JPS58152880A - Nematic liquid crystal and manufacture - Google Patents

Nematic liquid crystal and manufacture

Info

Publication number
JPS58152880A
JPS58152880A JP2389083A JP2389083A JPS58152880A JP S58152880 A JPS58152880 A JP S58152880A JP 2389083 A JP2389083 A JP 2389083A JP 2389083 A JP2389083 A JP 2389083A JP S58152880 A JPS58152880 A JP S58152880A
Authority
JP
Japan
Prior art keywords
dioquinane
crystal
otori
feng
ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2389083A
Other languages
Japanese (ja)
Other versions
JPH0362195B2 (en
Inventor
デイ−トリツヒ・デムス
ホルスト・ツアシユケ
ハンス−マツトヒアス・フオルブロツト
アントン・ハウゼル
イエルク・フオ−ゲル
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Werk fuer Fernsehelektronik GmbH
Original Assignee
Werk fuer Fernsehelektronik GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Werk fuer Fernsehelektronik GmbH filed Critical Werk fuer Fernsehelektronik GmbH
Publication of JPS58152880A publication Critical patent/JPS58152880A/en
Publication of JPH0362195B2 publication Critical patent/JPH0362195B2/ja
Granted legal-status Critical Current

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  • Liquid Crystal Substances (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本脅嘴は,透通または友射するt.な羨調喜セる為また
曇工叙事.記号および一廖を再構する為の竃嵐光学的榔
造賛嵩層のネ▼テック績晶および腋鮒属{k金物の顧途
方kl絢する.象晶,41Kネマチッタ・メイグの4の
はh,t!#的%am性的および竃鬼的性質κ轡黴絢等
1岐を示丁.この性買の為K4マtツク畝蟲は.党vI
R脚の為の並びκ款字.配号および一影の4楓の為の竃
jiL元学釣梼瀧褒嵩の纏造κ勤農帥K^用される.こ
の一の榔造*gは電子時計,計算器およびその軸のマイ
I一−エレIト−1ツクa晶り為のタスグレーとして卓
越して適している0 近代#薮置で細いも為kは,デスプレーで1いる淑蟲物
買Kは富Kttし<且つ高まった要求があ9.そり一k
これら物jIiの脣崖な性質がデスプレーの性買および
1l!用+iirsi性k寿富k関番している.これら
全てのIII求を大体で4#Jiする関枠な化会愉は醤
嵌しないので.lk厘の化会物の1命物が夷sKは両外
なく値用されている.この蟲會物の性質は一會戚分の臀
性kよって充分に一蝋でき麓つ変史できる.こり亀金一
が閣鴫の全ての膚途κ通し得る為kは.食ク4l1舅な
性貞を舊した植々の化倉物機鋼の#B米るだけ多くのー
々の成分#&必豊とされる.低い一点および尤分κ^い
静&la[の仙κ、例えばシャーデクトIIヘAI7リ
ツ絋漬41 ( Bob*4t−M*htrlok−鳳
110kt鄭)(ねじれセル)を!一とする尉しいパリ
エーシ1冫の^κは%#竃κ僅かの41属折な有する物
質が4blIとされる〔会.バー7(la誠r)の1練
晶偵置ノlI14lI′slよび化学( Th@Pky
siosand Ohm一ロ+try or Iaiq
@id Orystal Mevioss)’.(19
&@),ニエーW−クのグレニク▲出販社( PLam
uwr Pmbh.Qmrp.フ, iJ.スグ交ケル
( 8pr*k@l )κよりatmされる〕.憾米公
知のジオキナ7dI体の11sは.不所纏の憾い静皺点
または,スメクデツク4111を形成する不所望の一崗
を有している〔例えば.5一1一アルキルーよ−シアン
7エニルー1.5−ジオ中ナン.J[ドイツI1lit
lt41I/!t厘1 5 ?.lI 5 M令および
岡纂1 5 PJ 4 7号;史κ,置換シターヘキ$
/k−ジオキナン.J[ドイツ麺#II1畳許aS!五
/宜S宜.4h6/0〕. 本姑嘴の目的は,有利なー@的怯買,畳κ融点および靜
設点,鵬的負iII&tおよび竃1aκ贈する安ffl
a差びκ低いI[jll折κ―しての有舅な性質を有す
る新嵐のネ▼チクク藏晶および皺値晶一負のam方tc
Kある. 本竜−は.IN求される上紀の有利な性質を奮する*換
−1.s−ジオ命ナンを碁礎とするIi親のネ!テツl
績蟲gよびその履造万法をIIa弛することを睡題とし
ている. 本脅@看は,一般式 〔式中,xxm@−そしてi寓凰1 .または1 1 W l’そしてY一鳳2,または夏冨鳳1 そして
!=鳳4 を意藏し,但し 1’  ” ’a”lm+1  *  ’m”la+,
’  e  Ojg  s  MOB  # ” ”e
ndpage:2 ダン. K m −000− . −000− なお.11〜18を意味する●〕 で表わされる新嵐の龜晶2−i11jl%−1.3−ジ
オキナン−5一力羨ポン鍍エステルが.単−で,橿亙の
畠會状履Sよび/または−の一晶物質または非疲晶物質
との墨金状一で.遼通−または諏射光の変一の為の着び
κ叔字.紀号および図拳の再塊の為の11jIL党字的
備造物κおいて使用するのκ適していることをj!出し
た.本発一の化会物の例を久のJlll〜4IIK示す
.慶中, KエIII蟲買一体 1職スメタナツタ砿 舗冨ネマチツク砺 iam等方性献 endpage:3 本處@の化金物は,一都が低い一点一譬κ蟲★状麹で−
#CIItびk−鄭が高い靜筺楓度K4I−があり,倉
鄭が化ダ的および鶏的−響韮びκ電jlhKml,.て
の高い安定性を示しそして一赦V−光学#値属折り値が
