JPS58206750A - Wiping cloth - Google Patents

Wiping cloth

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Publication number
JPS58206750A
JPS58206750A JP57089960A JP8996082A JPS58206750A JP S58206750 A JPS58206750 A JP S58206750A JP 57089960 A JP57089960 A JP 57089960A JP 8996082 A JP8996082 A JP 8996082A JP S58206750 A JPS58206750 A JP S58206750A
Authority
JP
Japan
Prior art keywords
wiping cloth
parts
wiping
fatty acid
acid ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57089960A
Other languages
Japanese (ja)
Inventor
昇 松田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Duskin Franchise Co Ltd
Original Assignee
Duskin Franchise Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Duskin Franchise Co Ltd filed Critical Duskin Franchise Co Ltd
Priority to JP57089960A priority Critical patent/JPS58206750A/en
Publication of JPS58206750A publication Critical patent/JPS58206750A/en
Pending legal-status Critical Current

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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は、ワイピングクロスに関するもので、より詳細
には洗沙作用及び殺菌作用と共に除実効米をも有する水
性のワイピングクロスVこ関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a wiping cloth, and more particularly to a water-based wiping cloth V having a cleaning action, a bactericidal action, and an anti-inflammatory action.

従来、使い捨てのワイピングクロスとして、紙、不#布
等の繊維質基質に、アルコールや界面活性剤を含有する
払拭用水性媒体を金品させたものが広く1史用されてい
る。このようなワイピングクロ   −スは、物体或い
は人体の表面に付着した汚れを簡便に除去できるという
利点はあるものの、この汚れと共に付着する臭いを除去
するという目的には未九不満足なものである。
Conventionally, disposable wiping cloths made of a fibrous substrate such as paper or non-woven cloth coated with an aqueous wiping medium containing alcohol or a surfactant have been widely used. Although such wiping cloths have the advantage of being able to easily remove dirt adhering to the surfaces of objects or human bodies, they are still unsatisfactory for the purpose of removing odors adhering to the dirt.

更に、このようなワイピングクロスで払拭したガラスや
家具等の表面には拭きあとが残る傾向があり、清浄感、
清涼感において未だ十分満足するものである。
Furthermore, there is a tendency for wiping marks to remain on surfaces such as glass and furniture that have been wiped with such wiping cloths, reducing the sense of cleanliness.
The refreshing feeling is still quite satisfactory.

従って、本発明の目的は、洗浄乃至清浄化作用及び殺菌
乃至は滅菌作用と共に、漫れた防臭乃至(J消臭作用t
も有する水性ワイピングクロスを提供するにある。
Therefore, the purpose of the present invention is to provide cleaning, purifying, disinfecting, and sterilizing effects, as well as extensive deodorizing and deodorizing effects.
We also provide water-based wiping cloths.

本発明の他の目的は、ガラス面号の表面を拭いた後にも
拭きあとが残らないダスティング水性組成物に谷浸せし
めたワイピングクロスを提供するにある。
Another object of the present invention is to provide a wiping cloth soaked in a dusting aqueous composition that does not leave any wiping marks even after wiping the surface of a glass surface.

本発明によれば、アルコール′ftt有する水、性媒實
を紙或いは不繊巧基質に含浸させて成るワイピングクロ
スにおいて、前記アルコール性水性媒質中に全体当り0
.6乃至5.0重蓋%のアミン質及び0.1乃至2.0
重量%の抗鉋抗カビ剤を含有させて成ることを特徴とす
るワイピングクロスが提供される。
According to the present invention, in a wiping cloth formed by impregnating paper or a non-woven substrate with water or an aqueous medium containing alcohol, a total amount of 0% is added to the alcoholic aqueous medium.
.. 6 to 5.0% amines and 0.1 to 2.0%
A wiping cloth is provided, characterized in that it contains an anti-sweat and anti-mildew agent in an amount by weight.

本発明のワイピングクロスは、紙或いは不繊巧基質に含
浸させるアルコール性水性媒質中にフミン質を含有させ
ることが顕著な特徴である。即ち、本発明は、上記基質
中のアルコール性水性媒質中に分散したフミン質が払拭
すべき而に付着した臭いの除去及び消臭に極めて有効に
作用するという新規知見に基ずくものである。
The wiping cloth of the present invention is distinctive in that it contains humic substances in the alcoholic aqueous medium that is impregnated into the paper or non-woven substrate. That is, the present invention is based on the new finding that humic substances dispersed in the alcoholic aqueous medium in the above-mentioned substrate act extremely effectively in removing and deodorizing the odor attached to the surface to be wiped away.

