JPS5828468A - Method of coating and forming abrasive material small piece to brush tool as metal tool and brush tool as metal tool manufactured through said method - Google Patents

Method of coating and forming abrasive material small piece to brush tool as metal tool and brush tool as metal tool manufactured through said method

Info

Publication number
JPS5828468A
JPS5828468A JP56172695A JP17269581A JPS5828468A JP S5828468 A JPS5828468 A JP S5828468A JP 56172695 A JP56172695 A JP 56172695A JP 17269581 A JP17269581 A JP 17269581A JP S5828468 A JPS5828468 A JP S5828468A
Authority
JP
Japan
Prior art keywords
brush
tool
brush tool
metal
abrasive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP56172695A
Other languages
Japanese (ja)
Other versions
JPH0158027B2 (en
Inventor
オズワルト・コツプ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KADEIA DEIAMANTO MASHIINEN UNT
Kadeia Deiamanto Mashiinen Unto Berukutsuoiku Fuaburiiku Ookotsupu Unto Co GmbH
Original Assignee
KADEIA DEIAMANTO MASHIINEN UNT
Kadeia Deiamanto Mashiinen Unto Berukutsuoiku Fuaburiiku Ookotsupu Unto Co GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KADEIA DEIAMANTO MASHIINEN UNT, Kadeia Deiamanto Mashiinen Unto Berukutsuoiku Fuaburiiku Ookotsupu Unto Co GmbH filed Critical KADEIA DEIAMANTO MASHIINEN UNT
Publication of JPS5828468A publication Critical patent/JPS5828468A/en
Publication of JPH0158027B2 publication Critical patent/JPH0158027B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1655Process features
    • C23C18/1662Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D13/00Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor
    • B24D13/02Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by their periphery
    • B24D13/10Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by their periphery comprising assemblies of brushes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/007Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent between different parts of an abrasive tool
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/04Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
    • B24D3/06Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1603Process or apparatus coating on selected surface areas
    • C23C18/1605Process or apparatus coating on selected surface areas by masking
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1803Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
    • C23C18/1824Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
    • C23C18/1827Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment only one step pretreatment
    • C23C18/1834Use of organic or inorganic compounds other than metals, e.g. activation, sensitisation with polymers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/32Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Brushes (AREA)

Abstract

1. Method for studding the free ends of the bristles of metallic brush tools with particles of grinding material, with which the tool is provided with a covering whilst these portions which shall studded with the grinding material particles, are left free, and subsequently the partially covered tool is dipped into a galavanic bath, into which the grinding material particles have been introduced, and further subsequently a layer of preferably hard metallic carrier material is deposited, whilst at least a plurality of grinding material particles is partially embedded onto said portions of tool, which had been left free, by electrolytic or currentless galvanic metal deposition, and in which further subsequently the cover from the corresponding portion of the tool is moved, wherein at least the bristle carrying brush tool portion is filled with non-conducting material by dipping it into a non-conducting material, which solidifies within a certain ambient temperature range and which at a higher temperature is liquid, preferably viscous, and that thereafter the cover is again removed from said ends of the bristles, which shall be studded with grinding material particles.

Description

【発明の詳細な説明】 本発明は、金属工具としての刷子工具に、ダイヤモンド
、窒化硼素粒子、鋼玉などの研磨材小片を被覆して設け
る方法及びこの方法によって製作された金属工具として
の刷子工具に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention provides a method for coating a brush tool as a metal tool with small pieces of abrasive material such as diamond, boron nitride particles, and corundum, and a brush tool as a metal tool manufactured by this method. It is related to.

被研磨物のパリ取り用、被研磨物の研磨用の刷子工具と
して、研磨材小片と結合材とからなる焼結グラインダー
が知られている。この焼結グライ/ダーに、これ金取り
付けるためのホルダー装置に装着されて、穿孔作業によ
って穿設された孔の周縁、局面のパリ取り、研磨などに
も使用されている。
A sintered grinder made of small pieces of abrasive material and a binder is known as a brush tool for deburring and polishing objects to be polished. This sintered glider/grider is attached to a holder device for attaching the metal, and is also used for deburring and polishing the periphery of the hole and the curved surface formed by the drilling operation.

ところで、孔の周縁、局面のパリ取りには、刷子工具の
方がはるかに有利である。微妙な箇所は、手持ち用のハ
ケブラシ等の刷子工具で行なった方が、パリ等を効率工
く取ることができるからである。その場合、研磨材小片
を被覆した刷子工具を用いることが好ましい、プラスチ
ックス製の刷子工具であって、その刷子尖端部に球状キ
ャップを設けた刷子工具は、DE−PS2518244
号においてずでに開示されている。
By the way, a brush tool is much more advantageous for removing burrs from the periphery of the hole and the curved surface. This is because it is more efficient to remove spots on sensitive areas using a brush tool such as a handheld brush. In that case, it is preferable to use a brush tool coated with small pieces of abrasive material, and the brush tool is made of plastic and has a spherical cap on the tip of the brush according to DE-PS2518244.
It is already disclosed in the issue.