小さい. 本烏limitつて盾嵐の駅晶ト2冫スー2一置換−t
es−ジオキナンーS −*ルボン虐工遍ナルを履達す
る為κは..!−置換一場,3−ジオ中ナンーカルボン
一をテオニルターツイド.ス#7リルタ調ツイドまたは
^−ダン化り冫のJlll I/1鑓グン倶与体と.偉
K4I嶺皐塩基の不壽任下κ反応させ′C@応する一夕
鑓2イドとし.次kそれを自体公知の方法でアルコール
または置換フェノールκてエステル化する. 反応式: この反応の場金κは竃ろ《ぺきことκ,置員−1,墨−
ジオキナンカルポン*が鳳状ア竜ナートとして^−グン
供与体Kよって,通富はIJ−ジオ今ty劇の嶺会#C
鋏蟲する蔵《.一本分,ssれない. 2一置jl−1.J−ジオキナンー2−カルポy歳は,
!−イソ1闘ビル−1.1−ジオキt冫一S−力klM
y1llIKついての文畝k騙示された舎成ffiK従
って,機応するアルデヒドとビスkド詣キシメチル−マ
一冫駿ジエテルエステルとを本屏一潮の存査下κ反応喜
せて2−イノグ鑓ビendpage:4 ルー1.s−ジオキナン−5.5−ジカルポン歳ジエチ
ルエステルとしそして次の加水分解および腕力ルポdP
シルj1iκよって容麺κ入チし得る〔厘.L.工ν−
ル(慝l1●l ) , I.D.パンクス(鵬ank
s ) ;ジャーナル・オプ・アメリカン・少々カル・
ソV工? − ( J.▲■●膳.Ok●鵬.1●0.
)?4.Jl171員(1?72))eこの旭方を修正
することκよって.文献Kおいて公知κなっていない2
一膳−7ルキルーおよび2−(置秦−アリ一ル) − 
tms−ジオキナン−5−カルポン績の属遼κ成功する
.得られる纜タwテイドなアルコールまたは置換7エノ
ールでエステル化丁4ことで.*秦κは公知でない2一
置換−1.i−ジオキナン−2−カルポン歳エステルが
もたらされる.分一したこのエステルのシス/トツンス
ー^髄体感金物は.トツンス−A懺体だけが龜晶St−
拳威する一力が島る為κ.分嶌―晶κよって分けること
ができる. 本脅−の11&κよれば.以下の農i真κ挙げたm科島
るいは中#a生威一でも本脅明の績晶物質を纒造できる
: 本発判を以下のlI麹儒κよって頁k靜一k諷鶴する. mm例1〜1k,本竜判の化会物を含有する1合物を挙
げセして試一丁る. 本宛−1)H造万tkな夷一例4〜畠κよって何示#K
威明丁る. 夷總儒1: 普通の原壜〔メイアー( M@i@r ) , (}.
: fツク!冫(畠aokm亀論論),m.:jl17
’マイアー( Grabma1sr ) , J.@.
; g晶の用途(▲pj11i(1&tiOIIJ●r
Liquia  crystaxs ) #べ69冫/
/%イデルベルダ/=エー■一/(1975))κ従つ
そ榔威されておりそしてVヤーデツF・ヘル7vツヒ効
最を碁礎とする電気党字セル中で.以下のaI威の蟲會
物を試−す4(臘威:■Ol%,金郷で1(1@): この温金物は.次の性買をボした. 1  1.5〜4.S . M 4 1.ra I#一
竃圧 :Qml.4▼ 調I一時間  冨 t鳳..、− 5 0 0 11#
1減時関 : t5。%富1畠@1−層厚さ :del
2.1μ論 諷 j[   :T=”20℃ 夷總$4!. 夷總II11の−kAI中で次の墨金物を試験する(倉
部でI O 2 1101%)● この轟合物は次の性買を示丁: KM−111−1−1os In 調電圧 :蓼■噛.4▼ 膳紬時関 :t鳳..%−6意−龜一 ―絨時関 :t厘,.%−17 ●@S層廖さ 二一鳳
12.●^烏 亀 J[:!麿20℃ endpage:5 貞一飼1: 実IIA真IK健ラセル中で以下の1合物を試験丁4(
盆鰺でIQj鳳●l%): こ#)墨金物は次の性貫を示す: K  t〜11    II  us〜t畠!1間電圧
 :U■L.S V ―鍮時間 ! t    m I O 1  @ 11
8鳳S―% 篩絨”Ili@   t    myxomm1is% 履厚@  : a m 1 1.5 pm温 度 :!
■2●℃ 11711114:  1−(4−―〜へ中シルオキシ
ーフエエル)−1.1一ジオ命ナン− 5−カルポン鐵(sll)0員造: 2  L4  1  (  0.1  11@l  )
#)4  −  m  −へ+Vz*キシベンズアルデ
ヒドおよび2 4.2 J (0.11mol )のビ
スーヒドtidPシメtルー▼■冫麿一ジエデルエステ
ルを.1j@―のべ冫{冫41Kおいてo,III)p
−トルエンスル本冫aの′4l奄下KIl#F下Km時
関Jg熱する.冷却した畿κMaMO0.  2%#[
Kてそして次κ本Kて倣鷹卿K洗浄し,威圧下Kべ冫{
冫を曽★し(一転式j蝿#I)セして鯛癒(ffi−(
4−@一ヘキwayjdpY−7xxst)− 1.I
−1)#dttl− L@−ジカルボン綴一ジエfkエ
ステ#1〕をアルx − # K ?再鯖晶8< Lm
 I f)’lLIkkl m 1 1cs論値の76
%冫である.1は易●℃の4jでS厳する(―−へ中ナ
ンから冫.貢K毅轟橿14為K, n I J ( 1
1.0 7 4 mol ) l)1m1び1 a I
 ( Qj ! son )のILOMをIs(Isd
O?S%エタノール中でma下κ1啼MJlg−丁番.
その+Ikκ良応晶合一からエタノールをw★し.jE
応畠合一K本を添1しそして本性砺な1●〜S●a4κ
aimする。1●●―のエメノーkを―如した後K@T
:K冷却しそして攪拌下k績塩献を−1までm加する.
次K直ちkエーテル憾分を静一一★し.本で洗−L 1
1 M a2tao4  で籠蝕さセそしてamを一転
式IIA発器で論<aX−(4−真−へ命Vルオキシ−
7工晶ル) − 1.i−ジオ◆ナンー5.S−ジカル
ポンjil(1j8″C枳上で分解丁る〕なる鯛m(1
4.s#.−論値の62%)を,120℃〜170℃の
一とで本八ポンプ威圧下Klliカルポキシル碁反応さ
せる●sayzoo,@生の員了殼K員渣なべ冫ゼンま
たは$’/lmへ+t/K”l(Jl艙晶処植す4m5
aO収亭は、埴論憾の4暴%である.■の鎗点は174
 〜171’C”eある. 麹の糊を藻1111K*Lてある. 肯膳#l5:  2一脆−ヘキクル−11−ジオキt冫
−5−カルポンIll(ha)の 纏造 114I(1鳳●l)のヘプIノールと2411 ( 
1.1 mol )のビスーk}′−キシメチルー!一
yllジエテルエステルとから夷Jul4と崗嶺κして
2−I1−へキシル−14−ジオキt冫−5.5−ジカ
ルボンIIIを編造丁る.24#( 0.0 1 is
ol ) Ol &’, 1 h eel #)jl水
ビVジンまたは中ノリンの存在下K.@井下で五つ一気
鋳鎗下KjlaLながら(2時関》腕力ルポ中シル轟反
応させる@檜MllkK20%MQIIICC(―加k
よ9》績性としそしてその一概をエーテルK″ca1崗
