate is used because power efficiency and one-time printing depend on the thermal characteristics of the substrate. However, since an alumina substrate has good thermal conductivity, when a heating resistor is formed directly on an alumina substrate, a large amount of heat is dissipated to the substrate, making it difficult to crystallize the temperature on the surface of the heating element. Therefore, by providing glazed glass with low thermal conductivity on an alumina substrate, power efficiency is improved by utilizing the heat storage effect of G specific heat generated by the heating resistor. However, the use of a glass glaze heat storage layer also increases the time constant for cooling the heat generating resistor element, resulting in printing quality problems such as trailing and smearing in high-speed printing. It is necessary to take both of these into consideration and determine the optimal glaze thickness according to the conditions for 1ψ. Usually, a thickness of about 30 to 100 microns is adopted, and the power efficiency is about 0.8 to 1.0 microns in a thermal recording head with a power efficiency of 8 dots/mm in the main scanning direction and 7.7 lines/mm in the sub scanning direction. The printing energy required is 0 millijoules/dot, and the maximum printing speed is about 5 milliseconds/line, which has now been achieved and is approaching its limit, thanks in part to the development of constituent materials such as heating resistors. There is.

このように電力効率および印字速度における主要な阻害
要因は発熱抵抗体近傍、特にグレーズガラス層の比熱が
大きく実効的な熱容量が大きいことにあると判断される
As described above, it is judged that the main factor inhibiting power efficiency and printing speed is that the specific heat near the heating resistor, especially the glaze glass layer, is large and the effective heat capacity is large.

本発明は上記の知見を基に、発熱部の実効的な熱容量を
大巾に低減するために架橋状に発熱部を形成し、晶市力
効率、高速印字を実現したものである。
Based on the above knowledge, the present invention forms a heat generating part in a cross-linked manner in order to greatly reduce the effective heat capacity of the heat generating part, thereby achieving high printing efficiency and high speed printing.

本発明の目的は従来の感熱記録ヘッドを改良し、高電力
効率で且高印字速度が得られる感熱記録ヘッドを提供す
ることにある。
SUMMARY OF THE INVENTION An object of the present invention is to provide a thermal recording head that improves conventional thermal recording heads and provides high power efficiency and high printing speed.

更に本発明の他の目的は発熱部の実効的な熱容量を大巾
に低減するために発熱部を架橋状に形成した感熱記録ヘ
ッドを提供することにある。
Still another object of the present invention is to provide a heat-sensitive recording head in which a heat-generating portion is formed in a cross-linked manner in order to greatly reduce the effective heat capacity of the heat-generating portion.

本発明によれば、シリコンウェハーの基板と、発熱抵抗
体とを有する感熱記録ヘッドにおいて、前記基板の異方
性エツチングによシ形成された架橋部と、該架橋部上に
設けた発熱抵抗体とを備えたことを%徴とする感熱記録
ヘッドが得られる。
According to the present invention, in a thermal recording head having a silicon wafer substrate and a heat generating resistor, a bridge portion formed by anisotropic etching of the substrate, and a heat generating resistor provided on the bridge portion. A thermosensitive recording head having the following characteristics can be obtained.

更に本発明によれば、発熱抵抗体及びそれに対応するシ
リコンウェハー基板に形成される架橋部は千鳥格子状に
配置したことを特徴とする特許^ft求の範囲第1項記
載の感熱記録ヘッドがイ!Iられる。
Further, according to the present invention, there is provided a thermal recording head according to item 1 of the claimed scope of the patent, characterized in that the heating resistor and the corresponding bridge portion formed on the silicon wafer substrate are arranged in a staggered pattern. Gai! I get caught.

以下本発明の実相例について図面を参照して説明する。An actual example of the present invention will be described below with reference to the drawings.

第2図(イ)および(ロ)は本発明の一実施例の感熱記
録ヘッドの平面督よびそのa−a’断面を示す。第2図
(イ)および(ロ)において、本実施例はシリコンウェ
ハー基板6、エッチストップ層7および電気絶縁層8か
らなる基板上に発熱抵抗体3、リード電極4および表面
保護層5が形成される。シリコンウェハー基板6にはエ
ツチングマスク9の穴(長さl)を通して、異方性エツ
チングされ、第2N−)に示される台形の溝が形成され
る。エッチストップ層7は界面での溝の[Jl’が架橋
状に形成され、この架橋状の部分に発熱抵抗体が形成さ
れ、この発熱抵抗体3を表面保護1−5と電気絶縁層8
及びエッチストップ層7とに挾んだ構造に形成する。
FIGS. 2A and 2B show a plan view of a thermal recording head according to an embodiment of the present invention and its a-a' cross section. In FIGS. 2(a) and 2(b), in this embodiment, a heating resistor 3, a lead electrode 4, and a surface protection layer 5 are formed on a substrate consisting of a silicon wafer substrate 6, an etch stop layer 7, and an electrical insulating layer 8. be done. The silicon wafer substrate 6 is anisotropically etched through the hole (length 1) of the etching mask 9 to form a trapezoidal groove shown at 2N-). In the etch stop layer 7, [Jl' of the groove at the interface is formed in a bridged manner, and a heating resistor is formed in this bridged portion, and this heating resistor 3 is connected to the surface protection layer 1-5 and the electrical insulating layer 8.
and an etch stop layer 7.

