JPS5851821B2 - Synthetic resin products subjected to vacuum deposition - Google Patents
Synthetic resin products subjected to vacuum depositionInfo
- Publication number
- JPS5851821B2 JPS5851821B2 JP49126702A JP12670274A JPS5851821B2 JP S5851821 B2 JPS5851821 B2 JP S5851821B2 JP 49126702 A JP49126702 A JP 49126702A JP 12670274 A JP12670274 A JP 12670274A JP S5851821 B2 JPS5851821 B2 JP S5851821B2
- Authority
- JP
- Japan
- Prior art keywords
- vacuum
- resin
- synthetic resin
- deposited layer
- vacuum deposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Description
【発明の詳細な説明】
本発明は、真空蒸着を施した合成樹脂製製品の構造に関
するもので、真空蒸着を施した合成樹脂製製品の表面強
度を増大させることを目的としたものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to the structure of synthetic resin products subjected to vacuum deposition, and is aimed at increasing the surface strength of synthetic resin products subjected to vacuum deposition.
Ｃ以下１図面参照）アクリルニトリル・ブタジェン・ス
チレンコーポリマ樹脂（一般には、簡単のためＡＢＳと
呼ばれている）、ポリプロピレン系樹脂（一般には、簡
単のためＰＰと呼ばれている）そしてユリアフェノール
系樹脂等の合成樹脂製製品としての基体１の表面にアル
ミニウムまたは金等の金属を真空蒸着する場合、１ず基
体１の表面にウレタン系樹脂、エポキシ系樹脂またはア
クリル系樹脂等を使用した塗料を塗布してアンダー：７
−）２を被膜状に形成しておき、このアンダーコート２
表面上にアルミニウムまたは金等の金属の真空蒸着を施
して真空蒸着層３を形成している。C) Acrylonitrile-butadiene-styrene copolymer resin (generally referred to as ABS for simplicity), polypropylene resin (generally referred to as PP for simplicity), and ureaphenol When vacuum-depositing a metal such as aluminum or gold on the surface of the substrate 1, which is a product made of synthetic resin, first, a paint using urethane resin, epoxy resin, acrylic resin, etc. is applied to the surface of the substrate 1. Apply under: 7
-) 2 is formed in the form of a film, and this undercoat 2
A vacuum-deposited layer 3 is formed by vacuum-depositing a metal such as aluminum or gold on the surface.
このようにしてアンダーコート２を介して基体１表面上
に形成された真空蒸着層３は単に金属の微粒子がアンダ
ーコート２の表面に耐着しているだけに過ぎないので、
指先で軽くこする程度でアンダーコート２表面から簡単
に剥離してしすう。The vacuum-deposited layer 3 thus formed on the surface of the substrate 1 via the undercoat 2 is simply fine metal particles adhering to the surface of the undercoat 2;
It can be easily peeled off from the surface of Undercoat 2 by rubbing it lightly with your fingertips.
それゆえ、従来はこのアンダーコート２を介して基体１
の表面に形成された真空蒸着層３を保護すると同時にそ
の剥離を防止すべくこの真空蒸着層３の表面上にさらに
ウレタン系樹脂、エポキシ系樹脂またはアクリル系樹脂
等の塗料を塗布してトップコートを形成していた。Therefore, conventionally, the substrate 1 is coated via this undercoat 2.
In order to protect the vacuum-deposited layer 3 formed on the surface of the vacuum-deposited layer 3 and at the same time prevent its peeling, a paint such as urethane resin, epoxy resin, or acrylic resin is further applied on the surface of the vacuum-deposited layer 3 to form a top coat. was forming.
しかしながら、上記トップコートに使用される塗料はそ
のいづれもが合成樹脂を母材としているので、高温で乾
燥焼付をすることができず、そのためいづれも充分な被
膜強度を得ることができなかった。However, since all of the paints used for the above-mentioned top coats have synthetic resin as a base material, they cannot be dried and baked at high temperatures, and therefore, it has not been possible to obtain sufficient film strength with any of them.
また、上記トップコートは充分な硬度を有していないた
めに真空蒸着を施した製品の表面光沢すなわち外観が悪
く金属感の乏しいものとなっていた。Moreover, since the top coat does not have sufficient hardness, the surface gloss or appearance of the vacuum-deposited product is poor and the product lacks a metallic feel.
本発明は、上記した従来例における欠点を解消すべく創
案されたもので、以下本発明の基本的実施例を図面に従
って説明する。The present invention was devised to eliminate the drawbacks of the conventional examples described above, and basic embodiments of the present invention will be described below with reference to the drawings.