紬肯鳥櫃する.一一Kしたエーtk111kmlllを
,419aJF)1 11%aiOJ, lm!ヒ胞和
ハctH畝κて洗浄し.鍼も一o4で砿燥しそして蝿瘉
を#Imlの論★f&K一転式厘嚢―中でV夕闘ヘキナ
ンκ工再駿蟲番せる. Saの収率:ts#(@論一〇)85%),m点=11
t〜目at, 夷膳例4: 2r島−へキシル−1.暴−ジオ中f冫−
 !%−i1kskl冫歳一(4−vアンー7エニルエ
スナk)(唱礁》 の纏造 1.o a I ( Q−●1 膳ol )の51を噛
●―の劇本エーテルK#解し,●.4−の一本ビリジν
なendpage:6 S加しそして氷/食塩一混合物を用いて●〜101:κ
冷却する.次1cfJ.41のチオニルクロツイドを―
如しそして1時陶嶽κ生じた沈殿物(ビリジンーヒドw
 / o 9イド)を1引P*する.生じる毅夕El2
イド(母直)な5−の誕水ビ曽ジンおよび11 1 (
 9.0 1醜o1 )の4−ヒドー命シーベンゾニト
νルの串加後Km温κて2〜5時閾ll片する.その畿
κ反応蟲會物をi(laJのz−tzと畠會し.水.M
aMO01  111mκて洗浄し.Mazl04  
で砿蝕しそして一層を關転式1竜善でw去する.残渣を
メタノールで再紬晶させる. 1−の収量二〇.h−1 (植一値の51%).K4 
4 ( M 4 7.5 )▲1.w41IIA$91
:  2−*−#Ifh−Lm−ジ10ナンー5−カル
ポン鍾−(4−シ アン7工二ルエステル)(If) の纏造 2.4 4 1 ( 0.9 1 m@l )の2一跪
一オタチル−1.i−ジオキナン−5一力#ポン毅he
を,濃気の鋳論下K2−のテオエルターツイドと.気体
脅生が員了するまでRa下κ加熱″f番(麹2Q分).
その嫌κ水藏ポング威圧下#C,4−のチオニルクu’
)イドをw貴し.鯛濠な一水ビνジン(S―)中K#鱒
しそして141 (●.●唱−冫の4−ヒドOキシベン
ゾニ}V#とI1a#)もとで2〜S時関攪拌する.こ
の反応a会物を氷上#C注1,生じ4mm物をメタノー
zlliて歇回4a1蟲#i&橿するかある−9寡エー
テ#k癖解し.1M−[OMlll腋.1●%厘atお
よび厘一κて洗浄し, llax#04  で乾線させ
,鋳廟を奮★しそして員濠をメタノールで再繍晶#&壌
する.1t#)収量:橿論値の4s%,K49.@II
7  0.5  1s 夷總例●:2−(4一膳−ヘキシルーアエエル) − 
1.s−ジオ中t冫−2−★ルボン#!−4−シアン7
工晶ルエ ステル(11)の展造 Ll 4 1 ( 0.0 0 7 mI@l )の5
1.●.a I(●.●●7膳●l)の4−ヒドw4F
シベンゾ1トリル, 1.4 kl ( il.0 0
 7 mol )#)ジV/Elへ今シル*#Mジイミ
ド.0.551(LD07e@l )のビージンな.5
011JJ!)臘水エーテル中κおい曵麿温κて5時関
ll拌する.次κ.生じたtjJll物をP去し.Fi
lを水, ilaMOo,  2 %lII区で#!−
シそして水で洗浄する.エーテル抽出物なma,go4
  でlEI&L.鋳鋼な一転式蒸発器で曽★しモし?
Il癒をメタノールでI/jL一再結晶島場する● ttの収1:1.y#(jll一値の4 o %) ;
 K1墨1  111471g, endpage:7
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The precarious nature of these things is the display of sex shopping and 1l! For +iirsi kjutomi k sekiban. Since all of these III requests are roughly 4#Ji, a Kakaiyu that is a seki framework will not fit. One of the monsters in the world, sK, is universally used. The nature of this insect community can be fully determined by the characteristics of each member of the insect family. This is because Korigame Kinichi can understand all of Kakushu's skin. It is said that the #B rice of #B rice, which is a plant made of plants that have given up their sexual chastity, is rich in #& essential ingredients. A low one point and a reasonable estimate of Shizuka &la['s Senκ, such as Shardect II to AI7 Ritsu Kizuke 41 (Bob*4t-M*htrlok-鳳110kt Zheng) (Twisted Cell)! The substance that has only 41 genus κ of the most important pariesi is 4blI [kai. Bar 7 (la serious)'s 1st training reconnaissance lI14lI'sl and chemistry (Th@Pky
siosand Ohmichiro + try or Iaiq
@id Orystal Mevioss)'. (19
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uwr Pmbh. Qmrp. F, iJ. Atm from κ (8pr*k@l)]. The 11s of the well-known 7dI form of Diocina is. It has an undesirable wrinkle spot or an undesirable lump forming a smegdeck 4111 [eg. 5-11 Alkiru-yo - Cyan 7 Enyllu 1.5-Geo Nakanan. J[Germany I1lit
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There is K. Honryu-ha. *Exchange -1. Ii Parent's Ne who uses s-geo life as the basis of Go! Tetsu l