本発明に用いるアミン質とは、草炭、亜炭等の、::。The amines used in the present invention include grass charcoal, lignite, etc.

低炭化度の石炭質中に含有される無定形有機質であって
、元素組成が炭素45〜65%、水素4〜6%で、残部
の大部分が酸素から成るものである。
It is an amorphous organic substance contained in coal with a low degree of carbonization, and has an elemental composition of 45 to 65% carbon, 4 to 6% hydrogen, and most of the remainder is oxygen.

このアミン質は、例えば、前述した低炭化度の草炭等を
水で処理し、水に懸濁する微細な固形分粒子として或い
は水浴液として油田分離することにより得られる。この
アミン質の内、本発明の目的に好適なアミン質は、水に
分散乃至俗解した比較的低分子蓋のフミン酸であり、こ
の酢液乃至は分散液をアルコール性水性媒質中に重加し
てこれを紙或いは不繊巧基質に含浸させる。
This amine substance can be obtained, for example, by treating the aforementioned grass charcoal with a low degree of carbonization with water and separating it in oil fields as fine solid particles suspended in water or as a water bath liquid. Among these amines, the amine suitable for the purpose of the present invention is humic acid, which has a relatively low molecular weight and is dispersed in water. This is then impregnated into paper or a fibrous substrate.

本発明VCおいては、この7ミン質を全水性媒質当り0
.6乃至5重蓋%、特に0.5乃至2重量%の量で含有
させることも1安である。後述する例に手す通り、この
アミン質の菫が上記範囲よりも少ないときには、払拭面
の防臭効果が十分でなく、一方上記緻よりも多電に使用
しても、この増加による格別の効果はなく、経隣的には
かえって不利となる。
In the VC of the present invention, this heptamine is added to 0 per total aqueous medium.
.. It is also advantageous to include it in an amount of 6 to 5% by weight, especially 0.5 to 2% by weight. As shown in the example below, when the amount of this amine violet is less than the above range, the deodorizing effect on the wiped surface will not be sufficient.On the other hand, even if it is used with more electricity than the above-mentioned density, this increase will result in an exceptional effect. This would actually be a disadvantage in terms of economic proximity.

一般VC,@庫或いは人体の表面に付着する慈臭には、
この表向に付着した異物そのものの某いのみならず、こ
の異物が細凶或いはカビ寺により分解されて発生する臭
いもめる。か力・る見地からは、払拭■の笑いを除くば
〃・りではなく、これec付層する菌やカビを除去し或
いはその繁殖を防止しておくことが防臭及び消臭の目的
から好都合である。
General VC, @The smell that adheres to the warehouse or the surface of the human body,
Not only the foreign matter itself that adheres to the surface, but also the odor generated when the foreign matter is decomposed by mold or mildew. From a strong point of view, it is not just a matter of eliminating the laughter, but it is convenient for the purpose of odor prevention and deodorization to remove the attached bacteria and mold or to prevent their proliferation. It is.

本発明においては、紙、不繊布等の基質中に含浸させる
アルコール性水性媒質に、該基質全蓋当90.1乃至2
.0重蓋%、特に0.1乃至0.5重蓋%の抗菌剤及び
/又は抗カビ剤を含有させる。
In the present invention, an alcoholic aqueous medium to be impregnated into a substrate such as paper or nonwoven fabric is mixed with 90.1 to 2
.. An antibacterial agent and/or an antifungal agent is contained in an amount of 0%, particularly 0.1 to 0.5%.

アルコール含有水性媒質としては、エタノール、インプ
ロピルアルコール、プロピレングリコール、グリセリン
等のアルコール類の181又は21al[以上全含有し
、更に所望により界面活性剤、特に非イオン界面活性剤
を含有する水性媒質が使用される。
The alcohol-containing aqueous medium may include alcohols such as ethanol, inpropyl alcohol, propylene glycol, glycerin, etc., containing all of the above and, if desired, a surfactant, especially a nonionic surfactant. used.

適当な非イオン界面活性剤の例は次の通りである。Examples of suitable nonionic surfactants are:

グリセリン脂肪酸(C8〜CH) ニスf ル、ンルビ
タン脂肪酸エステル、 プロピレングリコールハ旨肪酸エステル、ショ糖脂肪酸
エステル、 クエン酸モノ(ジ又はトリ)ステアリルエステル、 ペンタエリスリトール脂肪酸エステル、ポリグリセリン
脂肪酸エステル、 ポリオキシエチレングリセリン脂1i7[エステル、ポ
リオキシエチレンンルビタン脂肪酸エステル、ポリエチ
レングリコール脂肪酸エステル、ポリプロピレングリコ
ール脂肪酸エステル、ポリオキシエチレン脂肪族アルコ
ール(Cn”””Ct。)エーテル、 ポリオキシエチレンアルキルフェニルエーテル、#、A
/’−ビス(2−ヒドロキシエチル)脂肪族(Ca〜q
■)アミン、 脂肪酸とジェタノールアミンによる縮合生成物、ポリオ
キシプロピレンーポリオキシエチレンブロックコボリマ
ー。
Glycerin fatty acid (C8-CH) Varnish, rubitan fatty acid ester, propylene glycol fatty acid ester, sucrose fatty acid ester, citric acid mono (di or tri) stearyl ester, pentaerythritol fatty acid ester, polyglycerin fatty acid ester, poly Oxyethylene glycerin fat 1i7 [ester, polyoxyethylene rubitan fatty acid ester, polyethylene glycol fatty acid ester, polypropylene glycol fatty acid ester, polyoxyethylene fatty alcohol (Cn"""Ct.) ether, polyoxyethylene alkylphenyl ether, # ,A
/'-bis(2-hydroxyethyl) aliphatic (Ca~q
■) Amine, condensation product of fatty acid and jetanolamine, polyoxypropylene-polyoxyethylene block copolymer.

本発明の目的に蟻も好適なアルコール含有水性媒質は、
全体当り重量基準でエタノール?!−5乃至20部、特
に10乃至15部、グリセリン乃至はプロピレングリコ
ールの如き多価アルコール金0.1乃至5.0部、特に
0.2乃至2.0部、及び蔗糖脂肪酸エステル、グリセ
リン脂肪酸エステル、ンルビタン脂肪酸エステル、フロ
ピレンゲリコール脂肪酸エステル、ポリオキシェテレン
グリセリン脂肪酸エステル、ポリオキシエテレンンルビ
メン脂肪酸エステル、ポリグリセリン脂肪酸エステル等
の非イオン界面活性剤k 0.5乃至5.0部、特に1
.0乃至2.5部の量で含有する。上述した組合せ媒質
は、檀々の汚れた表面に対する洗浄作用に優れているの
みならず、ガラス表面を拭いた場合にも、該表面に拭き
跡を残さないとい5顕著な利点を有し、しかも前述した
フミン質による払拭面の防臭乃至は消臭作用を助長する
とい5部著な利点を有する。
Alcohol-containing aqueous media which are also suitable for the purposes of the present invention are:
Ethanol based on total weight? ! -5 to 20 parts, especially 10 to 15 parts, polyhydric alcohol gold such as glycerin or propylene glycol 0.1 to 5.0 parts, especially 0.2 to 2.0 parts, and sucrose fatty acid ester, glycerin fatty acid ester , 0.5 to 5.0 parts of nonionic surfactants such as nrubitan fatty acid ester, phlopylene gellicol fatty acid ester, polyoxyetherene glycerin fatty acid ester, polyoxyethylene nrubimen fatty acid ester, polyglycerin fatty acid ester, Especially 1
.. It is contained in an amount of 0 to 2.5 parts. The above-mentioned combined medium not only has an excellent cleaning effect on dirty surfaces, but also has the remarkable advantage that when a glass surface is wiped, it does not leave any traces on the surface. It has five significant advantages in that it promotes the deodorizing or deodorizing effect of the wiped surface due to the humic substances mentioned above.

本発明に用いるアルコール含有水性媒質Vこは、上述し
た成分に加えて、香料や艶出し用シリコーン類を所望に
よって配合できる。
In addition to the above-mentioned components, the alcohol-containing aqueous medium V used in the present invention may optionally contain fragrances and polishing silicones.

上述した組成のアルコール含有水性媒質を1テイツシユ
ペーパー、タオル用紙、ナプキン用紙等の家庭用薄葉紙
或いは針葉樹パルプ、木綿等の天然繊維、レーヨン等の
再生繊維、ビニロン、ポリエステル等の合成繊維から湿
式或いは乾式で製造した不織布等の繊維質基質に含浸さ
せる。勿論、この繊維質Anは、上述した水性媒質會含
浸場せた状態での払拭操作に耐えるように成る8度の湿
i4強度乃至は耐水性を有するものでなければならない
。アルコール含有水性媒質の繊維基質への含浸菫は、線
維の′ni類や基質の嵩によっても相違するが、一般的
に言って、繊維質基質当り100乃至200重蓋%、特
に150乃至180重蓋%の範囲とするのが好ましい。
An alcohol-containing aqueous medium having the above-mentioned composition is wet-processed or prepared from household tissue paper such as tissue paper, towel paper, or napkin paper, natural fibers such as softwood pulp, cotton, recycled fibers such as rayon, or synthetic fibers such as vinylon and polyester. It is impregnated into a fibrous substrate such as a dry-produced nonwoven fabric. Of course, this fibrous An must have a wet I4 strength of 8 degrees Celsius or water resistance so that it can withstand the wiping operation in the above-mentioned aqueous medium impregnated state. The amount of violet impregnated into the fiber matrix with an alcohol-containing aqueous medium varies depending on the fiber type and the bulk of the matrix, but generally speaking, it is 100 to 200% by weight, especially 150 to 180% by weight per fibrous matrix. It is preferable to set it as the range of lid %.

