JPS59117202A - Voltage and current nonlinear resistor - Google Patents

Voltage and current nonlinear resistor

Info

Publication number
JPS59117202A
JPS59117202A JP57226207A JP22620782A JPS59117202A JP S59117202 A JPS59117202 A JP S59117202A JP 57226207 A JP57226207 A JP 57226207A JP 22620782 A JP22620782 A JP 22620782A JP S59117202 A JPS59117202 A JP S59117202A
Authority
JP
Japan
Prior art keywords
voltage
current
nonlinear resistor
current nonlinear
resistor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57226207A
Other languages
Japanese (ja)
Other versions
JPH0425681B2 (en
Inventor
金井 秀之
孝 高橋
今井 基真
修 古川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP57226207A priority Critical patent/JPS59117202A/en
Priority to CA000443963A priority patent/CA1206742A/en
Priority to DE8383112992T priority patent/DE3370231D1/en
Priority to EP83112992A priority patent/EP0115050B1/en
Priority to US06/564,100 priority patent/US4527146A/en
Publication of JPS59117202A publication Critical patent/JPS59117202A/en
Publication of JPH0425681B2 publication Critical patent/JPH0425681B2/ja
Granted legal-status Critical Current

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  • Compositions Of Oxide Ceramics (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 [発明の技術分野] 本発明は酸化亜鉛(zno)を主成分とする焼結体から
なる電圧電流非直線抵抗体l1関する。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a voltage-current nonlinear resistor l1 made of a sintered body containing zinc oxide (zno) as a main component.

[発明の技術的背景とその問題点コ 従来から各種の電圧電流非直線抵抗体が研究されている
が、その中の一つにZnOを主成分とした焼結体を用い
たものがある。このZnOを主成分とした焼結体を用い
たものC二おいては、各種副成分が添加されて所望の特
性を得ることが試みられている。このような電圧電流非
直線抵抗体に要求される特性としては、電圧電流非直線
特性、寿命特性等があるが、いずれにも優れた特性を有
するものを得るのは困難なことである。例えば特開昭4
9−119188号f二示されているように、  Zn
Oを生成分としBi20B、 Coo、 6+1)20
B、 Nip、 MnOを副成分として添加した電圧電
流非直線抵抗体があるが、この場合も電圧電流非直線特
性において十分な特性は得られていない。
[Technical background of the invention and its problems] Various voltage-current non-linear resistors have been studied in the past, and one of them uses a sintered body containing ZnO as a main component. In C2, which uses a sintered body containing ZnO as a main component, attempts have been made to add various subcomponents to obtain desired characteristics. The characteristics required of such a voltage-current non-linear resistor include voltage-current non-linear characteristics, life-span characteristics, etc., but it is difficult to obtain one that has excellent characteristics in all of them. For example, Japanese Patent Application Publication No. 4
No. 9-119188 f2 As shown, Zn
With O as the generated component, Bi20B, Coo, 6+1)20
There are voltage-current non-linear resistors in which B, Nip, and MnO are added as subcomponents, but in this case as well, sufficient voltage-current non-linear characteristics are not obtained.

また特公昭56−33842号l二示されているように
Also, as shown in Japanese Patent Publication No. 56-33842.

ZnOを主成分とし酸化硼素を含むjj5スを添加して
焼結することf二より、直流通電において制限電圧の低
下しない電圧電流非直線抵抗体を得ることが試みられて
いる。しかしながらこのような電圧電流非直線抵抗体に
おいても、電圧電流非直線特性、寿命特性ども≦二すぐ
れたものは得られていない。特に避雷器等の大きなサー
ジ吸収を目的とする場合は特(二重圧電流非直線特性、
寿命特性に優れたものが要求される。
Attempts have been made to obtain a voltage-current nonlinear resistor in which the limiting voltage does not decrease in direct current flow by adding and sintering ZnO containing ZnO as a main component and containing boron oxide. However, even in such a voltage-current non-linear resistor, excellent voltage-current non-linear characteristics and life characteristics of ≦2 have not been obtained. Especially when the purpose is to absorb large surges such as lightning arresters,
A product with excellent life characteristics is required.