The purpose of my sleep is to relax all the creations and all the laws that have been created. This threat is a general formula [in the formula, xxm@- and i fable 1. Or 1 1 W l' and Y Ichiho 2, or Natsu Tomiho 1 and! =Regarding Otori 4, however, 1' ” 'a'lm+1 * 'm'la+,
' e Ojg s MOB # ” ”e
ndpage:2 Dan. K m -000- . -000- Note. ● which means 11 to 18] Shinarashi's 霜石2-i11jl%-1.3-dioquinane-5 Ichirikiponma ester is represented by. Single, with a single-crystalline substance or a non-tired crystalline substance. Liao Tong - or the κ Shu character for the transformation of rays of light. Suitable for use in 11JIL Party-like equipment for re-massification of Kigo and Zuken! I put it out. An example of this monster is shown in Hisa's Jllll~4IIK. Keichu, K E III Mushibuyi 1 job Smetana Tsuta Kyoho Tomi Machitsuku Toiam isotropic presentationendpage:3 The monster in this place is a low one point one κ Mushi★ shaped koji -
#CIItbik-Zheng has a high level of silence K4I-, and Kurazheng has a similar and chicken-like sound level Kml,. It exhibits high stability and low V-optical folding value. Honkarasu limit Tsute Shield Arashi no Eki Akira To 2 Chisu 21 Replacement -t
es-diokinan-S-*Kappa is to achieve the goal of es-diokinan-S. .. ! -Substituted one place, nan-carboxylic one in 3-dio theonyl tertide. S#7 Rilta-like Tweed or ^-Dan-like Jllll I/1 Yarigun Kudon body. Let's make the reaction of the base of K4I and make it the corresponding one-nighter 2-id. Next, it is esterified with alcohol or substituted phenol by a method known per se. Reaction formula: The field κ of this reaction is katal《pekikoto κ, okumen-1, sumi-
Dioquinancarpone* plays the role of a phoenix-like dragon named ^-Gun Donor K, and Mitsutomi is IJ-Geo now ty play's Minekai #C
A storehouse that has scissors. I can't ss for one. 21 place jl-1. J-dioquinane-2-carpo y years old is
! -Iso1 Tou Building-1.1-Gioki t-1 S-RikiklM
Accordingly, the corresponding aldehyde and bismethyl methyl-machini-shun diether ester were subjected to a κ reaction under the supervision of Kazushio Honpei. Inogu Yaribi endpage:4 Lou 1. s-dioquinane-5,5-dicarpone as diethyl ester and following hydrolysis and brachylupo dP
It is possible to add Yongmen κ according to the sill j1iκ [厘. L. Engineering ν-
Le (慝l1●l), I. D. punks (peng ank)
s) ; Journal of American Little Cal.
Soviet engineer? - (J.▲■●Zen.Ok●Peng.1●0.
)? 4. 171 members of Jl (1?72)) Please correct this Asahikata. Publicly known κ in document K2
One meal - 7 Rukiru and 2 - (Okihata - Ariichiru) -
The success of tms-dioquinane-5-carpone. The resulting pure substance can be esterified with a pure alcohol or substituted 7-enol. *Hata κ is an unknown 21 substitution-1. The i-dioquinane-2-carpone ester is produced. This separated ester's cis/totsunsu ^ marrow experience hardware is. Totsuns - Only the A body is crystal St -
