JPS59111920A - タリウム（１）のタリウム（３）への酸化方法 - Google Patents
タリウム（１）のタリウム（３）への酸化方法Info
- Publication number
- JPS59111920A JPS59111920A JP22925383A JP22925383A JPS59111920A JP S59111920 A JPS59111920 A JP S59111920A JP 22925383 A JP22925383 A JP 22925383A JP 22925383 A JP22925383 A JP 22925383A JP S59111920 A JPS59111920 A JP S59111920A
- Authority
- JP
- Japan
- Prior art keywords
- thallium
- oxidation
- hydrogen peroxide
- iii
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007254 oxidation reaction Methods 0.000 title claims description 15
- 230000003647 oxidation Effects 0.000 title claims description 14
- ZLUSCZLCHQSJRU-UHFFFAOYSA-N thallium(1+) Chemical compound [Tl+] ZLUSCZLCHQSJRU-UHFFFAOYSA-N 0.000 title description 5
- XWVKTOHUMPLABF-UHFFFAOYSA-N thallium(3+) Chemical compound [Tl+3] XWVKTOHUMPLABF-UHFFFAOYSA-N 0.000 title description 5
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 28
- 229910052716 thallium Inorganic materials 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 15
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- -1 thallium carboxylates Chemical class 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000003929 acidic solution Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002432 hydroperoxides Chemical class 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003476 thallium compounds Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241001432959 Chernes Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- LVAMVZXECCXUGI-UHFFFAOYSA-N acetic acid;thallium Chemical compound [Tl].CC(O)=O LVAMVZXECCXUGI-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- WKMKTIVRRLOHAJ-UHFFFAOYSA-N oxygen(2-);thallium(1+) Chemical compound [O-2].[Tl+].[Tl+] WKMKTIVRRLOHAJ-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910003438 thallium oxide Inorganic materials 0.000 description 1
- 229910021517 thallium(III) hydroxide Inorganic materials 0.000 description 1
- GEPJDKDOADVEKE-UHFFFAOYSA-K thallium(iii) hydroxide Chemical compound O[Tl](O)O GEPJDKDOADVEKE-UHFFFAOYSA-K 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44736982A | 1982-12-06 | 1982-12-06 | |
| US447369 | 1982-12-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59111920A true JPS59111920A (ja) | 1984-06-28 |
| JPS6241174B2 JPS6241174B2 (enExample) | 1987-09-01 |
Family
ID=23776100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22925383A Granted JPS59111920A (ja) | 1982-12-06 | 1983-12-06 | タリウム（１）のタリウム（３）への酸化方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59111920A (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0633172U (ja) * | 1991-06-28 | 1994-04-28 | 有限会社シンクドリーム | ラベル |
| WO2020090913A1 (ja) * | 2018-10-30 | 2020-05-07 | 浜松ホトニクス株式会社 | レーザ加工装置及びレーザ加工方法 |
-
1983
- 1983-12-06 JP JP22925383A patent/JPS59111920A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6241174B2 (enExample) | 1987-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Strukul | Catalytic oxidations with hydrogen peroxide as oxidant | |
| TWI255811B (en) | Process for the production of acrylic acid | |
| RU2003107342A (ru) | Способ получения оксидов железа | |
| NO20040435L (no) | Katalysator og dens anvendelse i syntese av hydrogenperoksyd | |
| CA2421363A1 (en) | Method for preparing iron oxides | |
| JPS62114922A (ja) | フエノ−ルとアセトンおよびメチルエチルケトンとの製造法 | |
| CA2082976A1 (en) | Catalytic production of aryl alkyl hydroperoxides by manganese complexes | |
| JPS59111920A (ja) | タリウム（１）のタリウム（３）への酸化方法 | |
| GB2055829A (en) | Preparation of carboxylic acids from aldehydes | |
| CA2436939A1 (en) | Process for producing dicarboxylic acids | |
| JPH09241009A (ja) | 過酸化水素の製造方法 | |
| JPH06510737A (ja) | 硫化水素の硫黄と水素への転換 | |
| US2871101A (en) | Manufacture of hydrogen peroxide | |
| JPH07116097B2 (ja) | ピロメリツト酸の製造方法 | |
| US4543423A (en) | Hydration of nitriles | |
| CN112742444B (zh) | 含钛介孔分子筛催化烯烃环氧化反应的方法 | |
| USRE20769E (en) | Manufacture of hydrogen peroxide | |
| JPH09110428A (ja) | 亜ひ酸の酸化方法 | |
| JP2005514372A5 (enExample) | ||
| US4418051A (en) | Process for preparing thallium (III) | |
| Barton et al. | On the oxidation of 3-ethylpentane under GifIV and Gif-orsay conditions | |
| JPH03287574A (ja) | クメンハイドロパーオキサイドの製造方法 | |
| JPH0216739B2 (enExample) | ||
| JPH0133099B2 (enExample) | ||
| JPS62178531A (ja) | ピロカテキンおよびヒドロキノンの製造法 |