JPS572272A - Preparation of n-phenylcyclopropanedicarboxylic acid imide derivative - Google Patents

Preparation of n-phenylcyclopropanedicarboxylic acid imide derivative

Info

Publication number
JPS572272A
JPS572272A JP7599680A JP7599680A JPS572272A JP S572272 A JPS572272 A JP S572272A JP 7599680 A JP7599680 A JP 7599680A JP 7599680 A JP7599680 A JP 7599680A JP S572272 A JPS572272 A JP S572272A
Authority
JP
Japan
Prior art keywords
phenylcyclopropanedicarboxylic
lower alkyl
preparation
acid imide
imide derivative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7599680A
Other languages
Japanese (ja)
Inventor
Noboru Nohara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP7599680A priority Critical patent/JPS572272A/en
Publication of JPS572272A publication Critical patent/JPS572272A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE: To prepare the titled compound useful as a nonmedical fungicide, in high purity, by hydrolyzing 2-dimethylcyclopropanedicarboxylic acid di-(lower alkyl) ester with heating in the presence of 3,5-dihalogennaniline under acidic conditions.
CONSTITUTION: In the preparation of an N-phenylcyclopropanedicarboxylic acid imide derivative of formula II by the hydrolysis of 1,2-dimethylcyclopropanedicarboxylic acid di-(lower alkyl) ester of formula I (R1 and R2 are lower alkyl) under acidic conditions in water, the hydrolysis is carried out by heating at 85W120°C, pref. 90°CW the boiling point of the reaction mixture, in the presence of 3,5-dihalogenoaniline (e.g. 3,5-dichloroaniline). The raw material is a mixture of cis- and trans-isomers. Only the cis isomer is imidized, and the trans-isomer can be removed as the aqueous solution.
COPYRIGHT: (C)1982,JPO&Japio
JP7599680A 1980-06-04 1980-06-04 Preparation of n-phenylcyclopropanedicarboxylic acid imide derivative Pending JPS572272A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7599680A JPS572272A (en) 1980-06-04 1980-06-04 Preparation of n-phenylcyclopropanedicarboxylic acid imide derivative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7599680A JPS572272A (en) 1980-06-04 1980-06-04 Preparation of n-phenylcyclopropanedicarboxylic acid imide derivative

Publications (1)

Publication Number Publication Date
JPS572272A true JPS572272A (en) 1982-01-07

Family

ID=13592398

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7599680A Pending JPS572272A (en) 1980-06-04 1980-06-04 Preparation of n-phenylcyclopropanedicarboxylic acid imide derivative

Country Status (1)

Country Link
JP (1) JPS572272A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59107071A (en) * 1982-12-12 1984-06-21 Nitto Kohki Co Ltd Device for forming reactive vapor deposited film on outside surface of object to be treated
JPS63105039A (en) * 1986-10-20 1988-05-10 Bridgestone Corp Production of rubber composite material
CN101906063A (en) * 2010-08-13 2010-12-08 陕西亿农高科药业有限公司 Scale synthesis process of procymidone original drug of efficient agricultural bactericide in two steps
CN111825597A (en) * 2020-07-27 2020-10-27 江西禾益化工股份有限公司 Method for synthesizing procymidone
CN114671797A (en) * 2020-12-24 2022-06-28 北京颖泰嘉和生物科技股份有限公司 Preparation method of procymidone

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS496121A (en) * 1972-04-12 1974-01-19
JPS5283366A (en) * 1975-12-27 1977-07-12 Toyobo Co Ltd Synthesis of 4-hydroxycarbonyl-n-(hydroxyalkyl)phthalimide
JPS5323964A (en) * 1976-08-12 1978-03-06 Mitsubishi Chem Ind Ltd Succinic acid imide derivatives and agricultural and horticultural fungicide containing the same
JPS5419965A (en) * 1977-07-12 1979-02-15 Mitsubishi Chem Ind Ltd Preparation of n-substituted phenyl-3,4,5,6-tetrahydro-phthalimide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS496121A (en) * 1972-04-12 1974-01-19
JPS5283366A (en) * 1975-12-27 1977-07-12 Toyobo Co Ltd Synthesis of 4-hydroxycarbonyl-n-(hydroxyalkyl)phthalimide
JPS5323964A (en) * 1976-08-12 1978-03-06 Mitsubishi Chem Ind Ltd Succinic acid imide derivatives and agricultural and horticultural fungicide containing the same
JPS5419965A (en) * 1977-07-12 1979-02-15 Mitsubishi Chem Ind Ltd Preparation of n-substituted phenyl-3,4,5,6-tetrahydro-phthalimide

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59107071A (en) * 1982-12-12 1984-06-21 Nitto Kohki Co Ltd Device for forming reactive vapor deposited film on outside surface of object to be treated
JPS6214218B2 (en) * 1982-12-12 1987-04-01 Nitto Kohki Co
JPS63105039A (en) * 1986-10-20 1988-05-10 Bridgestone Corp Production of rubber composite material
CN101906063A (en) * 2010-08-13 2010-12-08 陕西亿农高科药业有限公司 Scale synthesis process of procymidone original drug of efficient agricultural bactericide in two steps
CN111825597A (en) * 2020-07-27 2020-10-27 江西禾益化工股份有限公司 Method for synthesizing procymidone
CN114671797A (en) * 2020-12-24 2022-06-28 北京颖泰嘉和生物科技股份有限公司 Preparation method of procymidone

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