JPS59203253A - Optical disc and its production - Google Patents

Optical disc and its production

Info

Publication number
JPS59203253A
JPS59203253A JP58078494A JP7849483A JPS59203253A JP S59203253 A JPS59203253 A JP S59203253A JP 58078494 A JP58078494 A JP 58078494A JP 7849483 A JP7849483 A JP 7849483A JP S59203253 A JPS59203253 A JP S59203253A
Authority
JP
Japan
Prior art keywords
optical
recording medium
resin
optical disc
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58078494A
Other languages
Japanese (ja)
Inventor
Toru Tamura
徹 田村
Kensuke Kuchiba
口羽 健介
Masaaki Haruhara
正明 春原
Akitake Ito
伊藤 彰勇
Shunsuke Matsuda
俊介 松田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP58078494A priority Critical patent/JPS59203253A/en
Priority to DE3416607A priority patent/DE3416607C2/en
Priority to US06/606,461 priority patent/US4583102A/en
Priority to GB08411509A priority patent/GB2142767B/en
Publication of JPS59203253A publication Critical patent/JPS59203253A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor

Abstract

PURPOSE:To prevent the loss of information due to defects by laminating a grooved resin substrate, an optical recording medium layer covering the groove surface, a photo-setting adhesive which covers the optical recording medium layer, and a light-transmissive resin layer covering this adhesive in order from the side opposite to the irradiation direction of an optical signal. CONSTITUTION:A recording medium 7 such as a Te oxide or the like is vapor- deposited onto the gooved surface of a substrate 8 of a grooved resin disc, and a photo-setting adhesive 6 is applied uniformly onto this medium 7, and a transparent protecting resin plate 5 is put on this adhesive 6, and ultraviolet rays are irradiated, thus forming an optical disc. When a recording and reproducing laser light emitted from a laser 9 is irradiated through a condenser lens 14, the laser light is condensed through the resin plate 5 and the adhesive layer 6 successively to become spot light having about 1mum and reaches the surface of the recording medium 7. In this case, since the diameter of the projected laser light is large, recording and reproducing of information are not damaged by foreign matters, which are stuck onto the resin plate 5 and have above 100mum size, and foreign matters having <=10mum size in the resin plate 5.

Description

【発明の詳細な説明】 産業上の利用分野 本発明にビデオ、オーディオ、データー信号な全光変調
し、元レーザービームにより記録再生る光ディスクおよ
びその製造方法に関するものある。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to an optical disc in which video, audio, and data signals are all-optically modulated and recorded and reproduced using a laser beam, and a method for manufacturing the same.

従来例の構成とその問題点 従来の光ディスクの構成と記録再生を第1図をハて説明
する。寸ず光ディスクの構成は圧縮成又は射出成形によ
り厚い溝付きのディスク基体を成形し、このディスク基
体1の表面にレーザ方法で密着させたものであり、この
記録媒体2としては一般にはビスマス、モリブデン、テ
ルリウム、コバルト、ニッケル、ヒ素、亜鉛、スズなど
が用いられる。さらにこの記録媒体2上に接着剤層3を
設は透明な樹脂板4を貼り合わせて記録媒体面金保護し
た構造の光ディスクが構成されている。
Conventional Structure and Problems The structure and recording/reproduction of a conventional optical disk will be explained with reference to FIG. The structure of the Sunzu optical disk is that a disk base with thick grooves is molded by compression molding or injection molding, and is adhered to the surface of the disk base 1 using a laser method.The recording medium 2 is generally made of bismuth or molybdenum. , tellurium, cobalt, nickel, arsenic, zinc, tin, etc. Further, an adhesive layer 3 is provided on the recording medium 2, and a transparent resin plate 4 is bonded to the recording medium 2 to protect the surface of the recording medium, thereby constructing an optical disk.

