JPS565490A - Preparation of amine-borane - Google Patents
Preparation of amine-boraneInfo
- Publication number
- JPS565490A JPS565490A JP8086779A JP8086779A JPS565490A JP S565490 A JPS565490 A JP S565490A JP 8086779 A JP8086779 A JP 8086779A JP 8086779 A JP8086779 A JP 8086779A JP S565490 A JPS565490 A JP S565490A
- Authority
- JP
- Japan
- Prior art keywords
- amine
- borane
- dmf
- nabh
- raw materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
PURPOSE: To obtain an amine-borane from inexpensive raw materials in high yield through simple procedures in a short time, by reacting an amine salt with NaBH4 in DMF.
CONSTITUTION: A salt of an amine, e.g. tert-butyl-, dimethyl-or diethylamine or morpholine, preferably hydrochloride, is reacted with NaBH4 in a solvent, e.g. DMF, at room temperature or under cooling with ice for 0.5W1.5hr to give an amine-borane. The raw materials are inexpensive and readily handleable, and a special reactor is not required. The DMF is recovered by distillation and reusable very economically.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8086779A JPS565490A (en) | 1979-06-27 | 1979-06-27 | Preparation of amine-borane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8086779A JPS565490A (en) | 1979-06-27 | 1979-06-27 | Preparation of amine-borane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS565490A true JPS565490A (en) | 1981-01-20 |
JPS6145996B2 JPS6145996B2 (en) | 1986-10-11 |
Family
ID=13730286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8086779A Granted JPS565490A (en) | 1979-06-27 | 1979-06-27 | Preparation of amine-borane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS565490A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100449579B1 (en) * | 2002-02-06 | 2004-09-18 | 한국이엔에쓰 주식회사 | Process for Producting Morpholine-Borane |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63318983A (en) * | 1987-06-23 | 1988-12-27 | 株式会社タカラ | Deformable toy |
-
1979
- 1979-06-27 JP JP8086779A patent/JPS565490A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100449579B1 (en) * | 2002-02-06 | 2004-09-18 | 한국이엔에쓰 주식회사 | Process for Producting Morpholine-Borane |
Also Published As
Publication number | Publication date |
---|---|
JPS6145996B2 (en) | 1986-10-11 |
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