JPS58135427A - Pyroelectric infrared ray detector - Google Patents

Pyroelectric infrared ray detector

Info

Publication number
JPS58135427A
JPS58135427A JP57017303A JP1730382A JPS58135427A JP S58135427 A JPS58135427 A JP S58135427A JP 57017303 A JP57017303 A JP 57017303A JP 1730382 A JP1730382 A JP 1730382A JP S58135427 A JPS58135427 A JP S58135427A
Authority
JP
Japan
Prior art keywords
pyroelectric
electrode
photodetecting
basement
window material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57017303A
Other languages
Japanese (ja)
Inventor
Katsuyoshi Fukuda
福田 勝義
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Tokyo Shibaura Electric Co Ltd filed Critical Toshiba Corp
Priority to JP57017303A priority Critical patent/JPS58135427A/en
Publication of JPS58135427A publication Critical patent/JPS58135427A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/10Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
    • G01J5/34Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors using capacitors, e.g. pyroelectric capacitors
    • G01J5/35Electrical features thereof
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/10Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
    • G01J5/34Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors using capacitors, e.g. pyroelectric capacitors

Abstract

PURPOSE:To increase the adhesion of a photodetecting electrode to a pyroelectric body and at the same time to prevent deterioration of said electrode due to the surface oxidation to improve reliability of a pyroelectric infrared ray detector, by coating a protective film made of a silicon thin film over the photodetecting electrode of a pyroelectric element. CONSTITUTION:A pyroelectric chip, i.e., a pyroelectric element 10 which is obtained by coating a protecting silicon thin film over a photodetecting electrode, an FET12, an input resistance chip 13 and an output resistance chip 14 are attached by an adhesive on a basement 11. The basement 11 has a silicon window material 15 and is sealed with a shell 16 to keep the prescribed atmosphere at the inside the basement 11. The infrared rays are made incident through the window 15 and absorbed by the photodetecting surface of the element 10. As a result, the element 10 has a temperature change to generate the corresponding electric charge. This electric charge is led to the FET12 to undergo an impedance conversion and then extracted outward as signals through a lead terminal 17.