この元ディスクの記録再生は、ディスク基体1の1(↓
11からレーザー光12を、レンズ14により収束して
行っている。なお、レーザ光12ば、レーザー9より発
生し、光学系10全介してレンズ14に入る。記録媒体
2に達した光は一部反射し、同じ光路を径で光検知器1
1に到り、電気信号に変換されて電気信号13として出
力される。この場合ディスク基体10表面に付着した異
物に対しては、レーザービーム光の断面積がまだ十分に
収束されていないので異物によりレーザー光がさえぎら
れる割合は小さい。しかし記録媒体2の近傍に達したレ
ーザー光は1μm前後のスポットに絞り込でれているの
で記録媒体2の近傍に存在する異物は1μ772前後で
あってく)レーザー光12をさえぎる割合が大さく記録
再生情報に欠損を生じる。
Recording and playback of this original disc is performed in 1 of disc base 1 (↓
A laser beam 12 from 11 is converged by a lens 14. Note that the laser beam 12 is generated from the laser 9 and enters the lens 14 through the entire optical system 10. Part of the light that reaches the recording medium 2 is reflected, and the same optical path is passed through the photodetector 1 with the same diameter.
1, is converted into an electrical signal, and is output as an electrical signal 13. In this case, since the cross-sectional area of the laser beam light has not yet been sufficiently converged with respect to the foreign matter adhering to the surface of the disk base 10, the percentage of the laser light being blocked by the foreign matter is small. However, since the laser beam that reaches the vicinity of the recording medium 2 is narrowed down to a spot of around 1 μm, the foreign matter present near the recording medium 2 has a diameter of around 1 μm (772 μm). A loss occurs in the playback information.

従って、この構造の光ディスクでは、ディスク基体1に
用いる樹脂材料中の異物が小ないことやディスク基体1
の全面にわたって光学的に均質なことが要求され、この
用途に適した材料の選択や成形方法はきわめて難しかっ
た。実際にこの構成で小さなエラー率が要求される文書
ファイル、データーファイル光ディスクを実現するのは
困難であった。
Therefore, in the optical disc having this structure, there are no small foreign substances in the resin material used for the disc base 1, and the disc base 1
Optical homogeneity is required over the entire surface, and it has been extremely difficult to select materials and molding methods suitable for this purpose. In reality, it is difficult to realize an optical disc for document files and data files that requires a small error rate with this configuration.

発明の目的 本発明は上記の従来の元ディスクの問題全解決するもの
であり、溝付きのディスク基体中に多数の異物が存在し
ていたり、少々成形がう1ぐ行かずに光学的に不均質で
あっても情報の欠損が生じない光ディスクを提供するこ
とを目的としている。
Purpose of the Invention The present invention solves all of the above-mentioned problems with the conventional original disc, such as the presence of a large number of foreign substances in the grooved disc base, or the fact that the molding does not proceed smoothly and optical defects occur. The object of the present invention is to provide an optical disc that is homogeneous but does not suffer from loss of information.

発明の構成 本発明の光ディスクは、光信号の照射方向と反対側から
、溝付きの樹脂基板と、少く共前記溝の表面を覆う光記
録媒体層と、前記光記録媒体層を覆う光硬化性接着剤と
、前記光硬化性接着剤を覆う透光性樹脂層と全順次配列
する構成である。
Structure of the Invention The optical disc of the present invention includes, from the side opposite to the irradiation direction of an optical signal, a resin substrate with grooves, an optical recording medium layer that covers at least the surface of the groove, and a photocurable layer that covers the optical recording medium layer. The adhesive and the light-transmitting resin layer covering the photocurable adhesive are arranged in sequence.

本発明の光ディスクの製造方法は、射出成形又は圧縮成
形により溝付きの樹脂製光デイスク基板を成形する工程
と、この基板上に光で記録再生可能な記録媒体を密着さ
せる工程と、この記録再生媒体上に透明な光硬化性接着
剤を塗布する工程と、この接着剤上から透明な保護樹脂
板を重ねて紫外線を照射して前記保護樹脂板金接着する
工程とよりなるものである。
The method for manufacturing an optical disk of the present invention includes a step of molding a grooved resin optical disk substrate by injection molding or compression molding, a step of bringing a recording medium that can be recorded and played back with light into close contact with this substrate, and a step of making the recording and playback process possible. This method consists of a step of applying a transparent photocurable adhesive onto the medium, and a step of overlaying a transparent protective resin plate over the adhesive and irradiating it with ultraviolet rays to bond the protective resin sheet metal.

