JPS55126531A - Cuprous thiocyanate synthesizing method - Google Patents
Cuprous thiocyanate synthesizing methodInfo
- Publication number
- JPS55126531A JPS55126531A JP3470479A JP3470479A JPS55126531A JP S55126531 A JPS55126531 A JP S55126531A JP 3470479 A JP3470479 A JP 3470479A JP 3470479 A JP3470479 A JP 3470479A JP S55126531 A JPS55126531 A JP S55126531A
- Authority
- JP
- Japan
- Prior art keywords
- liquor
- thiosulfuric acid
- acid
- decolored
- mol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 230000002194 synthesizing effect Effects 0.000 title 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 abstract 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 4
- 150000001879 copper Chemical class 0.000 abstract 3
- 238000006477 desulfuration reaction Methods 0.000 abstract 3
- 230000023556 desulfurization Effects 0.000 abstract 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 abstract 3
- 239000002699 waste material Substances 0.000 abstract 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 2
- 239000000571 coke Substances 0.000 abstract 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
Landscapes
- Industrial Gases (AREA)
Abstract
PURPOSE: To obtain cuprous thiocyanate in a high yield by decoloring desulfurization waste liquor, with activated carbon, discharged from a coke oven gas wet desulfurization process and adding divalent copper salt in amts. equimolar with thiosulfuric acid in the decolored liquor to equimolar with thiocyanic acid.
CONSTITUTION: Waste liquor discharged from a coke oven gas wet desulfurization process is decolored with activated carbon, and on the supposition that thiosulfuric acid in the decolored waste liquor is T mol, sulfite to be added to the liquor Sa mol, thiosulfuric acid to be added to the liquor Ta mol and divalent copper salt C mole, the above-mentioned two cpds. are added to the liquor so as to satisfy thiosulfate and divalent copper salt (CuSO4 or the like) of equations I, II. Thus, thiocyanate and thiosulfuric acid in the liquor are effectively utilized, and cuprous thiocyanate can be synthesized cheaply only by supplying the shortage. The load of activated sludge treatment or other treatment of the liquor is reduced. In place of the thiosulfuric acid sulfurous acid may be used.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3470479A JPS55126531A (en) | 1979-03-23 | 1979-03-23 | Cuprous thiocyanate synthesizing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3470479A JPS55126531A (en) | 1979-03-23 | 1979-03-23 | Cuprous thiocyanate synthesizing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS55126531A true JPS55126531A (en) | 1980-09-30 |
Family
ID=12421737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3470479A Pending JPS55126531A (en) | 1979-03-23 | 1979-03-23 | Cuprous thiocyanate synthesizing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55126531A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5836920A (en) * | 1981-08-24 | 1983-03-04 | Sumikin Coke Co Ltd | Manufacture of cuprous thiocyanate |
| JPS59169926A (en) * | 1983-03-11 | 1984-09-26 | Sumikin Coke Co Ltd | Continuous production of cuprous thiocyanate |
| CN103342373A (en) * | 2013-06-08 | 2013-10-09 | 太原理工大学 | Decoloring method for ammonium thiocyanate salt extracted from coking desulfurization waste liquid |
-
1979
- 1979-03-23 JP JP3470479A patent/JPS55126531A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5836920A (en) * | 1981-08-24 | 1983-03-04 | Sumikin Coke Co Ltd | Manufacture of cuprous thiocyanate |
| JPH0131459B2 (en) * | 1981-08-24 | 1989-06-26 | Sumikin Kako Kk | |
| JPS59169926A (en) * | 1983-03-11 | 1984-09-26 | Sumikin Coke Co Ltd | Continuous production of cuprous thiocyanate |
| JPH055771B2 (en) * | 1983-03-11 | 1993-01-25 | Sumikin Kako Kk | |
| CN103342373A (en) * | 2013-06-08 | 2013-10-09 | 太原理工大学 | Decoloring method for ammonium thiocyanate salt extracted from coking desulfurization waste liquid |
| CN103342373B (en) * | 2013-06-08 | 2015-04-15 | 太原理工大学 | Decoloring method for ammonium thiocyanate salt extracted from coking desulfurization waste liquid |
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