JPS5925189A - Ceramic heater - Google Patents

Ceramic heater

Info

Publication number
JPS5925189A
JPS5925189A JP13594282A JP13594282A JPS5925189A JP S5925189 A JPS5925189 A JP S5925189A JP 13594282 A JP13594282 A JP 13594282A JP 13594282 A JP13594282 A JP 13594282A JP S5925189 A JPS5925189 A JP S5925189A
Authority
JP
Japan
Prior art keywords
heating element
ceramic heater
palladium
heater
gold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13594282A
Other languages
Japanese (ja)
Inventor
千秋 中山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toto Ltd
Original Assignee
Toto Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toto Ltd filed Critical Toto Ltd
Priority to JP13594282A priority Critical patent/JPS5925189A/en
Publication of JPS5925189A publication Critical patent/JPS5925189A/en
Pending legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は、セラミックヒータ−[i刈する。[Detailed description of the invention] The present invention is a ceramic heater.

今日セラミックスに雀鴎を埋設してなるセラミックヒー
タ−は、H熱′吐が1.7J<、化学的にも女定した牡
賀を具11iiI しているので、−1:り特機r生か
して工i、装置[便用されている。
Today's ceramic heaters, which are made by embedding sparrows in ceramics, have an H heat discharge of 1.7 J<, and are chemically determined to be female. The equipment is [conveniently used].

ところが、一般に小敵されている率!朱の雀嶋を埋設し
て形成しているセラミックヒータ−では、これに通電し
て発熱?しめる時、始動時に極めて大きい電αICが流
れる。
However, the rate is generally regarded as a small enemy! Does the ceramic heater, which is made by burying vermilion Suzushima, generate heat when electricity is applied to it? When the engine is closed and started, an extremely large amount of electricity αIC flows.

これは金属の電気抵抗が温度の上昇と共に増加するハ[
副、正の温度係数をMするためでヒーター始動時の電力
と胸囲温度と平衡した使用状態の電力との間には、大き
な差を生じる。
This is due to the fact that the electrical resistance of metal increases as the temperature rises.
Because of the negative and positive temperature coefficient M, a large difference occurs between the electric power at the time of starting the heater and the electric power in the state of use, which is balanced with the chest temperature.

それに加えてセラミックスは熱谷鈑が大きな為、平価し
た温度状態VC達するまで時間を貿し、この同は大きな
始動′電流がS1減しながら流れるため、速熱性fcy
求するような工業投置にeよイ蚕合するが、一方スイッ
チ、トランス等の′亀弾設補に大きな過負イdi耐礒て
妥し、使用時の平間的力に相当した′電源設備では設晦
谷鼠以上の負担を加えることになり、゛区綜設筒の対合
を縮める不具合を有する。
In addition, since ceramics have a large thermal valley, it takes time to reach the average temperature state VC, and this causes a large starting current to flow while decreasing S1, resulting in fast heating fcy.
It is very suitable for industrial installations such as switches, transformers, etc., but on the other hand, it has to withstand a large amount of overload and soaring power for the installation of switches, transformers, etc. In terms of equipment, the burden on the equipment is greater than that required for installation, and there is a problem in that the pairing of the construction cylinders is shortened.

即ち、従来のセラミックヒータ−では始動時に相当した
′眠力芥鍛を有する電踪設画が必装となり工学設u1m
又は民生設誦の加熱長1#’として・ぼ力設計上不具台
を生じ、実用上の間)A点會有し′ていた。
In other words, with conventional ceramic heaters, an electrical construction with a 'sleep force' corresponding to the start-up is required, and the engineering construction u1m is required.
Or, as a heating length of 1#' for civilian installations, a malfunction occurred due to the power design, and for practical purposes, there was a point A point.

