JPS5832685A - Ｃ↓４‐又はｃ↓５‐酸化水素混合物から共役ジオレフインを収得する方法 - Google Patents
Ｃ↓４‐又はｃ↓５‐酸化水素混合物から共役ジオレフインを収得する方法Info
- Publication number
- JPS5832685A JPS5832685A JP57078499A JP7849982A JPS5832685A JP S5832685 A JPS5832685 A JP S5832685A JP 57078499 A JP57078499 A JP 57078499A JP 7849982 A JP7849982 A JP 7849982A JP S5832685 A JPS5832685 A JP S5832685A
- Authority
- JP
- Japan
- Prior art keywords
- solvent
- thin film
- regenerated
- evaporation zone
- film evaporation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 238000001704 evaporation Methods 0.000 claims abstract description 31
- 230000008020 evaporation Effects 0.000 claims abstract description 31
- 238000000895 extractive distillation Methods 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
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- 239000012535 impurity Substances 0.000 claims abstract description 15
- 238000009835 boiling Methods 0.000 claims abstract description 14
- 238000000746 purification Methods 0.000 claims abstract description 4
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- 230000008929 regeneration Effects 0.000 claims description 10
- 238000011069 regeneration method Methods 0.000 claims description 10
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- 239000003085 diluting agent Substances 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
- SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
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- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- SUAKHGWARZSWIH-UHFFFAOYSA-N N,N‐diethylformamide Chemical compound CCN(CC)C=O SUAKHGWARZSWIH-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
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- 150000001412 amines Chemical class 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
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- 230000003247 decreasing effect Effects 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
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- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
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- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- GDHRQDYGUDOEIZ-UHFFFAOYSA-N n,n,2-trimethylpropan-1-amine Chemical compound CC(C)CN(C)C GDHRQDYGUDOEIZ-UHFFFAOYSA-N 0.000 description 1
- AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- TWSRVQVEYJNFKQ-UHFFFAOYSA-N pentyl propanoate Chemical compound CCCCCOC(=O)CC TWSRVQVEYJNFKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003139 primary aliphatic amines Chemical class 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical group CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- NUMQCACRALPSHD-UHFFFAOYSA-N tert-butyl ethyl ether Chemical compound CCOC(C)(C)C NUMQCACRALPSHD-UHFFFAOYSA-N 0.000 description 1
- 150000003510 tertiary aliphatic amines Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/40—Extractive distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/04—Purification; Separation; Use of additives by distillation
- C07C7/05—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds
- C07C7/08—Purification; Separation; Use of additives by distillation with the aid of auxiliary compounds by extractive distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3119540.7 | 1981-05-16 | ||
| DE19813119540 DE3119540A1 (de) | 1981-05-16 | 1981-05-16 | Verfahren zur gewinnung eines konjugierten diolefinsaus einem c(pfeil abwaerts)4(pfeil abwaerts)- oder c(pfeil abwaerts)5(pfeil abwaerts)-kohlenwasserstoffgemisch |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5832685A true JPS5832685A (ja) | 1983-02-25 |
| JPH0245672B2 JPH0245672B2 (enExample) | 1990-10-11 |
Family
ID=6132492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57078499A Granted JPS5832685A (ja) | 1981-05-16 | 1982-05-12 | Ｃ↓４‐又はｃ↓５‐酸化水素混合物から共役ジオレフインを収得する方法 |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0065194B1 (enExample) |
| JP (1) | JPS5832685A (enExample) |
| AT (1) | ATE9683T1 (enExample) |
| CA (1) | CA1182774A (enExample) |
| DE (2) | DE3119540A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6191302U (enExample) * | 1984-11-20 | 1986-06-13 | ||
| WO1998040448A1 (fr) * | 1997-03-11 | 1998-09-17 | Nippon Zeon Co., Ltd. | Procede de preparation de diene conjugue purifie |
| WO2003031377A1 (en) * | 2001-09-28 | 2003-04-17 | Nippon Zeon Co., Ltd. | Method of separating/purifying conjugated diene and separation/purification apparatus |
| JP2008535914A (ja) * | 2005-04-13 | 2008-09-04 | エクイスター ケミカルズ、 エルピー | ブタジエンの溶媒抽出 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3710434A1 (de) * | 1987-03-28 | 1988-10-06 | Basf Ag | Verfahren zur gewinnung von 1,3-butadien |
| DE4131938A1 (de) * | 1991-09-25 | 1993-04-01 | Krupp Koppers Gmbh | Verfahren zur aufarbeitung des sumpfproduktes einer extraktivdestillation zur gewinnung reiner kohlenwasserstoffe |
| ITTV20130045A1 (it) | 2013-04-09 | 2014-10-10 | Northwave Srl | Dispositivo di serraggio |
| PL248159B1 (pl) * | 2023-06-12 | 2025-10-27 | Siec Badawcza Lukasiewicz Inst Chemii Przemyslowej Imienia Profesora Ignacego Moscickiego | Sposób regeneracji rozpuszczalnika stosowanego w destylacji ekstrakcyjnej mieszanin węglowodorów nienasyconych C4 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50131863A (enExample) * | 1974-03-29 | 1975-10-18 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3000794A (en) * | 1958-05-19 | 1961-09-19 | Petro Tex Chem Corp | Extractive distillation of vinyl acetylene in the purification of butadiene |
| DE1443987A1 (de) * | 1962-05-08 | 1969-03-20 | Harpener Bergbau Ag | Extraktiv-Destillation |
-
1981
- 1981-05-16 DE DE19813119540 patent/DE3119540A1/de not_active Withdrawn
-
1982
- 1982-05-05 AT AT82103839T patent/ATE9683T1/de not_active IP Right Cessation
- 1982-05-05 EP EP82103839A patent/EP0065194B1/de not_active Expired
- 1982-05-05 DE DE8282103839T patent/DE3260874D1/de not_active Expired
- 1982-05-05 CA CA000402343A patent/CA1182774A/en not_active Expired
- 1982-05-12 JP JP57078499A patent/JPS5832685A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50131863A (enExample) * | 1974-03-29 | 1975-10-18 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6191302U (enExample) * | 1984-11-20 | 1986-06-13 | ||
| WO1998040448A1 (fr) * | 1997-03-11 | 1998-09-17 | Nippon Zeon Co., Ltd. | Procede de preparation de diene conjugue purifie |
| US6395953B1 (en) | 1997-03-11 | 2002-05-28 | Nippon Zeon Co., Ltd. | Process for preparing purified conjugated diene |
| WO2003031377A1 (en) * | 2001-09-28 | 2003-04-17 | Nippon Zeon Co., Ltd. | Method of separating/purifying conjugated diene and separation/purification apparatus |
| JP2008535914A (ja) * | 2005-04-13 | 2008-09-04 | エクイスター ケミカルズ、 エルピー | ブタジエンの溶媒抽出 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0065194A1 (de) | 1982-11-24 |
| EP0065194B1 (de) | 1984-10-03 |
| DE3260874D1 (en) | 1984-11-08 |
| DE3119540A1 (de) | 1982-12-02 |
| ATE9683T1 (de) | 1984-10-15 |
| CA1182774A (en) | 1985-02-19 |
| JPH0245672B2 (enExample) | 1990-10-11 |
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