この球状キャップは、研磨材小片を結合材でかためたも
ので、IWJ時に、この結合材は刷子工具の刷子尖端部
に研磨材小片の結合物からなる球状キャップを固足する
機能を有している。
This spherical cap is made by hardening small pieces of abrasive material with a binding material, and during IWJ, this binding material has the function of fixing the spherical cap made of a combination of small pieces of abrasive material to the tip of the brush of the brush tool. ing.

この刷子工具は、軟弱で、かつ、研磨材片を結合材でか
丸めた球状キャップが刷子尖端部に較べて相対的に大き
なものとなり個々の刷子の尖端部が不安定となるという
効果を有する。また、刷子の尖端部が折れ易い。この球
状キャップは、刷子工具の刷子尖端部の個数も、球状キ
ャッグの大きさに制約されて比較的少ない本のとなり、
普通の刷子を利用することは不可能で特別製のものが必
要である。
This brush tool is soft and has the effect that the spherical cap made of abrasive pieces rolled up with a binding material is relatively large compared to the tip of the brush, making the tip of each brush unstable. . Moreover, the tip of the brush is easily broken. With this spherical cap, the number of brush tip parts of the brush tool is also limited by the size of the spherical cap, resulting in a relatively small number of brush tips.
It is not possible to use a regular brush; a specially made brush is required.

本発明の目的は、金属工具の広い表面でも、普通の金属
製刷子工具の刷子の尖端部でも、同時に適用できて、金
属工具としての刷子尖端部に研磨材小片を被覆して設け
る方法及びその方法によって製作された金属工具として
の刷子工具を提供するものである。
The object of the present invention is to provide a method for coating the tip of a brush as a metal tool with small abrasive particles, which can be applied simultaneously to a wide surface of a metal tool and to the tip of a brush of a common metal brush tool. The present invention provides a brush tool as a metal tool manufactured by the method.

この方法の特徴は、金属工具としての刷子工具に、ダイ
ヤモンド、窒化硼素粒子、鋼玉などの研磨材小片を被覆
して設ける方法において、研磨材小片で被覆されるべき
部分を除いて刷子工具に被覆を施し、この様に部分的に
被覆された刷子工具を、研磨材小片を含んだメッキ浴の
中に浸漬して、ニッケル、クローム等の硬質の金属担材
層を、少なくとも多数の研磨材小片を部分的に埋め込み
ながらこの刷子工具の被覆されていない部分に、電気メ
ッキ、無電解メッキ等のメッキによって設け、この刷子
工具の被覆部分をその後除去するようにしたことにある
The feature of this method is that the brush tool, which is a metal tool, is coated with small pieces of abrasive material such as diamond, boron nitride particles, and corundum. The brush tool partially coated in this way is immersed in a plating bath containing abrasive particles to coat a layer of a hard metal carrier such as nickel or chrome with at least a large number of abrasive particles. The coating is provided on the uncovered portion of the brush tool by plating such as electroplating or electroless plating while partially embedding the brush tool, and the coated portion of the brush tool is then removed.

本発明の方法によれば、金属工具に、ダイヤモンド、窒
化硼素粉末、鋼玉などの研磨材小片を被覆して設けるこ
とができ、この研磨材小片は、金属工具の適当な部分で
あって、がっ、硬質性金属からなる金属組材層中に取り
込まれて固定されると共に、研磨材小片の一部はこの金
属組材層中から突出して研磨材として機能するものであ
る。このようにして、研磨材が被覆して設けられている
金属工具は、非常に耐久寿命が長く、かつ、従来の刷子
工具と較べてはるかに優れている。それは、研磨材小片
が結合材あるいは接着材によって刷子工具に取り付けら
れたものではなく、研磨材小片がメッキによって形成さ
れた金属組材層中に埋設されているからである。これに
加えて、金属組材層中からは、研磨をするに十分な個数
の研磨材小片の一部が突出しており、この突出部は研磨
に支障を来たさない程度に十分な広さの面積と、稜角と
全盲するからである。本発明の方法による他の利点は、
刷子工具の刷子尖端部に、研磨材小片から構成された比
較的小さなキャップを設けることが可能である。
According to the method of the present invention, a metal tool can be coated with small pieces of abrasive material such as diamond, boron nitride powder, corundum, etc., and the small piece of abrasive material is a suitable part of the metal tool, First, the small abrasive pieces are taken into and fixed in the metal composite layer made of hard metal, and a portion of the abrasive particles protrude from the metal composite layer to function as an abrasive. Metal tools coated with abrasive material in this way have a very long service life and are far superior to conventional brush tools. This is because the abrasive pieces are not attached to the brush tool by a bonding material or adhesive, but are embedded in a metal assembly layer formed by plating. In addition, a sufficient number of small pieces of abrasive material protrude from the metal assembly layer, and this protrusion has a sufficient width so as not to interfere with polishing. This is because the area and angle of the ridge are completely blind. Other advantages of the method of the invention are:
It is possible to provide the brush tip of the brush tool with a relatively small cap consisting of a small piece of abrasive material.

