JPS54111580A - Preparation of simultaneously biaxially oriented polyvinyl alcohol film - Google Patents

Preparation of simultaneously biaxially oriented polyvinyl alcohol film

Info

Publication number
JPS54111580A
JPS54111580A JP1930678A JP1930678A JPS54111580A JP S54111580 A JPS54111580 A JP S54111580A JP 1930678 A JP1930678 A JP 1930678A JP 1930678 A JP1930678 A JP 1930678A JP S54111580 A JPS54111580 A JP S54111580A
Authority
JP
Japan
Prior art keywords
film
dried
polyvinyl alcohol
water
water content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1930678A
Other languages
Japanese (ja)
Other versions
JPS5643022B2 (en
Inventor
Mutsuo Kuga
Kiyoshi Kitagawa
Motoo Kawasaki
Junkichi Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unitika Ltd
Original Assignee
Unitika Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unitika Ltd filed Critical Unitika Ltd
Priority to JP1930678A priority Critical patent/JPS54111580A/en
Priority to US06/008,106 priority patent/US4230654A/en
Priority to GB7905008A priority patent/GB2014476B/en
Priority to FR7903744A priority patent/FR2417520A1/en
Priority to BE0/193508A priority patent/BE874229A/en
Priority to DE2906240A priority patent/DE2906240C2/en
Priority to LU80950A priority patent/LU80950A1/en
Priority to NLAANVRAGE7901307,A priority patent/NL185756C/en
Priority to IT20381/79A priority patent/IT1110205B/en
Publication of JPS54111580A publication Critical patent/JPS54111580A/en
Publication of JPS5643022B2 publication Critical patent/JPS5643022B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/048Forming gas barrier coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/052Forming heat-sealable coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

PURPOSE: To prepare the title film having high tensile strength and Young's modulus, and coated with a polymeric layer having specific functions, by forming a water-containing polyvinyl alcohol to a film, coating the film with an aqueous dispersion of a polymer, simultanesously and diaxially drawing the film, drying the oriented film while relaxing the stresses, and finally heat-treating the dried film.
CONSTITUTION: A molten, water-containing polyvinyl alcohol is formed to a film, and dried while preventing the production of strains, to obtain a non-oriented base film containing 3W20% of water. An aqueous dispersion of a polymer is applied to one or both sides of the base film, and conditioned to give a film having an average water content of 5W30% (increment of water content of 2W10%). The coated film is drawn at an areal draw ratio of 600W1300% simultanesouly and biaxially, and dried to a water content of ≤3% while relaxing the stresses. The dried film is heat-treated at 160°C to the decomposition temp. for a short time.
COPYRIGHT: (C)1979,JPO&Japio
JP1930678A 1978-02-21 1978-02-21 Preparation of simultaneously biaxially oriented polyvinyl alcohol film Granted JPS54111580A (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
JP1930678A JPS54111580A (en) 1978-02-21 1978-02-21 Preparation of simultaneously biaxially oriented polyvinyl alcohol film
US06/008,106 US4230654A (en) 1978-02-21 1979-01-31 Method of concurrently-biaxially drawing polyvinyl alcohol film
GB7905008A GB2014476B (en) 1978-02-21 1979-02-13 Concurrent-biaxially drawn polyvinyl alcohol film
FR7903744A FR2417520A1 (en) 1978-02-21 1979-02-14 POLYVINYL ALCOHOL FILM BIAXIALLY STRETCHED SIMULTANEOUSLY
BE0/193508A BE874229A (en) 1978-02-21 1979-02-16 POLYVINYL ALCOHOL FILM BIAXIALLY STRETCHED SIMULTANEOUSLY
DE2906240A DE2906240C2 (en) 1978-02-21 1979-02-17 Process for the production of a biaxially oriented polyvinyl alcohol film
LU80950A LU80950A1 (en) 1978-02-21 1979-02-20 PROCESS FOR MANUFACTURING A BIAXIALLY STRESSED POLYVINYL ALCOHOL FILM
NLAANVRAGE7901307,A NL185756C (en) 1978-02-21 1979-02-20 METHOD FOR MANUFACTURING A BIAXIA-STRETCHED FILM OF POLYVINYL ALCOHOL
IT20381/79A IT1110205B (en) 1978-02-21 1979-02-21 POLYVINYL ALCOHOL FILM STRETCHED SIMULTANEOUSLY IN A BIAXIAL SENSE

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1930678A JPS54111580A (en) 1978-02-21 1978-02-21 Preparation of simultaneously biaxially oriented polyvinyl alcohol film

Publications (2)

Publication Number Publication Date
JPS54111580A true JPS54111580A (en) 1979-08-31
JPS5643022B2 JPS5643022B2 (en) 1981-10-08

Family

ID=11995726

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1930678A Granted JPS54111580A (en) 1978-02-21 1978-02-21 Preparation of simultaneously biaxially oriented polyvinyl alcohol film

Country Status (9)

