JPS5646845A - Preparation of aromatic amino compound - Google Patents
Preparation of aromatic amino compoundInfo
- Publication number
- JPS5646845A JPS5646845A JP12280779A JP12280779A JPS5646845A JP S5646845 A JPS5646845 A JP S5646845A JP 12280779 A JP12280779 A JP 12280779A JP 12280779 A JP12280779 A JP 12280779A JP S5646845 A JPS5646845 A JP S5646845A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- aromatic
- sodium borohydride
- stannous chloride
- aromatic amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To prepare an aromatic amino compound, economically, by the selective reduction of the nitro group of an aromatic nitro compound in an organic solvent containing an alcohol and/or water using stannous chloride and sodium borohydride as reducing agents.
CONSTITUTION: An aromatic nitro compound, especially a compound of formula I (R is H, halogen, alkoxycarbonyl, alkyl, CN, alkylcarbonyl, acyloxy, alkoxycarbonylallyl, or ketoxime; n is 1 or 2) is reduced with sodium borohydride and stannous chloride in an organic solvent containing an alcohol and/or water. The molar ratio of sodium borohydride to stannous chloride is pref. 1:5W1:20. The process enables the selective reduction of the nitro group of an aromatic nitro compound to amino group without affecting the other functional groups, and gives the objective aromatic amino compound, especially the compound of formula II, economically.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12280779A JPS5646845A (en) | 1979-09-25 | 1979-09-25 | Preparation of aromatic amino compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12280779A JPS5646845A (en) | 1979-09-25 | 1979-09-25 | Preparation of aromatic amino compound |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5646845A true JPS5646845A (en) | 1981-04-28 |
Family
ID=14845115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12280779A Pending JPS5646845A (en) | 1979-09-25 | 1979-09-25 | Preparation of aromatic amino compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5646845A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1036780C (en) * | 1993-12-04 | 1997-12-24 | 任洁 | Processing method of ethyl meta-aminobenzoate |
-
1979
- 1979-09-25 JP JP12280779A patent/JPS5646845A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1036780C (en) * | 1993-12-04 | 1997-12-24 | 任洁 | Processing method of ethyl meta-aminobenzoate |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS53119844A (en) | Optically active amino acid-mandelic acid complexes and theire preparation | |
JPS5646845A (en) | Preparation of aromatic amino compound | |
JPS5436235A (en) | 4-n-alkyl-delta'-cyclohexene-1-carboxylic acids | |
JPS54112864A (en) | Novel imidazole derivative, its mineral acid salt, and their preparation | |
JPS5655383A (en) | Amizine derivative and its preparation | |
JPS5742643A (en) | 6,10,14,18-tetramethyl-5,9,13,17-nonadecatetraene-2-ol | |
JPS543064A (en) | Benzothiazolylthiocarboxylic acid derivatives | |
JPS53105451A (en) | Thiourea derivatives, process for their preparation and controlling agents against harmful organisms containing the same | |
JPS52138527A (en) | Preparation of quinophthalones | |
JPS53149945A (en) | Preparation of alpha-phenylpropionic acid derivatives | |
JPS5545607A (en) | Preparation of dyestuff compound useful for chemotherapy | |
JPS5314755A (en) | Aromatic polyamide composition | |
JPS55145699A (en) | Steroid double salt effective for chemotheraphy | |
JPS5432487A (en) | Preparation of 1-carbamoyluracils | |
JPS55108898A (en) | 25-hydroxy-24-oxocholesterol derivative and its preparation | |
JPS5610150A (en) | Preparation of nitrotoluene derivative | |
JPS54109971A (en) | Novel furanoside derivative and its preparation | |
JPS5371066A (en) | Preparation of 3-phenylindole derivs. | |
JPS5495533A (en) | Preparation of derivative of anthranylaldehyde | |
JPS5436274A (en) | Preparation of propiophenone derivative | |
JPS5334765A (en) | Isolation of 1,5-dinitroanthraquinone | |
JPS54105133A (en) | Preparation of disperse dye having improved fluidity | |
JPS51131826A (en) | Process for preparation of the solution containing cystin | |
JPS55167264A (en) | Preparation of 2-amino-4-acylaminophenyl ether | |
JPS51133291A (en) | Process for preparing 3-metyl-3- trifluoroacetoxycephalosporanic acid derivatives |