金属工具としての刷子工具あるhは刷子工具の刷子の尖
端部に研磨材小片を被覆して設ける場合、刷子の尖端部
を備えてhる刷子工具部分をラッカー、ワックス、石膏
等の非導電性材料で完全に包囲し、次に、この刷子の尖
端sを適当な長さ、約1ないし2ミリ程flI出させる
ことが好ましい、この作業は、研磨用の刷子工具を使用
して行なうことができる。被覆されるべき刷子の尖端部
分をそのままにして被覆することは、非常に簡単にでき
る。
When a brush tool as a metal tool is provided with a small piece of abrasive material coated on the tip of the brush, the part of the brush tool with the tip of the brush is coated with a non-conductive material such as lacquer, wax, or plaster. It is preferable to surround the brush completely with the material and then extend the tip of the brush by a suitable length, about 1 to 2 mm. This can be done using an abrasive brush tool. can. It is very simple to coat the tip of the brush to be coated, leaving it intact.

有利な方法は、非導電性材料に、特定の温度範囲内で硬
化し、これから著しく逸脱する温度条件のもとて粘性化
するものを使用することである。この被覆作業は、刷子
工具を多数回浸漬し、非導電性材料を硬化することによ
って、非常に簡単に行なうことができる。非導電性材料
の被覆の除去は、刷子工具を適当な温度条件の本とで温
め、流動化した非導電性材料管刷子工具から適下させる
ことにより行なうものである。
An advantageous method is to use a non-conductive material that hardens within a certain temperature range and becomes viscous under temperature conditions significantly deviating from this. This coating operation can be carried out very simply by dipping the brush tool several times and curing the non-conductive material. Removal of the non-conductive material coating is accomplished by warming the brush tool to an appropriate temperature and dispensing fluidized non-conductive material from the brush tool.

本発明の詳細な構成は、以下の説明から明らかとなるで
あろう。
The detailed structure of the present invention will become clear from the following description.

第1図において、11#″tバリ取り用の刷子工具で、
このパリ取り用の刷子工具11には、金属刷子12が束
ねられてスパイラル状トサれ、工具回転軸15に取り付
けられている。この工具回転軸1!5fi、2本の金属
ワイヤーがひねシ合わされた構成とされており、その自
由端16は適当な駆動装置に取力付けうるようにされて
いる。
In Figure 1, with an 11#''t deburring brush tool,
In this brush tool 11 for deburring, metal brushes 12 are bundled together in a spiral shape and attached to a tool rotating shaft 15. The tool rotating shaft 1!5fi is constructed by twisting two metal wires together, and its free end 16 can be attached to a suitable drive device.

第3図に示すように、金属刷子12の各自由端18には
、各々キャップ19が設けられており、このキャップ1
9の厚さは金属刷子12の約2〜3倍とされている。キ
ャップ19は金属組材21としてのニッケルを有してお
り、この金属組材21には、研磨材小片としてのダイヤ
モ/)’粒子22の一部分が、この金Mffi材21か
ら突出するように埋設されている。ダイヤモ/ド粒子2
2全体の約2分の1から約5分の1が金属組材21から
突出するようにすることが好ましい、金属組材21の内
部には、多数の研磨材小片22が埋設されている。完全
に金属組材21に埋没している研磨材小片としてのダイ
ヤモンド22Fi、刷子工具11の使用によって金属組
材21が摩耗することによって露出する。
As shown in FIG. 3, each free end 18 of the metal brush 12 is provided with a cap 19.
The thickness of the metal brush 9 is about 2 to 3 times that of the metal brush 12. The cap 19 has nickel as a metal composite 21, and a portion of diamond/)' particles 22 as small pieces of abrasive material are embedded in the metal composite 21 so as to protrude from the gold Mffi material 21. has been done. Diamond/Do Particle 2
A large number of small abrasive pieces 22 are embedded inside the metal assembly 21, preferably about one-half to about one-fifth of the abrasive pieces 22 protruding from the metal assembly 21. The diamond 22Fi, which is a small abrasive piece completely buried in the metal assembly 21, is exposed when the metal assembly 21 is worn away by the use of the brush tool 11.

研磨材小片としてのダイヤモンド220粒度は使用目的
に応じて適宜選択すればよろしい。
The diamond 220 grain size of the abrasive particles may be appropriately selected depending on the purpose of use.

第2図に示されている、パリ取り用刷子工具26は、第
1図に示すものとは異なる構成のもので、その軸27に
は、弾性棒28が取り付けられている。この弾性棒28
Fi、軸27を取り囲むように分散配置され、この弾性
棒28の両端はソケッ)29.29’に取シ付けられて
いる。
The deburring brush tool 26 shown in FIG. 2 has a different configuration from that shown in FIG. 1, and has an elastic rod 28 attached to its shaft 27. This elastic rod 28
The elastic rods 28 are arranged in a distributed manner so as to surround the shaft 27, and both ends of the elastic rods 28 are attached to sockets 29 and 29'.