実施例の説明 以下本発明の実施例を図面を参照にしながら説明する。Description of examples Embodiments of the present invention will be described below with reference to the drawings.

実施例1 第2図は本発明の光ディスクを示す断面図である。8は
圧縮又は射出成形により得た溝付きの樹脂製ディスク基
板であり、その溝付き面に酸化テルリウム系の記録媒体
7を蒸着などにより密着させる。その後記録媒体の表面
に透明で粗さ0.2μmのフィルターを通して濾過精製
した光硬化性接着剤6を50〜20011mの均一な厚
みで塗布し、この上から透明な保護樹脂板5を重ねて紫
外線を照射して接着?して元ディスクを作成する。
Embodiment 1 FIG. 2 is a sectional view showing an optical disc of the present invention. 8 is a grooved resin disk substrate obtained by compression or injection molding, and a tellurium oxide recording medium 7 is adhered to the grooved surface by vapor deposition or the like. Thereafter, a photocurable adhesive 6 filtered and refined through a transparent filter with a roughness of 0.2 μm is applied to the surface of the recording medium to a uniform thickness of 50 to 20,011 m, and a transparent protective resin plate 5 is overlaid on top of the photocurable adhesive 6, which is exposed to ultraviolet light. Irradiated and glued? to create the original disc.

第3図は前記本発明の実施例の光ティスフの再生法金示
す概念図である。レーザー9より発したレーザーfは光
学系iof!:通って集光レンズ14で集光され、集光
されたレーザー光は矢印12の様に焦収束されながら保
護樹脂板5から元硬化件接着剤層6を径で、記録媒体7
の表面に到達して一部反射し同じ光路を径で光検知器1
1に到り電気信号に変換されて電気信号13として出力
される。実際にこの様な方法で作成した光デイスク全上
述の方法で記録再生した結果アクリル樹脂を保護板とし
て用いたときにエラー率(t−48X 10  であり
、−!だポリカーボネート樹脂を保護板としたときには
3×10 であった。
FIG. 3 is a conceptual diagram showing a method for regenerating optical tissue according to the embodiment of the present invention. The laser f emitted from the laser 9 is the optical system iof! : The focused laser beam passes through the condensing lens 14 and is focused as shown by the arrow 12 while passing from the protective resin plate 5 to the original hardened adhesive layer 6 in a diameter direction to the recording medium 7.
It reaches the surface of the photodetector 1 and is partially reflected, and the same optical path is passed through the photodetector 1.
1 and is converted into an electrical signal and output as an electrical signal 13. In fact, all optical discs made using this method were recorded and reproduced using the method described above. When acrylic resin was used as a protective plate, the error rate was (t-48×10, -!) when polycarbonate resin was used as a protective plate. Sometimes it was 3x10.

このように、エラー率が低下したの(は、次の理由によ
る。記録再生用のレーザー光VJ、透明な保護樹脂板5
から光硬化性樹脂接着層6を径で順次絞り込葦れながら
最終的には1μm前後のスポット光となり記録媒体70
面上に到達するわけである。
In this way, the error rate has decreased due to the following reasons: laser beam VJ for recording and reproduction, transparent protective resin plate 5
As the photocurable resin adhesive layer 6 is sequentially narrowed down by diameter, it finally becomes a spot light of around 1 μm on the recording medium 70.
It reaches the surface.

この場合レンズの開口数にもよるが開口数05程度のレ
ンズでは、外側の保護樹脂板6上に付着した100μ?
n前後の異物や樹脂中に存在する1Q11227迄の太
ささの異物は、レーザー光の直径が大きいのでレーザー
光がさえぎられる割合が少なく、情報の記録再生に欠損
を生じることは殆んどない。
In this case, it depends on the numerical aperture of the lens, but for a lens with a numerical aperture of about 05, the amount of 100 μ?
Since the diameter of the laser beam is large, the laser beam is blocked by a foreign particle with a diameter of around 1Q11227 or a foreign particle with a diameter of up to 1Q11227 present in the resin, so that there is almost no loss in the recording and reproduction of information.