本発明は上り己疲米事=11 vC頃みてなされたもの
で、その目的とする処はパラジウム、白金、苔、銀とが
固溶することゲ利用して合蛍比率を鋭えて、抵抗の温度
什数を制御することにより始り1時の電力の立上りの程
度を笈えて、速熱性の変更が口■能でありセラミックヒ
ータ−使用時の平衡電力に応じた亀力谷宸を・1−する
亀諒棹踊をも倚ることをuJ能としたセラミックヒータ
−を提供するものでるる〇 又、本夕ら明は熱衝1に性の尚いコーディエライトセラ
ミックスに酸化の恐れのないパラジウム、白金、金、銀
の内2つ以上の合金全埋設してセラミックヒータ−全形
成せしひるものでコーチイエライトセラミックスのゲl
 j戊と、内部の抵抗発熱体となるその廿釜の黙1勇’
Jl+係数の整合性が良好で、その焼成時、金4の1夜
化を防止するためのテラ水雰囲気の如く中社又は水系雰
囲気の如く礒元雰囲気が不蒙で抵抗発熱体とセラミック
界面との剥離、セラミックヒータ−基板の変形、破壊、
抵抗発熱体の断線等も至ったく生ぜずM価基性が扁くイ
6頼性のあるコーディエライトセラミックヒーターヲ提
供せんとするものである。
The present invention was developed around 11 vC, and the purpose of this invention is to sharpen the combination ratio by utilizing the solid solution of palladium, platinum, moss, and silver. By controlling the temperature factor, it is possible to change the heating speed by controlling the degree of power rise at the beginning of the first hour, and it is possible to change the heating speed according to the equilibrium power when using a ceramic heater. In addition, Motoyura Akira has developed a ceramic heater that is capable of supporting even the turtle dance. Fully embedded ceramic heater made of alloys of two or more of palladium, platinum, gold, and silver.
j戊 and the internal resistance heating element of the kettle, Moku 1 Yu'
The consistency of the Jl+ coefficient is good, and during firing, the resistance heating element and the ceramic interface are unfavorable, such as a tera water atmosphere or a water-based atmosphere, to prevent gold 4 from becoming overnight. peeling off, deformation and destruction of the ceramic heater substrate,
It is an object of the present invention to provide a cordierite ceramic heater which is highly reliable and has a flat M-value base without causing any breakage of the resistance heating element.

以下、本発明の実施例で説明する。Examples of the present invention will be explained below.

セラミックヒータ−は、コーチイエライトを主体とする
セラミックスと、そのセラミックス内に埋設して形成し
た貞着鴎糸合金(銀、雀、白金、パラジウム)の内所望
の=V4金含Mせしめた抵抗発熱体からなる。
Ceramic heaters are made of ceramics mainly composed of kochiyerite, and a resistor containing the desired =V4 gold-containing M of Teishiki-Oito alloys (silver, sparrow, platinum, palladium) embedded in the ceramics. Consists of a heating element.

ル[るコーディエライトからなるセラミックスの基板は
、レリえばマグネシア言南原料35貞鍛都、長石12重
箪都、アルミナ粉末3車量部、カオリン40本−都、ペ
タライト10重置部、を混合し、粉砕することにより調
合粉砕物を得、これに有% バインダーとしてポリビニ
ルブチラール金40重振部金加え、混練した畝押出成形
伝により厚さ1mmの生シート状に形成し、これk 4
J寸法125mm、横寸法85 mmで切断し、乾燥す
る。
The ceramic substrate made of cordierite consists of 35 layers of magnesia, 12 layers of feldspar, 3 parts of alumina powder, 40 pieces of kaolin, and 10 layers of petalite. A blended pulverized product was obtained by mixing and pulverizing, to which was added 40% polyvinyl butyral gold as a binder, and formed into a green sheet with a thickness of 1 mm by kneading and ridge extrusion molding.
Cut into J dimension 125 mm and horizontal dimension 85 mm and dry.

