JPS5557533A - Preparation of methacrolein - Google Patents
Preparation of methacroleinInfo
- Publication number
- JPS5557533A JPS5557533A JP13047578A JP13047578A JPS5557533A JP S5557533 A JPS5557533 A JP S5557533A JP 13047578 A JP13047578 A JP 13047578A JP 13047578 A JP13047578 A JP 13047578A JP S5557533 A JPS5557533 A JP S5557533A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- methacrolein
- isobutylene
- element selected
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 abstract 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 3
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- 229910020647 Co-O Inorganic materials 0.000 abstract 1
- 229910020704 Co—O Inorganic materials 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000009257 reactivity Effects 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To obtain the title compound, by the oxidation of isobutylene using a catalyst having excellent durability, and obtained by adding Cs, an element selected from V and Pd, and an element selected from Ti, Sn and Zr to a catalyst system of Mo-Bi-Fe-Co-O.
CONSTITUTION: Methacrolein is obtained by the catalytic reaction of isobutylene with O2 in the vapor-phase of high temperature in the presence of a catalyst having the composition of formula (X is V and/or Pd; Y is at least one element selected from a group of Ti, Sn and Zr; when a=12, b=2W12, c=0.5W7, d=0.1W5, e=0.0005W0.5, f=0.01W2, and g=0.1).
EFFECT: Both reactivity of isobutylene and selectivity of methacrolein are improved. The abrasion resistance, crushing strength, etc. of the catalyst are high. Operation can be continued safely over a long period.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP53130475A JPS584693B2 (en) | 1978-10-25 | 1978-10-25 | Method for producing methacrolein |
US06/015,903 US4217309A (en) | 1978-06-12 | 1979-02-28 | Process for producing methacrolein |
GB7908415A GB2023597B (en) | 1978-06-12 | 1979-03-09 | Process for producing methacrolein |
FR7914945A FR2432007A1 (en) | 1978-06-12 | 1979-06-12 | PROCESS FOR THE PREPARATION OF METHACROLEIN |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP53130475A JPS584693B2 (en) | 1978-10-25 | 1978-10-25 | Method for producing methacrolein |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5557533A true JPS5557533A (en) | 1980-04-28 |
JPS584693B2 JPS584693B2 (en) | 1983-01-27 |
Family
ID=15035127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53130475A Expired JPS584693B2 (en) | 1978-06-12 | 1978-10-25 | Method for producing methacrolein |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS584693B2 (en) |
-
1978
- 1978-10-25 JP JP53130475A patent/JPS584693B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS584693B2 (en) | 1983-01-27 |
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