エッチストップ層7はシリコンウェハーの異方性エツチ
ング液に犯されない材料を成膜して用いても良いが残留
歪の点でホウ素がドープされたシリコン層を利用する方
が好ましい。また電気絶縁層8はシリコン熱酸化膜を利
用できる、勿論5iO1や8i1N4等を成膜して用い
ても良い。
Although the etch stop layer 7 may be formed of a material that is not affected by the anisotropic etching solution for silicon wafers, it is preferable to use a boron-doped silicon layer from the viewpoint of residual strain. Further, the electrical insulating layer 8 can be made of a silicon thermal oxide film, or of course may be formed by forming a film of 5iO1, 8i1N4, or the like.

本実施例の感熱記録ヘッドは発熱部の厚さを薄くするこ
とが可能であシ、また比熱の大きいガラス層を有してお
らず、電気絶縁層としての5in2等は1ミクロン以下
の厚さしか必要としない為に、全体として発熱部の熱容
量を大巾に小さくできる。
The heat-sensitive recording head of this embodiment can reduce the thickness of the heat generating part, and does not have a glass layer with a large specific heat, and the thickness of the electrically insulating layer, such as 5in2, is less than 1 micron. Since only a small amount of heat is required, the overall heat capacity of the heat generating part can be greatly reduced.

従って発熱抵抗体3で発生する熱量は発熱部の熱容量が
小さいことと、基板部への熱散失がtヨとんど防止され
ているために高い温度を発生し、有効に感熱紙を発色せ
しめる。また、通電終了後は発熱部に蓄積されている熱
量が小さい為に印字の尾引きやにじみを発生させず、電
力効率の向上と共に高速印字が実現されたものである。
Therefore, the amount of heat generated by the heating resistor 3 generates a high temperature because the heat capacity of the heating part is small and heat dissipation to the substrate part is almost prevented, which effectively colors the thermal paper. . Furthermore, since the amount of heat accumulated in the heat generating part is small after the energization ends, trailing or blurring of the print does not occur, and high-speed printing is realized along with improved power efficiency.

本実施例である感熱記録ヘッドの製造工程の概略を第3
図に示す。第3図において、両面研磨された基板6は(
イ)に示すように厚さ0.20ミリメートルの(100
)面シリコンウェハーの基板であり、この基板6は(ロ
)に示すようにホウ素をPPMドープしたシリコン層7
を5ミクロンCVD法により成膜する。この後、基板6
は(/→に示すように両面を熱酸化により0.3ミクロ
ンの8i01膜8を形成する。この基板はに)に示すよ
うに裏面の8i02層9 K シ!jコンの異方性エツ
チング用マスク穴9′をホトソゾクラフ技術によシ形成
する。シリコン基板の異方性エツチング液であるエチレ
ンジアミン、パイロカテコール、水を使用することにょ
ルシリコン層6の(111)面はエツチングされず、最
終的に4枚の(111)面とエッチストップ層界面を頂
面とする窪6′が形成される。マスク穴9′の径lと頂
面の径l′との間にはシリコン基板の厚さをdに関して
l=1.4d+l’の関係であυ、本実施例ではlを0
.39ミリメートルとして 1/は0.11ミリメート
ルを得た。
The outline of the manufacturing process of the thermal recording head of this example is explained in the third section.
As shown in the figure. In FIG. 3, the double-sided polished substrate 6 is (
(100 mm) with a thickness of 0.20 mm as shown in b).
) is a silicon wafer substrate, and this substrate 6 has a silicon layer 7 doped with PPM boron as shown in (b).
A 5 micron film is formed by the CVD method. After this, the board 6
(As shown in /→, a 0.3 micron 8i01 film 8 is formed on both sides by thermal oxidation.This substrate is coated with an 8i02 layer 9 on the back side as shown in ()). A mask hole 9' for anisotropic etching of the J-con is formed by photolithography. By using ethylene diamine, pyrocatechol, and water, which are anisotropic etching solutions for silicon substrates, the (111) plane of the silicon layer 6 is not etched, and the interface between the four (111) planes and the etch stop layer is etched. A depression 6' serving as a top surface is formed. The relationship between the diameter l of the mask hole 9' and the diameter l' of the top surface is l=1.4d+l' with respect to the thickness of the silicon substrate d, and in this example, l is 0.
.. Assuming 39 mm, 1/ obtained 0.11 mm.

