JPS5566522A - Preparation of optically active bicyclic compounds by asymmetric diels-alder reaction - Google Patents
Preparation of optically active bicyclic compounds by asymmetric diels-alder reactionInfo
- Publication number
- JPS5566522A JPS5566522A JP13892978A JP13892978A JPS5566522A JP S5566522 A JPS5566522 A JP S5566522A JP 13892978 A JP13892978 A JP 13892978A JP 13892978 A JP13892978 A JP 13892978A JP S5566522 A JPS5566522 A JP S5566522A
- Authority
- JP
- Japan
- Prior art keywords
- optically active
- alder reaction
- formula
- diels
- bicyclic compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005698 Diels-Alder reaction Methods 0.000 title abstract 3
- 125000002619 bicyclic group Chemical group 0.000 title abstract 2
- 239000011982 enantioselective catalyst Substances 0.000 abstract 3
- 239000002841 Lewis acid Substances 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 150000007517 lewis acids Chemical class 0.000 abstract 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical class C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
- 150000001299 aldehydes Chemical group 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001728 carbonyl compounds Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 230000000144 pharmacologic effect Effects 0.000 abstract 1
- 238000007363 ring formation reaction Methods 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13892978A JPS5566522A (en) | 1978-11-13 | 1978-11-13 | Preparation of optically active bicyclic compounds by asymmetric diels-alder reaction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13892978A JPS5566522A (en) | 1978-11-13 | 1978-11-13 | Preparation of optically active bicyclic compounds by asymmetric diels-alder reaction |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5566522A true JPS5566522A (en) | 1980-05-20 |
| JPS6239134B2 JPS6239134B2 (enrdf_load_stackoverflow) | 1987-08-21 |
Family
ID=15233431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13892978A Granted JPS5566522A (en) | 1978-11-13 | 1978-11-13 | Preparation of optically active bicyclic compounds by asymmetric diels-alder reaction |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5566522A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0641014A (ja) * | 1991-06-26 | 1994-02-15 | Union Carbide Chem & Plast Technol Corp | 不飽和脂環式エステル及びその誘導体の製造 |
| JP2012087077A (ja) * | 2010-10-18 | 2012-05-10 | Toyohashi Univ Of Technology | 光学活性シクロヘキセン誘導体の製造方法、光学活性シクロヘキセン誘導体、並びにそれを用いた光学活性シクロヘキサジエン誘導体の製造方法及び光学活性シクロヘキサジエン誘導体 |
-
1978
- 1978-11-13 JP JP13892978A patent/JPS5566522A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0641014A (ja) * | 1991-06-26 | 1994-02-15 | Union Carbide Chem & Plast Technol Corp | 不飽和脂環式エステル及びその誘導体の製造 |
| JP2012087077A (ja) * | 2010-10-18 | 2012-05-10 | Toyohashi Univ Of Technology | 光学活性シクロヘキセン誘導体の製造方法、光学活性シクロヘキセン誘導体、並びにそれを用いた光学活性シクロヘキサジエン誘導体の製造方法及び光学活性シクロヘキサジエン誘導体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6239134B2 (enrdf_load_stackoverflow) | 1987-08-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR920000956B1 (ko) | 아줄렌 유도체의 제조방법 | |
| JPS5566522A (en) | Preparation of optically active bicyclic compounds by asymmetric diels-alder reaction | |
| Sera et al. | High pressure mediated Diels-Alder reaction of furan with dialkyl (acetoxymethylene) malonate | |
| Naoshima et al. | The Synthesis of Cyclotene and Its Related Compounds by the Acyloin Condensation | |
| CA1190551A (en) | Process for the production of 7-oxabicyclo-(2,2, 1)hept-5-ene derivatives | |
| JPS5424818A (en) | Preparation of high purity maleic acid monoalcohol ester | |
| Kutney et al. | Chemistry of thujone. IV. Cyclopropane derivatives and analogs of pyrethrins | |
| JPS5439043A (en) | Preparation of phenylalkane carboxylic acids | |
| Cornelius et al. | Synthesis of 2-acetylbicyclo [2.2. 1] hept-2-ene | |
| JPS5432444A (en) | Preparation of cis-2-pentene derivative | |
| JPS53149952A (en) | Preparation of cyclopentenones | |
| JPS53130619A (en) | Preparation of high purity isoprenylacetic acid | |
| Jones et al. | Convergent syntheses of 9-deoxy-12-phenylthioprostanoids and 9-deoxy-Δ 8 (12)-PGD 1 derivatives | |
| JPS5368766A (en) | Preparation of diterpene | |
| JPS5527161A (en) | Production of alcohol or its ether derivative | |
| SU427924A1 (ru) | Способ получения эфиров 2,3-дифенил-2- инден-1-карбоновой кислоты | |
| JPS5283436A (en) | Preparation of intermediates for synthesis of prostaglandin | |
| JPS5231093A (en) | Preparation of 3- methylenecephalosporanic acid derivatives | |
| JPS52118447A (en) | Synthesis of unsaturated alicyclic ketones | |
| N-COCH et al. | a,/9-Unsaturated Carboxylic Acid Derivatives. XIX. The Convenient Synthesis of a-Alkoxy-, a-Hydroxy-a-amino Acid, and Its Cyclic Dipeptide from a-Dehydroamino Acid4 | |
| JPS5334750A (en) | Preparation of cyclopentadeca-4-yne-one | |
| JPS5246049A (en) | Process for preparation of 2-methyl-3-alkyl-2-cyclopentene-1,4-dione | |
| JPS52133972A (en) | Synthesis of gamma-lactam esters | |
| JPS5395965A (en) | Preparation of indoles | |
| JPS54117423A (en) | Preparation of jasmonic acid ester derivative, and novel intermediate |