[発明の目的] 本発明は電圧電流非直線特性、寿命特性ともC優れた電
圧電流非直線抵抗体を提供することを目的とする。
[Object of the Invention] An object of the present invention is to provide a voltage-current nonlinear resistor that is excellent in both voltage-current nonlinear characteristics and life characteristics.

[発明の概要] 本発明は酸化亜鉛を主成分とし、副成分としてビスマス
、コバルト、マンガン、アンチモン、ニッケル、アルミ
ニウムがそれぞれBi20B、 0020B。
[Summary of the Invention] The main component of the present invention is zinc oxide, and the subcomponents are bismuth, cobalt, manganese, antimony, nickel, and aluminum, respectively, Bi20B and 0020B.

MnO,5bzOB、 Nip、 AJ” に換算して
、Bigot、 0.1〜5mo2%  、 0020
B  0.1−5mo4%  +MnO0,1−5mo
2%  、 EIJOB  0.1〜5 moJ% 。
MnO, 5bzOB, Nip, AJ” converted to Bigot, 0.1-5mo2%, 0020
B 0.1-5mo4% +MnO0,1-5mo
2%, EIJOB 0.1-5 moJ%.

NiO’0.1〜5 mo2%  、 A4”  0.
001−0.05 mof%含有すされ;かつこの組成
に対してB20 B 、Ap 20+ 5iosのうち
少なくとも一種がそれぞれ0.002〜0.2wt%。
NiO'0.1-5 mo2%, A4" 0.
001-0.05 mof% of sushi; and based on this composition, at least one of B20B and Ap20+ 5ios is each 0.002 to 0.2 wt%.

0.0011−0,4wt% 、 0.001〜0.1
 wt%含有された焼結体からなることを特徴とする電
圧電流非直線抵抗体である。
0.0011-0.4wt%, 0.001-0.1
This is a voltage/current nonlinear resistor characterized in that it is made of a sintered body containing wt%.

上記組成をとることC二より、電圧電流非直線特性、寿
命特性ともに向上するO B1201B、 0020B
、 MnO+Sbg09. NiOをそれぞれ0.1 
= 5 mo2%としたのは、この範囲をはずれると、
非直線特性、寿命特性が劣化してしまうからである。ま
7’CAJ8+を0.001〜0.05 mo1%とし
たのは、この範囲をはずれると、非直線特性、寿命特性
%慎重非直線特性が大幅C劣化してしまうからである。
O B1201B, 0020B which has the above composition improves both voltage-current non-linear characteristics and life characteristics.
, MnO+Sbg09. 0.1 each of NiO
= 5 mo2% is because outside this range,
This is because non-linear characteristics and life characteristics deteriorate. The reason why 7'CAJ8+ is set to 0.001 to 0.05 mo1% is because if it deviates from this range, the nonlinear characteristics, life characteristics (%), and nonlinear characteristics will deteriorate significantly.

まfCB20B、 kfzO,5i02をそれぞれ0.
002−0.27t%t0.002 = 0.2wt、
%、 0.001−0.1 wt%としたのは、この範
囲より少ない含有量だと、寿命特性を改善する効果があ
られれず、この範囲を越えてしまうと、寿命特性を改善
する効果がほとんどあられれず、かえって非直線性をも
劣化させてし1うからである。
MafCB20B, kfzO, and 5i02 were each set to 0.
002-0.27t%t0.002 = 0.2wt,
%, 0.001-0.1 wt% because if the content is less than this range, the effect of improving the life characteristics will not be achieved, and if it exceeds this range, the effect of improving the life characteristics will not be achieved. This is because it hardly occurs, and on the contrary, it deteriorates the nonlinearity.

