JPS5831031A - Production of steel pipe having high strength and toughness - Google Patents
Production of steel pipe having high strength and toughnessInfo
- Publication number
- JPS5831031A JPS5831031A JP12840981A JP12840981A JPS5831031A JP S5831031 A JPS5831031 A JP S5831031A JP 12840981 A JP12840981 A JP 12840981A JP 12840981 A JP12840981 A JP 12840981A JP S5831031 A JPS5831031 A JP S5831031A
- Authority
- JP
- Japan
- Prior art keywords
- steel pipe
- pipe
- toughness
- steel
- strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 32
- 239000010959 steel Substances 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 19
- 229910000851 Alloy steel Inorganic materials 0.000 claims abstract description 7
- 238000005496 tempering Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 abstract description 17
- 229910001566 austenite Inorganic materials 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 229910000734 martensite Inorganic materials 0.000 abstract description 3
- 229910001563 bainite Inorganic materials 0.000 abstract description 2
- 229910000859 α-Fe Inorganic materials 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- 230000000717 retained effect Effects 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 description 7
- 230000009466 transformation Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 235000014653 Carica parviflora Nutrition 0.000 description 1
- 241000243321 Cnidaria Species 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000017105 transposition Effects 0.000 description 1
- 238000009785 tube rolling Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は強度と靭性のすぐれた鋼管の調造法に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for preparing steel pipes with excellent strength and toughness.
流体物の輸送用あるいは橋や高層ビルのaiis用及び
構造物用として使用される鋼管は強度と靭性のすぐれ几
性質が!求きれる。これまで強靭性のすぐれた鋼管は鋼
KNi、Or、No等の強靭性向上元素を微量添加した
低合金鋼管が多く使用されている。しかしながらその鋼
管は成管材をムcs変聰点以上oais度に加熱して急
冷する篩λmMを施して強度を付与した後、Ac1変履
点以下のil&に再加熱して冷却するmJi!L処mを
施して靭性を付与する調質処理法でmnされているため
高温度に曝される時間が長く、シタがって硬質組織から
軟質組織に調質するため靭性が過剰に改善され強度と靭
性のアンバランスな性質が得られる仁と及び鋳戻し処理
を行うため、生産性の低下をもたらすことと、エネルギ
ー消費が大きいことから生産コストの増大をよぎなくす
る問題があつ九0強度低下の問題は一般に強化元素の多
量添加で解決されている。Steel pipes used for transporting fluids, AIIS for bridges and high-rise buildings, and structures have excellent strength and toughness! I can ask for it. Until now, many steel pipes with excellent toughness have been used as low-alloy steel pipes to which trace amounts of toughness-improving elements such as steel KNi, Or, and No are added. However, the steel pipe is made by heating the pipe material to a degree of oais above the mcs transformation point, applying a sieve λmM to rapidly cool it to give it strength, and then reheating and cooling it to il& below the AC1 transformation point. Since the material is subjected to L treatment to impart toughness, it is exposed to high temperatures for a long time, and the toughness is excessively improved as the material undergoes heat treatment from a hard structure to a soft structure. 90-strength steel has unbalanced properties of strength and toughness, and because of the back-casting process, it causes a decrease in productivity and increases production costs due to large energy consumption. The problem of deterioration is generally solved by adding large amounts of reinforcing elements.
本発明は焼戻し処理によらない強度と靭性のすぐれた鋼
管の製造法を提供すること1に目的とする4ので、その
要旨はO@q:0−26〜0・45%の低合金鋼片を熟
間成管加工するかあるいは熱間圧延後冷関尻管加工した
後、温度880〜10500に加熱して空冷以上の急速
冷却をその冷却途中まで行い。The purpose of the present invention is to provide a method for manufacturing steel pipes with excellent strength and toughness that does not involve tempering treatment. After being processed into a mature tube or hot rolled and then processed into a cold tube, it is heated to a temperature of 880 to 10,500 and rapidly cooled at a rate higher than air cooling until the middle of cooling.
続いて鋼管自己保有熱で焼戻し処理する強度と靭性のす
ぐれた鋼管の製造法である。This is followed by a method of manufacturing steel pipes with excellent strength and toughness, in which the steel pipes are tempered using their own heat.