Because Ichiriki is an island with a strong fist, κ. It can be divided according to Bakusaku - Akira κ. According to 11&κ of this threat. It is possible to assemble the crystal material of the present invention even with the following Nong I Shin κ cited by M Kajima Rui or Naka # A Sheng Weiichi: This discovery is given by the following lI koji Yu κ page k Seiichi k Mizutsuru. do. Examples 1 to 1k of mm, one compound containing a Honryu-sized chemical compound was listed and tried. Book address - 1) H-zomantk na i example 4 ~ Hatake κ is what it says #K
I'm going to die. Confucianism 1: Ordinary original bottle [Meyer (M@i@r), (}.
: ftsuk!冫(Hatake Aokm Kameronron), m. :jl17
'Grabma1sr, J. @.
; Use of g crystal (▲pj11i(1&tiOIIJ●r
Liquia crystals) #be69冫/
/%Idelbelda/=A■1/(1975)) κ has been used in the electric party cell based on the Go basis. Try the following aI Wei's Insect Society 4 (臘Wei: ■Ol%, 1 (1@) in Kingo): This warm hardware has stolen the following sex purchase. 1 1.5~4. S.M 4 1.ra I#One gun pressure: Qml.4▼ Key I one hour Tomi tho.., -5 0 0 11#
1 decrease time: t5. % wealth 1 field @ 1-layer thickness: del
2.1μ Argument j[ :T=”20℃ Yoshiso $4!. Test the following ink metal in −kAI of Yoshiso II11 (I O 2 1101% at Kurabe)● This roaring compound is Indication of sex purchase: KM-111-1-1os In Adjustment voltage: 蓼■ .4▼ Zen pongee time: t 鳳..%-6 い-锜一-絨掘: t 厘,.% -17 ●@S layer 廖Sa Niichiho 12.●^Karasukame J[:!Maro 20℃ endpage:5 Teiichikai 1: Test the following 1 compound in Jitsui IIA Shin IK Kenrasel with test knife 4 (
IQj 鳳●l%) in the bonsai: This #) Sumikinmono shows the following sexual penetration: K t~11 II us~t Hatake! 1 voltage: U L. SV - brass time! t m IO 1 @ 11
8 鳳S-% Sieve” Ili @ t myxomm1is% Thickness @: a m 1 1.5 pm Temperature:!
■2●℃ 11711114: 1-(4--~Henaka syloxy-fer)-1.1-diomenan-5-Calpon iron (sll) 0-member structure: 2 L4 1 (0.1 11@l )
#) to 4-m-+Vz*xybenzaldehyde and 24.2 J (0.11 mol) of bishydride tidP-simet-diedel ester. 1j@-Nobe 冫{冫41K tte o, III) p
-Toluensul Honjia'4l Amagan KIl#F Lower Km Toki Seki Jg heats up. Cooled KiκMaMO0. 2%#[
Then, the next book, K, imitates the Hawk Lord, washes it, and then Kbe under pressure.
Seize the woman (Ichitenshiki jfly #I) and heal the sea bream (ffi-(
4-@ichihekiwayjdpY-7xxst)-1. I
-1) #dttl-L@-Dicarbonate Tsujie fk esthetics #1] Alx-#K? Re-Saba Akira 8 < Lm
If)'lIkkl m 1 1cs logical value 76
It is % medicine. 1 is easy ● ℃ 4j and S strict (-- to Nakanan to 冫.tribute K Takeo Todoroki 14 for K, n I J ( 1
1.0 7 4 mol) l) 1 m1 and 1 a I
Is(Isd) the ILOM of (Qj!son)
O? κ1 under ma in S% ethanol MJlg-hinge.
From that +Ikκ Ryōsho coalescence, add ethanol w★. jE
Attached is 1K books by Goichi Ohata, and the true nature of 1●~S●a4κ
Aim. 1●●-'s Emeno k-K@T
: Cool and add salt to -1 m while stirring.
Next, I'm going to do a quick Ether episode with Shizuka. Wash with books-L 1
1 M
7) - 1. i-Geo◆Nan-5. Sea bream m (1
4. s#. - 62% of the theoretical value) is reacted at 120℃ to 170℃ under the pressure of Honpachi pump. /K”l (Jl crystal treatment 4m5
