JPS5643242A - Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component - Google Patents

Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component

Info

Publication number
JPS5643242A
JPS5643242A JP11811879A JP11811879A JPS5643242A JP S5643242 A JPS5643242 A JP S5643242A JP 11811879 A JP11811879 A JP 11811879A JP 11811879 A JP11811879 A JP 11811879A JP S5643242 A JPS5643242 A JP S5643242A
Authority
JP
Japan
Prior art keywords
formula
derivative
carboxylic acid
1mol
antifungal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11811879A
Other languages
Japanese (ja)
Other versions
JPS623828B2 (en
Inventor
Yasuhiro Morisawa
Seiji Konishi
Mitsuru Kataoka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sankyo Co Ltd
Original Assignee
Sankyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sankyo Co Ltd filed Critical Sankyo Co Ltd
Priority to JP11811879A priority Critical patent/JPS5643242A/en
Priority to GB8022499A priority patent/GB2053916B/en
Priority to NO802066A priority patent/NO153966C/en
Priority to SU802950406A priority patent/SU1519523A3/en
Priority to SE8005119A priority patent/SE448374B/en
Priority to CA000355959A priority patent/CA1165327A/en
Priority to FR8015471A priority patent/FR2460917A1/en
Priority to DE19803026431 priority patent/DE3026431A1/en
Publication of JPS5643242A publication Critical patent/JPS5643242A/en
Priority to US06/410,695 priority patent/US4487781A/en
Publication of JPS623828B2 publication Critical patent/JPS623828B2/ja
Granted legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

NEW MATERIAL:A trihaloallyl derivative of formula I (X is Br or I; n is 1 or 2; R is alkyl, benzyl or phenyl).
EXAMPLE: 3-Methoxycarbonylmethoxy-1,1,2-triodo-1-propene.
USE: An antifungal and preservative agent useful to prevent the deterioration of various products such as the growth of fungi (e.g. those belonging to Penicillium genus, etc.) on industrial raw materials, deterioration of substrate, etc. It also prevents the damages of wood causd by wood destroying fungi, white rot fungi, etc.
PROCESS: An ester of formula I is prepared by (1) reacting a propargyl derivative of formula II with 1mol of I2 or Br2 in the presence of ≥2mol equivalent of an alkali, (2) adding 1mol of I2 to the monohalide of formula III obtained above to afford a carboxylic acid of formula III obtained above to afford a carboxylic acid of formula V as an intermediate, (3) converting the carboxylic acid to an acid chloride with SOCl2, and (4) contacting the product with ROH. When the amount of the alkali is 1mol equivalent, the trihalo drivative of formula I is obtained via a monohalide of formula IV.
COPYRIGHT: (C)1981,JPO&Japio
JP11811879A 1979-07-13 1979-09-14 Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component Granted JPS5643242A (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP11811879A JPS5643242A (en) 1979-09-14 1979-09-14 Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component
GB8022499A GB2053916B (en) 1979-07-13 1980-07-09 Trihaloallyl derivatives having anti-fungal and preservative activities
NO802066A NO153966C (en) 1979-07-13 1980-07-10 TRIHALOGENALLY ALLEGED DERIVATIVES WITH SUSPENSIVE AND CONSERVATIVE EFFECTS AND AGENTS CONTAINING THESE COMPOUNDS.
CA000355959A CA1165327A (en) 1979-07-13 1980-07-11 Trihaloallyl derivatives having anti-fungal and preservative activities
SE8005119A SE448374B (en) 1979-07-13 1980-07-11 TRIHALOGENALLY OIL DERIVATIVES WITH FUNGICIDE AND CONSERVATIVE EFFECTS AND COMPOSITIONS CONTAINING THESE
SU802950406A SU1519523A3 (en) 1979-07-13 1980-07-11 Fungicidal composition
FR8015471A FR2460917A1 (en) 1979-07-13 1980-07-11 TRIHALOGENOALLYL DERIVATIVES HAVING ANTIFUNGAL AND PRESERVATIVE ACTIVITY AND COMPOSITIONS CONTAINING THESE DERIVATIVES
DE19803026431 DE3026431A1 (en) 1979-07-13 1980-07-11 TRIHALOGENALLYL COMPOUNDS AND PRESERVATIVES AND FUNGICIDES CONTAINING THESE COMPOUNDS
US06/410,695 US4487781A (en) 1979-07-13 1982-08-23 Trihaloallyl derivatives having anti-fungal activities

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11811879A JPS5643242A (en) 1979-09-14 1979-09-14 Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component

Publications (2)

Publication Number Publication Date
JPS5643242A true JPS5643242A (en) 1981-04-21
JPS623828B2 JPS623828B2 (en) 1987-01-27

Family

ID=14728469

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11811879A Granted JPS5643242A (en) 1979-07-13 1979-09-14 Trihaloallyl derivative, and antifungal and preservative agent containing said derivative as effective component

Country Status (1)

Country Link
JP (1) JPS5643242A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4558098A (en) * 1982-12-28 1985-12-10 Mitsubishi Rayon Co., Ltd. Methacrylic resin composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4558098A (en) * 1982-12-28 1985-12-10 Mitsubishi Rayon Co., Ltd. Methacrylic resin composition

Also Published As

Publication number Publication date
JPS623828B2 (en) 1987-01-27

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