JPS59186354A - Metal member for lead frame - Google Patents

Metal member for lead frame

Info

Publication number
JPS59186354A
JPS59186354A JP6117783A JP6117783A JPS59186354A JP S59186354 A JPS59186354 A JP S59186354A JP 6117783 A JP6117783 A JP 6117783A JP 6117783 A JP6117783 A JP 6117783A JP S59186354 A JPS59186354 A JP S59186354A
Authority
JP
Japan
Prior art keywords
metal member
lead frame
thin film
bonding
carbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6117783A
Other languages
Japanese (ja)
Other versions
JPH0770661B2 (en
Inventor
Shoji Shiga
志賀 章二
Akira Matsuda
晃 松田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Furukawa Electric Co Ltd
Original Assignee
Furukawa Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Furukawa Electric Co Ltd filed Critical Furukawa Electric Co Ltd
Priority to JP58061177A priority Critical patent/JPH0770661B2/en
Publication of JPS59186354A publication Critical patent/JPS59186354A/en
Publication of JPH0770661B2 publication Critical patent/JPH0770661B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/48Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the subgroups H01L21/06 - H01L21/326
    • H01L21/4814Conductive parts
    • H01L21/4821Flat leads, e.g. lead frames with or without insulating supports
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Lead Frames For Integrated Circuits (AREA)

Abstract

PURPOSE:To realize good direct bonding by providing a thin film consisting of fatty acid hydrogen compound having the number of carbons more than the specified one at the surface of metal member for lead frame of an integrated circuit, etc. CONSTITUTION:A metal member for lead frame having the clean surface is processed by the fatty acid hydrogen compound having the 10 or more carbons, for example, a fluid, solid or crystalline paraffin or vaseline. While a metal member is dipped into the solution having the concentration of 0.00001-1.0% obtained by dissolving these compounds into an organic solvent of low melting point, for example, into benzin, trichloroethane, tetrachloroethylene or various kinds of Freons or such solution is sprayed to said metal member surface, the solvent is dried up and thereby the thin film can be formed on the surface.

Description

【発明の詳細な説明】 本発明は半導体特に集積回路の実装に使用されるリード
フレーム用又はその中間体用の金属部材に関するもので
あり、特にダイレクトポンディングに好適な金属部材を
得んとするものである〇 従来トランジスターなどの半導体素子、特に集Mt回路
即チ、IC,I、SI、VLSI(以下、ICと称す)
はり一ドフレームと称される金属基体上にマウントして
外部回路との導通がなされる。例えば第1図に示す如く
金属板条がら打ち抜かれるものであり、1はICチップ
のマウント部、2はボンディング部、3は外部端子部で
ある。通常少なくとも上記1及び2の部分にAu 、 
Agなどのメッキを施しICチップをろう付けすると共
にAu  細線を用いてチップ上の回路端子とボンディ
ング部とを超音波溶接などの手法で接続しているもので
ある。又リードフレームは高価なNi −Fe  合金
、 Ni −Co −Fe  合金が使用されるが、集
積度の向上と共に伝熱性が強く要求されるため、これら
の合金に代え七安価なCu −Sn 、 Cu −Ni
 −Sn 系などのCu 合金が殆んど使用さnる傾向
にある。更にコストを低下せしめるために前記Au 、
 Agメッキを省略して直接ブーツブを実装することが
強く望まれているO ICブーツブのろう付けはポリイミドやエポキシなどの
導電性接着剤を用いて行うことが出来るが、前記のボン
ディングは現行の貴金属」二への溶接に対し、卑金属へ
の接合が大きな問題となっている。即ち金属特に前記の
Cu  やCu  合金では酸化被膜を発生し易く、ボ
ンディングの大きな障害となっている。リードフレーム
は通常素材となる板条体をプレスにて打板も成型してか
ら実装工程に供給される。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a metal member for a lead frame used for mounting semiconductors, particularly integrated circuits, or an intermediate thereof, and is particularly directed to a metal member suitable for direct bonding. 〇 Conventional semiconductor devices such as transistors, especially integrated Mt circuits, IC, I, SI, VLSI (hereinafter referred to as IC)
It is mounted on a metal base called a beam frame and electrically connected to an external circuit. For example, as shown in FIG. 1, a metal plate strip is punched out, and 1 is an IC chip mounting part, 2 is a bonding part, and 3 is an external terminal part. Usually, at least parts 1 and 2 above contain Au,
The IC chip is plated with Ag or the like and brazed, and the circuit terminals on the chip and the bonding parts are connected using techniques such as ultrasonic welding using thin Au wires. In addition, expensive Ni-Fe alloys and Ni-Co-Fe alloys are used for lead frames, but as the degree of integration increases and heat conductivity is strongly required, these alloys are replaced with inexpensive Cu-Sn and Cu alloys. -Ni
-Cu alloys such as Sn-based alloys tend to be mostly used. In order to further reduce the cost, the Au,
It is strongly desired to omit Ag plating and directly mount the boot tab. Brazing of the IC boot tab can be done using a conductive adhesive such as polyimide or epoxy, but the above bonding is performed using current precious metals. Welding to base metals is a major problem compared to welding to base metals. That is, metals, especially the above-mentioned Cu and Cu alloys, tend to form an oxide film, which is a major hindrance to bonding. Lead frames are usually made by forming a strip of material using a press into a stamped plate and then supplying it to the mounting process.

