JPS567647A - Catalyst for isotopic exchange reaction of water-hydrogen system - Google Patents
Catalyst for isotopic exchange reaction of water-hydrogen systemInfo
- Publication number
- JPS567647A JPS567647A JP8249279A JP8249279A JPS567647A JP S567647 A JPS567647 A JP S567647A JP 8249279 A JP8249279 A JP 8249279A JP 8249279 A JP8249279 A JP 8249279A JP S567647 A JPS567647 A JP S567647A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- porous particles
- water
- styrene
- divinylbenzene copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 239000001257 hydrogen Substances 0.000 title abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 3
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 230000000155 isotopic effect Effects 0.000 title abstract 2
- 239000002245 particle Substances 0.000 abstract 5
- 229920001577 copolymer Polymers 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical group CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 229940117389 dichlorobenzene Drugs 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Catalysts (AREA)
Abstract
PURPOSE: To manufacture a catalyst which increases the ratio of hydrogen isotope yield to equipment cost, by allowing specific catalyst metal to be carried on the outside surface of porous particles and the inside surface of pores of the porous particles of styrene divinylbenzene copolymer having a specific particle diameter.
CONSTITUTION: On the outside surface of porous particles and the inside surface of pores of the porous particles of styrene divinylbenzene copolymer having 0.5W 10mm sphere equivalent diameter is carried a catalyst metal composed of one or more members selected from the metals of the eighth group of the periodic table in order to prepare a catalyst for water-hydrogen system hudrogen isotopic exchange reaction. Porous styrene divinylbenzene copolymer is prepared, for example, by mixing 280pts. styrene, 120pts. divinylbenzene, 200pts. secondary hexylalcohol, 200pts. dichlorobenzene, with 4pts. benzoyl peroxide, by initiating the polymerization of the mixture at 85°C, by adding water and calcium tertiary phosphate when the viscosity is increased to 80W120cp, and by polymerizing the mixture for 10hrs.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8249279A JPS567647A (en) | 1979-06-29 | 1979-06-29 | Catalyst for isotopic exchange reaction of water-hydrogen system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8249279A JPS567647A (en) | 1979-06-29 | 1979-06-29 | Catalyst for isotopic exchange reaction of water-hydrogen system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS567647A true JPS567647A (en) | 1981-01-26 |
| JPS5741299B2 JPS5741299B2 (en) | 1982-09-02 |
Family
ID=13775983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8249279A Granted JPS567647A (en) | 1979-06-29 | 1979-06-29 | Catalyst for isotopic exchange reaction of water-hydrogen system |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS567647A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016035737A1 (en) * | 2014-09-05 | 2016-03-10 | 国立研究開発法人日本原子力研究開発機構 | Catalyst for water-hydrogen exchange reaction, method for producing same and apparatus for water-hydrogen exchange reaction |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59211999A (en) * | 1983-05-16 | 1984-11-30 | 三洋電機株式会社 | Device for firing discharge lamp |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53106397A (en) * | 1977-02-28 | 1978-09-16 | Agency Of Ind Science & Technol | Prepararion of catalyst for water-hydrogen type exchanging hydrogen isotopes |
| JPS5425289A (en) * | 1977-07-27 | 1979-02-26 | Agency Of Ind Science & Technol | Molded catalyst for exchange reaction of water-hydrogen system hydrogen isotope and method of producing same |
-
1979
- 1979-06-29 JP JP8249279A patent/JPS567647A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53106397A (en) * | 1977-02-28 | 1978-09-16 | Agency Of Ind Science & Technol | Prepararion of catalyst for water-hydrogen type exchanging hydrogen isotopes |
| JPS5425289A (en) * | 1977-07-27 | 1979-02-26 | Agency Of Ind Science & Technol | Molded catalyst for exchange reaction of water-hydrogen system hydrogen isotope and method of producing same |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016035737A1 (en) * | 2014-09-05 | 2016-03-10 | 国立研究開発法人日本原子力研究開発機構 | Catalyst for water-hydrogen exchange reaction, method for producing same and apparatus for water-hydrogen exchange reaction |
| JP2016055210A (en) * | 2014-09-05 | 2016-04-21 | 国立研究開発法人日本原子力研究開発機構 | Catalyst for water/hydrogen exchange reaction and production method thereof, and water/hydrogen exchange reaction apparatus |
| RU2666351C1 (en) * | 2014-09-05 | 2018-09-07 | Танака Кикинзоку Когио К.К. | Catalyst for water-hydrogen exchange reaction, method for production thereof and device for water-hydrogen exchange reaction |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5741299B2 (en) | 1982-09-02 |
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