JPS5948779B2 - Composite fireproof insulation materials and fireproof structures using them - Google Patents

Composite fireproof insulation materials and fireproof structures using them

Info

Publication number
JPS5948779B2
JPS5948779B2 JP55059975A JP5997580A JPS5948779B2 JP S5948779 B2 JPS5948779 B2 JP S5948779B2 JP 55059975 A JP55059975 A JP 55059975A JP 5997580 A JP5997580 A JP 5997580A JP S5948779 B2 JPS5948779 B2 JP S5948779B2
Authority
JP
Japan
Prior art keywords
fire
resistant
weight
fireproof
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP55059975A
Other languages
Japanese (ja)
Other versions
JPS56160383A (en
Inventor
成雄 吉野
忠 前仏
巌 家村
肇 浅見
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinagawa Refractories Co Ltd
Original Assignee
Shinagawa Refractories Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinagawa Refractories Co Ltd filed Critical Shinagawa Refractories Co Ltd
Priority to JP55059975A priority Critical patent/JPS5948779B2/en
Publication of JPS56160383A publication Critical patent/JPS56160383A/en
Publication of JPS5948779B2 publication Critical patent/JPS5948779B2/en
Expired legal-status Critical Current

Links

Description

【発明の詳細な説明】 本発明は各種炉および容器の断熱を目的として使用され
る耐火断熱材に関するものであり、断熱性に優れた耐用
性のある複合耐火断熱材および該複合耐火断熱材を各種
高温炉および容器の内外面に施工して成る耐火構造体を
提供することを目的とする。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a fire-resistant insulation material used for the purpose of insulating various furnaces and containers, and relates to a durable composite fire-resistant insulation material with excellent insulation properties, and a fire-resistant insulation material using the composite fire-resistant insulation material. The purpose of the present invention is to provide a fireproof structure constructed on the inner and outer surfaces of various high-temperature furnaces and containers.

最近、省資源、省エネルギーの観点から各種炉、容器の
断熱が試みられている。
Recently, attempts have been made to insulate various furnaces and containers from the viewpoint of resource and energy conservation.

従来、この種の目的の断熱材として断熱れんがあるいは
無機繊維質断熱材が使用されているが、前者は高温にお
ける断熱性が不十分であると共に形状が小さく築造施工
に長時間を要するという欠点がある、また後者は高温で
の断熱性は優れるが長時間使用した場合、繊維の結晶化
が起り粉状化するという問題があり、加熱炉内面に施工
した場合粉状化した繊維粉末が炉内の製品を汚染する等
の問題があつた。
Traditionally, insulation bricks or inorganic fiber insulation materials have been used as insulation materials for this type of purpose, but the former has the disadvantages of insufficient insulation at high temperatures, its small shape, and the need for a long construction period. The latter has excellent insulation properties at high temperatures, but when used for a long time, the fibers crystallize and turn into powder, so if it is applied to the inner surface of the heating furnace, the pulverized fiber powder will be inside the furnace. There were problems such as contamination of other products.

