JPS54117414A - New vinyl ethers containing fluorine and their synthesis - Google Patents

New vinyl ethers containing fluorine and their synthesis

Info

Publication number
JPS54117414A
JPS54117414A JP2276978A JP2276978A JPS54117414A JP S54117414 A JPS54117414 A JP S54117414A JP 2276978 A JP2276978 A JP 2276978A JP 2276978 A JP2276978 A JP 2276978A JP S54117414 A JPS54117414 A JP S54117414A
Authority
JP
Japan
Prior art keywords
formula
vinyl ethers
containing fluorine
ethers containing
synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2276978A
Other languages
Japanese (ja)
Other versions
JPS5914012B2 (en
Inventor
Masahiro Ozawa
Yoshihiro Tasaka
Masaaki Matsuoka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Glass Co Ltd
Original Assignee
Central Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Glass Co Ltd filed Critical Central Glass Co Ltd
Priority to JP2276978A priority Critical patent/JPS5914012B2/en
Publication of JPS54117414A publication Critical patent/JPS54117414A/en
Publication of JPS5914012B2 publication Critical patent/JPS5914012B2/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

NEW MATERIAL:Vinyl ethers containing fluorine shown in formula I (R1, R2= C1W20 alkyl, alkenyl, H, chlorine, phenyl which may contain a substituent group) and formula II.
EXAMPLE: A compound of formula III (R1=R2=H).
USE: Synthetic intermediates of polymeric fluoro compounds, e.g. water repellents, oil repellents, surfactants etc.
PROCESS: Perfluoro-2-methyl-2-pentene of formula IV and an aldehyde having α-carbon and hydrogen of formula V (α, β-unsaturated aldehydes except crotonaldehyde) are made to react in the presence of a catalyst of tertiary amine, e.g. trimethylamine, to afford compounds of formula I and formula II. When tri-n- butylamine is used as the catalyst, the dehydrofluorination reaction is suppressed, and the compound I is obtained as the main product.
COPYRIGHT: (C)1979,JPO&Japio
JP2276978A 1978-03-02 1978-03-02 Novel fluorine-containing vinyl ethers and their synthesis method Expired JPS5914012B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2276978A JPS5914012B2 (en) 1978-03-02 1978-03-02 Novel fluorine-containing vinyl ethers and their synthesis method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2276978A JPS5914012B2 (en) 1978-03-02 1978-03-02 Novel fluorine-containing vinyl ethers and their synthesis method

Publications (2)

Publication Number Publication Date
JPS54117414A true JPS54117414A (en) 1979-09-12
JPS5914012B2 JPS5914012B2 (en) 1984-04-02

Family

ID=12091871

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2276978A Expired JPS5914012B2 (en) 1978-03-02 1978-03-02 Novel fluorine-containing vinyl ethers and their synthesis method

Country Status (1)

Country Link
JP (1) JPS5914012B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019111989A1 (en) * 2017-12-07 2019-06-13 関東電化工業株式会社 Chlorinated bis(3, 3, 3-trifluoro-1-propenyl) ether, method for producing same and use of same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019111989A1 (en) * 2017-12-07 2019-06-13 関東電化工業株式会社 Chlorinated bis(3, 3, 3-trifluoro-1-propenyl) ether, method for producing same and use of same
JPWO2019111989A1 (en) * 2017-12-07 2020-12-03 関東電化工業株式会社 Chlorinated bis (3,3,3-trifluoro-1-propenyl) ether, its production method and its use

Also Published As

Publication number Publication date
JPS5914012B2 (en) 1984-04-02

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