次に抵抗発熱体となる金用ペーストの製造工程全説明す
れば白金、パラジウム、釜1、限の内所望の〈Oは用い
、下t[8に小すベースト配行例と電気l持性夕の9口
くエテルセルロース、目ト酸ブチカルピトール必要曳量
部を加えて混合してベーストをつる〇 ペースト配合し1」とi、気性f′):光来TCR−厄
気抵抗の温度係μ このペーストラ用い上記コーディエライトの生シート上
に、スクリーン印刷俄により発熱体回路を印刷し、これ
ケ80°Cで30分間乾譲する。
Next, I will explain the entire manufacturing process of the gold paste that will become the resistance heating element. Add the required amount of ethyl cellulose and butycarpitol methacrylate and mix to make base paste. A heating element circuit was printed on the green cordierite sheet using this paster by screen printing, and this was dried at 80° C. for 30 minutes.

この印刷した生シートに別の印刷しでいない生シートを
重ね200kg/cmt、150’Cで圧治績層する。
This printed raw sheet was overlaid with another unprinted raw sheet and pressed at 200 kg/cmt and 150'C.

積層後あらかじめ通電の為抵抗つ6熱体と連通せしめる
ように開孔したスルーホール内部に抵抗発熱体と同じペ
ーストケ■布し、電極層を形成する。
After lamination, the same paste as that for the resistive heating element is applied inside the through hole previously opened so as to communicate with the resistive heating element for energization, thereby forming an electrode layer.

Jνfる如くに形成したセラミック基板を、電気炉を用
い大気中1300’Cで1時IW4焼成した故無畦屏ニ
ッケル法により屯)ljに3Iの埋さのニッケル膜を形
成せしめ辿゛亀用引出線としてニッケルーを氷菓雰囲気
中1000°Cで屯1≠都に続ろう付してコーディエラ
イトセラミックヒータ−を得る。
The ceramic substrate formed as shown in Jvf was fired for 1 hour at 1300'C in the air using an electric furnace to form a buried nickel film of 3I on the surface of the ceramic substrate using the unfinished nickel method. A cordierite ceramic heater is obtained by brazing nickel as a leader wire at 1000° C. in a frozen atmosphere following the tun 1≠to.

斯碌に製造したコーディエライトセラミックヒータ−と
、全く同じ方法で装造したバラノウム金属単味のコーデ
ィエライトセラミックヒータ−の2di類を電気炉に入
れ−〔チト占し、ナシタルオーム計をもって抵抗の温度
係数を(911定したところ、パラジウム金鴎単味のヒ
ーターは、3800M’m% パラジウムと金、パラジ
ウムと銀、山雀と金、パラジウムとく限と白金、パラジ
ウムと原と釜、パラジウムと金と白金、山雀と金と・、
眼、の夫々は340ppm 、 800ppm 、 1
200ppm、 750ppm s720ppm 、 
300ppm、  1300ppmと最大のものでも略
し3、最小のものでも略しとなることが判ったミこれに
より白金、パラジウム、蛍、銀の内2つ以上の合金に含
有されるそのf %比率を変化させることにより抵抗の
温度係数は自由に変更できることが解明された。
The cordierite ceramic heater made in this manner and the cordierite ceramic heater made of balanoum metal made in exactly the same way were placed in an electric furnace. When the temperature coefficient was determined by (911), the heater made of palladium and gold roe was 3800 M'm%. Platinum, Yamajaku and gold...
eyes, respectively 340ppm, 800ppm, 1
200ppm, 750ppm s720ppm,
It was found that the maximum amount is 300 ppm and 1300 ppm, and the minimum value is also abbreviated. This changes the f% ratio contained in an alloy of two or more of platinum, palladium, firefly, and silver. It was revealed that the temperature coefficient of resistance can be changed freely.

