JPS5785359A - Preparation of chlorobenzenesulfochloride (chlorobenzenesulfonyl chloride) - Google Patents
Preparation of chlorobenzenesulfochloride (chlorobenzenesulfonyl chloride)Info
- Publication number
- JPS5785359A JPS5785359A JP16074380A JP16074380A JPS5785359A JP S5785359 A JPS5785359 A JP S5785359A JP 16074380 A JP16074380 A JP 16074380A JP 16074380 A JP16074380 A JP 16074380A JP S5785359 A JPS5785359 A JP S5785359A
- Authority
- JP
- Japan
- Prior art keywords
- water
- chlorosulfonic acid
- sulfuric acid
- acid
- excess
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled compound of high purity without discharging the waste water, by decomposing and removing the excess chlorosulfonic acid in the reaction product of chlorobenzene with the chlorosulfonic acid, dissolving the excess chlorosulfonic acid in an organic solvent, washing the solution with a small amount of water, and reusing the resultant waste water in the decomposing step.
CONSTITUTION: The reaction product of chlorobenzene with chlorosulfonic acid is dropped to water or dilute sulfuric acid metered to give the sulfuric acid concentration of 60W90% in the sulfuric acid layer after completing the decomposition of the excess chlorosulfonic acid to decompose the excess chlorosulfonic acid, and the formed hydrogen chloride is driven out of the system. A chlorobenzenesulfochloride (chlorobenzenesulfonyl chloride) layer is then separated from the sulfuric acid layer into a liquid state at 50°C or above, dissolved in an organic solvent, e.g. hexane, washed with a small amount of water and purified. The waste water after the washing with water is reused as a water component in decomposing the excess chlorosulfonic acid or as the water component in preparing the dilute sulfuric acid used for the similar purpose.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16074380A JPS6034946B2 (en) | 1980-11-17 | 1980-11-17 | Method for producing chlorobenzene sulfochloride |
GB8130118A GB2087386B (en) | 1980-10-14 | 1981-10-06 | Process for producing chlorobenzene sulfochloride |
FR8119353A FR2491923A1 (en) | 1980-10-14 | 1981-10-14 | PROCESS FOR PRODUCING CHLOROBENZENE SULFOCHLORIDE |
DE19813140854 DE3140854A1 (en) | 1980-10-14 | 1981-10-14 | METHOD FOR PRODUCING CHLORBENZENE SULFOCHLORIDE |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16074380A JPS6034946B2 (en) | 1980-11-17 | 1980-11-17 | Method for producing chlorobenzene sulfochloride |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5785359A true JPS5785359A (en) | 1982-05-28 |
JPS6034946B2 JPS6034946B2 (en) | 1985-08-12 |
Family
ID=15721488
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16074380A Expired JPS6034946B2 (en) | 1980-10-14 | 1980-11-17 | Method for producing chlorobenzene sulfochloride |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6034946B2 (en) |
-
1980
- 1980-11-17 JP JP16074380A patent/JPS6034946B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS6034946B2 (en) | 1985-08-12 |
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