JPS5579357A - Purification of 2-cyano-4-nitroaniline - Google Patents
Purification of 2-cyano-4-nitroanilineInfo
- Publication number
- JPS5579357A JPS5579357A JP15315978A JP15315978A JPS5579357A JP S5579357 A JPS5579357 A JP S5579357A JP 15315978 A JP15315978 A JP 15315978A JP 15315978 A JP15315978 A JP 15315978A JP S5579357 A JPS5579357 A JP S5579357A
- Authority
- JP
- Japan
- Prior art keywords
- cna
- nitroaniline
- cyano
- purification
- butanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain CNA(2-cyano-4-nitroaniline) useful as an intermediate for dyes, inexpensively and in high yield, by purification of CNA comprising impurities through heat treatment with n-butanol, aqueous pyridine, etc.
CONSTITUTION: 5g of crude CNA comprising 2-cyano-6-nitroaniline and the like, for example, of 98.5% purity, having the mp(melting point) of 203W208°C, and 50g of n-butanol, for examle, in an amount of 1W20 times that of the crude CNA, are heat-treated in a 100ml flask with reflux and stirring for 30minW3hr, e.g. 1hr, at 70°C or above, preferably reflux temperature and then cooled to 35°C, to obtain the crystals of the purified CNA. Too short heating and stirring time gives low purification rate; too long time, low recovery.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15315978A JPS6039268B2 (en) | 1978-12-13 | 1978-12-13 | Method for purifying 2-cyano-4-nitroaniline |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15315978A JPS6039268B2 (en) | 1978-12-13 | 1978-12-13 | Method for purifying 2-cyano-4-nitroaniline |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5579357A true JPS5579357A (en) | 1980-06-14 |
JPS6039268B2 JPS6039268B2 (en) | 1985-09-05 |
Family
ID=15556316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15315978A Expired JPS6039268B2 (en) | 1978-12-13 | 1978-12-13 | Method for purifying 2-cyano-4-nitroaniline |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6039268B2 (en) |
-
1978
- 1978-12-13 JP JP15315978A patent/JPS6039268B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS6039268B2 (en) | 1985-09-05 |
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