JPS55125111A - Purification of unreacted monomer and/or recovered solvent - Google Patents
Purification of unreacted monomer and/or recovered solventInfo
- Publication number
- JPS55125111A JPS55125111A JP3363279A JP3363279A JPS55125111A JP S55125111 A JPS55125111 A JP S55125111A JP 3363279 A JP3363279 A JP 3363279A JP 3363279 A JP3363279 A JP 3363279A JP S55125111 A JPS55125111 A JP S55125111A
- Authority
- JP
- Japan
- Prior art keywords
- water
- recovered
- lowering
- small amount
- solvents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: In purifying and reusing unreacted monomers and/or solvents recovered from the step of polymerizing conjugated dienes in the presence of catalysts, to make it possible to recycle and reuse purified products without lowering of polymerization activity, by countercurrent contact with water containing a small amount of oxygen.
CONSTITUTION: Unreacted monomers and/or solvents such as pentane or xylene, containing a small amount of water-soluble alcohols, recovered from the step of polymerizing conjugated dienes such as 1.3-butadiene, isoprene, or 1,3-pentadiene, in the presence of a (coordinated) anionic catalyst such as Ziegler catalyst, are brought into countercurrent contact with water to separate the water-soluble alcohols and then purified before they are recycled and reused in the polymerization step. Thereby, the water to be used contains ≤2ppm, preferably ≤1ppm, more preferably ≤0.2ppm of dissolved oxygen. Consequently, cthe recycling auses no lowering of polymerization activity and physical properties of the polymerized products.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3363279A JPS55125111A (en) | 1979-03-22 | 1979-03-22 | Purification of unreacted monomer and/or recovered solvent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3363279A JPS55125111A (en) | 1979-03-22 | 1979-03-22 | Purification of unreacted monomer and/or recovered solvent |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55125111A true JPS55125111A (en) | 1980-09-26 |
JPS6411641B2 JPS6411641B2 (en) | 1989-02-27 |
Family
ID=12391819
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3363279A Granted JPS55125111A (en) | 1979-03-22 | 1979-03-22 | Purification of unreacted monomer and/or recovered solvent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55125111A (en) |
-
1979
- 1979-03-22 JP JP3363279A patent/JPS55125111A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6411641B2 (en) | 1989-02-27 |
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