この弾性棒28は、ソケット29からソケット2?’に
向かって延びており、中央が膨らんだ樽形状とされてい
る。すなわち、この軸27からこの軸の半径方向に向か
う距離について考えてみると、この軸に沿って延びる弾
性棒28の各部分までの距離は、軸方向のどの距wiを
測定しても異なるものとされている。さらに、この弾性
棒26は、軸27の長手方向に対してややねじれ形状と
されている。
This elastic rod 28 is connected from the socket 29 to the socket 2? It extends toward ', and is said to be barrel-shaped with a bulging center. That is, if we consider the distance from this axis 27 in the radial direction of this axis, the distance to each part of the elastic rod 28 extending along this axis will be different no matter which distance wi in the axial direction is measured. It is said that Further, the elastic rod 26 is slightly twisted with respect to the longitudinal direction of the shaft 27.

符号Aで表示した範囲では、弾性棒28に研磨材小片2
2′としてのダイヤモンド粒子が被覆して設けられて−
るが、この場合にも、研磨材小片22′としてのダイヤ
モンド粒子は、金属組材21′としてのニッケルに部分
的に置設され、その約2分の1から5分の1が金属組材
21′から突出されている。
In the area indicated by the symbol A, the elastic rod 28 is covered with a small abrasive material 2.
Coated with diamond particles as 2'-
However, in this case as well, the diamond particles as the abrasive particles 22' are partially placed on the nickel as the metal assembly 21', and approximately one-half to one-fifth of the diamond particles are on the metal assembly 21'. It protrudes from 21'.

ここでは、この二つの刷子工具11.26の金属組材と
してニッケルが使用されているが、他の硬質金属、たと
えば、クロームを使用することもでき、また、これとは
全く別の軟質金属、友とえば、銅金属、亜鉛金属等を使
用できることもちろんである。なお、研磨材小片として
、ここでは、ダイヤモンド粒子22.22’  が使用
されているが、他のもの、たとえば、鋼玉、ナファイア
、ルビー等を使用するようにしてもよい。もちろん、第
2図に示されている刷子工具26の他に、広い研磨面積
を有する刷子工具に、金属組材を設け、この金属組材に
研磨材小片を埋設して被覆することもできる。
Here, nickel is used as the metal assembly of the two brush tools 11.26, but other hard metals, such as chrome, can also be used, or completely different soft metals, Of course, materials such as copper metal, zinc metal, etc. can be used. Although diamond particles 22, 22' are used here as the abrasive particles, other materials such as corundum, naphire, ruby, etc. may also be used. Of course, in addition to the brush tool 26 shown in FIG. 2, a brush tool having a large polishing area may be provided with a metal assembly, and the metal assembly may be covered with small pieces of abrasive material embedded therein.

刷子工具11の刷子12にキャップ19を設ける作業は
以下のごとく行なうのである。
The operation of attaching the cap 19 to the brush 12 of the brush tool 11 is performed as follows.

まず、刷子工具11の少くとも刷子12を有する部分を
完全に非導電性材料を用いて被覆する。すなわち、熱せ
られた状態では流動性があυ、かつ、特定の温度範囲で
は硬化するような非導電性材料を使用する。このような
非導電性材料として、たとえば、ワックスがある。ワッ
クスは、約40度C以下で硬化し、この温度を越えると
柔らかくなる。そして、ワックスは温度が200[C近
くになると、流動性を有するLうになる。このような、
流動状態を呈する非導電性材料中に、刷子工具の被覆し
ようとする部分を浸漬し、次にこれを取り出しつつ回転
させて余分に付着した非導電性材料を振り払う。
First, at least the portion of the brush tool 11 having the brush 12 is completely coated with a non-conductive material. That is, a non-conductive material is used that has fluidity when heated and hardens within a specific temperature range. An example of such a non-conductive material is wax. Wax hardens below about 40 degrees Celsius and softens above this temperature. When the temperature of the wax approaches 200C, the wax becomes fluid. like this,
The part of the brush tool to be coated is dipped into the flowing non-conductive material, and then removed and rotated to shake off excess non-conductive material.

刷子工具に付着している非導電性材料は、その後、冷却
して硬化する。この一連の作業、すなわち、刷子工具の
浸漬−刷子工具の取り出し一刷子工具の回転作業は、刷
子工具11の刷子12の取シ付は部分が、完全に被覆さ
れるまで繰返す。なお、非導電性材料として、ラッカー
、石膏等を利用できることもちろんである。
The non-conductive material adhering to the brush tool then cools and hardens. This series of operations, ie, immersion of the brush tool, removal of the brush tool, and rotation of the brush tool, is repeated until the attachment portion of the brush 12 of the brush tool 11 is completely covered. It goes without saying that lacquer, plaster, etc. can be used as the non-conductive material.

この作業が終了後、刷子工具11を回転台等に取り付け
て、その外周全普通の研磨刷子によって研磨し、刷子1
2の自由端部のうち約1′lkいし2ミリの長さにわた
って刷子12t−被覆している非導電性材料を除去する
。非導電性材料が除去された刷子12のこの尖端部分1
8に、キャップ1を金メッキに工って設ける。
After this work is completed, the brush tool 11 is attached to a rotary stand, etc., and the entire outer periphery of the brush tool 11 is polished with an ordinary polishing brush.
The non-conductive material covering the brush 12t is removed over a length of about 1'lk to 2 mm of the free end of the brush 12t. This point 1 of the brush 12 from which the non-conductive material has been removed
8, the cap 1 is plated with gold.