以上の工程で得られた基板6上に、通常の薄膜感熱ヘッ
ドの製造工程によシ(へ)に示されるように発熱抵抗体
3、およびリード電極4を形成した。
On the substrate 6 obtained in the above steps, a heat generating resistor 3 and lead electrodes 4 were formed as shown in FIG.

ここで発熱抵抗体3はTa−8iC系のスパッタ膜を、
電極4はAIを用い、発熱抵抗体および電極のパターン
化は基板の架橋部と目金せて行う。更に表面保換層lO
はSiCの3ミクロン厚さのスパッタ膜で表面を覆った
。最後にアルミ板上にマウントした。
Here, the heating resistor 3 is made of a Ta-8iC sputtered film.
The electrode 4 is made of AI, and the heating resistor and electrode are patterned so as to be flush with the bridge portion of the substrate. Furthermore, a surface storage layer lO
The surface was covered with a 3 micron thick sputtered film of SiC. Finally, it was mounted on an aluminum plate.

なお、本実施例の感熱記録ヘッドはかならずしも本実施
例で説明した製造工程に従う必要はなく、例えばシリコ
ン基板の異方性エツチングを全熱部形成後に行なっても
良いし、異方性エツチング液としてKOH等を使用して
も良い。また、エッチストップ層あるいはマスク材とし
てシリコンの酸化膜や窒化膜を使用しても良い。この場
合は電気絶縁層と兼用し得る。
It should be noted that the thermal recording head of this example does not necessarily need to follow the manufacturing process described in this example; for example, the silicon substrate may be anisotropically etched after the entire heated portion is formed, or an anisotropic etching liquid may be used. KOH or the like may also be used. Furthermore, a silicon oxide film or a silicon nitride film may be used as an etch stop layer or mask material. In this case, it can also be used as an electrical insulating layer.

本実施例の感熱記録ヘッドは32X32画素(ドツト)
で形成される漢字印字用シリアルプリンターヘッドであ
り、第4図(イ)、(ロ)に示すように106ミクロン
ピッチで合計32個の蛇行状の発熱抵抗体を千鳥格子状
に配置している。千鳥格子状に配置することは、隣接画
素(ドツト)間の熱影響を避け、また大型の発熱体を形
成し得る利点を持つものであるが、本実施例においては
発熱部が架橋上にあシ機械的強度不足の欠点を補う効果
をも有するものである。
The thermal recording head of this example has 32 x 32 pixels (dots).
This is a serial printer head for printing kanji characters, and as shown in Figure 4 (a) and (b), a total of 32 meandering heating resistors are arranged in a houndstooth pattern at a pitch of 106 microns. There is. Arranging in a houndstooth pattern has the advantage of avoiding thermal effects between adjacent pixels (dots) and forming a large heating element, but in this example, the heating part is placed on the bridge. This also has the effect of compensating for the lack of mechanical strength of the foot.

尚、本実施例と同一パターンの発熱部を有する感熱記録
ヘッドを通常のグレーズドアルミナ基板上に作成し特性
比較を行なった。本実施例のヘッドは印字エネルギーが
0.2ミリジユール/ドツトで0.5ミリ秒/ラインに
相当する60字/秒の高速印字が良好な印字品質で実現
された。これはグレーズドアルミナ基板を使用した場合
に比較して\印字エネルギーが約3分の1、印字速度が
約6倍である。
A thermal recording head having a heat generating part with the same pattern as that of this example was fabricated on an ordinary glazed alumina substrate, and the characteristics were compared. The head of this example achieved high-speed printing of 60 characters/second, which corresponds to 0.5 milliseconds/line, with good printing quality at a printing energy of 0.2 millijoules/dot. This is about one-third the printing energy and about six times the printing speed compared to when a glazed alumina substrate is used.