本発明者等は前記のメッキを省略するダイレクトボンデ
ィングの欠陥原因が各種の工程条件に係り、実装置前の
リードフレーム表面が清浄に安定して保持されなければ
ならないことについて、リードフレームの処理について
鋭意研究を行った結果本発明に至ったものである。特に
本発明者等は前記素材がプレス工程又はプレス製品が実
装工程に供される際に実際上多くの場合不可避的にスト
ックされたり、又は71ンドリング時に外気などにより
汚染酸化されることがその主因であることを究明し、実
装の際の表面清沙な状態にあるリードフレーム用金属部
材を得たもので、表面に炭素数10以上の脂肪族炭化水
素化合物からなる薄膜を設けたことを特僧とするリード
フレーム用金属部材である。
The inventors of the present invention have explained that the causes of defects in direct bonding that omit plating are related to various process conditions, and that the surface of the lead frame before the actual device must be kept clean and stable. The present invention was achieved as a result of intensive research. In particular, the present inventors believe that the main reason for this is that the material is unavoidably stocked in many cases during the pressing process or when the pressed product is subjected to the mounting process, or is contaminated and oxidized by outside air during 71-ndling. We have obtained a metal member for a lead frame that has a clean surface during mounting, and is unique in that it has a thin film made of an aliphatic hydrocarbon compound with a carbon number of 10 or more on the surface. This is a metal member for lead frames.

本発明においてリードフレーム用金属部材とは、前記ブ
レヌ品のほかプレス前の金属素材をも含むものである。
In the present invention, the metal member for a lead frame includes not only the Brene product described above but also a metal material before pressing.

本発明において脂肪族炭化水素化合物とは直鎖状又は分
岐状或は環状の飽和炭化水素化合物であり、常温におい
て単体としては高粘流体或は固体状である。通常単一化
合物としてエリは分子1の異なる化合物の混合体として
入手される。例えば流動、固形酸は結晶性のノくラフイ
ン。
In the present invention, the aliphatic hydrocarbon compound is a linear, branched, or cyclic saturated hydrocarbon compound, and as a single substance, it is a highly viscous fluid or solid at room temperature. Eri is usually obtained as a single compound or as a mixture of different compounds in the molecule. For example, liquid and solid acids are crystalline rough-in.

ワセリンなどであり、天然鉱油やこれを用いた市販潤滑
油は上記化合物より低分子であり且つ吸着性物質を含有
するため使用し得ないものである。
Natural mineral oils and commercially available lubricating oils using these oils cannot be used because they have lower molecular weight than the above-mentioned compounds and contain adsorbent substances.

これらの化合物を低沸点の有機溶剤例えばベンジン、ト
リクロロエタン、テトラクロロエチレン、各種フレオン
類に溶解した濃度0.001〜1.0%の溶液中に上記
の金属部材を浸漬、又は該溶液を金属部材表面にスプレ
ーしたりして一様に耐着せしめ溶媒を乾燥することによ
り部材表面に薄膜を形成することができる。
The metal member is immersed in a solution of 0.001 to 1.0% concentration of these compounds dissolved in a low-boiling organic solvent such as benzene, trichloroethane, tetrachloroethylene, or various freons, or the solution is applied to the surface of the metal member. A thin film can be formed on the surface of the member by spraying or drying the solvent to make it uniformly resistant to adhesion.