しかしレーザービーム光が絞ジ込壕れる光硬化性接着剤
層6では数1t772の太ささの異物でも情報の記録再
生の欠損に太さな影響を力える。従って、本実施例の光
ディスクの場合は記録媒体7上に絞り込寸れるレーザ光
のスポット径1μm以上の異物を全く含有しないように
液状の光硬化性接着剤は使用直前に0.2μmの粗さの
フィルターで濾過精製して使用した。このようにして作
成した光ディスクの記録再生時のエラー率は従来の方法
で作成したものに比べて約2桁エラー率が低下した。
However, in the photocurable adhesive layer 6 where the laser beam is focused, even a foreign particle with a thickness of several 1t772 can have a considerable influence on the loss of information recording and reproduction. Therefore, in the case of the optical disc of this embodiment, the liquid photocurable adhesive is applied to the recording medium 7 with a roughness of 0.2 μm immediately before use so as to contain no foreign matter with a laser beam spot diameter of 1 μm or more. It was purified by filtration and used. The error rate during recording and reproduction of the optical disc created in this manner was reduced by about two orders of magnitude compared to that of the optical disc created using the conventional method.

すなわち、本実施例の光ディスクは、異物の存在全極め
て少なくすべき記録媒体7の近傍の部分に、異物の含有
を防止できる光硬化性樹脂接着層6を形成した点に特徴
がある。
That is, the optical disc of this embodiment is characterized in that a photocurable resin adhesive layer 6 that can prevent the inclusion of foreign matter is formed in the vicinity of the recording medium 7 where the presence of foreign matter should be extremely reduced.

なお、光硬化性接着剤7の厚みが50μ以下ではエラー
率が1桁以上悪くなり、文通に200μ以上では実際に
接着剤層6を均一な厚さに保って保護樹脂板5と貼り合
せることが難しく、レーザ光の光路長が光ディスクの各
部分で異る様になるので光硬化性接着剤7の厚さくは6
0〜200μ?nつ範囲が最適である。
Note that if the thickness of the photocurable adhesive 7 is less than 50 μm, the error rate will be worse by one order of magnitude or more, and if it is more than 200 μm, it is actually difficult to maintain the adhesive layer 6 at a uniform thickness and bond it to the protective resin plate 5. The thickness of the photo-curing adhesive 7 is 6.5 mm because the optical path length of the laser beam is different for each part of the optical disk.
0~200μ? A range of n is optimal.

比較例 実施例1の光ディスクの特性と比較するために本比較例
での実験結果を述べる。第1図の従来法による元ディス
クを作成した場合、すなわち透明なポリカーボネート樹
脂、アクリル樹脂などで溝付きの光デイスク基体1を成
形し、その表面に実施f111と同じ条件手法で酸化テ
ルリウム系記録媒体7′ff:密着させ、実施例1と同
様の光硬化性接着剤6で透明な保護板8を貼ジ合せて光
ディスクを作成し、第3図に示した方法で記録再生を行
なった。その結果、ポリカーボネート樹脂基板の場合ハ
、エラー率がax1o’、アクリル樹脂の場合はエラー
率が3×10 であった。参考迄に、ここで使用したポ
リカーボネート樹脂1グラム中には0.21N77以上
の太ささの異物が5万個、1だ、アクリル樹脂中には3
,8万個観察された。
Comparative Example In order to compare the characteristics of the optical disc of Example 1, the experimental results of this comparative example will be described. When the original disk is created by the conventional method shown in Fig. 1, that is, a grooved optical disk base 1 is molded from transparent polycarbonate resin, acrylic resin, etc., and a tellurium oxide recording medium is formed on its surface under the same conditions as in f111. 7'ff: A transparent protective plate 8 was bonded with the same photocurable adhesive 6 as in Example 1 to prepare an optical disc, and recording and reproduction were performed by the method shown in FIG. As a result, the error rate was ax1o' in the case of the polycarbonate resin substrate, and 3×10 2 in the case of the acrylic resin substrate. For reference, there are 50,000 foreign particles with a diameter of 0.21N77 or larger in 1 gram of the polycarbonate resin used here, 1, and 3 in the acrylic resin.
, 80,000 were observed.