またこのB2O3,Al5o、 B102はそれぞれ単
独で加えても寿命改善の効果はあがるが、単独よりは2
種さらには38加えた方がより一層の効果を得ることが
できる。
Also, even if B2O3, Al5o, and B102 are added alone, the effect of improving the lifespan increases, but it is better to add them alone.
If you add 38 seeds, you can get even more effect.

[発明の効果] 以上説明したように不発明によれば、電圧電流非直線特
性、寿命4(−性ともに優れた電圧軍1流非直線抵抗体
を得ることができる。従って避箱器等の大きいサージ吸
収を行なう場合(1用いると好適である。
[Effects of the Invention] As explained above, according to the invention, it is possible to obtain a first-class voltage nonlinear resistor that is excellent in both voltage and current nonlinear characteristics and service life. When performing large surge absorption (it is preferable to use 1).

[発明の実施例] 以下本発明の詳細な説明する。[Embodiments of the invention] The present invention will be explained in detail below.

ZnOに副成分として13120B、 CO2O3,M
nO,5b20B。
13120B, CO2O3,M as subcomponents in ZnO
nO,5b20B.

N1o、 Az(N、oB)B・9H20,B2O3,
AfzO,5i02を所望のll成比でσ4合 混合の
後、ノ<イングーとしてPVAを加え造イqし、円板状
の板材(:成形した。この板材を乾燥した後1100〜
1300°C2hr程度の焼成の後両面研磨を施して、
直径20.厚さ2ηコの焼結体を形がこしたQ この試料の両面にA1溶射によりt82を設は電圧電流
非直線抵抗体を形成し各種特性を測定したOこの結果を
第1表孟ユ示す。第1衣には各組成分で本発明の範囲外
のものについても比較例として示した。第1表において
、電圧電流非直線特性はVlKA/V1mA ’寿命特
性はL200で示す。
N1o, Az(N,oB)B・9H20,B2O3,
AfzO.
After baking at 1300°C for 2 hours, both sides are polished.
Diameter 20. A sintered body with a thickness of 2η was shaped, and t82 was formed on both sides of this sample by A1 thermal spraying to form a voltage-current nonlinear resistor and various characteristics were measured.The results are shown in Table 1. . In the first coating, compositions that were outside the scope of the present invention were also shown as comparative examples. In Table 1, the voltage-current nonlinear characteristics are VlKA/V1mA' and the lifespan characteristics are shown as L200.

(ただし各電圧は50H2正弦波波高値1mA通電時の
電圧)ν、下金白 第1表から明らかなよう(二、本発明の実施例1〜72
においては、非直線特性(VIKA/Vlユ〕、寿命特
性(Lzoo )ともに、比較例1〜15に比べ優れて
喘 いることがわかる。
(However, each voltage is the voltage when 50H2 sine wave peak value 1mA is applied) ν, as is clear from Table 1 of Shimokane Shiro (2. Examples 1 to 72 of the present invention)
It can be seen that both the nonlinear characteristics (VIKA/Vl) and the life characteristics (Lzoo) are superior to Comparative Examples 1 to 15.

実施例1〜9はB20B、 Af2o、 5iozのう
ち一種を含有するもの、実施例10〜36は2棹を含有
するもの、実施例37〜72は3種を含有するものであ
るが、1種より2種、さらに3種と寿命特性が向上して
いることがわかる。しかしながら比較例13〜15から
れかるように含有量か多くなってし1うと、寿命特性を
改善する効果があられれないはかりか、非直線性をも悪
くしてしまう。
Examples 1 to 9 contain one of B20B, Af2o, and 5ioz, Examples 10 to 36 contain two, and Examples 37 to 72 contain three, but one. It can be seen that the life characteristics are improved for 2 types and then 3 types. However, if the content increases as shown in Comparative Examples 13 to 15, the effect of improving the life characteristics may not be achieved, or the nonlinearity may become worse.

