JPS5626830A - Hydroformylation of lower olefin - Google Patents

Hydroformylation of lower olefin

Info

Publication number
JPS5626830A
JPS5626830A JP10257979A JP10257979A JPS5626830A JP S5626830 A JPS5626830 A JP S5626830A JP 10257979 A JP10257979 A JP 10257979A JP 10257979 A JP10257979 A JP 10257979A JP S5626830 A JPS5626830 A JP S5626830A
Authority
JP
Japan
Prior art keywords
lower olefin
complex compound
compound
aryls
equivalents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10257979A
Other languages
English (en)
Inventor
Mitsuo Matsumoto
Masuhiko Tamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP10257979A priority Critical patent/JPS5626830A/ja
Priority to US06/175,842 priority patent/US4306087A/en
Priority to DE3030108A priority patent/DE3030108C2/de
Priority to GB8025948A priority patent/GB2056874B/en
Publication of JPS5626830A publication Critical patent/JPS5626830A/ja
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B01J31/2457Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP10257979A 1979-08-10 1979-08-10 Hydroformylation of lower olefin Pending JPS5626830A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP10257979A JPS5626830A (en) 1979-08-10 1979-08-10 Hydroformylation of lower olefin
US06/175,842 US4306087A (en) 1979-08-10 1980-08-06 Hydroformylation of olefinic compounds
DE3030108A DE3030108C2 (de) 1979-08-10 1980-08-08 Verfahren zur Herstellung von Aldehyden durch Hydroformylierung
GB8025948A GB2056874B (en) 1979-08-10 1980-08-08 Hydroformylation of olefinic compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10257979A JPS5626830A (en) 1979-08-10 1979-08-10 Hydroformylation of lower olefin

Publications (1)

Publication Number Publication Date
JPS5626830A true JPS5626830A (en) 1981-03-16

Family

ID=14331129

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10257979A Pending JPS5626830A (en) 1979-08-10 1979-08-10 Hydroformylation of lower olefin

Country Status (4)

Country Link
US (1) US4306087A (ja)
JP (1) JPS5626830A (ja)
DE (1) DE3030108C2 (ja)
GB (1) GB2056874B (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010523558A (ja) * 2007-04-02 2010-07-15 ライオンデル ケミカル テクノロジー、 エル.ピー. ヒドロホルミル化方法

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4522933A (en) * 1981-08-17 1985-06-11 Union Carbide Corporation Hydroformylation catalyst containing bisphosphine monooxide ligands
US4593011A (en) * 1981-08-17 1986-06-03 Union Carbide Corporation Hydroformylation process using triarylphosphine and bisphosphine monooxide ligands
US4400548A (en) 1981-08-17 1983-08-23 Union Carbide Corporation Hydroformylation process using bisphosphine monooxide ligands
EP0096986B1 (en) * 1982-06-11 1987-04-22 DAVY McKEE (LONDON) LIMITED Hydroformylation process
DE3372361D1 (en) * 1982-06-11 1987-08-13 Davy Mckee London Hydroformylation process
DE3480845D1 (de) * 1983-04-06 1990-02-01 Shell Int Research Verfahren zur herstellung von polyketonen.
US4625068A (en) * 1985-03-20 1986-11-25 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of internal olefins
US4642388A (en) * 1985-08-30 1987-02-10 Exxon Chemical Patents Inc. Rhodium catalyzed hydroformylation of alpha-substituted alpha-olefins
US4694109A (en) * 1986-06-13 1987-09-15 Eastman Kodak Company Chelate ligands for low pressure hydroformylation catalyst and process employing same
GB8722460D0 (en) * 1987-09-24 1987-10-28 Shell Int Research Hydroformylation of olefins
ES2051862T3 (es) * 1987-10-02 1994-07-01 Ueno Seiyaku Oyo Kenkyujo Kk Un metodo para producir un medicamento que tiene un efecto catartico.
US4960949A (en) * 1988-12-22 1990-10-02 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
US5233093A (en) * 1992-07-20 1993-08-03 Arco Chemical Technology, L.P. Hydroformylation process and bimetallic catalyst therefor
KR100596365B1 (ko) 2004-06-12 2006-07-03 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
US7271295B1 (en) * 2006-10-13 2007-09-18 Lyondell Chemical Technology, L.P. Hydroformylation process
US7655821B1 (en) 2008-11-25 2010-02-02 Lyondell Chemical Technology, L.P. Direct hydrocarbonylation process
US7612241B1 (en) 2009-03-23 2009-11-03 Lyondell Chemical Technology, L.P. Hydroformylation process
US20100292514A1 (en) * 2009-05-13 2010-11-18 White Daniel F Hydroformylation process
US7790932B1 (en) 2009-12-21 2010-09-07 Lyondell Chemical Technology, L.P. Hydroformylation process
FR2993557B1 (fr) 2012-07-23 2015-11-13 Arkema France Synthese de methyl propane diol a partir d'alcool allylique
US8742180B1 (en) 2012-11-13 2014-06-03 Lyondell Chemical Technology, L.P. Process control with Raman spectroscopy
US11370737B2 (en) 2020-09-25 2022-06-28 Lyondell Chemical Technology, L.P. Co-feeding ethylene with allyl alcohol in hydroformylation to make 1,4-butanediol and n-propanol