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は、焦電型赤外線検出製置の改良に関する・ 〔発明の蚊術的′に量とその間鰯点〕 焦を型赤外線検出装置は、無産1lllr体区二吸収さ
れた赤外線C;よる温度変化で表面(二発生する゛i荷
t−測定し、上紀赤外線感;対応した出力!検出するも
のである・赤外線の検出感度を高めると共に応答ン速め
るため、焦電体は、数10pmの薄片にして用いられる
・このため1例えば焦電体としてLiTa0.単結晶な
用いる場合、焦電体自身の吸収特性とも合まって赤外線
吸収塾はμm以上の長波長帯C;大きく、短波長帯では
小さくなる。膜長依存性ン少なくするため、SX体表面
に光吸収材な配賦するのが一般的であり、この場合電極
とかねてしばしば金属薄膜が用いられる。金−fII膜
としては、白金黒や全島等の賞金属の他に、ニッケルや
ニッケルーブロム合金等の比較的比抵抗の高い金−展が
用いられているO しかしなかす、前者では密春力が低く(1頼性か低いの
が欠点である・また、後者では数10〜数10OAとい
う非常−二薄い膜の状態で用いるため表面酸化等で性質
が変化し昌<、前者に比べて4I8I軸性は高いが、長
期安定性に欠けると云う間融があった◎ 〔発明の目的〕 不発例の目的は、受光−極の集電体への密看力1に:l
1ri化できると共(:、受光電極の表面酸化C二よる
餐實を防止することかでき、他軸性および安定性の向上
をはかり得る焦゛q型亦外線検出装置V提供Tること(
:ある・ 〔発明の概要〕 不発明者等は、^i1紀受光受光電極てのニッケル或い
はニッケルークロム合金膜の岐化Yl?j止するために
、該合金膜上Cニレジストからなる保護MY被嶺するこ
とt先≦:打電した0レジストは半尋体工業で実用化さ
れていて誤まりが少なく容易C;形成で8.かつ′1@
誉力が尚いので、その保護効果は極めて大きい。しかし
、不兄明者嗜の実験によれは 上記保m膜としてレジス
トY用いた場合、レジストが機械的C″−翁く引つかさ
−が入り易いこと3;起因して゛1歩留りの低下を招く
ことか見出された・そこで、レジストの代りに保護効果
が大で、かつ機械的にも強いシリコン膜を用いれば上記
問題は解決されると考えられる・ 本発明はこのような点I:看目し、赤外線v4人するた
めの密林と、この密林を支持すると共に該密林とで囲ん
だ空間を一定雰囲気C保持する容器と、焦電体の受光面
にニッケル或いはニッケルークロム合金膜からなる受光
電極を形成すると共に反対面に対電極な形成してなり、
上記窓材および容器で曲んだ空11j(:配設された戦
′IIL累子とtJ4備した思電型赤外線検出装置C:
おいて、前記胤電菓子の受光電極上1;V9コン麹膜か
らなる保護膜を被暑するようにしたものである0 〔−発明の効果〕 本発明感−よれば、受光電極としてニッケル或いはニッ
ケルークロム合金wAを用いていることから、受光電極
の焦電体への密省力を十分大きくすることができ、ざら
−二受光電極の酸化を防止する保護膜を設けているので
、受光電極の酸化による変1itt’未然C;防止する
ことができる・このため、悉菫型赤外線検出装置の信頼
性同上ネjよび経時安定性向上をはかり得る等の効果を
奏する・また、保a農として機械的42強度なシリコン
say用いているので、この保護膜の傷発生等感二起因
して上記装−の歩貿り低下を招くこともないと云う利点
がある・ 〔発明の実施例〕 第11V(1〜(d)は1本発明の一実施例I:使用し
た。5竃集子の製造工程を示す断面−である・ます、 
第11z(a) c示す如く直径60 m 、犀さ50
μmのL i T a Lea−Zカットウニ八からな
る焦電体l上6;受光電極2としてのニッケルークロム
台金膜w2ooXの厚さで直径2−リン真空蒸看等で遍
択形成した◎そしそ、受光電極21;−接して配線用の
At膜1v約2−の厚さシ:廐択形成した。
[Detailed Description of the Invention] [Technical Field of the Invention] The present invention relates to improvements in a pyroelectric infrared detection device. Infrared rays are absorbed by the body; due to temperature changes on the surface (2), the infrared rays generated on the surface are measured; In order to speed up the response, the pyroelectric material is used in thin pieces of several tens of pm.For this reason, for example, when using a single crystal of LiTa0 as the pyroelectric material, infrared absorption is Long wavelength band C of μm or more; large, and becomes small in short wavelength band.In order to reduce film length dependence, it is common to arrange a light absorbing material on the surface of the SX body, and in this case, it is often used as an electrode. A thin metal film is used.As the gold-fII film, in addition to prize metals such as platinum black and Zenjima, gold-based films with relatively high resistivity such as nickel and nickel-brom alloy are used. The disadvantage of the former is that the strength is low (low reliability).In addition, the latter is used in an extremely thin film of several tens to several tens of OA, so its properties change due to surface oxidation, etc. , the 4I8I axiality was higher than the former, but there was a problem that it lacked long-term stability. :l
To provide a concentric type extra-radiation detection device V which can be made into a single integrated circuit, which can prevent damage caused by surface oxidation of the light-receiving electrode, and which can improve multi-axis property and stability.
:Yes・ [Summary of the invention] Those who do not invent the invention are interested in the branching Yl of the nickel or nickel-chromium alloy film of the 1st generation light-receiving electrode. In order to prevent this, the alloy film must be covered with a protective MY resist made of a C resist.T ≦: The electrically applied O resist has been put into practical use by the Hanhiro Tai Kogyo and is easy to form with few errors. Katsu'1@
Since it has a high honor power, its protective effect is extremely large. However, according to unscrupulous experiments, when resist Y is used as the above-mentioned molar retaining film, the resist is susceptible to mechanical C'' - which leads to a decrease in yield. Therefore, it is thought that the above problem can be solved by using a silicon film that has a large protective effect and is mechanically strong instead of a resist.The present invention solves this problem. It consists of a jungle for four people to view and infrared rays, a container that supports this jungle and maintains a constant atmosphere C in the space surrounded by the jungle, and a nickel or nickel-chromium alloy film on the light-receiving surface of the pyroelectric body. A light receiving electrode is formed and a counter electrode is formed on the opposite side.
The sky 11j bent by the above window material and container (: Thought-type infrared detection device C equipped with Sen'IIL Seiko and tJ4 installed:
According to the sense of the present invention, a protective film made of a V9 koji film is exposed to heat on the light-receiving electrode of the Tanden confectionery. Since the nickel-chromium alloy wA is used, it is possible to sufficiently increase the density of the light-receiving electrode to the pyroelectric material, and since a protective film is provided to prevent the oxidation of the light-receiving electrode, the light-receiving electrode It is possible to prevent deterioration due to oxidation of Since mechanically strong silicone is used, there is an advantage that there is no reduction in the manufacturing efficiency of the device due to the occurrence of scratches on the protective film. [Embodiments of the Invention] 11V (1 to (d) are 1 Example I of the present invention: Used.
No. 11z (a) c As shown, diameter 60 m, rhinoceros size 50
On the pyroelectric material 1 consisting of L i T a Lea-Z cut sea urchin of μm 6; nickel-chromium base gold film as the light-receiving electrode 2 with a thickness of 2-diameter 2-phosphorus vacuum vaporization etc. Then, the light-receiving electrode 21 was formed with a thickness of about 2 volts and an At film for wiring in contact with it.