また加熱炉等の内面に施工した場合、ガス流による摩耗
、侵食性ガスによる侵食損耗を受ける等の問題があつた
。また各種炉、容器の内壁に断熱材を施工し、断熱と共
に鉄皮の酸化を防止する試みもなされているが、前記2
種の断熱材は通気性が大きく、断熱は付与し得るものの
鉄皮の酸化は防ぎ得ない欠点がある。また繊維質断熱材
の表面に耐火材のコーチングを施こすことも試みられて
いるが、築炉施工時、煩雑の欠点がある。本発明は上記
の諸問題を解決すべく種々検討の結果完成したものであ
り、本発明の要旨はアルミナ、マグネシア、シリカ、シ
ヤモツト、炭化珪素等の耐火原料100重量部に対し、
1〜20重量部の無機繊維及び/又は有機繊維、合成樹
脂エマルジョン及び/又はゴムラテックスを樹脂分とし
て3〜50重量部を添加してなる、乾燥後に可撓性を示
す耐火可撓性及び加圧収縮性を有する耐火可撓性ボード
ど無機繊維集合体よりなる複合耐火断熱材及びアルミナ
、マグネシア、シリカ、シヤモツト、炭化珪素等の耐火
原料100重量部に対し、1〜20重量部の無機繊維及
び/又は有機繊維、合成樹脂エマルジヨン及び/又はゴ
ムラテツクスを樹脂分として3〜50重量部を添加して
なる、乾燥後に可撓性を示す耐火可撓性及び加圧収縮性
を有する耐火可掃姓ボードと無機繊維集合体よりなる複
合耐火断熱材を、各種炉、容器の稼働面及び/又は鉄皮
等の内壁に施工してなる耐火構造体に存し、断熱性に優
れるとともに長期耐用性に優れた複合耐火断熱材及び耐
火断熱構造体を提供するものである。
Further, when applied to the inner surface of a heating furnace, etc., there were problems such as abrasion caused by gas flow and erosion caused by corrosive gas. Attempts have also been made to install heat insulating materials on the inner walls of various furnaces and containers to both insulate and prevent oxidation of the steel shell.
Seed insulation materials have high air permeability, and although they can provide insulation, they have the disadvantage that they cannot prevent oxidation of the iron skin. Attempts have also been made to coat the surface of the fibrous heat insulating material with a refractory material, but this approach has the disadvantage of being complicated during furnace construction. The present invention was completed as a result of various studies to solve the above-mentioned problems, and the gist of the present invention is to:
A fire-resistant flexible and processable material that exhibits flexibility after drying and is made by adding 1 to 20 parts by weight of inorganic fibers and/or organic fibers, synthetic resin emulsion and/or rubber latex as a resin component, and 3 to 50 parts by weight. 1 to 20 parts by weight of inorganic fibers per 100 parts by weight of a composite fire-resistant heat insulating material made of an inorganic fiber aggregate such as a fire-resistant flexible board having pressure shrinkability and fire-resistant raw materials such as alumina, magnesia, silica, siyamoto, silicon carbide, etc. and/or a fire-resistant and cleanable material which exhibits flexibility after drying and has fire-resistant flexibility and shrinkability under pressure, which is made by adding 3 to 50 parts by weight of organic fibers, synthetic resin emulsion and/or rubber latex as a resin component. This is a fireproof structure made by applying a composite fireproof insulation material made of a board and an inorganic fiber aggregate to the operating surfaces of various furnaces and containers and/or the inner walls of steel shells, etc., and has excellent heat insulation properties and long-term durability. The present invention provides an excellent composite fireproof insulation material and fireproof insulation structure.

本発明複合耐火断熱材の具体例を図面に基ずいて説明す
る。
A specific example of the composite fireproof heat insulating material of the present invention will be explained based on the drawings.

しかしながら本発明はこれら具体例および厚さ、長さ、
巾、層数等に限定するものでなく、本発明の要旨内の変
更、改変は本発明に包含されるものである。第1図は耐
火可撓性ボード2と繊維集合体1からなる複合耐火断熱
材を示す要部断面図である。
However, the present invention relates to these specific examples, thickness, length,
The invention is not limited to the width, the number of layers, etc., and changes and modifications within the gist of the invention are included in the invention. FIG. 1 is a sectional view of a main part of a composite fireproof heat insulating material made of a fireproof flexible board 2 and a fiber aggregate 1. As shown in FIG.

繊維集合体1はシート状で綿のように柔かく、従つて強
度も小さいがこのように層状化すると耐火可撓性ボード
が芯となつて取扱いが容易になると共にこれを施工する
場合、曲面にも随意に変形させることも容易である。ま
た長期間使用した場合でも繊維集合体は結晶化による粉
状化ならびにガス流等による損耗、侵食を阻止し、長期
の断熱耐用性が得られる。第2図は硬質耐火ボード3、
繊維果合体1および耐火可撓注ボード2からなる複合耐
火断熱材を示す要部断面図である。
The fiber aggregate 1 is sheet-like and soft like cotton, and therefore has low strength, but when it is layered in this way, the fire-resistant flexible board acts as a core, making it easy to handle, and when it is installed, it can be easily handled on curved surfaces. It is also easy to modify it as desired. Furthermore, even when used for a long period of time, the fiber aggregate prevents pulverization due to crystallization, wear and corrosion due to gas flow, etc., and provides long-term insulation durability. Figure 2 shows hard fireproof board 3,
FIG. 2 is a sectional view of a main part of a composite fireproof heat insulating material made of a fiber aggregate 1 and a fireproof flexible board 2. FIG.

該複合耐火断熱材は可撓性を有しないが、長期間使用し
た場合でも繊維集合体は結晶化による粉状化を阻止し長
期の断熱耐用性が得られる。また溶融金属に接する内張
に使用することもできるが、炉あるいは容器の内張材と
鉄皮間へ断熱を目的として使用する場合、内張材の膨張
あるいは溶融金属の靜圧等の応用を受けても該複合耐火
断熱材は収縮せず断熱性のある炉体構造が得られる。本
発明において耐火可撓性ボード2は耐火物粉末、無機繊
維を主体としたものであり、施工時の常温において可撓
性かつ加圧収縮性を有するものがよい。
Although the composite refractory heat insulating material does not have flexibility, even when used for a long period of time, the fiber aggregate prevents powdering due to crystallization and provides long-term insulation durability. It can also be used as a lining in contact with molten metal, but when used for the purpose of insulation between the lining material and steel shell of a furnace or container, expansion of the lining material or application of static pressure of the molten metal, etc. Even when exposed to heat, the composite refractory heat insulating material does not shrink and a heat insulating furnace structure can be obtained. In the present invention, the fireproof flexible board 2 is mainly made of refractory powder and inorganic fibers, and preferably has flexibility and shrinkability under pressure at room temperature during construction.