以下本発明につhてさらに詳細に説明する。The present invention will be explained in more detail below.
先ず、転炉、電気炉等の溶解炉で溶製され九溶鋼を連続
鋳造法%あるいは造塊1分塊法によってOeQ : O
−26〜0.451Gの低合金鋼片を製造スル。First, molten steel is melted in a melting furnace such as a converter or an electric furnace, and then converted to OeQ: O by continuous casting method or ingot making method.
- Manufacture of low alloy steel slabs of 26~0.451G.
0−E1+は次なる青で算出″#−1’4.−る一鋼の
溶接−性−5強度。0-E1+ is calculated by the following blue "#-1'4.-Weldability of steel-5 strength.
靭性に影響を及ぼすもので本発明に於ては降伏強度、最
高硬さ、及び溶接性からその範囲を限定した。It affects toughness, and in the present invention, its range is limited based on yield strength, maximum hardness, and weldability.
Mn Ov Ni Ou M
o VOeq=O+ /6+ イ、+ イ、+
/、+ /十/(qII)すなわち表2の実施例に
示すように@ Oe噸が0.269G未満では、焼入ま
ま材の降伏強度が得られず、0.4516e越えると鋼
管O最高硬さ及び溶接性の低下をもたらす欠点が発生す
る。Mn Ov Ni Ou M
o VOeq=O+ /6+ I, + I, +
/, + /ten/(qII) That is, as shown in the example in Table 2, if @Oe噸 is less than 0.269G, the yield strength of the as-quenched material cannot be obtained, and if it exceeds 0.4516e, the steel pipe O maximum hardness However, disadvantages occur that result in a decrease in the weldability and weldability.
また本発明において低合金鋼片の成分組IItは特に限
定するものではないが、目的とする性質が安定して得ら
れる理由から、好ましいのFiO:0.04〜0−18
5b s St : 0−01〜ロー5 参# him
: 04〜2.0%、P : 0.025優以下、
S:0.020チ以下。Further, in the present invention, the composition IIt of the low-alloy steel slab is not particularly limited, but it is preferably FiO: 0.04 to 0-18 because the desired properties can be stably obtained.
5b s St: 0-01~low 5 ref #him
: 04-2.0%, P: 0.025 or less,
S: 0.020 inch or less.
N:0.010%以下、 ht : o、を僑以下ある
いはさらに必要に応じてOe : 0−0010 ”
0−070 憾+0慕 : 0・007〜0.070
憾 、 Nb : 0.01〜0.1011
、 Cu : 0.05〜0−5 0憾 、
Nl : 0.0 5〜3.0% 、Or :0
.05〜!−01,Mo:+1−05〜o、sl。N: 0.010% or less, Ht: O, Oe: 0-0010 or more as required.
0-070 Regret + 0 Admiration: 0.007~0.070
Sorry, Nb: 0.01~0.1011
, Cu: 0.05~0-50,
Nl: 0.0 5-3.0%, Or: 0
.. 05~! -01, Mo: +1-05~o, sl.
Tt ! 0.005〜0.(150% 、V
: 0−010〜0−10饅−のIll叉社2種以上
−を−添加することができる。Tt! 0.005~0. (150%, V
: Two or more types of 0-010 to 0-10 types can be added.
鋼片を熱関数管加工あるいは板状に熱間圧延したl!、
曲げまたは捩りにより冷開成管加工して管状に成形した
4!、 11度880〜1050℃に加熱する。この加
熱は成管材に強度を付与する焼入温度で880℃未満で
はオーステナイト結晶粒の整粒化が不十分となシ均質な
材質特性が得られないことから880℃以上とした。こ
の加熱に於ては熱間或管終了後Ar&変態点以下の温度
まで冷却後。A steel billet processed into a thermofunction tube or hot rolled into a plate shape! ,
Formed into a tubular shape by cold-opening by bending or twisting 4! , Heat to 11 degrees 880-1050℃. This heating was carried out at a quenching temperature that imparts strength to the tube-forming material, and was set at 880°C or higher because if it was lower than 880°C, the austenite crystal grains would not be sufficiently sized and homogeneous material properties could not be obtained. In this heating, after heating or after cooling to a temperature below the Ar & transformation point.
