JPS59162656U - Ion selective field effect sensor - Google Patents

Ion selective field effect sensor

Info

Publication number
JPS59162656U
JPS59162656U JP2870084U JP2870084U JPS59162656U JP S59162656 U JPS59162656 U JP S59162656U JP 2870084 U JP2870084 U JP 2870084U JP 2870084 U JP2870084 U JP 2870084U JP S59162656 U JPS59162656 U JP S59162656U
Authority
JP
Japan
Prior art keywords
selective field
cation
effect sensor
field effect
ion selective
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2870084U
Other languages
Japanese (ja)
Inventor
菅野 卓雄
仁木 栄治
洋一 岡部
秋山 龍雄
Original Assignee
東京大学長
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 東京大学長 filed Critical 東京大学長
Priority to JP2870084U priority Critical patent/JPS59162656U/en
Publication of JPS59162656U publication Critical patent/JPS59162656U/en
Pending legal-status Critical Current

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  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本考案によるイオン選択性電界効果型センサの
イオン選択性電極素子の原理を示す断面図、第2図はイ
オン選択性電極素子の製造に用いるマスクパターンを示
す略平面図、第3図は完成゛したセンサの全体の概念を
略図として示す斜視図、第4a図は本考案センサの実装
状態であり、一部を破断して示す側面図、第4b図は第
4a図のセンサの部分を拡大して示す図、第5図は本考
案によるセンサの実測例を示す図表であり、横軸にに十
の陽イオンモル濃度、縦軸にドレイン電流より算出した
ゲートソース電位差V。、を示す特性図である。 11・・・ソース、12・・・ドレイン、13・・・基
板半一導体、14.15・・・絶縁膜、16・・・電解
質溶液、4ト・・注射針、42・・・比較電極、43・
・・測定電極。
FIG. 1 is a cross-sectional view showing the principle of the ion-selective electrode element of the ion-selective field-effect sensor according to the present invention, FIG. 2 is a schematic plan view showing the mask pattern used for manufacturing the ion-selective electrode element, and FIG. The figure is a perspective view schematically showing the overall concept of the completed sensor, Figure 4a is a partially cutaway side view showing the sensor of the present invention in a mounted state, and Figure 4b is the sensor of Figure 4a. FIG. 5 is a diagram showing an example of actual measurement of the sensor according to the present invention, in which the horizontal axis represents the cation molar concentration and the vertical axis represents the gate-source potential difference V calculated from the drain current. FIG. DESCRIPTION OF SYMBOLS 11... Source, 12... Drain, 13... Substrate semiconductor, 14.15... Insulating film, 16... Electrolyte solution, 4T... Syringe needle, 42... Reference electrode , 43・
...Measurement electrode.

Claims (1)

【実用新案登録請求の範囲】[Scope of utility model registration request] 測定対象となる陽イオンと安定な錯体を作るペテロ巨大
環状化合物を所望のパターンとして半導体表面に固定化
させた構造を有し、測定対象陽イオンに選択性感受性を
有する陽イオン選択性電界効果型センサ素子を微小電極
の形状として測定電極43を構成し、該測定電極43と
、比較電極42の液絡部425がともに注射針の先端の
開口部近傍に装置する如く構成し、かつ測定電極の先端
部にはに十選択性を有する固体感応膜を形成し、さらに
該注射針の基部に内部照合電極と接する内部液を収容し
てなるイオン選択性電界効果型センサ。
A cation-selective field-effect type that has a structure in which a petro macrocyclic compound that forms a stable complex with the cation to be measured is immobilized on the semiconductor surface in a desired pattern, and is selectively sensitive to the cation to be measured. The measurement electrode 43 is configured with the sensor element in the shape of a microelectrode, the measurement electrode 43 and the liquid junction 425 of the reference electrode 42 are both arranged near the opening at the tip of the injection needle, and An ion-selective field-effect sensor comprising a solid sensitive membrane having high selectivity formed at the tip and further containing an internal liquid in contact with an internal reference electrode at the base of the injection needle.
JP2870084U 1984-02-29 1984-02-29 Ion selective field effect sensor Pending JPS59162656U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2870084U JPS59162656U (en) 1984-02-29 1984-02-29 Ion selective field effect sensor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2870084U JPS59162656U (en) 1984-02-29 1984-02-29 Ion selective field effect sensor

Publications (1)

Publication Number Publication Date
JPS59162656U true JPS59162656U (en) 1984-10-31

Family

ID=30159580

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2870084U Pending JPS59162656U (en) 1984-02-29 1984-02-29 Ion selective field effect sensor

Country Status (1)

Country Link
JP (1) JPS59162656U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008542733A (en) * 2005-05-30 2008-11-27 メトラー−トレド アクチェンゲゼルシャフト Electrochemical sensor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008542733A (en) * 2005-05-30 2008-11-27 メトラー−トレド アクチェンゲゼルシャフト Electrochemical sensor

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