代理人 弁理士 則 近 慾 佑 (ほか1名)10− 手 続 補 正 書(自発) 1°帽、1.イ9B 、許庁長官殿 1、事件の表示 昭和57年特願第226207号 2、発明の名称 電圧を流罪直線抵抗体 3 補正をする者 事件との関係 特許出願人 (307)東京芝浦電気株式会社 4代理人 〒io。Agent: Patent attorney Noriyuki Kin (and 1 other person) 10- Supplementary manuscript (spontaneous) 1° cap, 1. i9B , Director-General of the Office 1.Display of the incident 1981 Special Application No. 226207 2. Name of the invention Straight line resistor carrying voltage 3 Person making the amendment Relationship to the case: Patent applicant (307) Tokyo Shibaura Electric Co., Ltd. 4 agents 〒io.

東京都千代田区内辛町1−1−6 明細書の特許請求の範囲の欄 及び発明の詳細な説明の欄 6 補正の内容 (1を明細書の特許請求の範囲を別紙のごとく訂正する
1-1-6 Uchisara-cho, Chiyoda-ku, Tokyo Contents of the amendment (1. The scope of claims in the specification is corrected as shown in the attached sheet.)

(2)明細書第4頁第1行乃至2行「B2O3,それぞ
れO,tl 02〜0.2wt%」とあるのを「硼素が
B2O3に換胸、シて0.002〜0.2wt%、かつ
銀及び珪素の少なくとも一種がAg2O,SiO2に換
算してそれぞオt」と訂正する。
(2) Lines 1 and 2 of page 4 of the specification, “B2O3, O, tl, respectively, 02-0.2wt%” have been replaced with “Boron is converted into B2O3, and the amount is 0.002-0.2wt%.” , and at least one of silver and silicon is Ot in terms of Ag2O and SiO2, respectively.''

(3)明細書第4頁第20行rB203.jとあるのを
削除する。
(3) Specification page 4 line 20 rB203. Delete the j.

(4)明wl書445頁第1行乃至2行「ざらには3種
」とあるのを削除する。
(4) Delete the line 1 to 2 of page 445 of the Mei-Wal Book that says ``3 types of sardines''.

(5)明細書第6頁第7行「(ただし ′屯田)」とあ
るのを と訂正する。
(5) On page 6, line 7 of the specification, ``(However, 'tonden)'' should be corrected.

(6)明紗賓第7頁乃至12頁の第1表を別紙のごとく
訂正する。
(6) Table 1 on pages 7 to 12 of Meishahin is corrected as shown in the attached sheet.

(力明細書第13頁第2行「72」とあるのを「54」
と訂正する。
(Page 13, line 2 of the force specification, replace “72” with “54”)
I am corrected.

(8)明細書第13頁第5行乃至9行「実施例1〜9・
わかる。」とあるのを1実施例1−18はAg 20 
(8) Page 13 of the specification, lines 5 to 9 “Examples 1 to 9.
Recognize. "Example 1-18 is Ag 20
.

5i02のうち一種を含有するもの、実施例19〜54
は2種を含有するものであるが、1麺より2種含有した
方が寿命特性が向上していることがわかる。」と訂正す
る。
Examples 19 to 54 containing one type of 5i02
contains two types of noodles, but it can be seen that the life characteristics are improved when the noodles contain two types than when they contain one type of noodles. ” he corrected.

以上 μ m□牢− 品 特許請求の範囲 il+酸化亜鉛を主成分とし、副成分としてビスマス、
コバルト、マンガン、アンチモン、ニッケル。
The above μ m □ prison product patent claims il + zinc oxide as a main component, bismuth as a subcomponent,
Cobalt, manganese, antimony, nickel.

アルミニウムがそれぞれBi2O3,C020a、]V
fnO,5b203゜、NiO,Al  に換算して、 Bi2030.1〜5mo1%、 CO2O30,1〜
5mo1%。
Aluminum is Bi2O3, C020a, ]V respectively
fnO,5b203°, converted to NiO, Al, Bi2030.1~5mo1%, CO2O30,1~
5mo1%.