本発明は叙上の如く、コーディエライトセラミックス内
にパラジウム、白m1.帳、余栄の2つ以上を含Mせし
めた合金の内、白金とパラジウムとの合金−橋類を除く
賞金PAホの合金を埋設して抵抗発熱体全形成し、その
含イf金・、偽の合誼比率を変化せしめることにより、
電気抵抗の温度係数を制(財)せしめてなるのでセラミ
7クヒーター使用時の平田電力に応じたm力谷址金11
゛する昨源設;1冶ケ伶ることが出来、又(品度保献ケ
変えることによって必恍に応じたg1幅ipL+]ヒを
も付与出来るので、工業的1曲1−は大である。
As described above, the present invention includes palladium, white m1. Of the alloys containing two or more of M and Yoei, an alloy of platinum and palladium - excluding bridges, is buried to form the entire resistance heating element, and the alloy containing M is , by changing the false union ratio,
Since it controls the temperature coefficient of electrical resistance, it is possible to reduce the power consumption according to Hirata electric power when using a ceramic 7 heater.
Since it is possible to change the original setting of 1, and also to add (g1 width ipL+ according to necessity by changing the quality guarantee), one industrial song 1- is not a big deal. be.

また、コーディエライトセラミックス4輩と内部のパラ
ジウム、白金、金、嫁の内2つ以上の合金からなる抵抗
先熱体との熱膨「廉保叡の差についても、柔軟な、R午
禍を用いることにより応力が緩和されているばかりでな
く焼成時の苔肯酸化防止のための中性又は水索搭囲気の
yu <の還元雰囲気が不快であり兄熱動11−幅展で
反応を起こして電気抵抗の変化や劣1ヒによって田[・
σJするようなことはなく、1g顆性がl’L?] <
 、耐熱例哄性VC潰れたセラミックヒータ−?供し倚
る。
In addition, regarding the difference in thermal expansion between the four cordierite ceramics and the internal resistor preheated body made of an alloy of two or more of palladium, platinum, gold, and metal, flexible, Not only is the stress alleviated by using the moss during firing, but the reducing atmosphere of neutral or water-filled air to prevent moss oxidation is unpleasant, so it is difficult to react in the oxidation process. Due to changes in electrical resistance and inferiority level,
There is no σJ, and the 1g condylarity is l'L? ] <
, Heat resistant VC crushed ceramic heater? Serve and swallow.

依ってQr N)の目的f4成し倚る。Therefore, the purpose f4 of Qr N) is achieved.

Claims (1)

【特許請求の範囲】[Claims] コーディエライトのセラミックス内に合雀を埋設して抵
抗つれ熱体を形IJ5Cシたセラミックヒータ−におい
て、上記抵抗発熱体は白戴、パラジウム、金、鎖中の2
つ以上を台上せしめた廿雀の内、白金とパラジウムとの
行金−・1…類をばく貢金桶糸合金にて形成し一〇なり
、十ijL抵抗兄熱体の含M釜属の合金比率ケ変化させ
ることによ!ll咀気抵抗の温度係数を制帥せしめてな
るセラミックヒータ−0
In the ceramic heater, which has a resistive heating element in the form of IJ5C by embedding it in cordierite ceramics, the resistive heating element is white, palladium, gold, and chain.
Of the three or more sparrows that have been mounted, there are 10 and 10 metal pots made of a metal thread alloy made of platinum and palladium, and a metal pot with a 10-IJL resistance heating element. By changing the alloy ratio! llCeramic heater that controls the temperature coefficient of mastication resistance-0
JP13594282A 1982-08-03 1982-08-03 Ceramic heater Pending JPS5925189A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13594282A JPS5925189A (en) 1982-08-03 1982-08-03 Ceramic heater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13594282A JPS5925189A (en) 1982-08-03 1982-08-03 Ceramic heater

Publications (1)

Publication Number Publication Date
JPS5925189A true JPS5925189A (en) 1984-02-09

Family

ID=15163443

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13594282A Pending JPS5925189A (en) 1982-08-03 1982-08-03 Ceramic heater

Country Status (1)

Country Link
JP (1) JPS5925189A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04215285A (en) * 1991-03-07 1992-08-06 Toshiba Lighting & Technol Corp Heater

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5533741A (en) * 1978-08-31 1980-03-10 Murata Manufacturing Co Method of manufacturing heater

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5533741A (en) * 1978-08-31 1980-03-10 Murata Manufacturing Co Method of manufacturing heater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04215285A (en) * 1991-03-07 1992-08-06 Toshiba Lighting & Technol Corp Heater

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