被覆が除去された刷子12の尖一部分18は、キャップ
19金メッキによって形成する前に、エツチング液中に
浸漬して尖端部分1a金エツチングし、この尖端部分1
Bを化学的に活性化し清浄にする。
The tip portion 18 of the brush 12 from which the coating has been removed is immersed in an etching solution to gold-etch the tip portion 1a before forming the cap 19 by gold plating.
Chemically activate and clean B.

この様に大部分が被覆され、尖端部分18のみが、約1
ないし2ミリの長さにわたって露出された金属刷子工具
11は、その後メッキ液に浸漬される。ここでは、この
メッキは、電気メッキによる方法を使用するが、無電解
メッキに工っでも行なうことができる。メッキ浴に浸漬
された金属刷子工具11は、一方の電極となってiる。
In this way, most of the area is covered, and only the tip portion 18 is covered by approximately 1
The exposed metal brush tool 11 over a length of 2 to 2 mm is then immersed in a plating solution. Here, electroplating is used for this plating, but electroless plating can also be used. The metal brush tool 11 immersed in the plating bath serves as one electrode.

他方の電極には、ニッケル材料が使用されてお夛、この
他方の電極を構成するニッケル材料は、通電することに
Lってメッキ液中に溶解され、一方の電極としての刷子
工具11には、その尖端部分18に、金属組材としての
ニッケルが析出し付着する。この時、尖端部18にニッ
ケル21が析出すると同時に、ダイヤモンド粒子22も
尖端部18に付着して、金属組材としてのニッケル中に
埋設される。
A nickel material is used for the other electrode, and the nickel material constituting the other electrode is dissolved in the plating solution when electricity is applied, and the brush tool 11 as one electrode is , nickel as a metal component precipitates and adheres to the tip portion 18 . At this time, at the same time as the nickel 21 is deposited on the tip 18, the diamond particles 22 also adhere to the tip 18 and are embedded in the nickel as the metal assembly.

研磨材としてのダイヤモンド粒子22が被覆して設けら
れた状態を示している第1図、第3図の刷子工具11に
おいて、刷子工具111i、たとえば5条溝状の支台に
載置されてメッキ浴中に浸漬され、完全にメッキ液中に
埋没される。
In the brush tool 11 shown in FIGS. 1 and 3, which shows the brush tool 11 coated with diamond particles 22 as an abrasive, the brush tool 111i is placed on a five-groove support for plating. It is immersed in the bath and completely submerged in the plating solution.

次に、刷子工具11の刷子12の上面に塗布される。そ
の後、メッキ液が活性化されて、金属組材21としての
ニッケルが刷子12の尖端部18上に析出され、このと
きダイヤモンド粉末の粒子も同時に埋設される。この作
業がある程度進行すると、今fは、刷子工具11を回転
させて刷子120反対面上にダイヤモンド粉末を塗布し
、しかる後、再び、メッキ液を活性化する。すると、ダ
イヤモンド粒子は、尖端部1Bにニッケルが析出するに
伴って、金属相材中に埋設される。
Next, it is applied to the upper surface of the brush 12 of the brush tool 11. Thereafter, the plating solution is activated, and nickel as the metal assembly 21 is deposited on the tip 18 of the brush 12, and at this time, the diamond powder particles are also embedded at the same time. After this work has progressed to a certain extent, the brush tool 11 is rotated to coat the opposite surface of the brush 120 with diamond powder, and then the plating solution is activated again. Then, the diamond particles are embedded in the metal phase material as nickel is precipitated at the tip portion 1B.

この状態では、ダイヤモンド粒子に、不完全な状態で尖
端部18に付着している。何故なら、ダイヤモンド粒子
に金属組材21中に比較的浅く埋設されているだけであ
るからである。ダイヤモンド粒子をさらに深く埋設させ
る丸めには、もう一度メツキを行なうべきである。ここ
では、最初のメッキ浴とは異なる第2のメッキ浴でメッ
キを行なうぶうにしているが、これには、電気メッキ、
あるいは無電解メッキによる方法を使用することができ
る。
In this state, the diamond particles are incompletely attached to the tip 18. This is because the diamond particles are only relatively shallowly embedded in the metal assembly 21. Rounds that embed diamond particles deeper should be plated again. Here, plating is performed in a second plating bath different from the first plating bath, which includes electroplating,
Alternatively, a method using electroless plating can be used.

この第2のメッキ浴においてメッキを行なうことにより
、刷子120表面に近い側のダイヤモンド粒子は完全に
金属相材中に埋設されるが、刷子120表面から遠い側
の粒子、すなわち、最も外側にあるダイヤモンド粒子は
、その粒子の約4分の1ないし5分の1が金属組材21
から露出するようにして埋設される。この作業に要する
時間は、メッキ液の条件によって変化する。この作業が
終了すると、ダイヤモンド粒子は金属組材21中に定着
され、ダイヤモンド粒子は研磨材として使用することが
でき、かつ、その使用寿命も長い。
By performing plating in this second plating bath, the diamond particles on the side closer to the surface of the brush 120 are completely embedded in the metal phase material, but the diamond particles on the side farther from the surface of the brush 120, that is, the outermost diamond particles are completely embedded in the metal phase material. Approximately one-fourth to one-fifth of the diamond particles are metal composites 21
It is buried so that it is exposed. The time required for this work varies depending on the conditions of the plating solution. When this operation is completed, the diamond particles are fixed in the metal assembly 21, and the diamond particles can be used as an abrasive and have a long service life.

