JPS5929523B2 - 硫化水素と固定窒素化合物の混合物から硫黄を製造する方法及びその装置 - Google Patents
硫化水素と固定窒素化合物の混合物から硫黄を製造する方法及びその装置Info
- Publication number
- JPS5929523B2 JPS5929523B2 JP51057180A JP5718076A JPS5929523B2 JP S5929523 B2 JPS5929523 B2 JP S5929523B2 JP 51057180 A JP51057180 A JP 51057180A JP 5718076 A JP5718076 A JP 5718076A JP S5929523 B2 JPS5929523 B2 JP S5929523B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction zone
- thermal reaction
- hydrogen sulfide
- gas
- thermal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 83
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims description 83
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 45
- 229910052717 sulfur Inorganic materials 0.000 title claims description 44
- 239000011593 sulfur Substances 0.000 title claims description 44
- 229910017464 nitrogen compound Inorganic materials 0.000 title claims description 32
- 150000002830 nitrogen compounds Chemical class 0.000 title claims description 32
- 239000000203 mixture Substances 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 198
- 239000007789 gas Substances 0.000 claims description 106
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 70
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 60
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 28
- 239000001301 oxygen Substances 0.000 claims description 28
- 229910052760 oxygen Inorganic materials 0.000 claims description 28
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 24
- 229910021529 ammonia Inorganic materials 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 229910001868 water Inorganic materials 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- PFRUBEOIWWEFOL-UHFFFAOYSA-N [N].[S] Chemical class [N].[S] PFRUBEOIWWEFOL-UHFFFAOYSA-N 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- 230000003197 catalytic effect Effects 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 238000005192 partition Methods 0.000 claims description 9
- 239000002912 waste gas Substances 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 46
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 13
- 238000002485 combustion reaction Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 206010021143 Hypoxia Diseases 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- -1 NH3 and HCN Chemical class 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- XAQHXGSHRMHVMU-UHFFFAOYSA-N [S].[S] Chemical compound [S].[S] XAQHXGSHRMHVMU-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0413—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the combustion step
- C01B17/0421—Multistage combustion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/506,305 US3970743A (en) | 1974-09-16 | 1974-09-16 | Process for the production of sulfur from mixtures of hydrogen sulfide and fixed nitrogen compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52140495A JPS52140495A (en) | 1977-11-24 |
| JPS5929523B2 true JPS5929523B2 (ja) | 1984-07-21 |
Family
ID=24014041
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51057180A Expired JPS5929523B2 (ja) | 1974-09-16 | 1976-05-18 | 硫化水素と固定窒素化合物の混合物から硫黄を製造する方法及びその装置 |
Country Status (6)
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2537451C2 (de) * | 1975-08-22 | 1987-05-27 | Carl Still Gmbh & Co Kg, 4350 Recklinghausen | Verfahren zum Umsetzen des in Koksofengasen enthaltenen Ammoniaks in Stickstoff und Wasser und des Schwefelwasserstoffs zu Schwefel |
| US4181706A (en) * | 1976-04-24 | 1980-01-01 | Firma Carl Still Recklinghausen | Method and apparatus for decomposing ammonia fumes having a high hydrogen sulfide content |
| US4032618A (en) * | 1976-05-11 | 1977-06-28 | The United States Energy Research And Development Administration | Conversion of ammonia into hydrogen and nitrogen by reaction with a sulfided catalyst |
| JPS5411097A (en) * | 1977-06-27 | 1979-01-26 | Zink Co John | Apparatus for producing material capable of recovering free sulfur |
