JPS557836A - Polymerizing method of alpha-olefins - Google Patents
Polymerizing method of alpha-olefinsInfo
- Publication number
- JPS557836A JPS557836A JP7982578A JP7982578A JPS557836A JP S557836 A JPS557836 A JP S557836A JP 7982578 A JP7982578 A JP 7982578A JP 7982578 A JP7982578 A JP 7982578A JP S557836 A JPS557836 A JP S557836A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- acid ester
- olefins
- organo
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To prepare the title polymer having high stereo-regularity, by polymerizing α-olefins in the presence of a highly active catalyst comprising an active titanium component treated with an aromatic ortho-carboxylic acid ester, an organo- aluminum compound, and an electrodonative compound.
CONSTITUTION: A catalyst system for the polymerization of α-olefines, comprising (A) an active titanium component obtained by treating a co-crushed product of (a) a magnesium halide, (b) an aluminum halide, and (c) an aromatic ortho-carboxylic acid ester (pref. a compound II where R1 is aromatic hydrocarbon, R2 to R4 are hydrocarbons, e.g. orthobenzoic acid methyl ester, etc.), (B) an organo-aluminum compound I (R is hydrocarbon; X is alkoxy, halogen, etc.; m is 1.5W3), and (C) an electron donor (e.g. organic acid ester, etc.).
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7982578A JPS5821921B2 (en) | 1978-07-03 | 1978-07-03 | Polymerization method of α↓-olefins |
US05/972,673 US4220745A (en) | 1978-03-01 | 1978-12-26 | Process for polymerization of α-olefins |
GB7900203A GB2015545B (en) | 1978-03-01 | 1979-01-04 | Catalyst for the polymerisation of -olefins |
NLAANVRAGE7900142,A NL183585C (en) | 1978-03-01 | 1979-01-09 | PROCESS FOR PREPARING A CATALYST AND PROCESS FOR CARRYING OUT A STEREO-SPECIFIC POLYMERIZATION OF ALFA OLEFINS. |
PT69055A PT69055A (en) | 1978-03-01 | 1979-01-10 | Process for the polymerization of alpha-olefins |
FR7900779A FR2423259A1 (en) | 1978-03-01 | 1979-01-12 | A-OLEFINS POLYMERIZATION PROCESS |
DE19792901393 DE2901393A1 (en) | 1978-03-01 | 1979-01-15 | METHOD FOR THE STEREOSPECIFIC POLYMERIZATION OF ALPHA -OLEFS |
CS348681A CS221805B2 (en) | 1978-07-03 | 1979-01-15 | Method of stereocopic polymeration of the alpha-olefine |
AU44606/79A AU523865B2 (en) | 1978-03-01 | 1979-02-26 | Polymerization of alpha-olefins |
ES478177A ES478177A1 (en) | 1978-03-01 | 1979-02-28 | Process for polymerization of alpha -olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7982578A JPS5821921B2 (en) | 1978-07-03 | 1978-07-03 | Polymerization method of α↓-olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS557836A true JPS557836A (en) | 1980-01-21 |
JPS5821921B2 JPS5821921B2 (en) | 1983-05-04 |
Family
ID=13700978
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7982578A Expired JPS5821921B2 (en) | 1978-03-01 | 1978-07-03 | Polymerization method of α↓-olefins |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS5821921B2 (en) |
CS (1) | CS221805B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5736104A (en) * | 1980-05-02 | 1982-02-26 | Dart Ind Inc | |
JPS58206613A (en) * | 1982-05-26 | 1983-12-01 | Mitsubishi Petrochem Co Ltd | Production of ethylene copolymer |
JPS61145206A (en) * | 1984-12-18 | 1986-07-02 | Mitsubishi Petrochem Co Ltd | Production of olefin plymer |
US6777508B1 (en) | 1980-08-13 | 2004-08-17 | Basell Poliolefine Italia S.P.A. | Catalysts for the polymerization of olefins |
-
1978
- 1978-07-03 JP JP7982578A patent/JPS5821921B2/en not_active Expired
-
1979
- 1979-01-15 CS CS348681A patent/CS221805B2/en unknown
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5736104A (en) * | 1980-05-02 | 1982-02-26 | Dart Ind Inc | |
JPH0327567B2 (en) * | 1980-05-02 | 1991-04-16 | Phillips Petroleum Co | |
US6777508B1 (en) | 1980-08-13 | 2004-08-17 | Basell Poliolefine Italia S.P.A. | Catalysts for the polymerization of olefins |
JPS58206613A (en) * | 1982-05-26 | 1983-12-01 | Mitsubishi Petrochem Co Ltd | Production of ethylene copolymer |
JPH0322403B2 (en) * | 1982-05-26 | 1991-03-26 | Mitsubishi Petrochemical Co | |
JPS61145206A (en) * | 1984-12-18 | 1986-07-02 | Mitsubishi Petrochem Co Ltd | Production of olefin plymer |
Also Published As
Publication number | Publication date |
---|---|
CS221805B2 (en) | 1983-04-29 |
JPS5821921B2 (en) | 1983-05-04 |
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