JPS55139420A - Polyurethane oligomer impact and shrinkage modifier for thermosetting polyester - Google Patents
Polyurethane oligomer impact and shrinkage modifier for thermosetting polyesterInfo
- Publication number
- JPS55139420A JPS55139420A JP2524080A JP2524080A JPS55139420A JP S55139420 A JPS55139420 A JP S55139420A JP 2524080 A JP2524080 A JP 2524080A JP 2524080 A JP2524080 A JP 2524080A JP S55139420 A JPS55139420 A JP S55139420A
- Authority
- JP
- Japan
- Prior art keywords
- isocyanate
- polyester resin
- oligomer
- modifier
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003607 modifier Substances 0.000 title abstract 4
- 229920000728 polyester Polymers 0.000 title abstract 2
- 239000004814 polyurethane Substances 0.000 title abstract 2
- 229920002635 polyurethane Polymers 0.000 title abstract 2
- 229920001187 thermosetting polymer Polymers 0.000 title abstract 2
- 229920001225 polyester resin Polymers 0.000 abstract 4
- 239000004645 polyester resin Substances 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 239000012763 reinforcing filler Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
PURPOSE: To obtain a polyester resin having improved impact resistance and shrink characteristics, by a method wherein an isocyanate-terminated prepolymer is reacted with an unsaturated monomer having isocyanate-reactive gp. to obtain an oligomer which is then added to a polyester resin.
CONSTITUTION: An isocyanate-terminated prepolymer resulting from the reaction of an org. diisocyanate with a polyol having an average equivalent of 300W4000 in an equivalent ratio of NCO to OH of 1.02/1W1.6/1, is reacted with an unsaturated monomer having isocyanate-reactive gp. to obtain a polyurethane oligomer modifier having final free NCO content of 0W1%. The oligomer modifier is added to a thermosetting polyester resin compsn. consisting of a polyester resin, a catalyst and a reinforcing agent or filler. Pref. the oligomer modifier is added to the resin compsn. in an amount of 5W30pts.wt. per 100pts.wt. of the sum of polyester and a copolymerizable solvent.
COPYRIGHT: (C)1980,JPO&Japio
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1685779A | 1979-03-02 | 1979-03-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS55139420A true JPS55139420A (en) | 1980-10-31 |
Family
ID=21779367
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2524080A Pending JPS55139420A (en) | 1979-03-02 | 1980-03-03 | Polyurethane oligomer impact and shrinkage modifier for thermosetting polyester |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS55139420A (en) |
BR (1) | BR8001134A (en) |
DE (1) | DE3007614A1 (en) |
FR (1) | FR2450269A1 (en) |
GB (1) | GB2045259B (en) |
IT (1) | IT1144042B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5765714A (en) * | 1980-10-06 | 1982-04-21 | Nippon Synthetic Chem Ind Co Ltd:The | Photocurable resin composition |
JPS61502541A (en) * | 1984-06-25 | 1986-11-06 | ザ バツド カンパニ− | dual function additive |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU558337B2 (en) * | 1981-09-03 | 1987-01-29 | Olin Corporation | Polyurethane modifiers for thermoset polyesters |
US4524178A (en) * | 1983-06-09 | 1985-06-18 | The Dow Chemical Company | Compositions of unsaturated polyesters or polyesteramides and efficient flexibilizers therefor |
US20010031830A1 (en) * | 1999-04-26 | 2001-10-18 | Probir K. Guha | Composite molding compound additive |
CN111825834B (en) * | 2020-07-31 | 2023-05-30 | 肇庆福田化学工业有限公司 | Low-viscosity ultraviolet light curing modified polyester acrylate and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51116851A (en) * | 1975-04-07 | 1976-10-14 | Toyobo Co Ltd | Thixotropic radical polymerization type thermosetting resin compositio ns |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO126024B (en) * | 1967-07-04 | 1972-12-11 | Bayer Ag | |
US4062826A (en) * | 1969-06-23 | 1977-12-13 | Imperial Chemical Industries Limited | Polymeric shaped articles |
GB1453840A (en) * | 1973-05-15 | 1976-10-27 | Ici Ltd | Moulding composition |
JPS5323600B2 (en) * | 1973-07-02 | 1978-07-15 |
-
1980
- 1980-02-27 BR BR8001134A patent/BR8001134A/en unknown
- 1980-02-28 DE DE19803007614 patent/DE3007614A1/en not_active Withdrawn
- 1980-02-29 IT IT48047/80A patent/IT1144042B/en active
- 1980-02-29 FR FR8004640A patent/FR2450269A1/en active Granted
- 1980-02-29 GB GB8006977A patent/GB2045259B/en not_active Expired
- 1980-03-03 JP JP2524080A patent/JPS55139420A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51116851A (en) * | 1975-04-07 | 1976-10-14 | Toyobo Co Ltd | Thixotropic radical polymerization type thermosetting resin compositio ns |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5765714A (en) * | 1980-10-06 | 1982-04-21 | Nippon Synthetic Chem Ind Co Ltd:The | Photocurable resin composition |
JPH0210166B2 (en) * | 1980-10-06 | 1990-03-07 | Nippon Synthetic Chem Ind | |
JPS61502541A (en) * | 1984-06-25 | 1986-11-06 | ザ バツド カンパニ− | dual function additive |
JPH0529647B2 (en) * | 1984-06-25 | 1993-05-06 | Budd Co |
Also Published As
Publication number | Publication date |
---|---|
FR2450269A1 (en) | 1980-09-26 |
BR8001134A (en) | 1980-11-04 |
GB2045259A (en) | 1980-10-29 |
IT8048047A0 (en) | 1980-02-29 |
IT1144042B (en) | 1986-10-29 |
DE3007614A1 (en) | 1980-09-11 |
FR2450269B1 (en) | 1984-08-10 |
GB2045259B (en) | 1983-03-16 |
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