本発明は、前記した如く、基体１の表面にアンダーコー
ト２を介して耐着形成された真空蒸着層３の表面に、こ
の真空蒸着層３を被膜する形態でソノ生成に高温による
乾燥焼付を必要としない硬化膜４を被覆形成したもので
、この硬化膜４の材料としては電子線、放射線または紫
外線が照射されると硬化しかつ真空蒸着層３に強力に接
着する塗料が使用される。As described above, the present invention provides a form in which the vacuum vapor deposited layer 3 is coated on the surface of the vacuum vapor deposited layer 3 formed on the surface of the substrate 1 via the undercoat 2 to prevent adhesion. It is coated with an unnecessary cured film 4, and the cured film 4 is made of a paint that hardens when irradiated with electron beams, radiation, or ultraviolet rays and strongly adheres to the vacuum-deposited layer 3.
すなわち、電子線、放射線または紫外線の照射によって
硬化しかつ真空蒸着層３に強力に接着する液状となって
いる塗料を真空蒸着層３０表面上に直接適宜手段によっ
て均一に塗布し、この真空蒸着層３の表面上に塗布され
た上記塗料に電子線放射線または紫外線を照射して１秒
前後の短時間で硬化膜４を真空蒸着層３の表面に形成す
るのである。That is, a liquid paint that is cured by irradiation with electron beams, radiation, or ultraviolet rays and strongly adheres to the vacuum-deposited layer 3 is uniformly applied directly onto the surface of the vacuum-deposited layer 30 by an appropriate means, and this vacuum-deposited layer is By irradiating the paint coated on the surface of layer 3 with electron beam radiation or ultraviolet rays, a cured film 4 is formed on the surface of vacuum-deposited layer 3 in a short period of about 1 second.
この硬化膜４を形成する塗料は、照射によって硬化する
ためその中には溶剤はほとんど含壕れていない。The paint forming the cured film 4 is cured by irradiation, so it contains almost no solvent.
従って、金属の真空蒸着層３０表面上に該塗料を塗布・
接着しても１合成樹脂製品としての基体１、真空蒸着層
３には、何らの変化、変質そして溶解がみられず全く悪
影響を与えることなく、塗布が達成される。Therefore, the paint is applied on the surface of the metal vacuum-deposited layer 30.
Even after adhesion, the substrate 1 as a synthetic resin product and the vacuum-deposited layer 3 undergo no change, deterioration, or dissolution, and the coating is accomplished without any adverse effects at all.
もって真空蒸着層３による優れた装飾性を劣化させるこ
となく現出できるのである。As a result, the excellent decorative properties of the vacuum-deposited layer 3 can be exhibited without deteriorating.
またこの硬化膜４を形成する塗料の硬化は、照射による
ので高温を要しない。Furthermore, since the coating material forming the cured film 4 is cured by irradiation, high temperatures are not required.
従って、基体１、真空蒸着層３．アンダーコート２が、
温度変化のために熱膨張し、もって、真空蒸着層３にし
わがよったり破れ目が出来たりすることは、全く起こら
ない。Therefore, the substrate 1, the vacuum deposited layer 3. Undercoat 2 is
The vacuum-deposited layer 3 does not undergo any wrinkles or tears due to thermal expansion due to temperature changes.
特に、すでに所定形状に成形されている基体１が、硬化
膜４成形のために、熱変形させられることも確実に防止
されるのである。In particular, it is possible to reliably prevent the base body 1, which has already been formed into a predetermined shape, from being thermally deformed in order to form the cured film 4.
更に硬化膜４ばその分子結合形態が３次元網状結合とな
っているので、その硬度は極めて高い。Furthermore, since the molecular bonds of the cured film 4 are three-dimensional network bonds, its hardness is extremely high.
すなわち、高温焼付は塗装と同程度の硬度を有してなり
、製品表面の耐摩耗性を高めることができ、製品が傷つ
き難いものとなるとともに、真空蒸着層３の保護がより
確実になる。That is, high-temperature baking has a hardness comparable to that of painting, which increases the wear resistance of the product surface, making the product less likely to be damaged, and further ensuring the protection of the vacuum-deposited layer 3.
そして更に製品表面の光沢の面でも優れていることにな
る等により、真空蒸着層３が現出する金属感による外観
上の装飾効果がより高められるに至るのである。Moreover, since the surface of the product is excellent in terms of gloss, the decorative effect on the external appearance due to the metallic appearance of the vacuum-deposited layer 3 is further enhanced.
なむ上記塗料の硬化は、電子線、放射線、紫外線等を照
射することによって、１秒前後で完了するので、硬化膜
４の完成１での操作は、短時間のうちにしかも簡単容易
に達成されるのである。Since the curing of the above-mentioned paint is completed in about one second by irradiation with electron beams, radiation, ultraviolet rays, etc., the operation in step 1 to complete the cured film 4 can be easily accomplished in a short time. It is.