中ヤッグ19がある程度の大きさを有し、かツ、キャッ
プ19の内部にはダイヤモンド粒子が存在し、仁のダイ
ヤモンド粒子はキャラ119が磨耗する過程において露
出され、研磨材として使用に供されることとなるので、
研磨材としてのダイヤモンド粒子の消耗がある程度防止
される。
The middle yag 19 has a certain size, and there are diamond particles inside the cap 19, and the core diamond particles are exposed during the process of wear of the yag 119 and are used as an abrasive. Because of this,
The consumption of diamond particles as an abrasive is prevented to some extent.

刷子12の尖端部18を、エッチフグして活性化し友後
、特殊なメッキ液に浸漬し、この刷子12の尖端部18
に金属組材21を薄層状に形成することもできる。iた
、ダイヤモンド粒子の完全なる埋設は、上述のような特
殊なメッキ浴を使用しなくとも行なうことができる。ダ
イヤモンドのような比較的安価な研磨材を使用する場合
には、研磨材小片としてのこのダイヤモンド粒子をプー
ル状のメッキ液中に設けておき、電気メッキの作業中に
刷子工具11の尖端部18をこのプール状のメッキ液中
に浸漬放置することが可能で、その場合メッキ作業にお
いて刷子工具11を回転させる必要はない。
The pointed end 18 of the brush 12 is activated by etching, and then immersed in a special plating solution.
The metal assembly 21 can also be formed in a thin layer. Additionally, complete embedding of diamond particles can be achieved without the use of a special plating bath as described above. When using a relatively inexpensive abrasive material such as diamond, diamond particles as abrasive particles are provided in a pool of plating solution, and the pointed end 18 of the brush tool 11 is used during the electroplating operation. can be left immersed in this pool-like plating solution, in which case there is no need to rotate the brush tool 11 during plating work.

刷子12の尖端部151fCそれぞれキャップ19を織
り付ける場合には、非導電性材料としてのワックス等の
被覆材は再び除去しなければならな一0H4子工具11
の所要部分は適尚な環境条件のもとで加熱して、ワック
スを流動化させ、これにより取“〕除く。
When weaving a cap 19 on each of the pointed ends 151fC of the brush 12, the covering material such as wax as a non-conductive material must be removed again.
The required portions of the wax are heated under suitable environmental conditions to fluidize the wax and thereby remove it.

第2図におめて示されている工JL24KTh%Aて、
組材中に埋設されている研磨材小片22′を被覆する作
業も同様である。第2図において、刷子工具26のAs
分のみに研磨材が設けられる。それゆえ、残余の部分に
は、たとえば、絶縁バンドを巻き付けてこの部分を被覆
する。つづいて、上記と同様の作業を行なう。す彦わち
、刷子工具をエツチングし、必要に応じて、ニッケルメ
ッキし、しかる後、メッキ浴によって、金属組材と研磨
材とを設ける。e後に、絶縁バンドを取り除く、この作
業においては、刷子工具26の軸270部分も不要に被
嶺されるが、他の部分の被覆作業も非常に簡単に行われ
る。
The engineering JL24KTh%A shown in Figure 2,
The same applies to the operation of covering the small pieces of abrasive material 22' embedded in the assembly. In FIG. 2, As of the brush tool 26
An abrasive material is provided only in the minute. Therefore, the remaining part is covered, for example by wrapping an insulating band around it. Next, perform the same operations as above. That is, the brush tool is etched and, if necessary, nickel plated, and then the metal assembly and abrasive material are provided in a plating bath. After e, the insulating band is removed. In this operation, the shaft 270 portion of the brush tool 26 is also unnecessarily covered, but the covering operation of other portions is also very easily performed.

この場合、刷子工具26の弾性棒28の必要部分のみに
研磨材22′を被覆し九−場合には、この部分を個別的
にメッキ液に浸漬することもできる。
In this case, if only a necessary portion of the elastic rod 28 of the brush tool 26 is coated with the abrasive material 22', this portion may be individually immersed in the plating solution.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の方法に係る第1実施例のパリ取り用刷
子工具の透視図。 第2図は本発明の方法に係る第2実施のパリ取り用刷子
工具の透視図であって、弾性棒付きのパリ取り用刷子工
具の透視図。 第3wA#i第1図に示されえ刷子工具の断面図と立面
図。 總4図はs2図に示された刷子工具の弾性棒部分の拡大
図。 11.26−−パリ取シ用刷子工具 11−−−−刷子 21−・−金属組材 22−−−−ダイヤモンド粒子 1g −−・尖端部 特許出願人 カディアーディアマント マシーネンークントペルクツ
オイ77アプリーク オー、 =ツプゲーエムペーハー
 クント コンパニー(ほか1名)
FIG. 1 is a perspective view of a first embodiment of a deburring brush tool according to the method of the present invention. FIG. 2 is a perspective view of a second embodiment of a deburring brush tool according to the method of the present invention, and is a perspective view of a deburring brush tool equipped with an elastic rod. 3rd wA#i Sectional and elevational views of the brush tool shown in FIG. 1. Figure 4 is an enlarged view of the elastic rod portion of the brush tool shown in Figure s2. 11.26--Brush tool for deburring 11--Brush 21--Metal assembly 22--Diamond particles 1g--Pointed part Patent applicant Kadia Diamant Maschinenkuntperkutuoi 77 Apric Oh, =Tsupgamepher Kunt Kompany (and 1 other person)