MnO0,1〜5 mo1%、 5b203 0.1〜
5mo1%。
MnO0.1~5 mo1%, 5b203 0.1~
5mo1%.

NiOO,1〜5moe%、 A13+0.001〜0
.05 mn 11 %含有され:かつこの組成に対し
てB2O3が0.+102〜0.2wt%、かつAg2
O5i02のうち少なくとも一種がそれぞれ0.002
〜0.2 wt%、 0.001〜0.1 wt%含有
された焼結体からなることを特徴とする電圧電流非直線
抵抗体。
NiOO, 1-5 moe%, A13+0.001-0
.. 05 mn 11%: and for this composition B2O3 is 0.05 mn. +102~0.2wt%, and Ag2
At least one of O5i02 is 0.002 each
A voltage/current nonlinear resistor comprising a sintered body containing ~0.2 wt% and 0.001~0.1 wt%.

(2、特許請求の範囲第1項において前記B2O3。(2. The B2O3 in claim 1.

AgzO,5i02がそれぞれ0.002〜0.2wt
チ、0.002〜0.2wt%、0.001〜0.1w
t係含有されたことを特徴とする電圧電流非直線抵抗体
AgzO and 5i02 are each 0.002~0.2wt
H, 0.002-0.2wt%, 0.001-0.1w
A voltage/current nonlinear resistor characterized by containing a t-coefficient.

Claims (2)

【特許請求の範囲】[Claims] (1)酸化亜鉛を主成分とし、副成分としてビスマス、
コバルト、マンガン、アンチモン、ニッケル、アルミニ
ウムがそれぞれB140B+ CO20B、 MnO。 5b2oB、 Nip、 At8+に侯算して、B14
OB  0.1−5 rno1%  + C!020B
  o、i 〜5 mo1%。 MnO0,1〜5 moノ96  、5b2OB  0
.1−5moJ% 。 NiOO,1−5mo1% * Aj”  0.001
−0.05mo2%含崩され;かりこの組成l二対して
B2O3,Ap20.5i02のうち少なくとも一種が
それぞれ0.002〜0.2wt%。 0.002!〜0蓼wt% 、 0.001−0.1w
t%官有された屍結体からなることを特徴とする電圧電
流非直線抵抗体。
(1) Zinc oxide is the main component, with bismuth as a subcomponent.
Cobalt, manganese, antimony, nickel, and aluminum are B140B+ CO20B and MnO, respectively. 5b2oB, Nip, At8+, B14
OB 0.1-5 rno1% + C! 020B
o, i ~5 mo1%. MnO0,1~5 mono96, 5b2OB 0
.. 1-5moJ%. NiOO, 1-5mo1% * Aj” 0.001
-0.05 mo2% is dissolved; at least one of B2O3 and Ap20.5i02 is each 0.002 to 0.2 wt% based on the composition of Kariko. 0.002! ~0wt%, 0.001-0.1w
A voltage-current non-linear resistor characterized by comprising t%-owned corpse bodies.
(2)  %許訪求の範囲第1項l二おいて前記E 2
08 +Af2,0.5io2がそれぞれ0.002〜
0.2 wt%、 o、oo2−o2wt%、 0.0
01〜0.1wt%含有されたことを特徴とする電圧電
流非直線抵抗体。
(2) Scope of Permission Visits Paragraph 1 2 above E 2
08 +Af2, 0.5io2 are each 0.002 ~
0.2 wt%, o, oo2-o2 wt%, 0.0
A voltage/current nonlinear resistor characterized in that the voltage/current nonlinear resistor contains 01 to 0.1 wt%.
JP57226207A 1982-12-24 1982-12-24 Voltage and current nonlinear resistor Granted JPS59117202A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP57226207A JPS59117202A (en) 1982-12-24 1982-12-24 Voltage and current nonlinear resistor
CA000443963A CA1206742A (en) 1982-12-24 1983-12-21 Varistor
DE8383112992T DE3370231D1 (en) 1982-12-24 1983-12-22 Varistor
EP83112992A EP0115050B1 (en) 1982-12-24 1983-12-22 Varistor
US06/564,100 US4527146A (en) 1982-12-24 1983-12-22 Varistor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57226207A JPS59117202A (en) 1982-12-24 1982-12-24 Voltage and current nonlinear resistor