直ちに加熱しても曳い。但しこの場合のAr1変態点は
6016以上のα変態量を有する温度とする。Cannot be pulled even if heated immediately. However, the Ar1 transformation point in this case is a temperature at which the amount of α transformation is 6016 or more.
′tたl (150Cを越えてはオーステナイト結晶粒
が粗大化し粗大なマルテンサイト、ベーナイト及びフェ
ライト組織を形成して焼入後aemな性質となる。(If the temperature exceeds 150C, the austenite crystal grains become coarse, forming coarse martensite, bainite, and ferrite structures, resulting in aem properties after quenching.
このような焼入温度に加熱された管材は直ちに空冷以上
O遮い冷却速度でその冷却途中まで冷却することによっ
て強度を付与し続いて鋼管自体が保有する熱、すなわち
鋼管自己保有熱で焼戻され降伏強度と靭性が付与される
。The pipe material heated to such a quenching temperature is immediately cooled by air-cooling or more at a cooling rate that is shielded with O to give it strength, and then tempered using the heat possessed by the steel pipe itself, that is, the heat possessed by the steel pipe itself. and imparts yield strength and toughness.
急速冷却の停止温度、すなわち鋼管自己保有熱による蝿
戻しiit:は強化元素の含有量、鋼管の肉厚、急速冷
却前の温度、急速冷却速度等諸条件によって決められる
がa変yao*張により発生する転移が消滅するかある
いは析出する炭化物によp固定されることによp降伏強
度の上昇が計れる150〜500℃で行うことが好まし
い、このようにして得られる鋼管は焼入温度からの急速
冷却過程でオーステナイトからマルテンサイト、4−ナ
イト及び細粒7エライトが現出して強度が付与され、さ
らに焼戻し処理により降伏強度と靭性が付与される。The stop temperature of rapid cooling, i.e., the return temperature due to the steel pipe's own heat, is determined by various conditions such as the content of reinforcing elements, the wall thickness of the steel pipe, the temperature before rapid cooling, and the rapid cooling rate. It is preferable to carry out the process at a temperature of 150 to 500°C, where the p-yield strength increases due to the disappearance of the generated dislocations or p-fixation by precipitated carbides. In the rapid cooling process, martensite, 4-nite, and fine-grained 7-erite appear from austenite, imparting strength, and further, yield strength and toughness are imparted by tempering.
以下本発明の実施例について説明する。Examples of the present invention will be described below.
表1に実施例供試鋼の化学成分を示す、供試鋼tt記号
A−z6人1〜ムSの31チヤージであり。Table 1 shows the chemical composition of the sample steel of the example, and the sample steel has a tt symbol A-z 6 people 1 to 31 charges.
本発明に骸幽する成分系はそのうち20チヤージである
。A−Zは実験室溶解材を板圧嬌して供試材としたもの
でありOu −N’b系をペース成分としてO、Mn、
Nl 、 Or 、 V の壺種組合せによりC@篭
を種々変化させ九ものである0人1〜人5については一
8i −Mu −Nb $ t’ベースに−Q 、 O
u 。The component system that is essential to the present invention is 20 charges. A-Z is a test material made by compressing laboratory melted material into a plate, and O, Mn,
By changing the C@ basket in various ways depending on the pot type combination of Nl, Or, V, for nine people 0 person 1 to person 5, -Q, O based on 18i -Mu -Nb $ t'
u.
Ni、Mo、V、4D各檀組合せにより継目無し鋼管材
として製造したものである。It is manufactured as a seamless steel pipe material using a combination of Ni, Mo, V, and 4D wood.
表2に処理条件と機械的性質を示す。Table 2 shows the processing conditions and mechanical properties.
焼入ま\材の引張強さはC・Sの増加と共に上昇するが
降伏強度に於1はOeqが0・26憾を境にしてそれ以
上になると急激に低下するか、わるいLOe睡が増加し
ても降伏強[F!上昇せず高強寂材の製造が降伏強度の
面から困難であることを知見した。The tensile strength of quenched materials increases with the increase in C and S, but the yield strength decreases rapidly when the Oeq reaches 0.26 or more, or the poor LOe increases. Even if it is strong [F! It was found that it is difficult to produce high-strength timber without increasing yield strength.
