JPS57185236A - Preparation of acrylic or methacrylic ester having hydroxyl group - Google Patents

Preparation of acrylic or methacrylic ester having hydroxyl group

Info

Publication number
JPS57185236A
JPS57185236A JP56070336A JP7033681A JPS57185236A JP S57185236 A JPS57185236 A JP S57185236A JP 56070336 A JP56070336 A JP 56070336A JP 7033681 A JP7033681 A JP 7033681A JP S57185236 A JPS57185236 A JP S57185236A
Authority
JP
Japan
Prior art keywords
catalyst
methacrylic ester
acrylic
opening polymerization
ring opening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP56070336A
Other languages
Japanese (ja)
Other versions
JPS6366307B2 (en
Inventor
Masaharu Watanabe
Kiyoshi Okitsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daicel Corp
Original Assignee
Daicel Corp
Daicel Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daicel Corp, Daicel Chemical Industries Ltd filed Critical Daicel Corp
Priority to JP56070336A priority Critical patent/JPS57185236A/en
Priority to GB08213533A priority patent/GB2101121B/en
Priority to DE3217653A priority patent/DE3217653C2/en
Publication of JPS57185236A publication Critical patent/JPS57185236A/en
Priority to US07/244,525 priority patent/US4916254A/en
Publication of JPS6366307B2 publication Critical patent/JPS6366307B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PURPOSE: To obtain the titled compound useful for coating materials, etc., by the ring opening polymerization of a hydroxyalkyl acrylic ester or methacrylic ester with ε-caprolactone in the presence of a stannous halide except fluorine as a catalyst.
CONSTITUTION: A hydroxyalkyl acrylic ester or methacrylic ester is subjected to the ring opening polymerization with ε-caprolactone to give an acrylic or methacrylic ester having a hydroxyl group. In the process, a stannous halide except fluorine expressed by the formula SnX2 (X is Cl, Br or I) is used as a catalyst for the ring opening polymerization. The catalyst is highly active, and the reaction proceeds fully at a low temperature of 80W130°C with a small amount of the catalyst. The formation of diacrylates or dimethacrylates as by-products is slight. The copolymerization with another monomer provides a resin, having improved reactivity with a crosslinking agent, and rich in flexibility.
COPYRIGHT: (C)1982,JPO&Japio
JP56070336A 1981-05-11 1981-05-11 Preparation of acrylic or methacrylic ester having hydroxyl group Granted JPS57185236A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP56070336A JPS57185236A (en) 1981-05-11 1981-05-11 Preparation of acrylic or methacrylic ester having hydroxyl group
GB08213533A GB2101121B (en) 1981-05-11 1982-05-11 Process for producing e-caprolactone-modified hydroxyalkyl acrylate or methacrylate and coating copolymer from the same
DE3217653A DE3217653C2 (en) 1981-05-11 1982-05-11 Process for the preparation of an epsilon-caprolactone-modified vinyl monomer and its use for the preparation of a copolymer
US07/244,525 US4916254A (en) 1981-05-11 1988-09-09 Process for producing epsilon-caprolactone-modified hydroxyalkyl acrylate or methacrylate and coating copolymer from the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56070336A JPS57185236A (en) 1981-05-11 1981-05-11 Preparation of acrylic or methacrylic ester having hydroxyl group

Publications (2)

Publication Number Publication Date
JPS57185236A true JPS57185236A (en) 1982-11-15
JPS6366307B2 JPS6366307B2 (en) 1988-12-20

Family

ID=13428468

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56070336A Granted JPS57185236A (en) 1981-05-11 1981-05-11 Preparation of acrylic or methacrylic ester having hydroxyl group

Country Status (1)