実施例2 本発明の構成の元ディスクおよびその製造方法は、片面
溝付き光ディスクに限るものではなく両面溝付きの光デ
ィスクについても適用することが可能である。第4図に
両面溝付きの光ディスクの実姉例を示す。同図において
8は圧縮または射出成形により得た両面溝付きの樹脂製
ディスク基板であり、その溝表面に酸化テルリウム系の
記録媒  4体了&+7t)k蒸着々どの手法で両面に
密着させる。その後記録媒体の表面に透明で粗さ0.2
μ277のフィルターを通して精製した光硬化性接着剤
7?L、Tbを50〜200μmの均一な厚みで同じく
両面に塗布し、この上から透明な保護樹脂板6a、6b
f、yそれぞれ重ねて紫外線全照射して両面記録再生が
可能な光ディスクを得た。なお、この光ディスクの記録
再生については実施例1と全1 。
Embodiment 2 The original disk having the structure of the present invention and its manufacturing method are not limited to an optical disk with grooves on one side, but can also be applied to an optical disk with grooves on both sides. FIG. 4 shows an actual example of an optical disc with grooves on both sides. In the figure, reference numeral 8 denotes a resin disk substrate with grooves on both sides obtained by compression or injection molding, and a tellurium oxide recording medium is adhered to both sides of the groove surface by any method such as vapor deposition. After that, the surface of the recording medium is transparent and has a roughness of 0.2.
Photocurable adhesive 7 purified through μ277 filter? L and Tb are applied to both sides with a uniform thickness of 50 to 200 μm, and transparent protective resin plates 6a and 6b are applied on top of this.
An optical disk capable of double-sided recording and reproduction was obtained by superimposing each of f and y and irradiating the entire surface with ultraviolet rays. Regarding recording and reproduction of this optical disc, Example 1 and All 1 are described.

く同様の方法により行なった。The same method was used.

発明の効果 以上の説明から明らかな様に、従来−の光ディスクはそ
の構成上、情報の記録再生時に樹脂中に存在する異物の
影響を受は易く、エラー率はかなり高かった。しかし本
発明の光ディスクおよびその製造方法によりエラー率は
従来の光ディスクに比べて約2桁改善さ扛、エラー率’
18X10〜3×165に達成することが可能となり、
光ディスクを小型化、大容量 信頼性を高める上できわ
めて有効である。
Effects of the Invention As is clear from the above explanation, due to its structure, conventional optical discs are susceptible to the influence of foreign matter present in the resin when recording and reproducing information, resulting in a fairly high error rate. However, with the optical disc and its manufacturing method of the present invention, the error rate has been improved by about two orders of magnitude compared to conventional optical discs.
It is now possible to achieve 18x10 to 3x165,
It is extremely effective in making optical discs smaller and increasing their capacity and reliability.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来の光ディスクの構成とそれを用いた記録再
生方法を示す図、第2図は本発明の一実施例の元ディス
クの断面図、第3図は同党ディスクの記録再生法を示す
図、第4図は本発明の他の実施例の光ディスクの断面図
である。 5、 52L、  5 b−=−保護樹脂板、6.6a
、 6b・・・・・・光硬化性接着剤層、7.7a、7
b・・・・・記録媒体、8・・・・・・保護板。
Fig. 1 is a diagram showing the structure of a conventional optical disc and a recording/reproducing method using it, Fig. 2 is a sectional view of an original disc according to an embodiment of the present invention, and Fig. 3 is a diagram showing a recording/reproducing method of the optical disc. The figure shown in FIG. 4 is a sectional view of an optical disk according to another embodiment of the present invention. 5, 52L, 5 b-=-protective resin plate, 6.6a
, 6b...photocurable adhesive layer, 7.7a, 7
b...Recording medium, 8...Protection plate.