又0@qが0・3496以上になると降伏強rも再び上
昇するがこの降伏強度の上昇する0・(は急速冷却速度
によりJ%ることがわかった。いずれにしろ現行O調質
(情入−焼戻し)処理材及び本発明による鋼管自己保有
熱による焼戻し材に比べ靭性及び降伏強度の面で焼入ま
\材は劣ること力;明らt≧である。Furthermore, when 0@q becomes 0.3496 or more, the yield strength r increases again, but it was found that this increase in yield strength 0. It is clear that the quenched material is inferior in toughness and yield strength to the treated material and the material tempered by self-retained heat of the steel pipe according to the present invention; it is clear that t≧.
本発明に骸轟する熱処理法によればOeqの増加と共に
引張強さ、#伏強度共に上昇し、現行の焼入−焼戻し処
理材に比べ高強度でかつ靭性レベルもP1y同等の横様
的性質を有している。According to the heat treatment method described in the present invention, both tensile strength and #deflection strength increase as the Oeq increases, and the strength is higher than that of the current quenched-tempered material, and the toughness level is also the same as that of P1y. have.
Oeqが0.31の供試材2に於てはオーステナイト化
温度が高く本発WilKは#当しないものであるが靭性
の劣化が着るしい。In sample material 2 with an Oeq of 0.31, the austenitization temperature is high and the WilK produced by the present invention does not correspond to #, but the toughness seems to deteriorate.
以上説明したように本発明は熱関数管加工するかあるい
は熱関圧延彼冷関成管加工した後、 il&880〜1
osocに加熱して空冷以上の急速冷却をその冷却途中
まで行い、続いて鋼管自己保有熱で焼戻し旭理を行うた
め1通常の関質熟珊(焼入−焼戻し)に比べ大巾1に生
産性の向上を計ることが出来ると同時に焼戻し島理によ
るエネルギーを必要とせず、#!造;ストO著るしい低
下を計り得ることを可能にするものであシ従来法では予
測し得ない新規性を有するものである。As explained above, in the present invention, after processing the thermofunction tube or hot rolling and cold tube forming,
It is heated to osoc and rapidly cooled faster than air cooling until halfway through the cooling process, and then tempered using the heat possessed by the steel pipe, resulting in a product with a width of 1 compared to normal mature coral (quenched-tempered). At the same time, it does not require energy due to tempering process, and #! It is a novel method that could not be predicted by conventional methods, as it makes it possible to measure a significant reduction in the structural and industrial stress O.
特許庁長官 殿
1.事件の表示
特願昭56=第128409 号
2、発明の名称キ1クド ジ″′イ
強度と靭性のすぐれた鋼管の製造法
3、補正をする者
事件との関係 出 願人
住所(居所) 東京都千代田区大手町2丁目6番3号8
6補正の内容 別紙の通り
補 正 の 内 容
il+ 本願特許請求のllB5囲なT1の通り訂正
する。Commissioner of the Patent Office, 1. Indication of the case Japanese Patent Application No. 128409 No. 128409 2, Name of the invention 3. Process for manufacturing steel pipes with excellent strength and toughness 3. Person making the amendment Relationship to the case Applicant's address (residence) ) 2-6-3-8 Otemachi, Chiyoda-ku, Tokyo
6. Contents of the amendments The contents of the amendments are as per the attached sheet.il+ Corrections are made as per T1 in 11B5 of the patent claim of the present application.
r(11Cep O,26〜0.45%の低合金鋼片
を熱間製管加工するかあるいは熱間圧延後冷関製管加喝
−−−―−−−−−
エした後、温度880〜1050℃に加熱して空冷以上
の急速冷却をその冷却途中まで行い、続いて囁管自己保
有熱で焼戻し処理することな特徴とする強度と靭性のす
ぐれた鋼管の製造法。」(2)明細書オ1N20行、矛
2頁16行、17行。r(11Cep O, 26~0.45%) A low alloy steel billet is subjected to hot tube forming or after hot rolling and cold tube forming process, the temperature is 880℃. A method for manufacturing steel pipes with excellent strength and toughness, which is characterized by heating the pipe to ~1050°C, performing rapid cooling faster than air cooling until halfway through the cooling process, and then tempering the pipe using the tube's own heat.'' (2) Specification page 1N, line 20, page 2, lines 16 and 17.