aO Shuutei is 4% of Hanronkei. ■'s spear point is 174
There is ~171'C"e. There is 1111K*L of koji paste. Ceremony #15: 21-brittle-hekicle-11-diokit-5-carpon Ill (ha) composition 114I (1 l) hep I-nor and 2411 (
1.1 mol) of bis-k}'-xymethyl-! 2-I1-hexyl-14-dioxyl-5,5-dicarboxylic acid is prepared from the 1yll diester ester and Jul4. 24#( 0.0 1 is
ol ) Ol &', 1 h eel #) jl K. @KjlaL with five casting spears at once at Inoshita (2 o'clock Seki) Arm strength report Nakasil roaring reaction @Hinoki MllkK20%MQIIICC (-K
11% aiOJ, lm! Hysulwaha ctH ridges and cleansed. Dry it in 1 o 4, and then put it in a #Iml theory★F & K one-turn type bag - in the V Yuto Hekinan κ process. Sa yield: ts# (@Ron 10) 85 %), m points = 11
t~th at, Yizen example 4: 2r island-hexyl-1. Violent-Gio Chuf-
! %-i1kskl 冫子一 (4-v AN-7ENIL ESNA K) (Sho Reef》) 1. o a I (Q-●1 ol)'s 51 is chewed ●-'s drama book Ether K # Interpretation,● .4-Ippon virigi ν
endpage:6 Add S and use ice/salt mixture ●~101:κ
Cooling. Next 1cfJ. 41 thionyl clotoid-
As a result, a precipitate (pyridine-hydride) was formed.
/ o 9 id) is drawn 1 P*. Arising Koyu El2
Ido (motherly) 5-birth water bisozin and 11 1 (
9.0 After adding 4-hidden benzonitrile to the temperature of 2 to 5 o'clock, the temperature reaches the threshold of 2 to 5 o'clock. I (laJ's z-tz and Hatakekai.Wed.M
Wash with aMO01 111mκ. Mazl04
Then, remove the first layer with Kantenshiki 1 Ryuzen. Re-crystallize the residue with methanol. 1-Yield 20. h-1 (51% of the plant value). K4
4 (M 4 7.5)▲1. w41IIA$91
: Preparation of 2-*-#Ifh-Lm-di10nan-5-carpone-(4-cyanyl 7-diyl ester) (If) 2.4 4 1 (0.9 1 m@l) 21 Kneeling Otachiru-1. i-dioquinane-5 Ichiriki #Ponki he
, with Teo Elter Tweed of K2- under the dark casting theory. Heat ``f'' under Ra until the gaseous growth dies (for 2Q worth of koji).
Under the pressure of that dislike κ Mizuzo Pong #C, 4-'s thioniruku u'
) I love you. Place K# trout in a single water solution (S-) and stir under 141 (●.●sing-冫の4-HYDOXYBENZONI}V# and I1a#) from 2 to S. Place this reaction material on ice, mix the resulting 4mm material with methanol, and then repeat the process with 4a1 and 4a1. 1M-[OMlll armpit. Wash with 1●% concentration and 100% chloride, dry line with llax #04, stir the casting mound, and re-stamp with methanol. 1t#) Yield: 4s% of the theoretical value, K49. @II
7 0.5 1s Example ●: 2- (4 servings - Hexyluael) -
1. s-geo junior high school teacher-2-★Rebon #! -4-cyan 7
5 of 4 1 (0.0 0 7 mI@l) of ester (11)
1. ●. a I (●.●●7 servings●l) of 4-hyde w4F
Cybenzo 1 tolyl, 1.4 kl (il.0 0
7 mol)#) DiV/El to now sil *#M diimide. Beejin of 0.551 (LD07e@l). 5
011JJ! ) Stir the water in ether at 5 o'clock. Next κ. The resulting tjJll product was removed. Fi
# in water, ilaMOo, 2% lII district! −
Then wash with water. Ether extract ma, go4
EI&L. A cast steel one-turn type evaporator is the best?
Recrystallize I/jL with methanol ● tt concentration 1:1. y#(4o% of jll value);
K1 ink 1 111471g, endpage:7