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1090823A (en) * 1976-04-08 1980-12-02 Everard A.V. Brewester Cyclic hydroformylation process
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
US4221743A (en) * 1976-07-07 1980-09-09 Union Carbide Corporation Hydroformylation process
US4139565A (en) * 1977-03-31 1979-02-13 Celanese Corporation Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
FR2428021A1 (fr) * 1978-06-05 1980-01-04 Kuraray Co Hydroformylation de composes olefiniques

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010523558A (ja) * 2007-04-02 2010-07-15 ライオンデル ケミカル テクノロジー、 エル.ピー. ヒドロホルミル化方法

Also Published As

Publication number Publication date
DE3030108C2 (de) 1982-12-02
GB2056874A (en) 1981-03-25
GB2056874B (en) 1983-09-07
US4306087A (en) 1981-12-15
DE3030108A1 (de) 1981-04-02

Similar Documents

Publication Publication Date Title
JPS5626830A (en) Hydroformylation of lower olefin
RU2336261C2 (ru) Способ каталитического гидроформилирования высших олефинов в присутствии циклических эфиров угольной кислоты
US4139565A (en) Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands
ATE86885T1 (de) Hydroformylation von olefinen unter schwachem druck mit einem rhodium-katalysator.
JPS54119407A (en) Preparation of aldehydes
BE854403A (fr) Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
ATE16475T1 (de) Hydroformylierungsverfahren.
US5756854A (en) Process for the hydroformylation of olefinically unsaturated compounds
PL128785B1 (en) Method of removing triorganophospine from a liquid composition
CA1262555A (en) RHODIUM CATALYZED HYDROFORMYLATION OF .alpha.- SUBSTITUTED .alpha.-OLEFINS
Tanaka et al. Catalytic Asymmetric Hydroformylation with a Chiral Phosphine–Rhodium Complex
SE7709110L (sv) Hydroformyleringsforfarande
GB1428715A (en) Manufacture of predominantly straight-chain aldehydes
JPS5645436A (en) Hydroformylation of olefin
Rosales et al. Kinetics and mechanisms of homogeneous catalytic reactions: Part 15. Regio-specific hydroformylation of limonene catalysed by rhodium complexes of phosphine ligands
GB1372334A (en) Continuous production of metal carbonyl compounds
ES541724A0 (es) Un procedimiento de hidroformilacion, catalizado por bodio con recirculacion de liquido, para producir aldehidos
GB1423911A (en) Production of optically active alcohols
JPS56118034A (en) Preparation of aldehyde
Fujitsu et al. Reactivities of aldehydes in homogeneous catalytic hydrogenation with cationic rhodium complexes
Mantovani et al. Selective oligomerization of phenylacetylene to 1, 2, 4-triphenylbenzene catalyzed by Ni (CO) 3 (P (Oi-C3H7) 3
JPS5633040A (en) Activation of rhodium complex catalyst
Sokolskii et al. Effect of hydrogen pressure on the selectivity of 2-butene-1-al hydrogenation
Matsui et al. Hydroformylation of Olefins Using Rhodium Complex Catalysts (Part 1) Effects of Reaction Variables on Reactivity and Selectivity
JPS54144307A (en) Preparation of octadienol