JPS5551030A - Preparation of trans-sabinene hydrate - Google Patents

Preparation of trans-sabinene hydrate

Info

Publication number
JPS5551030A
JPS5551030A JP12486378A JP12486378A JPS5551030A JP S5551030 A JPS5551030 A JP S5551030A JP 12486378 A JP12486378 A JP 12486378A JP 12486378 A JP12486378 A JP 12486378A JP S5551030 A JPS5551030 A JP S5551030A
Authority
JP
Japan
Prior art keywords
trans
thujane
pref
flavor
epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12486378A
Other languages
Japanese (ja)
Other versions
JPS582213B2 (en
Inventor
Masamoto Shinpo
Haruhiko Toda
Hitoshi Saga
Kunitomo Suzuki
Yasukuni Nishida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Lion Hamigaki KK
Original Assignee
Lion Corp
Lion Hamigaki KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lion Corp, Lion Hamigaki KK filed Critical Lion Corp
Priority to JP12486378A priority Critical patent/JPS582213B2/en
Publication of JPS5551030A publication Critical patent/JPS5551030A/en
Publication of JPS582213B2 publication Critical patent/JPS582213B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To prepare the title compound useful as an agent for reinforcing the flavor of peppermint or spearmint, in a relatively high yield, with simple process, by reacting trans-3,4-epoxy-thujane (novel substance) with a reducing agent.
CONSTITUTION: The objective compound of formula II is prepared by reacting trans- 3,4-epoxy-thujane of formula I (novel substance) with a reducing agent such as aluminum lithium hydride, trialkoxyaluminum lithium hydride, Li, Na, NaK alloy, etc., pref. in a solvent at -80W100°C, pref. 0W80°C. The starting material I can be prepared by the photo-sensitized oxidation of sabinene III with oxygen in the presence of an α-diketone such as benzyl(phCOCOPh) etc. as a sensitizer.
USE: Flavor of tooth paste, food, etc.
COPYRIGHT: (C)1980,JPO&Japio
JP12486378A 1978-10-11 1978-10-11 Trans↓-method for producing sabinene hydrate Expired JPS582213B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12486378A JPS582213B2 (en) 1978-10-11 1978-10-11 Trans↓-method for producing sabinene hydrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12486378A JPS582213B2 (en) 1978-10-11 1978-10-11 Trans↓-method for producing sabinene hydrate

Publications (2)

Publication Number Publication Date
JPS5551030A true JPS5551030A (en) 1980-04-14
JPS582213B2 JPS582213B2 (en) 1983-01-14

Family

ID=14895955

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12486378A Expired JPS582213B2 (en) 1978-10-11 1978-10-11 Trans↓-method for producing sabinene hydrate

Country Status (1)

Country Link
JP (1) JPS582213B2 (en)

Also Published As

Publication number Publication date
JPS582213B2 (en) 1983-01-14

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