Claims (1)

【特許請求の範囲】 (1)特にK.透過または反射する光を変sie8せる
為の着びIIcI11字.起号および一彫を再構する為
の竃気光学的構造費本用の,置満一唱.5−ジオキす冫
を基礎とするネ!チツク畝晶において.一鍍式 C式41.Xズ鳳10そしてfz鳳,またを寡X!l’
そLでv m m” ,またはx m m’  そして
!=一 な意鰍し,fflL Z 遮 −GQQ−  .  −000−なM.―富壜
〜1oを意鍬する.〕 で表わされる盾璃の痕蟲2一置換−Iμ−ジオキナン−
5−カルポン繊エステルな畳蒙とする上記ネ▼テツク痕
蟲. (至)早−で.−亙の蟲合状履および/または伽の献晶
物質または#績晶物質との墨金状層で使用する 41許
一求のsim属1硯起槙0ネ▼チツク献晶. (4)lI#K.遥通または反射する光を変関させる為
の並びκ倣字,紀号およびilsを4楓する為の竃jl
Lt.学的榔造畳嵩用の,置換−1.1一ジオ今ナンを
−顧とするネ!チッタ漉晶0−鍍式 ?〔武中,X==鳳1−  そしてYmが.ま*はX 
Illm l’そして!一翼1,またはlwa鳳1 そ
しendpage:1 てY賦鳳4 を意Ii&L,但し なお,烏聰1〜10を1kする.〕 で貴わされるIliI臘の龜晶トツンス一意一置換− 
lj−ジオキナンー5−カルポン鐵エステルを凋造する
#C−って.2一置儀−1.s−ジオキナン−6−11
kポン置をtオニルクーツイド,スル7リルタmyイド
またはAllグン化リンの如會^−ダン供与体kよって
殊K有磯4槻&の不憂奄下κ相応する毅クayイドκ転
化し.aKm体公知の方法でアルコールまたは1m−フ
ェノールと反応させることt脣黴とす41上紀卑マチツ
タ畝晶#)II造方法.
[Claims] (1) Especially K. Kimono IIcI11 letters for changing the transmitted or reflected light. Kazusho Okimitsu for the cost of the optical structure for reconstructing the original name and Ichibori. 5-Based on Geokisu Me! In Chitsuku Uneaki. One shot type C type 41. X's Otori 10 and fz Otori, again, a small X! l'
A shield represented by "v m m", or x m m' and! Ri no Katamushi 2-substituted-Iμ-dioquinane-
5-The above-mentioned technique is used as a carpon fiber ester tatami mat. (to) early. - Used in a black gold-like layer with 亙's 蟲联体 and/or 伽's crystal offering substance or #绿 Crystal substance. (4) lI#K. Arrangement for translating long distance or reflected light κ imitation character, Kigo and ils for 4 Kaede jl
Lt. Replacement-1.1 for Gakusukizuko Tatami-dake with one geo nowan as a reference! Citta filtration crystal 0-shading style? [Takenaka, X==Otori 1- and Ym. M* is X
Illm l'and! Ichiyoku 1, or lwa Feng 1, then endpage:1 te Y Feng Feng 4 means Ii & L, however, Utian 1 to 10 are 1k. 〕 Unique replacement of IliI 臘
#C- which produces lj-dioquinane-5-carpone iron ester. 2 Ichigi-1. s-dioquinane-6-11
By converting the kpon to the onylkutoid, sul7lyltamyid, or all-glycan phosphorus like ^-dan donor k, the corresponding kikuayid κ is converted to the corresponding keikyuid κ. aKm body is reacted with alcohol or 1m-phenol by a known method to form a mold.
JP2389083A 1982-02-17 1983-02-17 Nematic liquid crystal and manufacture Granted JPS58152880A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DD23746882A DD204102A1 (en) 1982-02-17 1982-02-17 APPLICATION OF NEMATIC LIQUID CRYSTALS
DD07D/237467-3 1982-02-17
DD09K/237468-1 1982-02-17

