JPS59166596A - 離型剤 - Google Patents
離型剤Info
- Publication number
- JPS59166596A JPS59166596A JP4189183A JP4189183A JPS59166596A JP S59166596 A JPS59166596 A JP S59166596A JP 4189183 A JP4189183 A JP 4189183A JP 4189183 A JP4189183 A JP 4189183A JP S59166596 A JPS59166596 A JP S59166596A
- Authority
- JP
- Japan
- Prior art keywords
- mold release
- mold
- release agent
- group
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006082 mold release agent Substances 0.000 title claims abstract description 21
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012736 aqueous medium Substances 0.000 claims abstract description 8
- 125000000962 organic group Chemical group 0.000 claims abstract description 3
- 239000002609 medium Substances 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 239000002023 wood Substances 0.000 abstract description 5
- 229920001971 elastomer Polymers 0.000 abstract description 3
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000011369 resultant mixture Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 7
- 238000000465 moulding Methods 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 235000013869 carnauba wax Nutrition 0.000 description 4
- 239000004203 carnauba wax Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- -1 amine salts Chemical class 0.000 description 3
- 239000004200 microcrystalline wax Substances 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000012778 molding material Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- PCEAEURPWOIORP-UHFFFAOYSA-N OP([O-])=O.CC[NH+](CC)CC Chemical compound OP([O-])=O.CC[NH+](CC)CC PCEAEURPWOIORP-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- USFRYJRPHFMVBZ-UHFFFAOYSA-M benzyl(triphenyl)phosphanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)CC1=CC=CC=C1 USFRYJRPHFMVBZ-UHFFFAOYSA-M 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- UNXNGGMLCSMSLH-UHFFFAOYSA-N dihydrogen phosphate;triethylazanium Chemical compound OP(O)(O)=O.CCN(CC)CC UNXNGGMLCSMSLH-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229940095696 soap product Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Landscapes
- Moulds For Moulding Plastics Or The Like (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4189183A JPS59166596A (ja) | 1983-03-14 | 1983-03-14 | 離型剤 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4189183A JPS59166596A (ja) | 1983-03-14 | 1983-03-14 | 離型剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59166596A true JPS59166596A (ja) | 1984-09-19 |
| JPH0378244B2 JPH0378244B2 (enrdf_load_stackoverflow) | 1991-12-13 |
Family
ID=12620904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4189183A Granted JPS59166596A (ja) | 1983-03-14 | 1983-03-14 | 離型剤 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59166596A (enrdf_load_stackoverflow) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0597115A4 (en) * | 1992-04-28 | 1994-03-08 | Daikin Ind Ltd | RELEASE AGENT. |
| WO2011030775A1 (ja) * | 2009-09-11 | 2011-03-17 | ユニマテック株式会社 | ポリフルオロアルキルホスホン酸オキシアルキレンエステル、その製造法およびそれを有効成分とする離型剤 |
| JP2011056835A (ja) * | 2009-09-11 | 2011-03-24 | Unimatec Co Ltd | 離型剤 |
| JP2011057632A (ja) * | 2009-09-11 | 2011-03-24 | Unimatec Co Ltd | ポリフルオロアルキルホスホン酸オキシアルキレンエステルおよびその製造法 |
| US8197586B2 (en) | 2009-03-13 | 2012-06-12 | Unimatec Co., Ltd. | Polyfluoroalkylphosphonic acid, method for producing the same and mold-releasing agent comprising the same as active ingredient |
| US8313573B2 (en) | 2009-09-11 | 2012-11-20 | Unimatec Co., Ltd. | Mold-releasing agent |
| US8361215B2 (en) | 2009-11-04 | 2013-01-29 | Unimatec Co., Ltd. | Polyfluoroalkylphosphonic acid salt emulsifier and mold-releasing agent comprising the same as active ingredient |
| US8377187B2 (en) | 2009-06-04 | 2013-02-19 | Unimatec Co., Ltd. | Graft copolymer and mold-releasing agent comprising same as active ingredient |
| US8454738B2 (en) | 2009-06-05 | 2013-06-04 | Unimatec Co., Ltd. | Mold-releasing agent |