Claims (1)

【特許請求の範囲】 (1)  金属工具としての刷子工具に、ダイヤモンド
、窒化硼素粒子、鋼玉等の研磨材小片を被覆して設ける
方法において、 研磨材小片で被覆されるべき部分を除いて刷子工具に被
覆116L、この様に部分的に被覆された刷子工具を、
研磨材を含んだメッキ浴の中に浸漬し、ニッケル、クロ
ーム等の硬質の金属指材層を、少なくとも多数の研磨材
小片t一部分的に埋め込みながら、この刷子工具の被覆
されていない部分に、電気メッキ、無電解メッキ等のメ
ツ キによって設け、この刷子工具の被覆部分をその後
除去するようにしたことを特徴とする金属工具としての
刷子工具に研磨材小片を−mat、て設ける方法。 (2、特許請求の範囲第1項に記載の方法において、部
分的に被覆され友刷子工具をメッキ液に浸漬スる前に、
これをエツチング液に浸漬することt−特徴とするもの
。 (3)  特許請求の範囲第1項または#!2項に記載
の方法において、部分的に被覆された刷子工具の無被覆
部分に、メッキ浴中において、まず、金属組材の基層が
設けられていることを特徴とするもの。 (4)  特許請求の範囲第1項の記載の方法において
、金属組材に、研磨材小片のうち、その全体の大きさの
5分の2ないし4分の5の部分が埋設されていることを
特徴とするもの。 (5)特許請求の範囲第1項ないし第4項に記載の方法
において、金属組材への研磨材小片の埋設が、基層形成
用のメッキ浴とは別個のメッキ浴中で行なわれるもの。 (6)特許請求の範囲第1項ないし第5項に記載の方法
において、刷子工具の刷子の尖端部に研磨材小片を被覆
して設ける方法であって、刷子工具の刷子を取り付けた
部分には少なくとも非導電性材料が設けられ、その後、
刷子の被覆されるべき尖端部に付着した非導電性材料を
除去するようにしたもの。 (7)%許請求の範囲第6項に記載の方法において、刷
子工具の刷子が、特定の温度範囲で硬化しこの温度範囲
外では溶解し、好ましくは粘性を呈する非導電性材料に
浸漬されることを特徴とするもの。 (8)  特許請求の範囲第6項又は第7項に記載の方
法において、刷子工具の刷子が加熱された非導電性材料
の中に浸漬され、かつ、これ全取り出して、この非導電
性材料がこの刷子工具の回転によって硬化され、この作
業は刷子工具の刷子が完全に被覆されるまで繰返される
もの。 (9)%許請求の範囲第6項ないし第8項のうち匹ずれ
か一項に記載の方法において、非導電性材料が、ラッカ
ーあるいはワックスであることを特徴とするもの。 00  特許請求の範囲8g1項ないし第9項に記載の
方法において、研磨材がダイヤモンド粉末とされ、その
粒度が使用目的に応じて適宜選択されるもの。 (財)特許請求の範囲第6項ないし第10項に記載の方
法において、 刷子工具が一つの条溝状の支台に載置され、メッキ液中
に浸漬されて、ダイヤモンド粉末がペースト状とされて
均等に工具表面に塗布されるもの。 @ 特許請求の範囲第11項に記載の方法において、ダ
イヤモンド粉末の刷子工具表面への塗布が少くとも2段
階で行われ、ダイヤモンド粉末を散布し、金属組材をメ
ッキする吾戚階後、刷子を回転させることt−特徴とす
るもの。 (至)特許請求の範囲第1項ないし第12項のうちいず
れか1項に記載の方法において製作され友金属工具とし
ての刷子工具であって、該刷子工具の少くとも外面が好
ましくは硬質の金属組材に1部分的にメッキによって研
磨材が埋設して設けられている刷子工具。 04  %許請求の範囲第15−項に記載の刷子工具に
おいて、金属刷子の尖端部に、ニッケル、クローム等の
硬質金属層が金属組材として設けられ、該金属担材中に
部分的に研磨材粒子が埋設されてそのキャップがメッキ
によって形成されているもの。
[Scope of Claims] (1) A method in which a brush tool as a metal tool is coated with small pieces of abrasive material such as diamond, boron nitride particles, corundum, etc. Coating 116L on the tool, the brush tool partially coated in this way,
immersing the brush tool in a plating bath containing an abrasive and partially embedding a hard metal finger layer of nickel, chrome, etc. on the uncovered portion of the brush tool, at least partially embedding a plurality of small pieces of the abrasive; A method for providing abrasive particles on a brush tool as a metal tool, characterized in that the abrasive material is provided by plating such as electroplating or electroless plating, and the coated portion of the brush tool is subsequently removed. (2. In the method described in claim 1, before immersing the partially coated brush tool in the plating solution,
It is characterized by immersing it in an etching solution. (3) Claim 1 or #! 3. A method according to claim 2, characterized in that the uncoated portion of the partially coated brush tool is first provided with a base layer of metal assembly in a plating bath. (4) In the method described in claim 1, two-fifths to five-quarters of the total size of the small abrasive pieces are embedded in the metal assembly. characterized by. (5) In the method according to any one of claims 1 to 4, the embedding of the abrasive particles into the metal assembly is carried out in a plating bath separate from the plating bath for forming the base layer. (6) A method according to claims 1 to 5, in which a small piece of abrasive material is coated on the tip of a brush of a brush tool, and the portion of the brush tool where the brush is attached is coated with a small piece of abrasive material. is provided with at least a non-conductive material, and then
A device designed to remove non-conductive material attached to the tip of the brush that is to be coated. (7) % In the method according to claim 6, the brush of the brush tool is immersed in a non-conductive material which hardens in a certain temperature range, melts outside this temperature range and preferably exhibits viscosity. Something that is characterized by (8) In the method according to claim 6 or 7, the brush of the brush tool is immersed in a heated non-conductive material, and the brush is completely taken out and the brush is removed from the heated non-conductive material. is cured by rotating the brush tool, and this operation is repeated until the brush of the brush tool is completely covered. (9) The method according to any one of claims 6 to 8, characterized in that the non-conductive material is lacquer or wax. 00 Claim 8g In the method according to items 1 to 9, the abrasive is diamond powder, and the particle size of the abrasive is appropriately selected depending on the purpose of use. In the method according to claims 6 to 10, a brush tool is placed on a groove-shaped support and immersed in a plating solution to form a diamond powder into a paste. applied to the tool surface evenly. @ In the method described in claim 11, the diamond powder is applied to the surface of the brush tool in at least two stages, and after the diamond powder is spread and the metal assembly is plated, the brush tool is applied to the surface of the brush tool in at least two stages. Rotating the t-characteristic. (To) A brush tool as a companion metal tool manufactured by the method according to any one of claims 1 to 12, wherein at least the outer surface of the brush tool is preferably hard. A brush tool in which an abrasive material is partially embedded in a metal assembly by plating. 04% In the brush tool according to claim 15, a hard metal layer of nickel, chrome, etc. is provided as a metal assembly on the tip of the metal brush, and the metal carrier is partially polished. Material particles are embedded and the cap is formed by plating.
JP56172695A 1981-08-11 1981-10-28 Method of coating and forming abrasive material small piece to brush tool as metal tool and brush tool as metal tool manufactured through said method Granted JPS5828468A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3131641.7 1981-08-11
DE19813131641 DE3131641A1 (en) 1981-08-11 1981-08-11 METHOD FOR PUTTING METAL TOOLS, IN PARTICULAR BRUSH TOOLS WITH ABRASIVE PARTICLES, AND METAL TOOL PRODUCED THEREFOR, IN PARTICULAR BRUSH TOOL