このような処理は圧延やプレス加工油の脱脂工程に通常
同種の溶剤を用いるので、この脱脂工程に後続して実施
するのが便宜である。
Since such a treatment usually uses the same type of solvent as the degreasing process for rolling or pressing oil, it is convenient to carry out this process subsequent to the degreasing process.

なお膜厚は通常1μ以下であり、01〜0005μのも
のが有効如使用される。
The film thickness is usually 1 μm or less, and those with a thickness of 01 to 0005 μm are effectively used.

これらの化合物は銅合金などの金属表面に表面張力の作
中で展開して連続した撥水上の低表面エネルギー被膜を
形成し且つ大気中の酸素を遮断するため、大気汚染或は
表面酸化を防止することが出来る。更に該化合物は有機
溶剤に易溶であり、非吸着性であるため容易に洗浄除去
し且つ清浄な表面に回復することか出来る。即ち実装工
程の第1工程として通常の蒸気洗浄などにエリ十分に除
去しうるのでダイレクトボンデングを可能にする。
These compounds develop on the surface of metals such as copper alloys under the action of surface tension, forming a continuous, water-repellent, low surface energy film and blocking oxygen in the atmosphere, thus preventing air pollution and surface oxidation. You can. Furthermore, since the compound is easily soluble in organic solvents and non-adsorbent, it can be easily removed by washing and the surface can be restored to a clean state. That is, as the first step of the mounting process, the surface area can be sufficiently removed by ordinary steam cleaning, thereby making direct bonding possible.

このように本発明における脂肪族炭化水素化合物薄膜は
上記の如き優れた効果を発揮するものであり、従来金属
特にCu  又はCu  合金の表面保護に広く使用さ
れる高級脂肪族アミン又はベンゾトリアゾールの如き吸
着性或は化学結合性の物質(従来物質)に比べて格段の
差異を生ずるものである。即ち従来物質にエリ被膜を設
けた場合には洗浄除去が極めて困難であり、アルカリ電
解洗浄や更に酸エツチングを必要とするものである。な
おこのことは本発明者が[実務表面技術J1981年3
月号P123や「伸銅技術研究会誌J 1982.Vo
t21.P64  に発表しているものである。
As described above, the aliphatic hydrocarbon compound thin film of the present invention exhibits the above-mentioned excellent effects, and is similar to higher aliphatic amines or benzotriazole, which are conventionally widely used for surface protection of metals, especially Cu or Cu alloys. This produces a significant difference compared to adsorbent or chemically binding substances (conventional substances). That is, when an edge coating is provided on a conventional material, it is extremely difficult to wash and remove it, requiring alkaline electrolytic cleaning or further acid etching. This matter has been confirmed by the present inventor in [Practical Surface Technology J, 1981, 3].
Monthly issue P123 and “Copper Rolling Technology Research Society Journal J 1982.Vo
t21. This is what was announced on page 64.

従って従来の如き保護被膜に設けた場合にはダイレクト
ボンデングの効力を著しく阻害するものであり、本発明
はボンディングなどのIC実装に最適の表面処理を実現
したものである。
Therefore, if it is provided on a conventional protective film, it will significantly inhibit the effectiveness of direct bonding, and the present invention realizes a surface treatment that is optimal for IC mounting such as bonding.

次に本発明の実施例について説明する。Next, examples of the present invention will be described.

実施例(1) Cu−0,158n−0,0I P合金クーポンについ
て第1表に示す5種類の表面処理を行った後、室内に1
ケ月放置し、次いでフレオン113 の中に浸漬し30
秒間超音波洗浄を行い、乾燥したクーポンを、プレート
温度160℃、ボンディング力45 gr  の超音波
ボンダーにて25μφA、u線を熔接した。この熔接し
たクーポン50本について引張試験を行った。その結果
は第2表に示す通りである。
Example (1) After performing the five types of surface treatments shown in Table 1 on a Cu-0,158n-0,0IP alloy coupon, one
Leave it for a few months, then soak it in Freon 113 for 30 minutes.
Ultrasonic cleaning was performed for seconds, and the dried coupons were welded with a 25 μφA, U-wire using an ultrasonic bonder with a plate temperature of 160° C. and a bonding force of 45 gr. A tensile test was conducted on 50 of these welded coupons. The results are shown in Table 2.