| US8987397B2 (en) | 2010-09-13 | 2015-03-24 | Unimatec Co., Ltd. | Fluorine-containing copolymer |
| US9068059B2 (en) | 2010-05-25 | 2015-06-30 | Unimatec Co., Ltd. | Fluorine-containing polymer aqueous dispersion |
| US9120833B2 (en) | 2009-03-13 | 2015-09-01 | Unimatec Co., Ltd. | Polyfluoroalkylphosphonic acid ester and process for producing the same |
| US9610634B2 (en) | 2009-09-17 | 2017-04-04 | Unimatec Co., Ltd. | Emulsion and mold-releasing agent using the same |
| US10836780B2 (en) | 2017-03-22 | 2020-11-17 | Unimatec Co., Ltd | Polyfluoroalkyl phosphoric acid ester or salt thereof, and mold-releasing agent comprising the same as an active ingredient |
| JP2021109917A (ja) * | 2020-01-10 | 2021-08-02 | 三菱マテリアル電子化成株式会社 | 離型用液組成物 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07304043A (ja) * | 1994-05-11 | 1995-11-21 | Daikin Ind Ltd | 成形方法及び離型剤用希釈剤 |
| KR101387359B1 (ko) * | 2009-07-10 | 2014-04-21 | 유니마테크 가부시키가이샤 | 폴리플루오로알킬포스폰산에스테르 및 그 제조법 |
| JP5840044B2 (ja) * | 2012-03-22 | 2016-01-06 | 株式会社ネオス | 水系離型剤組成物。 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5252188A (en) * | 1975-10-24 | 1977-04-26 | Shinnitsutou Kagaku Kk | F-cont. surfactants |
| JPS5340052A (en) * | 1976-09-24 | 1978-04-12 | Daikin Ind Ltd | Mold releasing agent |
-
1983
- 1983-03-14 JP JP4189183A patent/JPS59166596A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5252188A (en) * | 1975-10-24 | 1977-04-26 | Shinnitsutou Kagaku Kk | F-cont. surfactants |
| JPS5340052A (en) * | 1976-09-24 | 1978-04-12 | Daikin Ind Ltd | Mold releasing agent |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5525150A (en) * | 1992-04-28 | 1996-06-11 | Daikin Industries Ltd. | Mold release agent |
| EP0597115A4 (en) * | 1992-04-28 | 1994-03-08 | Daikin Ind Ltd | RELEASE AGENT. |
| US9120833B2 (en) | 2009-03-13 | 2015-09-01 | Unimatec Co., Ltd. | Polyfluoroalkylphosphonic acid ester and process for producing the same |
| US8197586B2 (en) | 2009-03-13 | 2012-06-12 | Unimatec Co., Ltd. | Polyfluoroalkylphosphonic acid, method for producing the same and mold-releasing agent comprising the same as active ingredient |
| US8377187B2 (en) | 2009-06-04 | 2013-02-19 | Unimatec Co., Ltd. | Graft copolymer and mold-releasing agent comprising same as active ingredient |
| US8454738B2 (en) | 2009-06-05 | 2013-06-04 | Unimatec Co., Ltd. | Mold-releasing agent |
| JP2011057632A (ja) * | 2009-09-11 | 2011-03-24 | Unimatec Co Ltd | ポリフルオロアルキルホスホン酸オキシアルキレンエステルおよびその製造法 |
| US8313573B2 (en) | 2009-09-11 | 2012-11-20 | Unimatec Co., Ltd. | Mold-releasing agent |
| US8377188B2 (en) | 2009-09-11 | 2013-02-19 | Unimatec Co., Ltd. | Polyfluoroalkylphosphonic acid oxyalkylene ester, method for producing the same, and mold-releasing agent comprising the same as active ingredient |
| JP2011056835A (ja) * | 2009-09-11 | 2011-03-24 | Unimatec Co Ltd | 離型剤 |
| WO2011030775A1 (ja) * | 2009-09-11 | 2011-03-17 | ユニマテック株式会社 | ポリフルオロアルキルホスホン酸オキシアルキレンエステル、その製造法およびそれを有効成分とする離型剤 |
| US9610634B2 (en) | 2009-09-17 | 2017-04-04 | Unimatec Co., Ltd. | Emulsion and mold-releasing agent using the same |
| US9937551B2 (en) | 2009-09-17 | 2018-04-10 | Unimatec Co., Ltd. | Emulsion and mold-releasing agent using the same |
| US8361215B2 (en) | 2009-11-04 | 2013-01-29 | Unimatec Co., Ltd. | Polyfluoroalkylphosphonic acid salt emulsifier and mold-releasing agent comprising the same as active ingredient |
| US9068059B2 (en) | 2010-05-25 | 2015-06-30 | Unimatec Co., Ltd. | Fluorine-containing polymer aqueous dispersion |
| US8987397B2 (en) | 2010-09-13 | 2015-03-24 | Unimatec Co., Ltd. | Fluorine-containing copolymer |
| US10836780B2 (en) | 2017-03-22 | 2020-11-17 | Unimatec Co., Ltd | Polyfluoroalkyl phosphoric acid ester or salt thereof, and mold-releasing agent comprising the same as an active ingredient |
| JP2021109917A (ja) * | 2020-01-10 | 2021-08-02 | 三菱マテリアル電子化成株式会社 | 離型用液組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0378244B2 (enrdf_load_stackoverflow) | 1991-12-13 |
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