Publications (2)

Publication Number Publication Date
JPS59117202A true JPS59117202A (en) 1984-07-06
JPH0425681B2 JPH0425681B2 (en) 1992-05-01

Family

ID=16841568

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57226207A Granted JPS59117202A (en) 1982-12-24 1982-12-24 Voltage and current nonlinear resistor

Country Status (1)

Country Link
JP (1) JPS59117202A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6159704A (en) * 1984-08-31 1986-03-27 株式会社東芝 Nonlinear resistor
JPS6182401A (en) * 1984-09-29 1986-04-26 株式会社東芝 Voltage non-linearity resistor and manufacture thereof
US6184771B1 (en) 1998-05-25 2001-02-06 Kabushiki Kaisha Toshiba Sintered body having non-linear resistance characteristics
JP2007228741A (en) * 2006-02-24 2007-09-06 Jfe Steel Kk Current collector
JP2007329148A (en) * 2006-06-06 2007-12-20 Toshiba Corp Current-voltage nonlinear resistor
JP2010010466A (en) * 2008-06-27 2010-01-14 Doshisha Method of manufacturing antimony-added zinc oxide varistor
CN111718192A (en) * 2012-12-27 2020-09-29 东莞令特电子有限公司 Zinc oxide based varistor and method of manufacture

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49119188A (en) * 1973-03-20 1974-11-14
JPS50131094A (en) * 1974-04-04 1975-10-16
JPS5676504A (en) * 1979-11-27 1981-06-24 Matsushita Electric Ind Co Ltd Voltage nonnlinear resistance element and method of manufacturing same
JPS57154802A (en) * 1981-03-20 1982-09-24 Hitachi Ltd Voltage nonlinear resistor and method of producing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49119188A (en) * 1973-03-20 1974-11-14
JPS50131094A (en) * 1974-04-04 1975-10-16
JPS5676504A (en) * 1979-11-27 1981-06-24 Matsushita Electric Ind Co Ltd Voltage nonnlinear resistance element and method of manufacturing same
JPS57154802A (en) * 1981-03-20 1982-09-24 Hitachi Ltd Voltage nonlinear resistor and method of producing same

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6159704A (en) * 1984-08-31 1986-03-27 株式会社東芝 Nonlinear resistor
JPH0519802B2 (en) * 1984-08-31 1993-03-17 Tokyo Shibaura Electric Co
JPS6182401A (en) * 1984-09-29 1986-04-26 株式会社東芝 Voltage non-linearity resistor and manufacture thereof
JPH0584041B2 (en) * 1984-09-29 1993-11-30 Tokyo Shibaura Electric Co
US6184771B1 (en) 1998-05-25 2001-02-06 Kabushiki Kaisha Toshiba Sintered body having non-linear resistance characteristics
JP2007228741A (en) * 2006-02-24 2007-09-06 Jfe Steel Kk Current collector
JP2007329148A (en) * 2006-06-06 2007-12-20 Toshiba Corp Current-voltage nonlinear resistor
JP2010010466A (en) * 2008-06-27 2010-01-14 Doshisha Method of manufacturing antimony-added zinc oxide varistor
CN111718192A (en) * 2012-12-27 2020-09-29 东莞令特电子有限公司 Zinc oxide based varistor and method of manufacture
CN111718192B (en) * 2012-12-27 2023-07-21 东莞令特电子有限公司 Varistor based on zinc oxide and method for manufacturing same

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