Claims (1)

【特許請求の範囲】 (1)光信号の照射方向と反対側から、溝付きの樹脂基
板と、少なく共前記溝の表面を覆う光記録   (6)
媒体層と、前記光記録媒体層を覆う光硬化性接着剤と、
前記光硬化性接着剤を覆う透光性樹脂層とを順次配列し
てなる光ディスク。      3、(2)光硬化性接
着剤は、その中に0.2μm以上の異物を含せない接着
剤である特許請求の範囲第1項記載の光ディスク。  
            ど(3)光硬化性接着剤層の
厚みが50〜200μn2    すの均一な厚みであ
る特許請求の範囲第1項記載   での光ディスク。 (4)射出成形又は圧縮成形により溝付きの樹脂製光デ
イスク基板を成形する工程と、前記基板上   用1な
保護樹脂板を重ねて紫外線を照射して接着する工程とよ
りなる光ディスクの製造方法。 光硬化性接着剤として0.2μm以上の異物を含まない
様に沖過精製したものを使用する特許請求の範囲第4項
記載の光ディスクの製造方法。 光硬化性接着剤の塗布の厚さが50〜200μノ22で
ある特許請求の範囲第4項記載の光ディスクの製造方法
[Claims] (1) Optical recording that covers at least the surface of a grooved resin substrate and the grooves from the side opposite to the irradiation direction of the optical signal (6)
a medium layer; a photocurable adhesive covering the optical recording medium layer;
An optical disc comprising a light-transmitting resin layer covering the photocurable adhesive and sequentially arranging the light-transmitting resin layer. 3. (2) The optical disc according to claim 1, wherein the photocurable adhesive does not contain foreign matter of 0.2 μm or more.
(3) The optical disc according to claim 1, wherein the photocurable adhesive layer has a uniform thickness of 50 to 200 μn2. (4) A method for manufacturing an optical disc, which comprises the steps of molding a grooved resin optical disc substrate by injection molding or compression molding, and stacking a protective resin plate on the substrate and bonding it by irradiating it with ultraviolet rays. . 5. The method of manufacturing an optical disk according to claim 4, wherein a photocurable adhesive that has been purified so as not to contain foreign matter of 0.2 μm or more is used. 5. The method of manufacturing an optical disk according to claim 4, wherein the thickness of the photocurable adhesive is 50 to 200 μm.
JP58078494A 1983-05-04 1983-05-04 Optical disc and its production Pending JPS59203253A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP58078494A JPS59203253A (en) 1983-05-04 1983-05-04 Optical disc and its production
DE3416607A DE3416607C2 (en) 1983-05-04 1984-05-03 Optical disk and method of making the same
US06/606,461 US4583102A (en) 1983-05-04 1984-05-03 Optical disc and method of manufacturing
GB08411509A GB2142767B (en) 1983-05-04 1984-05-04 Optical disc and method of manufacturing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58078494A JPS59203253A (en) 1983-05-04 1983-05-04 Optical disc and its production

Publications (1)

Publication Number Publication Date
JPS59203253A true JPS59203253A (en) 1984-11-17

Family

ID=13663520

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58078494A Pending JPS59203253A (en) 1983-05-04 1983-05-04 Optical disc and its production

Country Status (1)

Country Link
JP (1) JPS59203253A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02214038A (en) * 1989-02-14 1990-08-27 Pioneer Electron Corp Optical information recording carrier

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5489704A (en) * 1977-12-12 1979-07-17 Philips Nv Disk recording medium with coating layer
JPS5968849A (en) * 1982-10-12 1984-04-18 Toshiba Corp Information storage medium

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5489704A (en) * 1977-12-12 1979-07-17 Philips Nv Disk recording medium with coating layer
JPS5968849A (en) * 1982-10-12 1984-04-18 Toshiba Corp Information storage medium

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02214038A (en) * 1989-02-14 1990-08-27 Pioneer Electron Corp Optical information recording carrier

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