JPS54106407A - Hydroformylation of allyl alcohol - Google Patents

Hydroformylation of allyl alcohol

Info

Publication number
JPS54106407A
JPS54106407A JP1441078A JP1441078A JPS54106407A JP S54106407 A JPS54106407 A JP S54106407A JP 1441078 A JP1441078 A JP 1441078A JP 1441078 A JP1441078 A JP 1441078A JP S54106407 A JPS54106407 A JP S54106407A
Authority
JP
Japan
Prior art keywords
hydroformylation
allyl alcohol
tri
complex compound
diphosphinoalkane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1441078A
Other languages
Japanese (ja)
Other versions
JPS565372B2 (en
Inventor
Mitsuo Matsumoto
Masuhiko Tamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Priority to JP1441078A priority Critical patent/JPS54106407A/en
Priority to US06/007,660 priority patent/US4215077A/en
Priority to GB7903651A priority patent/GB2014138B/en
Priority to DE2904782A priority patent/DE2904782C2/en
Publication of JPS54106407A publication Critical patent/JPS54106407A/en
Publication of JPS565372B2 publication Critical patent/JPS565372B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To prolong the life of the catalyst, remarkably, in the hydroformylation of allyl alcohol in an organic medium in the presence of a Rh complex compound and tri-substituted phosphine, by adding a specific amount of diphosphinoalkane to the reaction system.
CONSTITUTION: Allyl alcohol is subjected to hydroformylation in an organic medium, e.g. benzene, in the presence of a Rh complex compound {e.g. HRh(CO)[P (C6H5)3]3} and tri-substituted phosphine (e.g. tri-phenylphosphine, etc.). Hydroxybutylaldehyde is extracted from the hydroformylation mixture with water, and the residual solution after the extraction is circulated as a catalytic solution to the hydroformylation process where diphosphinoalkane of the formula [A1 and A2 are aryl; R1 and R2 are aryl, -CnH2n+1(n≥4); Z=alkylene] is used in a ratio 2P/Rh= 0.2W2.0 to the Rh complex compound.
COPYRIGHT: (C)1979,JPO&Japio
JP1441078A 1978-02-09 1978-02-09 Hydroformylation of allyl alcohol Granted JPS54106407A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP1441078A JPS54106407A (en) 1978-02-09 1978-02-09 Hydroformylation of allyl alcohol
US06/007,660 US4215077A (en) 1978-02-09 1979-01-29 Hydroformylation of olefins
GB7903651A GB2014138B (en) 1978-02-09 1979-02-02 Hydroformylation of lower olefins
DE2904782A DE2904782C2 (en) 1978-02-09 1979-02-08 Process for the production of aldehydes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1441078A JPS54106407A (en) 1978-02-09 1978-02-09 Hydroformylation of allyl alcohol

Publications (2)

Publication Number Publication Date
JPS54106407A true JPS54106407A (en) 1979-08-21
JPS565372B2 JPS565372B2 (en) 1981-02-04

Family

ID=11860264

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1441078A Granted JPS54106407A (en) 1978-02-09 1978-02-09 Hydroformylation of allyl alcohol

Country Status (1)

Country Link
JP (1) JPS54106407A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS606630A (en) * 1983-06-24 1985-01-14 Kuraray Co Ltd Continuous hydroformylation of allyl alcohol
JPS60158124A (en) * 1983-12-29 1985-08-19 シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ Manufacture of 1,4-butanediol
JP2014024852A (en) * 2007-09-07 2014-02-06 Dow Global Technologies Llc Hydrogenation of aliphatic dialdehyde to aliphatic diol

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02132753A (en) * 1988-11-11 1990-05-22 Ngk Insulators Ltd Temperature rise and fall device in adiabatic case housing high temperature type single cell

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS606630A (en) * 1983-06-24 1985-01-14 Kuraray Co Ltd Continuous hydroformylation of allyl alcohol
JPH0581576B2 (en) * 1983-06-24 1993-11-15 Kuraray Co
JPS60158124A (en) * 1983-12-29 1985-08-19 シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ Manufacture of 1,4-butanediol
JPH0564132B2 (en) * 1983-12-29 1993-09-14 Shell Int Research
JP2014024852A (en) * 2007-09-07 2014-02-06 Dow Global Technologies Llc Hydrogenation of aliphatic dialdehyde to aliphatic diol

Also Published As

Publication number Publication date
JPS565372B2 (en) 1981-02-04

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