Publications (2)

Publication Number Publication Date
JPS5828468A true JPS5828468A (en) 1983-02-19
JPH0158027B2 JPH0158027B2 (en) 1989-12-08

Family

ID=6139029

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56172695A Granted JPS5828468A (en) 1981-08-11 1981-10-28 Method of coating and forming abrasive material small piece to brush tool as metal tool and brush tool as metal tool manufactured through said method

Country Status (4)

Country Link
EP (1) EP0072374B1 (en)
JP (1) JPS5828468A (en)
AT (1) ATE18441T1 (en)
DE (2) DE3131641A1 (en)

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JPH01264777A (en) * 1988-04-18 1989-10-23 Fsk Corp Wire brush and manufacture thereof

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US5329730A (en) * 1989-09-20 1994-07-19 Jason, Inc. Abrasive finishing tool
US5158405A (en) * 1991-05-31 1992-10-27 John Serafin Deburring tool and method
DE4121839C2 (en) * 1991-07-02 2003-01-09 Werner Hermann Wera Werke Tool with torque transmitting work surfaces and method for manufacturing the same
DE4312017A1 (en) * 1993-04-13 1994-10-20 Artec Design & Entwicklungsges Bristle
DE19904944A1 (en) * 1999-02-06 2000-04-20 Bosch Gmbh Robert Oscillated and twisted de-burring tool, for rounding and polishing hole edges, includes spreading head and highly stressed inner edge of fuel injection nozzle
DE102017115540A1 (en) * 2017-07-11 2019-01-17 Gühring KG deburring

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JPH01264777A (en) * 1988-04-18 1989-10-23 Fsk Corp Wire brush and manufacture thereof

Also Published As

Publication number Publication date
DE3131641A1 (en) 1983-03-03
DE3173978D1 (en) 1986-04-10
EP0072374B1 (en) 1986-03-05
ATE18441T1 (en) 1986-03-15
EP0072374A1 (en) 1983-02-23
JPH0158027B2 (en) 1989-12-08

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