| FR2424875A1 (fr) * | 1978-05-02 | 1979-11-30 | Elf Aquitaine | Procede de production de soufre a partir de deux gaz acides renfermant h2s et dont un seul contient nh3 |
| US4391790A (en) * | 1981-09-28 | 1983-07-05 | Standard Oil Company (Indiana) | Method and apparatus for reducing the ammonia concentration of sulfur recovery facility gas streams |
| US4438069A (en) | 1981-12-30 | 1984-03-20 | Atlantic Richfield Company | System for temperature control of a Claus sulfur unit thermal reactor |
| US4543245A (en) * | 1981-12-30 | 1985-09-24 | Atlantic Richfield Company | Process for controlling temperature of a Claus sulfur unit thermal reactor |
| HU198154B (en) * | 1986-05-04 | 1990-08-31 | N Proizv Ob Tekhenergokhimprom | Process for producing sulfur from gas containing hydrogen sulfide |
| US5508013A (en) * | 1991-04-25 | 1996-04-16 | Elf Aquitaine Production | Process for the production of sulphur from at least one sour gas containing hydrogen sulphide and a fuel effluent and thermal reactor |
| US5304361A (en) * | 1992-06-26 | 1994-04-19 | Union Carbide Chemicals & Plastics Technology Corporation | Removal of hydrogen sulfide |
| US5372706A (en) * | 1993-03-01 | 1994-12-13 | Mobil Oil Corporation | FCC regeneration process with low NOx CO boiler |
| US5904910A (en) * | 1997-11-07 | 1999-05-18 | Black & Veatch Pritchard, Inc. | Method for producing sulfur and hydrogen from a gaseous stream containing hydrogen sulfide and ammonia |
| JP3924150B2 (ja) * | 2001-10-26 | 2007-06-06 | 三菱重工業株式会社 | ガス燃焼処理方法およびその装置 |
| IT1396917B1 (it) * | 2009-10-23 | 2012-12-20 | Sini S P A Gia Siirtec Nigi S P A | Processo per il recupero dello zolfo da correnti gassose ricche in ammoniaca, da correnti di gas acidi e di anidride solforosa |
| US9259680B2 (en) | 2011-09-06 | 2016-02-16 | Frank Bela | Claus hydrocarbon destruction via staged solvent regeneration |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB686469A (en) * | 1950-03-14 | 1953-01-28 | Koppers Gmbh Heinrich | A process and apparatus for the recovery of sulphur from hydrogen sulphide |
| DE1202772B (de) * | 1963-01-25 | 1965-10-14 | Still Fa Carl | Verfahren zur Verbrennung des bei der Aufarbeitung von Kokerei- oder Gaswerksgas anfallenden Ammoniaks |
| US3518056A (en) * | 1968-09-26 | 1970-06-30 | Chevron Res | Hydrogen sulfide recovery by degassing,distillation and ammonia recycle with subsequent sulfur production |
| US3819816A (en) * | 1969-05-21 | 1974-06-25 | G Wunderlich | Process for the manufacture of sulfur or sulfuric acid from coke oven gas |
| DE1926629C3 (de) * | 1969-05-24 | 1979-04-26 | Guenter Dr. 4250 Bottrop Wunderlich | Verfahren zur Beseitigung des aus Koksofengasen und ihren Kondensaten abgetrennten Ammoniaks |
| CA928043A (en) * | 1970-08-07 | 1973-06-12 | Amoco Canada Petroleum Company Ltd. | Processing sulfur plant feed gases containing ammonia |
| US3877879A (en) * | 1973-02-26 | 1975-04-15 | Amoco Prod Co | Apparatus for handling ammonia-containing acid gas streams |
| US3860697A (en) * | 1973-04-23 | 1975-01-14 | Amoco Prod Co | Method for recovery of elemental sulfur from low hydrogen sulfide sulfur plant feed gas |
-
1974
- 1974-09-16 US US05/506,305 patent/US3970743A/en not_active Expired - Lifetime
-
1976
- 1976-05-04 CA CA251,768A patent/CA1057935A/en not_active Expired
- 1976-05-11 GB GB19303/76A patent/GB1545915A/en not_active Expired
- 1976-05-11 DE DE19762620700 patent/DE2620700A1/de active Granted
- 1976-05-14 FR FR7614655A patent/FR2351047A1/fr active Granted
- 1976-05-18 JP JP51057180A patent/JPS5929523B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2620700A1 (de) | 1977-12-01 |
| CA1057935A (en) | 1979-07-10 |
| FR2351047A1 (fr) | 1977-12-09 |
| US3970743A (en) | 1976-07-20 |
| GB1545915A (en) | 1979-05-16 |
| JPS52140495A (en) | 1977-11-24 |
| FR2351047B3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-09-28 |
| DE2620700C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-11-09 |
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