次いで、弔1図(呻≦二示す如くシリコン薄膜からな゛
る保護FI44’に受光電極2 ’C合せて2000〜
5000 A蒸着形成した・ざら(−1恩電体lの表面
C一対′蝋4!ikjとしてのニッケルークロム合金膜
・v200λの厚さで全面に形成した・その後。
Next, as shown in Figure 1 (Oan ≦ 2), the protection FI 44' made of a silicon thin film and the light receiving electrode 2'C are combined to 2000 ~
A nickel-chromium alloy film with a thickness of 200λ was formed on the entire surface as 5000A by vapor deposition.

!I%IIN(c)に示す如くエツチング等で中空加工
した中空シリコン支持体6を電極形成した焦電体J c
導電接着剤r等で接着する′こと砿:より、1枚のウニ
八日C:多数の焦電素子10v形成した。
! I%IIN (c) As shown in (c), a pyroelectric body J c is formed by forming an electrode on a hollow silicon support 6 that has been hollowed out by etching or the like.
A large number of pyroelectric elements (10v) were formed on one sheet of pyroelectric elements by bonding them with a conductive adhesive or the like.

次いで、第1−(d)C示す如き各々の無電素子10に
するため、ダイリング一二よりウニへを分割した・ 第2内は、本発明の一実施例製麹の概略構成ヲ一部切欠
して示す斜視−である・4105ヘツダの基台lJ上C
;上記の方法で作られた焦電テップ、fなわち焦電素子
lOと、FBTz J、入力抵抗チップtsi6よび出
力抵抗テップ14とが接看剤≦;よって配設されている
・これら無電素子10、FBTIJ、入出力抵抗13.
14は、ボンデングによって電気的に接続される・基台
全体は、シリコン窓材15が支持され、なおかつ内部を
一定雰囲気に保持できるシェル16で封止されている・ 赤外−はシリコンWE715 j’通して入射し、焦電
素子IOの受光[kl 10 a c吸収され、焦11
素千lOの温度変化ケおこし、これ5:対応して電f七
Y発生させる・軍備はFITJ2に辱びかれ。
Next, in order to make each electroless element 10 as shown in Part 1-(d)C, the die ring 12 was divided into sea urchins. Part 2 shows a part of the schematic structure of the koji-made koji according to an embodiment of the present invention. This is a perspective view shown with a cutaway.4105 header base lJ top C
The pyroelectric tip, f, that is, the pyroelectric element lO, made by the above method, the FBTz J, the input resistor chip tsi6, and the output resistor tip 14 are disposed as a contacting agent≦;Thus, these non-electronic elements 10. FBTIJ, input/output resistance 13.
14 is electrically connected by bonding.The entire base supports the silicon window material 15 and is sealed with a shell 16 that can maintain a constant atmosphere inside.Infrared is made of silicon WE715 j' The light enters through the pyroelectric element IO and is absorbed by the pyroelectric element IO [kl 10 a c, and the pyroelectric element IO
A temperature change of 1,000 lO is caused, and this 5: In response, an electric current of f7Y is generated.・The armament is humiliated by FITJ2.

インピーダンス変換された後FBTI:Iのソース側か
らm++記基台11v押通し、かつ絶猷体によって支持
されたリード端子12を介して外部にイ目号として取出
される。
After impedance conversion, the m++ mark is pushed through the base 11v from the source side of the FBTI:I and taken out as an I mark to the outside via the lead terminal 12 supported by the insulated body.

このように41Htkされた本装置gkv12s℃。This device gkv12s℃ was heated for 41Htk in this way.

1000時間のIIibIM保存試験を行なったところ
A 1000 hour IIbIM storage test was conducted.

従来の保護膜なしの焦?liI型赤外線検出装置では不
良率3僑であったのが、保dISを形成した本装置では
0.1鳴以下I:同上した・これは、受光−極2として
のニッケルークロム台金膜の酸化1による不良が減少し
たためである・かくして1本爽弛例3:よれは、ニッケ
ルークロム台金Y用いた受光電極2の他軸性を大きく同
上させ。
Traditional oxidation without a protective film? In the liI type infrared detection device, the defect rate was 3%, but in this device with a protective IS formed, it was less than 0.1 I: Same as above. This is due to the failure rate of the nickel-chromium base metal film as the light receiving electrode 2. This is because the defects due to oxidation 1 have been reduced. Thus, one wire has become loose.