本発明のワイピングクロスは、家具類、調度品、台所用
X等の洗浄用に、また手拭き、化粧落し等の人体の清浄
化用に広く使用することができる。
The wiping cloth of the present invention can be widely used for cleaning furniture, furnishings, kitchen Xs, etc., and for cleaning the human body, such as wiping hands and removing makeup.

本発明を次の例で説明する。The invention is illustrated by the following example.

実施例1゜ 95%エタノール       10重量部ショ糖脂肪
酸エステル    1.11グリセリン       
 2.Ol フミン#             2.0 −殺陶剤
           0.21(ヒビテングルコネー
ト) 防カビ剤             0.51香料  
           微量 水           残量 から成る水性組成物t−調裏し、この水性組成itセル
ロース線維製不織布当り150重蓋%の電で含浸させ、
ワイピングクロスを製造した。
Example 1 95% ethanol 10 parts by weight Sucrose fatty acid ester 1.11 Glycerin
2. Ol Humin # 2.0 - Porcelain 0.21 (hibitengluconate) Antifungal agent 0.51 Fragrance
An aqueous composition consisting of a trace amount of water is prepared, and this aqueous composition is impregnated with 150% of the total amount per cellulose fiber nonwoven fabric.
Manufactured a wiping cloth.

このワイピングクロスを、家の窓拭きに用いたところ優
れた洗浄作用が得られ、払拭後転いたガラス表面には全
く拭き跡が認められなかった。
When this wiping cloth was used to clean windows at home, excellent cleaning action was obtained, and no wiping marks were observed on the glass surface that fell after wiping.

また、このワイピングクロスを、冷蔵庫の内は、食卓表
面、ゴミ箱の内側、靴の内底の払拭に用いたが、洗浄作
用と同時に防臭効果が得られることがわかった。
Furthermore, this wiping cloth was used to wipe the inside of a refrigerator, the surface of a dining table, the inside of a trash can, and the inner sole of shoes, and it was found that it had a deodorizing effect as well as a cleaning effect.

実施例2 本実施例はフミン酸による払拭面の防臭効果を示すもの
である。
Example 2 This example shows the deodorizing effect of humic acid on wiped surfaces.

フミン酸の懸濁液を、固形分として下り己第1表に示す
配合値で配合する以外は実施例1と同様Vこしてワイピ
ングクロスk Hjlした。
The suspension of humic acid was strained in the same manner as in Example 1, except that the solid content was blended with the blending values shown in Table 1, and then washed with a wiping cloth.

このワイピングクロスを用いて、下記第1表に示す面を
払拭操作に付し、家庭の主婦10人?パネラ−として官
能試験を行った。パネラ−VCよる回答に基づき次のv
F価を行った。
Using this wiping cloth, wipe the surfaces shown in Table 1 below with 10 housewives. A sensory test was conducted as a panelist. Based on the answers given by Panela-VC, the following v
An F value was performed.

■ 着香t−gめた人(元の笑いがその   1点まま
残っていると答えた人) ■ やや着香1−認めた人(元の臭いが   捧点やわ
らいでいると答えた人) ■ 全く層香tgめない人(元の臭い   0点が完全
に消えていると答えた人) 得られた結果は次の通りである。
■ Those who agreed with the t-g (those who answered that the original laughter remained the same) ■ Those who agreed with the slight t-g (those who answered that the original smell had softened) ■ People who don't like the scent at all (those who answered that the original odor score of 0 has completely disappeared) The results obtained are as follows.

