JPS5599903A - Polymerization of alpha-olefin - Google Patents
Polymerization of alpha-olefinInfo
- Publication number
- JPS5599903A JPS5599903A JP655379A JP655379A JPS5599903A JP S5599903 A JPS5599903 A JP S5599903A JP 655379 A JP655379 A JP 655379A JP 655379 A JP655379 A JP 655379A JP S5599903 A JPS5599903 A JP S5599903A
- Authority
- JP
- Japan
- Prior art keywords
- acid ester
- organic acid
- compound
- olefin
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To prepare an α-olefin polymer having improved crystallinity and bulk density, by using a catalyst comprising an aluminum compound, and electron donor and a composition provided by pulverizing a magnesium compound together with an organic acid ester, an unsaturated monomer, hydrocarbon, etc. and treating the mixture with a titanium compound.
CONSTITUTION: An α-olefin (e.g. propylene, etc.) is polymerized to give the desired polymer by using a polymerization catalyst comprising (A) a composition provided by pulverizing (a) a magnesium halide together with (b) an organic acid ester (e.g. ethyl benzoate, etc.), (c) an aromatic hydrocarbon having an unsaturated substiuent (e.g. α-methylstyrene, etc.), (d) a hydrocarbon (e.g. n-heptane, etc.), etc. and treating the mixture with (e) titanium tetrachloride at 80°C, (B) an organoaluminum compound (e.g. triisobutylaluminum, etc.) and (C) an electron donor, e.g. an organic acid ester or its complex with an aluminum halide, etc.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP655379A JPS5599903A (en) | 1979-01-25 | 1979-01-25 | Polymerization of alpha-olefin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP655379A JPS5599903A (en) | 1979-01-25 | 1979-01-25 | Polymerization of alpha-olefin |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5599903A true JPS5599903A (en) | 1980-07-30 |
JPS6351163B2 JPS6351163B2 (en) | 1988-10-13 |
Family
ID=11641516
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP655379A Granted JPS5599903A (en) | 1979-01-25 | 1979-01-25 | Polymerization of alpha-olefin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5599903A (en) |
-
1979
- 1979-01-25 JP JP655379A patent/JPS5599903A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6351163B2 (en) | 1988-10-13 |
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