不変−【3僑から0.1%以下(二大きく低減すること
かできた。
Unchanged: 3% to 0.1% or less (2) A significant reduction was achieved.

なお1本発明は上述した*&例(二限定されるものでは
なく、その要′#11に逸脱しない範囲で檀々変形して
実施することができる・例えばs 自+]紀受光電極と
してはニッケルークロム台金膜の代1月二ニッケルNY
用いてもよい・また、−1記焦電体はLITa01単結
晶としたが、他の魚篭体でも同様な効果が得られるのは
勿論のことである・
Note that the present invention can be carried out in various ways without departing from the above-mentioned *& examples (2), but are not limited to them, without departing from the main points. Nickel-chrome base gold film price January 2 Nickel NY
Also, although LITa01 single crystal was used as the pyroelectric substance in -1, it goes without saying that similar effects can be obtained with other fish cages.

【図面の簡単な説明】[Brief explanation of the drawing]

fm 1 図(4)〜(diは本発明の一実施例1ユ使
用した焦電素子の製造工程を示す断面内、第2図は本発
明の一実施例の概略構成を一部切欠して示す斜視図であ
る・ l・・・LiTaL)、ウェハ廖電体入2・・・受光電
極、3・・・At膜(配線電極)、4・・・シリコン保
護膜。 5・・・対電極、6・・・中空シリコン支持体、7・・
・尋゛岨性接暑剤、to・・・焦電素子、71・・・基
台、72・・・FNT、13・・・入力抵抗、14・・
・出力抵抗、ts・・・シリコンf/B、1g−r・シ
ェル、77・・・リード端子0
fm 1 Figures (4) to (di are cross-sectional views showing the manufacturing process of the pyroelectric element used in Example 1 of the present invention, and Figure 2 is a partially cutaway diagram of the schematic structure of an example of the present invention. 1...LiTaL), wafer-containing electrode 2...light receiving electrode, 3...At film (wiring electrode), 4...silicon protective film. 5...Counter electrode, 6...Hollow silicon support, 7...
- Thickening heat exchanger, to...pyroelectric element, 71...base, 72...FNT, 13...input resistance, 14...
・Output resistance, ts...Silicon f/B, 1g-r・Shell, 77...Lead terminal 0

Claims (1)

【特許請求の範囲】[Claims] 赤外線Y導入するための窓材と、この窓材を支持すると
某−;核窓材とで囲んだ空間l一定定日囲気保持する容
器と、煕鴫体の受光面にニッケル或いはニッケルークロ
ム合金膜からなる受光−極Y#成すると共に反対面6二
対爾極を形成してなり、上記窓材・および容器で囲んだ
空間に配設された思電素子とン興儒した嵐電型赤外線梗
出装−C;おいて、かjir′、麿、場素子の受光゛−
極上にシリコン#展からなる保wmyx′4j!看して
なるものであることを特徴とする烈電型赤外線検出製k
A space surrounded by a window material for introducing infrared rays Y, a nuclear window material that supports this window material, a container that maintains an atmosphere for a fixed period of time, and a nickel or nickel-chromium alloy on the light-receiving surface of the glass body. It is composed of a light-receiving pole Y# consisting of a membrane, and 62 pairs of opposite poles, and is an interesting Arashiden type with a thinking element arranged in the space surrounded by the window material and container. Infrared radiation exposure device-C;
Ho wmyx'4j consisting of the best silicon #exhibition! A product made by electric shock type infrared detection, which is characterized by the fact that it can be detected by
.
JP57017303A 1982-02-05 1982-02-05 Pyroelectric infrared ray detector Pending JPS58135427A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57017303A JPS58135427A (en) 1982-02-05 1982-02-05 Pyroelectric infrared ray detector

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57017303A JPS58135427A (en) 1982-02-05 1982-02-05 Pyroelectric infrared ray detector

Publications (1)

Publication Number Publication Date
JPS58135427A true JPS58135427A (en) 1983-08-12

Family

ID=11940233

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57017303A Pending JPS58135427A (en) 1982-02-05 1982-02-05 Pyroelectric infrared ray detector

Country Status (1)

Country Link
JP (1) JPS58135427A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62822A (en) * 1985-06-27 1987-01-06 Matsushita Electric Ind Co Ltd Infrared detecting element
JPS6367531A (en) * 1986-09-10 1988-03-26 Matsushita Electric Ind Co Ltd Dielectric thin film element and its manufacture

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62822A (en) * 1985-06-27 1987-01-06 Matsushita Electric Ind Co Ltd Infrared detecting element
JPS6367531A (en) * 1986-09-10 1988-03-26 Matsushita Electric Ind Co Ltd Dielectric thin film element and its manufacture

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