Country Link
JP (1) JPS57185236A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0108373A2 (en) * 1982-11-02 1984-05-16 Union Carbide Corporation Process for the preparation of polymeric compositions
EP0108372A2 (en) * 1982-11-02 1984-05-16 Union Carbide Corporation Compositions containing a reactive monomer derived from a lactone
JPS59168073A (en) * 1983-03-15 1984-09-21 Mitsubishi Chem Ind Ltd Film-forming composition and method for improving surface of synthetic resin molding by using the same
JPS60110710A (en) * 1983-10-26 1985-06-17 ユニオン、カーバイド、コーポレーシヨン Manufacture of high molecular composition
US4540809A (en) * 1982-06-25 1985-09-10 Nippon Kayaku Kabushiki Kaisha (Meth) acrylate esters of dipentaerythritol caprolactone condensates
JPS6143623A (en) * 1984-08-07 1986-03-03 Daicel Chem Ind Ltd Preparation of polycaprolactone-modified hydroxyalkyl acrylate or methacrylate
JPS61181877A (en) * 1985-02-06 1986-08-14 Nippon Paint Co Ltd Thermosetting metallic paint composition
JPS6268862A (en) * 1985-09-19 1987-03-28 Toyo Ink Mfg Co Ltd Coating composition curable with actinic radiation
JPS63285537A (en) * 1987-05-18 1988-11-22 Koyo Kagaku Kogyo Kk Photosensitive composition for planographic plate making
JPH04257545A (en) * 1991-02-12 1992-09-11 Mitsubishi Rayon Co Ltd Production of caprolactone-modified hydroxyalkyl acrylate or methacrylate
US5959037A (en) * 1995-08-31 1999-09-28 Nippon Mektron, Limited Acrylic copolymer elastomer, its blend rubber and blend rubber composition

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540809A (en) * 1982-06-25 1985-09-10 Nippon Kayaku Kabushiki Kaisha (Meth) acrylate esters of dipentaerythritol caprolactone condensates
EP0108372A2 (en) * 1982-11-02 1984-05-16 Union Carbide Corporation Compositions containing a reactive monomer derived from a lactone
JPS5998118A (en) * 1982-11-02 1984-06-06 ユニオン，カーバイド，コーポレーション Composition containing reactive monomer derived from lactone
EP0108373A2 (en) * 1982-11-02 1984-05-16 Union Carbide Corporation Process for the preparation of polymeric compositions
JPH0739375B2 (en) * 1982-11-02 1995-05-01 ユニオン・カーバイド・コーポレーション Method for producing composition containing reactive monomer derived from lactone
JPH06107595A (en) * 1982-11-02 1994-04-19 Union Carbide Corp Preparation of composition containing reactive monomer derived from lactone
JPS59168073A (en) * 1983-03-15 1984-09-21 Mitsubishi Chem Ind Ltd Film-forming composition and method for improving surface of synthetic resin molding by using the same
JPS60110710A (en) * 1983-10-26 1985-06-17 ユニオン、カーバイド、コーポレーシヨン Manufacture of high molecular composition
JPS6143623A (en) * 1984-08-07 1986-03-03 Daicel Chem Ind Ltd Preparation of polycaprolactone-modified hydroxyalkyl acrylate or methacrylate
JPH0516451B2 (en) * 1984-08-07 1993-03-04 Daicel Chem
JPH0559945B2 (en) * 1985-02-06 1993-09-01 Nippon Paint Co Ltd
JPS61181877A (en) * 1985-02-06 1986-08-14 Nippon Paint Co Ltd Thermosetting metallic paint composition
JPS6268862A (en) * 1985-09-19 1987-03-28 Toyo Ink Mfg Co Ltd Coating composition curable with actinic radiation
JPH0548791B2 (en) * 1985-09-19 1993-07-22 Toyo Ink Mfg Co
JPS63285537A (en) * 1987-05-18 1988-11-22 Koyo Kagaku Kogyo Kk Photosensitive composition for planographic plate making
JPH04257545A (en) * 1991-02-12 1992-09-11 Mitsubishi Rayon Co Ltd Production of caprolactone-modified hydroxyalkyl acrylate or methacrylate
US5959037A (en) * 1995-08-31 1999-09-28 Nippon Mektron, Limited Acrylic copolymer elastomer, its blend rubber and blend rubber composition

Also Published As

Publication number Publication date
JPS6366307B2 (en) 1988-12-20

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