Country Link
US (1) US4230654A (en)
JP (1) JPS54111580A (en)
BE (1) BE874229A (en)
DE (1) DE2906240C2 (en)
FR (1) FR2417520A1 (en)
GB (1) GB2014476B (en)
IT (1) IT1110205B (en)
LU (1) LU80950A1 (en)
NL (1) NL185756C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101217781B1 (en) * 2007-05-07 2013-01-02 주식회사 엘지화학 Method of preparing polyvinylalcohol film, polyvinylalcohol film prepared by the method, and polarizing plate comprising the polyvinylalcohol film
JP2018004707A (en) * 2016-06-27 2018-01-11 株式会社クラレ Manufacturing method for optical films

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2537049B1 (en) * 1982-12-01 1985-07-12 Rhone Poulenc Films POLYVINYL ALCOHOL FILM AND ITS APPLICATION FOR THE PREPARATION OF GAS-WATERPROOF COMPOSITE FILMS
US4731266A (en) * 1981-06-03 1988-03-15 Rhone-Poulenc, S.A. Water-resistant polyvinyl alcohol film and its application to the preparation of gas-impermeable composite articles
US4448622A (en) * 1982-04-26 1984-05-15 The United States Of America As Represented By The United States Department Of Energy Composite polymeric film and method for its use in installing a very thin polymeric film in a device
US4684573A (en) * 1985-03-07 1987-08-04 W. R. Grace & Co., Cryovac Div. High oxygen barrier composite film
CA1296852C (en) * 1985-10-11 1992-03-10 Henry George Schirmer High oxygen barrier coextruded film
US4729926A (en) * 1986-05-16 1988-03-08 W. R. Grace & Co., Cryovac Div. Packaging material for long-term storage of shelf stable food products and method of making same
US5035851A (en) * 1986-11-25 1991-07-30 W. R. Grace & Co.-Conn. Method of making very high barrier film
US4826730A (en) * 1987-10-02 1989-05-02 E. I. Du Pont De Nemours And Company Composite film for protective garments
US4772510A (en) * 1987-10-02 1988-09-20 E. I. Du Pont De Nemours And Company Fabric for protective garments
US5061534A (en) * 1988-04-22 1991-10-29 American National Can Company High oxygen barrier film
US5981011A (en) * 1992-01-22 1999-11-09 A*Ware Technologies, L.C. Coated sheet material
US6364987B1 (en) * 1999-03-10 2002-04-02 Kuraray Co., Ltd. Method for producing gas barrier film
KR101463799B1 (en) * 2012-03-22 2014-11-20 에스케이씨 주식회사 Polyvinyl alcohol-based polymeric film and method for preparing same
JP6084090B2 (en) * 2013-03-28 2017-02-22 日本合成化学工業株式会社 Polyvinyl alcohol film

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1012602A (en) * 1961-11-28 1965-12-08 Kurashiki Rayon Kk Method of treating polyvinyl alcohol films
US3136657A (en) * 1962-02-15 1964-06-09 Air Reduction Polyvinyl alcohol film coated with vinylidene chloride-vinyl chloride copolymer
US3214291A (en) * 1962-02-15 1965-10-26 Air Reduction Polyvinyl alcohol film coated with vinylidene chloride-acrylonitrile copolymer
US3440316A (en) * 1963-12-05 1969-04-22 Kuraray Co Method of manufacturing improved polyvinyl alcohol films
JPS5223368B2 (en) * 1973-11-26 1977-06-23
JPS5128169A (en) * 1974-09-03 1976-03-09 Unitika Ltd 2 jikuenshinhoribiniruarukoorufuirumuno seizohoho
JPS5234665B2 (en) * 1974-10-28 1977-09-05
JPS5161569A (en) * 1974-11-26 1976-05-28 Unitika Ltd 2 jikuenshinhoribiniruarukoorufuirumuno jushikooteinguhoho
JPS5226787A (en) * 1975-08-26 1977-02-28 Tadao Fujishita Method of searching cause of disease and curing disease utilizing human body energy in vivo and instrument therefor
JPS5269477A (en) * 1975-12-09 1977-06-09 Toshiba Machine Co Ltd Method of manufacturing poly vinyl alcohol film
DE2655523C2 (en) * 1975-12-09 1982-10-14 Toshiba Kikai K.K., Tokyo Process for the production of a film web from polyvinyl alcohol

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101217781B1 (en) * 2007-05-07 2013-01-02 주식회사 엘지화학 Method of preparing polyvinylalcohol film, polyvinylalcohol film prepared by the method, and polarizing plate comprising the polyvinylalcohol film
JP2018004707A (en) * 2016-06-27 2018-01-11 株式会社クラレ Manufacturing method for optical films

Also Published As

Publication number Publication date
LU80950A1 (en) 1979-06-18
DE2906240C2 (en) 1984-10-25
IT7920381A0 (en) 1979-02-21
DE2906240A1 (en) 1979-08-30
JPS5643022B2 (en) 1981-10-08
US4230654A (en) 1980-10-28
GB2014476B (en) 1982-05-06
GB2014476A (en) 1979-08-30
BE874229A (en) 1979-08-16
NL185756C (en) 1990-07-16
IT1110205B (en) 1985-12-23
FR2417520B1 (en) 1983-07-29
NL7901307A (en) 1979-08-23
FR2417520A1 (en) 1979-09-14
NL185756B (en) 1990-02-16

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