第1表 第  2  表 上表より明らかす如く本発明に、r、!シばボンディン
グ強度は比較例品に比べて著しく侵れでおり、この値は
従来のAu  を1.2μメツキした表面へのボンディ
ング強度12.3 gr (o =03 )と遊色ない
ものであった。
As is clear from the above table of Table 1, Table 2, the present invention has r,! The wrinkle bonding strength was significantly lower than that of the comparative example, and this value was 12.3 gr (o = 03), which was the same as the bonding strength to the conventional 1.2 μm Au plated surface, with no play of color. Ta.

又、上記の本発明品及び比較例品について表面の汚染酸
化防止と洗浄性との性能を試みるためにカソード還元法
による表面還元電気量を測定した。その結果は第3表に
示す通りである。
Furthermore, in order to test the surface contamination oxidation prevention and cleanability of the above-mentioned products of the present invention and comparative products, the amount of surface reduction electricity was measured by a cathodic reduction method. The results are shown in Table 3.

第 3 表 なお、」二記1・1リ一ドフレーム品に適用した場合を
示したがこれに限らず素材となる板条体を処理しても有
効Cある。又、上記において1:rメッキを省略したが
Au 、 Ag或はSn 、 Niなどをメッキする場
合についても有効である。更に貸金、Fiを節約するた
めにメッキ層を強くするとメッキ層が多孔質となり、銅
などの素地の酸化が起り易くなるが、かかる場合におい
ても本発明部材は有効に素地の酸化を防止する。
Although Table 3 shows the case in which the method is applied to lead frame products in 1.1 of 2.2, it is also effective to treat plate strips that serve as raw materials. Further, although 1:r plating is omitted in the above, it is also effective when plating Au, Ag, Sn, Ni, etc. Furthermore, if the plating layer is strengthened in order to save money and Fi, the plating layer becomes porous and oxidation of the substrate such as copper is likely to occur, but even in such a case, the member of the present invention effectively prevents oxidation of the substrate.

以上詳述した如く本発明はボンディング等実装の際表面
が渭浄な状態にあるリードフレーム又はその中間体を得
る金属部材であり、ダイレクトボンディングを効果的に
行うことかできる等電子工業上顕著な効果を奏するもの
である。
As described in detail above, the present invention is a metal member for obtaining a lead frame or its intermediate whose surface is in a clean state during bonding and other mounting, and is remarkable in the electronic industry, such as being able to perform direct bonding effectively. It is effective.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はリードフレームの形状の1例を示す平面図、第
2図はチップの実装の1例を示す側面図である。 1・・マウンド部、2・ボンディング部、3・”外部端
子部、4・・テップ、5・・ボンティングワイヤー。
FIG. 1 is a plan view showing an example of the shape of a lead frame, and FIG. 2 is a side view showing an example of chip mounting. 1. Mound part, 2. Bonding part, 3. External terminal part, 4. Tep, 5. Bonding wire.

Claims (1)

【特許請求の範囲】[Claims] 表面に炭素数10以上の脂肪族炭化水素化合物からなる
薄膜を設けたことを特徴とするリードフレーム用金属部
材0
Metal member 0 for lead frame, characterized in that a thin film made of an aliphatic hydrocarbon compound having 10 or more carbon atoms is provided on the surface.
JP58061177A 1983-04-07 1983-04-07 Metal member for lead frame Expired - Lifetime JPH0770661B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58061177A JPH0770661B2 (en) 1983-04-07 1983-04-07 Metal member for lead frame

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58061177A JPH0770661B2 (en) 1983-04-07 1983-04-07 Metal member for lead frame

Publications (2)

Publication Number Publication Date
JPS59186354A true JPS59186354A (en) 1984-10-23
JPH0770661B2 JPH0770661B2 (en) 1995-07-31

Family

ID=13163608

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58061177A Expired - Lifetime JPH0770661B2 (en) 1983-04-07 1983-04-07 Metal member for lead frame

Country Status (1)

Country Link
JP (1) JPH0770661B2 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5158068A (en) * 1974-11-18 1976-05-21 Hitachi Ltd JUSHIFUSHIGATAHANDOTAISOCHI
JPS5562193A (en) * 1978-10-27 1980-05-10 Hitachi Cable Ltd Partial plating method of blankded flat bar material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5158068A (en) * 1974-11-18 1976-05-21 Hitachi Ltd JUSHIFUSHIGATAHANDOTAISOCHI
JPS5562193A (en) * 1978-10-27 1980-05-10 Hitachi Cable Ltd Partial plating method of blankded flat bar material

Also Published As

Publication number Publication date
JPH0770661B2 (en) 1995-07-31

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