このような可撓性耐火ボードは施工時の曲面にも完全に
密着し、施工時の加工も少なく施工性の優れたものであ
り、繊維集合体1との複合により本発明の複合耐火断熱
材の一部として使用してもそのまま本来の特性を損わず
に使用に供しうる。この耐火可撓性ボードとして例えば
特開昭55ー7514号公報記載の無機耐火物粉末単独
の、無機耐火物粉末と無機繊維との両者の、無機耐火物
粉末と有機繊維との両者の、または無機耐火物粉末と無
機繊維と有機繊維との三者の100重量部を主原料とし
、これに結合剤として乾燥後に柔軟囲を有する液状バイ
ンダー、例えば合成樹脂エマルジヨンまたは/およびゴ
ムラテツクスを樹脂分として3〜50重量部を配合して
なることを特徴とする耐火可撓性ボードを用いることが
できる。
Such a flexible fireproof board completely adheres to curved surfaces during construction, requires little processing during construction, and has excellent workability, and when combined with the fiber aggregate 1, the composite fireproof insulation material of the present invention Even if it is used as a part of the product, it can be used as it is without losing its original properties. This fire-resistant flexible board may be made of an inorganic refractory powder alone, an inorganic refractory powder and an inorganic fiber, an inorganic refractory powder and an organic fiber, or The main raw materials are 100 parts by weight of inorganic refractory powder, inorganic fibers, and organic fibers, and 3 parts by weight of a liquid binder, such as synthetic resin emulsion or/and rubber latex, which has a flexible surface after drying as a binder. A fire-resistant flexible board characterized by containing ~50 parts by weight can be used.

または上記耐火可撓ボード組成物に発泡剤を添加発泡さ
せ加圧収縮性を具備せしめた耐火可撓性ボードを用いる
ことができる。本発明に用いる繊維集合体1として各種
形態のものが使用され、例えばスラグウール、セラミツ
クフアイバ一、グラスフアイバ一等フエルト状に形成あ
るいはこれらを積層したものが使用でき、対象となる使
用場所の温度条件により適宜選択する。
Alternatively, a fire-resistant flexible board can be used which is obtained by adding a foaming agent to the fire-resistant flexible board composition and foaming it to provide pressure shrinkability. Various forms of the fiber aggregate 1 used in the present invention can be used, such as slag wool, ceramic fiber, glass fiber, etc., which can be formed into a felt shape or laminated together. Select as appropriate depending on the conditions.

本発明複合耐火断熱材の形成手段は例えば繊維集合体と
耐火可撓性ボードを耐火接着材で接着する。
The means for forming the composite fire-resistant heat insulating material of the present invention is, for example, by bonding a fiber aggregate and a fire-resistant flexible board with a fire-resistant adhesive.

また繊維集合体上面に耐火可撓性ボード用坏土をコーチ
ングまたは流し込み後100℃以上で2時間以上乾燥し
て得られる。なお本発明の複合耐火断熱材はそのまま各
種炉、および容器の稼働面および/または非稼働面(鉄
皮側)に公知のモルタルあるいはボルト止めして施工し
得るが、作業性を向上させるため施工面に感圧接着剤を
塗布して使用することもできる。
It can also be obtained by coating or pouring a fire-resistant flexible board clay on the top surface of the fiber aggregate and then drying it at 100° C. or higher for 2 hours or more. The composite refractory heat insulating material of the present invention can be installed as it is on the operating and/or non-operating surfaces (shell side) of various furnaces and containers by fixing it with known mortar or bolts. It can also be used by applying a pressure sensitive adhesive to the surface.