オ4頁6行、7行、9行、 13行#オフ頁9行、10
行の「成管」を夫々「製管」と訂正する。Off page 4 lines 6, 7, 9, 13 lines #Off page 9 lines, 10
Correct "pipe making" in the lines to "pipe making" respectively.
(3)同1’3’liS行、オ8秦末行、と訂正する。(3) Corrected as 1'3'liS line, O8 end of Qin line.
(4)同士5119行「転移」を「転位」と訂正する。(4) Correct "transfer" to "transposition" in line 5119.
Claims (1)
片を熱間成管加工するかあるいは熱関圧延後冷間成管加
工した後、iI度880〜10501Cに加熱して空冷
以上の急速冷却をその冷却途中まで行い。 続いて鋼管自己保有熱で焼戻し処理することを特徴とす
る強度と靭性のすぐれた鋼#gの製造法。(1) A low alloy steel billet with an Oeq of O-26 to 0.4511 is hot-formed or hot-rolled and then cold-formed, then heated to an iI degree of 880 to 10,501C and rapidly cooled more than air-cooled. Cooling is performed halfway through the cooling process. A method for producing steel #g with excellent strength and toughness, which is characterized by subsequently tempering the steel pipe using its own heat.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12840981A JPS5831031A (en) | 1981-08-17 | 1981-08-17 | Production of steel pipe having high strength and toughness |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12840981A JPS5831031A (en) | 1981-08-17 | 1981-08-17 | Production of steel pipe having high strength and toughness |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5831031A true JPS5831031A (en) | 1983-02-23 |
Family
ID=14984061
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12840981A Pending JPS5831031A (en) | 1981-08-17 | 1981-08-17 | Production of steel pipe having high strength and toughness |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5831031A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2636549A1 (en) * | 1988-09-16 | 1990-03-23 | Voest Alpine Stahl Donawitz | PROCESS FOR MANUFACTURING SPIRE WINDING TUBES |
WO2002101098A1 (en) * | 2000-03-01 | 2002-12-19 | Komatsu Ltd. | Crawler bushing and method and device for producing the same |
US7306684B2 (en) | 2000-03-01 | 2007-12-11 | Komatsu Ltd | Crawler bushing and method and device for producing the same |
US7387694B2 (en) * | 2002-10-10 | 2008-06-17 | Rexroth Star Gmbh | Method of making a hardened steel part, especially a roll load-bearing steel part |
EP3006585A4 (en) * | 2013-05-31 | 2017-03-01 | Nippon Steel & Sumitomo Metal Corporation | Seamless steel pipe for line pipe used in sour environment |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5271329A (en) * | 1975-12-12 | 1977-06-14 | Nippon Steel Corp | Process for heat treatment of steel pipe or steel pipe welds |
-
1981
- 1981-08-17 JP JP12840981A patent/JPS5831031A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5271329A (en) * | 1975-12-12 | 1977-06-14 | Nippon Steel Corp | Process for heat treatment of steel pipe or steel pipe welds |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2636549A1 (en) * | 1988-09-16 | 1990-03-23 | Voest Alpine Stahl Donawitz | PROCESS FOR MANUFACTURING SPIRE WINDING TUBES |
WO2002101098A1 (en) * | 2000-03-01 | 2002-12-19 | Komatsu Ltd. | Crawler bushing and method and device for producing the same |
US7306684B2 (en) | 2000-03-01 | 2007-12-11 | Komatsu Ltd | Crawler bushing and method and device for producing the same |
US7282173B2 (en) | 2001-06-07 | 2007-10-16 | Komatsu Ltd. | Track bushing and method and apparatus for producing the same |
US7638005B2 (en) | 2001-06-07 | 2009-12-29 | Komatsu, Ltd. | Track bushing and method and apparatus for producing the same |
US7387694B2 (en) * | 2002-10-10 | 2008-06-17 | Rexroth Star Gmbh | Method of making a hardened steel part, especially a roll load-bearing steel part |
EP3006585A4 (en) * | 2013-05-31 | 2017-03-01 | Nippon Steel & Sumitomo Metal Corporation | Seamless steel pipe for line pipe used in sour environment |
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