JPS5462191A - High activity catalyst for polymerization of olefin - Google Patents
High activity catalyst for polymerization of olefinInfo
- Publication number
- JPS5462191A JPS5462191A JP12811677A JP12811677A JPS5462191A JP S5462191 A JPS5462191 A JP S5462191A JP 12811677 A JP12811677 A JP 12811677A JP 12811677 A JP12811677 A JP 12811677A JP S5462191 A JPS5462191 A JP S5462191A
- Authority
- JP
- Japan
- Prior art keywords
- cpd
- catalyst
- halide
- hydrocarbon
- contg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To obtain the title catalyst with high catalytic efficiency to unit transition metal and good grain size by bringing a solid reaction product of a hydrocarbon sol. specific org. Mg cpd. and a Si-H bond-contg. chlorosilane cpd. into contact with Ti or V halide, followed by treatment with an organometallic cpd.
CONSTITUTION: A solid reaction product of a hydrocarbon sol. cpd. of formula MgR'uR"vXw (where each of R' and R" is 4W6 C sec. or tert. alkyl, etc., X is an anionic radical contg. O, N or S, 0≤u≤2, 0≤v≤2, 0<w≤1 and u+v+w=2) and a cpd. of formula HaSiClbR4-(a+b) (where a>0, b>0, a+b≤4 and R is a hydrocarbon radical) is brought into contact with Ti or V halide such as TiCl4. The resulting solid substance is then treated with an organometallic cpd. such as triethyl Al. Using this catalyst a catalyst removing process can be omitted and a polymer is produced having high bulk density and narrow MW distribution.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52128116A JPS5846127B2 (en) | 1977-10-27 | 1977-10-27 | Highly active catalyst used for olefin polymerization |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP52128116A JPS5846127B2 (en) | 1977-10-27 | 1977-10-27 | Highly active catalyst used for olefin polymerization |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5462191A true JPS5462191A (en) | 1979-05-18 |
JPS5846127B2 JPS5846127B2 (en) | 1983-10-14 |
Family
ID=14976765
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP52128116A Expired JPS5846127B2 (en) | 1977-10-27 | 1977-10-27 | Highly active catalyst used for olefin polymerization |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5846127B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04227463A (en) * | 1990-05-18 | 1992-08-17 | Werner Kunz | Method of drying substance by drum type drier discharging no deleterious material |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59176932U (en) * | 1983-05-13 | 1984-11-27 | 株式会社 石田衡器製作所 | Hopper in automatic weighing equipment |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5340696A (en) * | 1976-09-28 | 1978-04-13 | Asahi Chem Ind Co Ltd | Olefin polymerization catalyst |
JPS5370991A (en) * | 1976-12-06 | 1978-06-23 | Asahi Chem Ind Co Ltd | Catalyst used for olefin polymerization |
-
1977
- 1977-10-27 JP JP52128116A patent/JPS5846127B2/en not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5340696A (en) * | 1976-09-28 | 1978-04-13 | Asahi Chem Ind Co Ltd | Olefin polymerization catalyst |
JPS5370991A (en) * | 1976-12-06 | 1978-06-23 | Asahi Chem Ind Co Ltd | Catalyst used for olefin polymerization |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04227463A (en) * | 1990-05-18 | 1992-08-17 | Werner Kunz | Method of drying substance by drum type drier discharging no deleterious material |
Also Published As
Publication number | Publication date |
---|---|
JPS5846127B2 (en) | 1983-10-14 |
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