例えば施工面に耐火材料微粉と無機結合剤と合成樹脂ま
たはゴム系粘着剤との混合物からなる感圧接着剤を裏打
ちしかつ離型紙を貼付した構造とすることにより一層施
工の作業性が向土される。実施例第1図に示す如き構造
を有し、かつ、図中1が50]!」厚のAIl2O3含
有量55%のセラミツク繊維集合体、2が5n厚のA/
!203含有量95%の耐火可撓性ボードである複合耐
火断熱材を熱延加熱炉壁に使用した結果、従来使用され
てきた上記セラミツク繊維集合体と同材質のAIl2O
3含有量55%のものは3ケ月使用後粉状化し、取替補
修せざるを得ない状態であつてのに比し、本発明複合耐
火断熱材は粉状化現象が見られず6ケ月以上の長期耐用
性が確認された。
For example, construction workability can be further improved by lining the construction surface with a pressure-sensitive adhesive made of a mixture of fireproof material fine powder, an inorganic binder, and a synthetic resin or rubber adhesive, and pasting release paper. be done. Embodiment It has a structure as shown in FIG. 1, and 1 in the figure is 50]! Ceramic fiber aggregate with 55% AIl2O3 content, 2 is 5n thick A/
! As a result of using a composite refractory insulation material, which is a refractory flexible board containing 95% 203, for the walls of the hot rolling furnace, AIl2O, which is made of the same material as the ceramic fiber aggregate previously used, was used for the walls of the hot rolling heating furnace.
Comparatively, the composite fire-resistant insulation material containing 55% 3 becomes powder after 3 months of use and has to be replaced and repaired, but the composite fireproof insulation material of the present invention does not show any pulverization phenomenon after 6 months of use. The above long-term durability was confirmed.

【図面の簡単な説明】[Brief explanation of the drawing]

添付図面は本発明の複合耐火断熱材の一例を示す要部断
面図である。
The accompanying drawing is a sectional view of a main part showing an example of the composite fireproof heat insulating material of the present invention.

Claims (1)

【特許請求の範囲】 1 アルミナ、マグネシア、シリカ、シヤモツト、炭化
珪素等の耐火原料100重量部に対し、1〜20重量部
の無機繊維及び/又は有機繊維、合成樹脂エマクジヨン
及び/又はゴムラテックスを樹脂分として3〜50重量
部を添加してなる、乾燥後に可撓性を示す耐火可撓性及
び加圧収縮性を有する耐火可撓性ボードと無機繊維集合
体よりなる複合耐火断熱材。 2 アルミナ、マグネシア、シリカ、シヤモツト、炭化
珪素等の耐火原料100重量部に対し、1〜20重量部
の無機繊維及び/又は有機繊維、合成樹脂エマルジョン
及び/又はゴムラテックスを樹脂分として3〜50重量
部を添加してなる、乾燥後に可撓性を示す耐火可撓性及
び加圧収縮性を有する耐火可撓性ボードと無機繊維集合
体よりなる複合耐火断熱材を、各種炉、容器の稼働面及
び/又は鉄皮等の内壁に施工してなる耐火構造体。
[Claims] 1. 1 to 20 parts by weight of inorganic fibers and/or organic fibers, synthetic resin emulsion and/or rubber latex to 100 parts by weight of refractory raw materials such as alumina, magnesia, silica, silica, silicon carbide, etc. A composite fire-resistant heat insulating material comprising a fire-resistant flexible board and an inorganic fiber aggregate that exhibits flexibility after drying and has fire-resistant flexibility and shrinkability under pressure, to which 3 to 50 parts by weight are added as a resin component. 2 1 to 20 parts by weight of inorganic fibers and/or organic fibers, synthetic resin emulsion and/or rubber latex as a resin content to 100 parts by weight of refractory raw materials such as alumina, magnesia, silica, silica, silicon carbide, etc. A composite fire-resistant insulation material made of a fire-resistant flexible board and an inorganic fiber aggregate, which exhibits flexibility after drying and is compressible under pressure, is used for the operation of various furnaces and containers. A fireproof structure constructed on the inner wall of a surface and/or iron skin.
JP55059975A 1980-05-08 1980-05-08 Composite fireproof insulation materials and fireproof structures using them Expired JPS5948779B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55059975A JPS5948779B2 (en) 1980-05-08 1980-05-08 Composite fireproof insulation materials and fireproof structures using them

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55059975A JPS5948779B2 (en) 1980-05-08 1980-05-08 Composite fireproof insulation materials and fireproof structures using them

Publications (2)

Publication Number Publication Date
JPS56160383A JPS56160383A (en) 1981-12-10
JPS5948779B2 true JPS5948779B2 (en) 1984-11-28

Family

ID=13128674

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55059975A Expired JPS5948779B2 (en) 1980-05-08 1980-05-08 Composite fireproof insulation materials and fireproof structures using them

Country Status (1)

Country Link
JP (1) JPS5948779B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6439880U (en) * 1987-09-03 1989-03-09

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6086539U (en) * 1983-11-22 1985-06-14 日新工機株式会社 Heat-resistant and compression-resistant insulation material
JPH0811703B2 (en) * 1993-03-16 1996-02-07 恒和化学工業株式会社 Fireproof coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6439880U (en) * 1987-09-03 1989-03-09

Also Published As

Publication number Publication date
JPS56160383A (en) 1981-12-10

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