第1表 無肉加  I Q/10 1 Q/10  1 Q/1
0 1 G/100.1%   8/10  6/10
  10/10 1 G/100.2% 7/105/
10 7/101Q//100.5% Vlo 0A0
 .5/105/101.0% 2/10 Q/10 
6/103/102.0% CJAOQ/10 1/1
05/10手続補正書(自発) 昭和57年8月2日 特許庁長官  若 杉 和 夫 殿 1 事件の表示 籍顧昭57−89960号 2 発明の名称 ワイピングクロス :3 補正をする者 事件との関係 特許出願人 イレリ、  大阪市大淀区豊崎4丁閂11番」6号2、
(!l   ダスキンフランチャイズ株式会社、1 代
  理  人  〒105 fl I(I    Il!足η1港1ス愛活+lI’
116悉7シじ夏宕山弁護■:ビル電話(436) 3
527 〜ノ 5 補正命令の11付 なし 6 補正の対象 明細書の発明の詳細な説明の欄 7 補正の内容 (1)明細書第2頁12乃至16行に「満足するもので
ある。」とあるを、〔満足するものでなし・。」と訂正
する。
Table 1 No meat addition I Q/10 1 Q/10 1 Q/1
0 1 G/100.1% 8/10 6/10
10/10 1 G/100.2% 7/105/
10 7/101Q//100.5% Vlo 0A0
.. 5/105/101.0% 2/10 Q/10
6/103/102.0% CJAOQ/10 1/1
05/10 Procedural Amendment (Voluntary) August 2, 1980 Director General of the Patent Office Kazuo Wakasugi 1 Case Display Register No. 1989-89960 2 Title of Invention Wiping Cross: 3 Person making the amendment Related: Patent applicant Ireri, No. 6, 11, Toyosaki 4-chome, Oyodo-ku, Osaka City, No. 2,
(!l Duskin Franchise Co., Ltd., 1st agent 〒105 fl I(I Il! Feet η1 port 1st love activity +lI'
116悉7shiji Natsagoyama Defense ■: Bill Telephone (436) 3
527 - No. 5 No 11 attached to the amendment order 6 Detailed description of the invention in the specification subject to amendment 7 Contents of the amendment (1) "It is satisfactory" on page 2 of the specification, lines 12 to 16. There is nothing that satisfies me. ” he corrected.

以上that's all

Claims (2)

【特許請求の範囲】[Claims] (1)アルコールを含有する水性媒質に紙或いは不織布
等の繊維質基質にt浸させて成るワイピングクロスにお
いて、前記アルコール性水性媒貿中に全体当り0.3乃
至5.0fit%のフミン質及び0.1乃至2.0重量
%の抗菌抗カビ剤を含有させて成ること全特徴とするワ
イピングクロス。
(1) In a wiping cloth made by soaking a fibrous substrate such as paper or nonwoven fabric in an aqueous medium containing alcohol, 0.3 to 5.0 fit% of humic substances and A wiping cloth characterized by containing 0.1 to 2.0% by weight of an antibacterial and antifungal agent.
(2)  1箪基準でエタノール5乃至20部、非イオ
ン界面活性剤0.5乃至5.0部、グリセリン万全はプ
ロピレングリコール0.1乃至5部、フミン質0.6乃
至5部、抗菌剤乃至は抗カビ剤0.1乃至2.0部及び
2Atが水から成る組成物を紙或いは不織■に苫浸させ
て成る%奸請求の範囲第1項記載のワイピングクロス。
(2) Based on one cup, 5 to 20 parts of ethanol, 0.5 to 5.0 parts of nonionic surfactant, 0.1 to 5 parts of propylene glycol, 0.6 to 5 parts of humic substance, and antibacterial agent for glycerin 2. The wiping cloth according to claim 1, wherein a composition comprising 0.1 to 2.0 parts of an antifungal agent and 2 At and 2 At is soaked into paper or non-woven fabric.
JP57089960A 1982-05-28 1982-05-28 Wiping cloth Pending JPS58206750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57089960A JPS58206750A (en) 1982-05-28 1982-05-28 Wiping cloth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57089960A JPS58206750A (en) 1982-05-28 1982-05-28 Wiping cloth

Publications (1)

Publication Number Publication Date
JPS58206750A true JPS58206750A (en) 1983-12-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP57089960A Pending JPS58206750A (en) 1982-05-28 1982-05-28 Wiping cloth

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Country Link
JP (1) JPS58206750A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6750160B1 (en) 1996-12-09 2004-06-15 Kao Corporation Detergent-impregnated article

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4972955A (en) * 1972-11-16 1974-07-15
JPS506595A (en) * 1973-05-21 1975-01-23
JPS5745568A (en) * 1980-09-01 1982-03-15 Ricoh Co Ltd Electrophotographic copier

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4972955A (en) * 1972-11-16 1974-07-15
JPS506595A (en) * 1973-05-21 1975-01-23
JPS5745568A (en) * 1980-09-01 1982-03-15 Ricoh Co Ltd Electrophotographic copier

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6750160B1 (en) 1996-12-09 2004-06-15 Kao Corporation Detergent-impregnated article

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