JPS579728A - Preparation of hydroxy aromatic compound - Google Patents
Preparation of hydroxy aromatic compoundInfo
- Publication number
- JPS579728A JPS579728A JP8392980A JP8392980A JPS579728A JP S579728 A JPS579728 A JP S579728A JP 8392980 A JP8392980 A JP 8392980A JP 8392980 A JP8392980 A JP 8392980A JP S579728 A JPS579728 A JP S579728A
- Authority
- JP
- Japan
- Prior art keywords
- aromatic compound
- ion
- pentaazacyclohexadecane
- dione
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled compound advantageously, by oxidizing an aromatic compound with molecular oxygen in liquid state in the presence of an aqueous solution of complex of a metal ion, e.g., Ni ion, etc. and 1,4,7,10,13-pentaazacyclohexadecane-14,16-dione in the weight ratio 1:1.
CONSTITUTION: A mononuclear or binuclear aromatic compound, e.g., benzene, naphthalene, etc. is subjected to contact reaction with molecular oxygen in the presence of an aqueous solution of complex comprising a metal ion, e.g., iron, nickel, cobalt, or copper ion and 1,4,7,10,13-pentaazacyclohexadecane-14,16-dione in the weight ratio 1:1 as a catalyst at preferably 20W40°C in liquid phase, to give directly at room temperature a hydroxy aromatic compound wherein hydroxyl group is bonded to the aromatic nucleus. Since the catalyst is recovered under reaction conditions to original active state, the addition of a third component, e.g., reducing agent is not required and the reaction is carried out catalytically.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8392980A JPS579728A (en) | 1980-06-23 | 1980-06-23 | Preparation of hydroxy aromatic compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8392980A JPS579728A (en) | 1980-06-23 | 1980-06-23 | Preparation of hydroxy aromatic compound |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS579728A true JPS579728A (en) | 1982-01-19 |
Family
ID=13816279
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8392980A Pending JPS579728A (en) | 1980-06-23 | 1980-06-23 | Preparation of hydroxy aromatic compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS579728A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010511045A (en) * | 2006-11-28 | 2010-04-08 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Method for the synthesis of hydroxyaromatic acids |
-
1980
- 1980-06-23 JP JP8392980A patent/JPS579728A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010511045A (en) * | 2006-11-28 | 2010-04-08 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Method for the synthesis of hydroxyaromatic acids |
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