Publications (2)

Publication Number Publication Date
JPS58152880A true JPS58152880A (en) 1983-09-10
JPH0362195B2 JPH0362195B2 (en) 1991-09-25

Family

ID=5536748

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2389083A Granted JPS58152880A (en) 1982-02-17 1983-02-17 Nematic liquid crystal and manufacture

Country Status (2)

Country Link
JP (1) JPS58152880A (en)
DD (1) DD204102A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017002006A (en) * 2015-06-15 2017-01-05 Dic株式会社 Manufacturing method of carbonyl compound
JP2017002005A (en) * 2015-06-15 2017-01-05 Dic株式会社 Manufacturing method of carbonyl compound using decarboxylation reaction

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5585583A (en) * 1978-12-13 1980-06-27 Ueruku Fuyuuru Fueruzeee Rekut Substituted liquid crystal 1*33dioxane*its manufacture and liquid crystal composition containing it for photoelectric element
JPS56156274A (en) * 1980-04-03 1981-12-02 Timex Corp 5-substituted-2-(4-cyanophenyl)-1,3-dioxane

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5585583A (en) * 1978-12-13 1980-06-27 Ueruku Fuyuuru Fueruzeee Rekut Substituted liquid crystal 1*33dioxane*its manufacture and liquid crystal composition containing it for photoelectric element
JPS56156274A (en) * 1980-04-03 1981-12-02 Timex Corp 5-substituted-2-(4-cyanophenyl)-1,3-dioxane

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017002006A (en) * 2015-06-15 2017-01-05 Dic株式会社 Manufacturing method of carbonyl compound
JP2017002005A (en) * 2015-06-15 2017-01-05 Dic株式会社 Manufacturing method of carbonyl compound using decarboxylation reaction

Also Published As

Publication number Publication date
DD204102A1 (en) 1983-11-16
JPH0362195B2 (en) 1991-09-25

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