以上の説明から明らかな如く、本発明は、真空蒸着を施
した合成樹脂製製品としてその表面硬度が極めて高いも
のとなって傷つき難く、かつ金属感の富かな光沢のある
表面となり、さらにその製作も硬化膜４の形成が短時間
に簡単に行なうことができることから従来のものよりも
はるかに短時間にかつ容易に達成される等真空蒸着を施
した合成樹脂製製品として多くの優れた作用効果を発揮
するものである。As is clear from the above description, the present invention is a vacuum-deposited synthetic resin product that has extremely high surface hardness, is hard to scratch, and has a glossy surface with a rich metallic feel. The cured film 4 can be easily formed in a short period of time, so it can be achieved much more quickly and easily than conventional products, and has many excellent effects as a vacuum-deposited synthetic resin product. It is something that demonstrates the.
図面ば本発明の基本的構造を示す縦断拡大図である。
符号の説明、１：基体、２：アンダーコート、３：真空
蒸着層、４：硬化膜。The drawing is an enlarged vertical view showing the basic structure of the present invention. Explanation of symbols: 1: Substrate, 2: Undercoat, 3: Vacuum deposited layer, 4: Cured film.
Claims (1)
マ樹脂、ポリプロピレン系樹脂そしてユリアフェノール
系樹脂等の合成樹脂製製品としての基体１の表面に、ウ
レタン系樹脂、エポキシ系樹脂またはアクリル系樹脂等
の塗料を使用したアンダーコート２と、アルミニウムま
たは金等の金属の真空蒸着層３と、そして電子線、放射
線または紫外線の照射を受けて硬化しかつ真空蒸着層３
に強力に接着する樹脂材料を主体とした塗料を使用した
硬化膜４とを順に積層形成して成る真空蒸着を施した合
成樹脂製製品。1. Paints such as urethane resin, epoxy resin, or acrylic resin are used on the surface of the substrate 1, which is a synthetic resin product such as acrylic resin, butadiene, and styrene copolymer resin, polypropylene resin, and ureaphenol resin. a vacuum-deposited undercoat 2 made of a metal such as aluminum or gold;
A vacuum-deposited synthetic resin product made by sequentially laminating a cured film 4 using a paint mainly made of a resin material that strongly adheres to the surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49126702A JPS5851821B2 (en) | 1974-11-02 | 1974-11-02 | Synthetic resin products subjected to vacuum deposition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49126702A JPS5851821B2 (en) | 1974-11-02 | 1974-11-02 | Synthetic resin products subjected to vacuum deposition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5152474A JPS5152474A (en) | 1976-05-10 |
| JPS5851821B2 true JPS5851821B2 (en) | 1983-11-18 |
Family
ID=14941722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP49126702A Expired JPS5851821B2 (en) | 1974-11-02 | 1974-11-02 | Synthetic resin products subjected to vacuum deposition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5851821B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0120925B2 (en) * | 1983-04-29 | 1989-04-19 | Orii Kk | |
| JPH0137769Y2 (en) * | 1984-06-14 | 1989-11-14 | ||
| JPH0545332B2 (en) * | 1984-05-22 | 1993-07-08 | Aida Eng Ltd |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5177635A (en) * | 1974-12-28 | 1976-07-06 | Kansai Paint Co Ltd | TOSOKOKAHOHO |
| JPS5479786A (en) * | 1977-12-06 | 1979-06-26 | Yoshino Kogyosho Co Ltd | Wall structure of container made of synthetic resin and copyyprinted |
| JPS5610450A (en) * | 1979-07-05 | 1981-02-02 | Teijin Ltd | Transparent conductive film |
| JPS5635706U (en) * | 1979-08-27 | 1981-04-07 | ||
| JPS58138737A (en) * | 1982-02-10 | 1983-08-17 | Honshu Paper Co Ltd | Manufacture of metallized plastic film |
| JPS59105030A (en) * | 1982-12-09 | 1984-06-18 | Dainippon Printing Co Ltd | Metallic foil decorating of plastic molding |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4843069A (en) * | 1971-09-28 | 1973-06-22 | ||
| JPS4860131A (en) * | 1971-11-30 | 1973-08-23 | ||
| JPS4927023A (en) * | 1972-07-11 | 1974-03-11 |
-
1974
- 1974-11-02 JP JP49126702A patent/JPS5851821B2/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4843069A (en) * | 1971-09-28 | 1973-06-22 | ||
| JPS4860131A (en) * | 1971-11-30 | 1973-08-23 | ||
| JPS4927023A (en) * | 1972-07-11 | 1974-03-11 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0120925B2 (en) * | 1983-04-29 | 1989-04-19 | Orii Kk | |
| JPH0545332B2 (en) * | 1984-05-22 | 1993-07-08 | Aida Eng Ltd | |
| JPH0137769Y2 (en) * | 1984-06-14 | 1989-11-14 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5152474A (en) | 1976-05-10 |
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