本発明は、以上説明したように発熱抵抗体の近傍にシリ
コン基板をエツチングし窪みを設けることにより、発熱
部の低熱容箪化を図り、高゛…カ効率、高速印字に適し
た感熱記録ヘッドが得られる。
As explained above, the present invention aims to reduce the heat capacity of the heat generating part by etching the silicon substrate to provide a depression near the heat generating resistor, thereby creating a thermal recording head suitable for high power efficiency and high speed printing. is obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は一般的な薄膜型感熱記録ヘッドの全熱部断面構
造を示す図、第2図は本発明の実施例である感熱記録ヘ
ッドの構造を示す図、第3図に本発明の実施例における
製造工程の概略を示す図、第4図は本発明の実施例を用
いたシリアルプリンターヘッドの構造を模式的に示す図
である。 1・・・・・・アルミナ基板、2・・・・・・ガラスグ
レーズ、3・・・・・・発熱抵抗体、4・・印・リード
電極、5・・・・・・表面保膜層、6・・・・・・シリ
コン基板、6′・・山lみ、7・・・・・・エッチスト
ップ層、8・・・・・・電気絶縁層、9・・・・・・エ
ツチングマスク、9′・・・・・・マスク穴。 第 / 図 第 Z 図 第3 図 第 4 図
FIG. 1 is a diagram showing the cross-sectional structure of the entire heating part of a general thin film type thermal recording head, FIG. 2 is a diagram showing the structure of a thermal recording head that is an embodiment of the present invention, and FIG. 3 is a diagram showing the structure of a thermal recording head that is an embodiment of the present invention. FIG. 4 is a diagram schematically showing the structure of a serial printer head using an example of the present invention. DESCRIPTION OF SYMBOLS 1...Alumina substrate, 2...Glass glaze, 3...Heating resistor, 4...Mark/lead electrode, 5...Surface film retaining layer , 6...Silicon substrate, 6'...Top depth, 7...Etch stop layer, 8...Electric insulation layer, 9...Etching mask , 9′...Mask hole. Figure / Figure Z Figure 3 Figure 4

Claims (2)

【特許請求の範囲】[Claims] (1)  シリコンウェハーの基板と、発熱抵抗体とを
有する感熱記録ヘッドにおいて、前記基板の異方性エツ
チングにより形成された架橋部と、該架橋部上に設けた
発熱抵抗体とを備えたことを特徴とする感熱記録ヘッド
(1) A thermal recording head having a silicon wafer substrate and a heat generating resistor, including a bridge formed by anisotropic etching of the substrate and a heat generating resistor provided on the bridge. A thermal recording head featuring
(2)発熱抵抗体及びそれに対応するシリコンウェハー
基板に形成される架橋部は千鳥格子状に配置したことを
特徴とする特許請求範囲第1項記載の感熱記録ヘッド。
(2) The heat-sensitive recording head according to claim 1, wherein the heating resistors and the corresponding bridge portions formed on the silicon wafer substrate are arranged in a staggered pattern.
JP18560882A 1982-10-22 1982-10-22 Heat sensitive recording head Pending JPS5973973A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18560882A JPS5973973A (en) 1982-10-22 1982-10-22 Heat sensitive recording head

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18560882A JPS5973973A (en) 1982-10-22 1982-10-22 Heat sensitive recording head

Publications (1)

Publication Number Publication Date
JPS5973973A true JPS5973973A (en) 1984-04-26

Family

ID=16173773

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18560882A Pending JPS5973973A (en) 1982-10-22 1982-10-22 Heat sensitive recording head

Country Status (1)

Country Link
JP (1) JPS5973973A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4712930A (en) * 1985-04-19 1987-12-15 Matsushita Electric Industrial Co., Ltd. Gradation thermal printhead and gradation heat transfer printing apparatus
US4841120A (en) * 1986-09-12 1989-06-20 Sony Corporation Thermal head
EP0605190A2 (en) * 1992-12-23 1994-07-06 Ngk Insulators, Ltd. Thermal head
US5940109A (en) * 1994-05-31 1999-08-17 Rohm Co. Ltd. Thermal printhead, substrate for the same and method for making the substrate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4712930A (en) * 1985-04-19 1987-12-15 Matsushita Electric Industrial Co., Ltd. Gradation thermal printhead and gradation heat transfer printing apparatus
US4841120A (en) * 1986-09-12 1989-06-20 Sony Corporation Thermal head
EP0605190A2 (en) * 1992-12-23 1994-07-06 Ngk Insulators, Ltd. Thermal head
EP0605190A3 (en) * 1992-12-23 1994-11-23 Ngk Insulators Ltd Thermal head.
US5459491A (en) * 1992-12-23 1995-10-17 Ngk Insulators, Ltd. Thermal head
US5940109A (en) * 1994-05-31 1999-08-17 Rohm Co. Ltd. Thermal printhead, substrate for the same and method for making the substrate

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