JPS5643242A - Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component - Google Patents
Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective componentInfo
- Publication number
- JPS5643242A JPS5643242A JP11811879A JP11811879A JPS5643242A JP S5643242 A JPS5643242 A JP S5643242A JP 11811879 A JP11811879 A JP 11811879A JP 11811879 A JP11811879 A JP 11811879A JP S5643242 A JPS5643242 A JP S5643242A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- derivative
- carboxylic acid
- 1mol
- antifungal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
NEW MATERIAL:A trihaloallyl derivative of formula I (X is Br or I; n is 1 or 2; R is alkyl, benzyl or phenyl).
EXAMPLE: 3-Methoxycarbonylmethoxy-1,1,2-triodo-1-propene.
USE: An antifungal and preservative agent useful to prevent the deterioration of various products such as the growth of fungi (e.g. those belonging to Penicillium genus, etc.) on industrial raw materials, deterioration of substrate, etc. It also prevents the damages of wood causd by wood destroying fungi, white rot fungi, etc.
PROCESS: An ester of formula I is prepared by (1) reacting a propargyl derivative of formula II with 1mol of I2 or Br2 in the presence of ≥2mol equivalent of an alkali, (2) adding 1mol of I2 to the monohalide of formula III obtained above to afford a carboxylic acid of formula III obtained above to afford a carboxylic acid of formula V as an intermediate, (3) converting the carboxylic acid to an acid chloride with SOCl2, and (4) contacting the product with ROH. When the amount of the alkali is 1mol equivalent, the trihalo drivative of formula I is obtained via a monohalide of formula IV.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11811879A JPS5643242A (en) | 1979-09-14 | 1979-09-14 | Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component |
GB8022499A GB2053916B (en) | 1979-07-13 | 1980-07-09 | Trihaloallyl derivatives having anti-fungal and preservative activities |
NO802066A NO153966C (en) | 1979-07-13 | 1980-07-10 | TRIHALOGENALLY ALLEGED DERIVATIVES WITH SUSPENSIVE AND CONSERVATIVE EFFECTS AND AGENTS CONTAINING THESE COMPOUNDS. |
CA000355959A CA1165327A (en) | 1979-07-13 | 1980-07-11 | Trihaloallyl derivatives having anti-fungal and preservative activities |
SE8005119A SE448374B (en) | 1979-07-13 | 1980-07-11 | TRIHALOGENALLY OIL DERIVATIVES WITH FUNGICIDE AND CONSERVATIVE EFFECTS AND COMPOSITIONS CONTAINING THESE |
SU802950406A SU1519523A3 (en) | 1979-07-13 | 1980-07-11 | Fungicidal composition |
FR8015471A FR2460917A1 (en) | 1979-07-13 | 1980-07-11 | TRIHALOGENOALLYL DERIVATIVES HAVING ANTIFUNGAL AND PRESERVATIVE ACTIVITY AND COMPOSITIONS CONTAINING THESE DERIVATIVES |
DE19803026431 DE3026431A1 (en) | 1979-07-13 | 1980-07-11 | TRIHALOGENALLYL COMPOUNDS AND PRESERVATIVES AND FUNGICIDES CONTAINING THESE COMPOUNDS |
US06/410,695 US4487781A (en) | 1979-07-13 | 1982-08-23 | Trihaloallyl derivatives having anti-fungal activities |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11811879A JPS5643242A (en) | 1979-09-14 | 1979-09-14 | Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5643242A true JPS5643242A (en) | 1981-04-21 |
JPS623828B2 JPS623828B2 (en) | 1987-01-27 |
Family
ID=14728469
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11811879A Granted JPS5643242A (en) | 1979-07-13 | 1979-09-14 | Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5643242A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4558098A (en) * | 1982-12-28 | 1985-12-10 | Mitsubishi Rayon Co., Ltd. | Methacrylic resin composition |
-
1979
- 1979-09-14 JP JP11811879A patent/JPS5643242A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4558098A (en) * | 1982-12-28 | 1985-12-10 | Mitsubishi Rayon Co., Ltd. | Methacrylic resin composition |
Also Published As
Publication number | Publication date |
---|---|
JPS623828B2 (en) | 1987-01-27 |
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